CODE OF FEDERAL REGULATIONS40 Protection of Environment PART 63 (§§ 63.1200—End) Revised as of July 1, 1999

CONTAINING

A CODIFICATION OF DOCUMENTS

OF GENERAL APPLICABILITY

AND FUTURE EFFECT

AS OF JULY 1, 1999 With Ancillaries

Published by

the Office of the Federal Register

National Archives and Records

Administration

as a Special Edition of

the Federal Register

As of July 1, 1999

Title 40, Parts 63

Revised as of July 1, 1998

Is Replaced by Two Volumes

Title 40, Part 63, (§§ 63.1-63.1199)

and

Title 40, Parts 63, (§ 63.1200-End

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 Table of Contents Page Explanation v Title 40: Chapter I—Environmental Protection Agency (Continued) 3 Finding Aids: Material Approved for Incorporation by Reference 701 Table of CFR Titles and Chapters 703 Alphabetical List of Agencies Appearing in the CFR 721 List of CFR Sections Affected 731

Cite this Code:CFR

To cite the regulations in this volume use title, part and section number. Thus, 40 CFR 63.1211 refers to title 40, part 63, section 1211. Explanation

The Code of Federal Regulations is a codification of the general and permanent rules published in the Federal Register by the Executive departments and agencies of the Federal Government. The Code is divided into 50 titles which represent broad areas subject to Federal regulation. Each title is divided into chapters which usually bear the name of the issuing agency. Each chapter is further subdivided into parts covering specific regulatory areas.

Each volume of the Code is revised at least once each calendar year and issued on a quarterly basis approximately as follows:

Title 1 through Title 16

as of January 1

Title 17 through Title 27

as of April 1

Title 28 through Title 41

as of July 1

Title 42 through Title 50

as of October 1

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The contents of the Federal Register are required to be judicially noticed (44 U.S.C. 1507). The Code of Federal Regulations is prima facie evidence of the text of the original documents (44 U.S.C. 1510).

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The Code of Federal Regulations is kept up to date by the individual issues of the Federal Register. These two publications must be used together to determine the latest version of any given rule.

To determine whether a Code volume has been amended since its revision date (in this case, July 1, 1999), consult the “List of CFR Sections Affected (LSA),” which is issued monthly, and the “Cumulative List of Parts Affected,” which appears in the Reader Aids section of the daily Federal Register. These two lists will identify the Federal Register page number of the latest amendment of any given rule.

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 OBSOLETE PROVISIONS

Provisions that become obsolete before the revision date stated on the cover of each volume are not carried. Code users may find the text of provisions in effect on a given date in the past by using the appropriate numerical list of sections affected. For the period before January 1, 1986, consult either the List of CFR Sections Affected, 1949-1963, 1964-1972, or 1973-1985, published in seven separate volumes. For the period beginning January 1, 1986, a “List of CFR Sections Affected” is published at the end of each CFR volume.

 INCORPORATION BY REFERENCE

What is incorporation by reference? Incorporation by reference was established by statute and allows Federal agencies to meet the requirement to publish regulations in the Federal Register by referring to materials already published elsewhere. For an incorporation to be valid, the Director of the Federal Register must approve it. The legal effect of incorporation by reference is that the material is treated as if it were published in full in the Federal Register (5 U.S.C. 552(a)). This material, like any other properly issued regulation, has the force of law.

What is a proper incorporation by reference? The Director of the Federal Register will approve an incorporation by reference only when the requirements of 1 CFR part 51 are met. Some of the elements on which approval is based are:

(a) The incorporation will substantially reduce the volume of material published in the Federal Register.

(b) The matter incorporated is in fact available to the extent necessary to afford fairness and uniformity in the administrative process.

(c) The incorporating document is drafted and submitted for publication in accordance with 1 CFR part 51.

Properly approved incorporations by reference in this volume are listed in the Finding Aids at the end of this volume.

What if the material incorporated by reference cannot be found? If you have any problem locating or obtaining a copy of material listed in the Finding Aids of this volume as an approved incorporation by reference, please contact the agency that issued the regulation containing that incorporation. If, after contacting the agency, you find the material is not available, please notify the Director of the Federal Register, National Archives and Records Administration, Washington DC 20408, or call (202) 523-4534.

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A subject index to the Code of Federal Regulations is contained in a separate volume, revised annually as of January 1, entitled CFR Index and Finding Aids. This volume contains the Parallel Table of Statutory Authorities and Agency Rules (Table I). A list of CFR titles, chapters, and parts and an alphabetical list of agencies publishing in the CFR are also included in this volume.

An index to the text of “Title 3—The President” is carried within that volume.

The Federal Register Index is issued monthly in cumulative form. This index is based on a consolidation of the “Contents” entries in the daily Federal Register.

A List of CFR Sections Affected (LSA) is published monthly, keyed to the revision dates of the 50 CFR titles.

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There are no restrictions on the republication of material appearing in the Code of Federal Regulations.

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 Raymond A. Mosley, Director, Office of the Federal Register. July 1, 1999. THIS TITLE

Title 40—Protection of Environment is composed of twenty-four volumes. The parts in these volumes are arranged in the following order: parts 1-49, parts 50-51, part 52 (52.01-52.1018), part 52 (52.1019-End), parts 53-59, part 60, parts 61-62, part 63 (63.1-63.1199), part 63 (63.1200-End), parts 64-71, parts 72-80, parts 81-85, part 86, parts 87-135, parts 136-149, parts 150-189, parts 190-259, parts 260-265, parts 266-299, parts 300-399, parts 400-424, parts 425-699, parts 700-789, and part 790 to End. The contents of these volumes represent all current regulations codified under this title of the CFR as of July 1, 1999.

Chapter I—Environmental Protection Agency appears in all twenty-four volumes. A Pesticide Tolerance Commodity/Chemical Index appears in parts 150-189. A Toxic Substances Chemical—CAS Number Index appears in parts 700-789 and part 790 to End. Redesignation Tables appear in the volumes containing parts 50-51, parts 150-189, and parts 700-789. Regulations issued by the Council on Environmental Quality appear in the volume containing part 790 to End. The OMB control numbers for title 40 appear in § 9.1 of this chapter.

For this volume, Ruth Reedy Green was Chief Editor. The Code of Federal Regulations publication program is under the direction of Frances D. McDonald, assisted by Alomha S. Morris.

CFRORDR.FRM <CFRTITLE> <LRH>40 CFR Ch. I (7-1-99 Edition)</LRH> <RRH>Environmental Protection Agency</RRH> <TITLEHD> <PRTPAGE P="1"/> <HD SOURCE="HED">Title 40—Protection of Environment</HD> <P>(This book contains part 63) </P> </TITLEHD> <CFRTOC> <PTHD>Part</PTHD> <CHAPTI> <SUBJECT> <E T="04">chapter i</E>—Environmental Protection Agency (Continued)</SUBJECT> <PG>63</PG> </CHAPTI> </CFRTOC> <LRH>40 CFR Ch. I (7-1-99 Edition)</LRH> <RRH>Environmental Protection Agency</RRH> </CFRTITLE> <CHAPTER> <TOC> <TOCHD> <PRTPAGE P="3"/> <HD SOURCE="HED">CHAPTER I—ENVIRONMENTAL PROTECTION AGENCY </HD> </TOCHD> <SUBCHAP> <HD SOURCE="HED">SUBCHAPTER C—AIR PROGRAMS (Continued)</HD> </SUBCHAP> <PTHD>Part</PTHD> <PGHD>Page</PGHD> <CHAPTI> <PT>63</PT> <SUBJECT>National emission standards for hazardous air pollutants for source categories</SUBJECT> <PG>5</PG> </CHAPTI> <EDNOTE> <HD SOURCE="HED">Editorial Note:</HD> <P>Subchapter C—Air Programs is contained in volumes 40 CFR parts 50-51, part 52 (52.01-52.1018), part 52 (52.1019-end), parts 53-59, part 60, parts 61-62, part 63 (63.1-63.1199, part 63 (63.1200-End), parts 64-71, parts 72-80, parts 81-85, part 86, and parts 87-135.</P> </EDNOTE> </TOC> <SUBCHAP TYPE="N"> <PRTPAGE P="5"/> <HD SOURCE="HED">SUBCHAPTER C—AIR PROGRAMS (Continued)</HD> <PART> <EAR>Pt. 63</EAR> <HD SOURCE="HED">PART 63—NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES</HD> <CONTENTS> <SUBPART> <HD SOURCE="HED">Subpart EEE—National Emission Standards for Hazardous Air Pollutants From Hazardous Waste Combustors</HD> <SECTNO>63.1200-63.1210</SECTNO> <SUBJECT>[Reserved]</SUBJECT> <SECTNO>63.1211</SECTNO> <SUBJECT>Notification requirements.</SUBJECT> <SECTNO>63.1212</SECTNO> <SUBJECT>Progress reports.</SUBJECT> <SECTNO>63.1213</SECTNO> <SUBJECT>Certification.</SUBJECT> <SECTNO>63.1214</SECTNO> <SUBJECT>Extension of the compliance date.</SUBJECT> <SECTNO>63.1215</SECTNO> <SUBJECT>Sources that become affected sources after the effective date of this subpart.</SUBJECT> <SECTNO>63.1216</SECTNO> <SUBJECT>Extension of compliance date to install pollution prevention or waste minimization controls.</SUBJECT> </SUBPART> <SUBPART> <RESERVED>Subpart FFF[Reserved]</RESERVED> </SUBPART> <SUBPART> <HD SOURCE="HED">Subpart GGG—National Emission Standards for Pharmaceuticals Production</HD> <SECTNO>63.1250</SECTNO> <SUBJECT>Applicability.</SUBJECT> <SECTNO>63.1251</SECTNO> <SUBJECT>Definitions.</SUBJECT> <SECTNO>63.1252</SECTNO> <SUBJECT>Standards: General.</SUBJECT> <SECTNO>63.1253</SECTNO> <SUBJECT>Standards: Storage tanks.</SUBJECT> <SECTNO>63.1254</SECTNO> <SUBJECT>Standards: Process vents.</SUBJECT> <SECTNO>63.1255</SECTNO> <SUBJECT>Standards: Equipment leaks.</SUBJECT> <SECTNO>63.1256</SECTNO> <SUBJECT>Standards: Wastewater.</SUBJECT> <SECTNO>63.1257</SECTNO> <SUBJECT>Test methods and compliance procedures.</SUBJECT> <SECTNO>63.1258</SECTNO> <SUBJECT>Monitoring requirements.</SUBJECT> <SECTNO>63.1259</SECTNO> <SUBJECT>Recordkeeping requirements.</SUBJECT> <SECTNO>63.1260</SECTNO> <SUBJECT>Reporting requirements.</SUBJECT> <SECTNO>63.1261</SECTNO> <SUBJECT>Delegation of authority.</SUBJECT> <APP>Table 1 to Subpart GGG—General Provisions Applicability to Subpart GGG</APP> <APP>Table 2 to Subpart GGG—Partially Soluble HAP</APP> <APP>Table 3 to Subpart GGG—Soluble HAP</APP> <APP>Table 4 to Subpart GGG—Monitoring Requirements for Control Devices</APP> <APP>Table 5 to Subpart GGG—Control Requirements for Items of Equipment That Meet the Criteria of § 63.1252(f)</APP> <APP>Table 6 to Subpart GGG—Wastewater—Compliance Options for Wastewater Tanks</APP> <APP>Table 7 to Subpart GGG—Wastewater—Inspection and Monitoring Requirements for Waste Management Units</APP> <APP>Table 8 to Subpart GGG—Fraction Measured (F<E T="52">m</E>) for HAP Compounds in Wastewater Streams</APP> <APP>Table 9 to Subpart GGG—Default Biorates for List 1 Compounds</APP> </SUBPART> <SUBPART> <HD SOURCE="HED">Subpart HHH—National Emission Standards for Hazardous Air Pollutants From Natural Gas Transmission and Storage Facilities</HD> <SECTNO>63.1270</SECTNO> <SUBJECT>Applicability and designation of affected source.</SUBJECT> <SECTNO>63.1271</SECTNO> <SUBJECT>Definitions.</SUBJECT> <SECTNO>63.1272</SECTNO> <SUBJECT>Startups, shutdowns, and malfunctions.</SUBJECT> <SECTNO>63.1273</SECTNO> <SUBJECT>[Reserved]</SUBJECT> <SECTNO>63.1274</SECTNO> <SUBJECT>General standards.</SUBJECT> <SECTNO>63.1275</SECTNO> <SUBJECT>Glycol dehydration unit process vent standards.</SUBJECT> <SECTNO>63.1276-63.1280</SECTNO> <SUBJECT>[Reserved]</SUBJECT> <SECTNO>63.1281</SECTNO> <SUBJECT>Control equipment requirements.</SUBJECT> <SECTNO>63.1282</SECTNO> <SUBJECT>Test methods, compliance procedures, and compliance demonstrations.</SUBJECT> <SECTNO>63.1283</SECTNO> <SUBJECT>Inspection and monitoring requirements.</SUBJECT> <SECTNO>63.1284</SECTNO> <SUBJECT>Recordkeeping requirements.</SUBJECT> <SECTNO>63.1285</SECTNO> <SUBJECT>Reporting requirements.</SUBJECT> <SECTNO>63.1286</SECTNO> <SUBJECT>Delegation of authority.</SUBJECT> <SECTNO>63.1287</SECTNO> <SUBJECT>Alternative means of emission limitation.</SUBJECT> <SECTNO>63.1288-63.1289</SECTNO> <SUBJECT>[Reserved]</SUBJECT> <APP>Appendix to Subpart HHH—Tables</APP> </SUBPART> <SUBPART> <HD SOURCE="HED">Subpart III—National Emission Standards for Hazardous Air Pollutants for Flexible Polyurethane Foam Production</HD> <SECTNO>63.1290</SECTNO> <SUBJECT>Applicability.</SUBJECT> <SECTNO>63.1291</SECTNO> <SUBJECT>Compliance schedule.</SUBJECT> <SECTNO>63.1292</SECTNO> <SUBJECT>Definitions.</SUBJECT> <SECTNO>63.1293</SECTNO> <SUBJECT>Standards for slabstock flexible polyurethane foam production.</SUBJECT> <SECTNO>63.1294</SECTNO> <SUBJECT>Standards for slabstock flexible polyurethane foam production—diisocyanate emissions.</SUBJECT> <SECTNO>63.1295</SECTNO> <SUBJECT>Standards for slabstock flexible polyurethane foam production—HAP ABA storage vessels.</SUBJECT> <SECTNO>63.1296</SECTNO> <SUBJECT>Standards for slabstock flexible polyurethane foam production—HAP ABA equipment leaks.</SUBJECT> <SECTNO>63.1297</SECTNO> <SUBJECT>Standards for slabstock flexible polyurethane foam production—HAP ABA emissions from the production line.</SUBJECT> <SECTNO>63.1298</SECTNO> <SUBJECT>Standards for slabstock flexible polyurethane foam production—HAP emissions from equipment cleaning.</SUBJECT> <SECTNO>63.1299</SECTNO> <SUBJECT>Standards for slabstock flexible polyurethane foam production—source-wide emission limitation.</SUBJECT> <SECTNO>63.1300</SECTNO> <SUBJECT>Standards for molded flexible polyurethane foam production.</SUBJECT> <SECTNO>63.1301</SECTNO> <SUBJECT>Standards for rebond foam production.</SUBJECT> <SECTNO>63.1302</SECTNO> <SUBJECT>Applicability of subpart A requirements.</SUBJECT> <SECTNO>63.1303</SECTNO> <SUBJECT>Monitoring requirements.</SUBJECT> <SECTNO>63.1304</SECTNO> <SUBJECT>Testing requirements.<PRTPAGE P="6"/> </SUBJECT> <SECTNO>63.1305</SECTNO> <SUBJECT>Alternative means of emission limitation.</SUBJECT> <SECTNO>63.1306</SECTNO> <SUBJECT>Reporting requirements.</SUBJECT> <SECTNO>63.1307</SECTNO> <SUBJECT>Recordkeeping requirements.</SUBJECT> <SECTNO>63.1308</SECTNO> <SUBJECT>Compliance demonstrations.</SUBJECT> <SECTNO>63.1309</SECTNO> <SUBJECT>Delegation of authority.</SUBJECT> <APP>Appendix to Subpart III—Tables</APP> </SUBPART> <SUBPART> <HD SOURCE="HED">Subpart JJJ—National Emission Standards for Hazardous Air Pollutant Emissions: Group IV Polymers and Resins</HD> <SECTNO>63.1310</SECTNO> <SUBJECT>Applicability and designation of affected sources.</SUBJECT> <SECTNO>63.1311</SECTNO> <SUBJECT>Compliance schedule and relationship to existing applicable rules.</SUBJECT> <SECTNO>63.1312</SECTNO> <SUBJECT>Definitions.</SUBJECT> <SECTNO>63.1313</SECTNO> <SUBJECT>Emission standards.</SUBJECT> <SECTNO>63.1314</SECTNO> <SUBJECT>Storage vessel provisions.</SUBJECT> <SECTNO>63.1315</SECTNO> <SUBJECT>Continuous process vents provisions.</SUBJECT> <SECTNO>63.1316</SECTNO> <SUBJECT>PET and polystyrene affected sources—emissions control provisions.</SUBJECT> <SECTNO>63.1317</SECTNO> <SUBJECT>PET and polystyrene continuous process affected sources—monitoring provisions.</SUBJECT> <SECTNO>63.1318</SECTNO> <SUBJECT>PET and polystyrene continuous process affected sources—testing and compliance demonstration provisions.</SUBJECT> <SECTNO>63.1319</SECTNO> <SUBJECT>PET and polystyrene continuous process affected sources—recordkeeping provisions.</SUBJECT> <SECTNO>63.1320</SECTNO> <SUBJECT>PET and polystyrene continuous process affected sources—reporting provisions.</SUBJECT> <SECTNO>63.1321</SECTNO> <SUBJECT>Batch process vents provisions.</SUBJECT> <SECTNO>63.1322</SECTNO> <SUBJECT>Batch process vents—reference control technology.</SUBJECT> <SECTNO>63.1323</SECTNO> <SUBJECT>Batch process vents—methods and procedures for group determination.</SUBJECT> <SECTNO>63.1324</SECTNO> <SUBJECT>Batch process vents—monitoring provisions.</SUBJECT> <SECTNO>63.1325</SECTNO> <SUBJECT>Batch process vents—performance test methods and procedures to determine compliance.</SUBJECT> <SECTNO>63.1326</SECTNO> <SUBJECT>Batch process vents—recordkeeping provisions.</SUBJECT> <SECTNO>63.1327</SECTNO> <SUBJECT>Batch process vents—reporting requirements.</SUBJECT> <SECTNO>63.1328</SECTNO> <SUBJECT>Heat exchange systems provisions.</SUBJECT> <SECTNO>63.1329</SECTNO> <SUBJECT>Process contact cooling towers provisions.</SUBJECT> <SECTNO>63.1330</SECTNO> <SUBJECT>Wastewater provisions.</SUBJECT> <SECTNO>63.1331</SECTNO> <SUBJECT>Equipment leak provisions.</SUBJECT> <SECTNO>63.1332</SECTNO> <SUBJECT>Emissions averaging provisions.</SUBJECT> <SECTNO>63.1333</SECTNO> <SUBJECT>Additional test methods and procedures.</SUBJECT> <SECTNO>63.1334</SECTNO> <SUBJECT>Parameter monitoring levels and excursions.</SUBJECT> <SECTNO>63.1335</SECTNO> <SUBJECT>General recordkeeping and reporting provisions.</SUBJECT> <FP SOURCE="FP-2"> <E T="05">Table 1 to Subpart JJJ—Applicability of General Provisions to Subpart JJJ Affected Sources</E> </FP> <FP SOURCE="FP-2"> <E T="05">Table 2 to Subpart JJJ—Group 1 Storage Vessels at Existing Affected Sources</E> </FP> <FP SOURCE="FP-2"> <E T="05">Table 3 to Subpart JJJ—Group 1 Storage Vessels at Existing Affected Sources Producing the Listed Thermoplastics</E> </FP> <FP SOURCE="FP-2"> <E T="05">Table 4 to Subpart JJJ—Group 1 Storage Vessels at New Affected Sources</E> </FP> <FP SOURCE="FP-2"> <E T="05">Table 5 to Subpart JJJ—Group 1 Storage Vessels at New Affected Sources Producing the Listed Thermoplastics</E> </FP> <FP SOURCE="FP-2"> <E T="05">Table 6 to Subpart JJJ—Known Organic Hazardous Air Pollutants From Thermoplastics Products</E> </FP> <FP SOURCE="FP-2"> <E T="05">Table 7 to Subpart JJJ—Group 1 Batch Process Vents—Monitoring, Recordkeeping, and Reporting Requirements</E> </FP> <FP SOURCE="FP-2"> <E T="05">Table 8 to Subpart JJJ—Operating Parameters for Which Levels are Required to be Established for Continuous and Batch Process Vents and Aggregate Batch Vent Streams</E> </FP> </SUBPART> <SUBPART> <RESERVED>Subpart KKK[Reserved]</RESERVED> </SUBPART> <SUBPART> <HD SOURCE="HED">Subpart LLL—National Emission Standards for Hazardous Air Pollutants From the Portland Cement Manufacturing Industry</HD> <SUBJGRP> <HD SOURCE="HED">General</HD> <SECTNO>63.1340</SECTNO> <SUBJECT>Applicability and designation of affected sources.</SUBJECT> <SECTNO>63.1341</SECTNO> <SUBJECT>Definitions.</SUBJECT> </SUBJGRP> <SUBJGRP> <HD SOURCE="HED">Emission Standards and Operating Limits</HD> <SECTNO>63.1342</SECTNO> <SUBJECT>Standards: General.</SUBJECT> <SECTNO>63.1343</SECTNO> <SUBJECT>Standards for kilns and in-line kiln/raw mills.</SUBJECT> <SECTNO>63.1344</SECTNO> <SUBJECT>Operating limits for kilns and in-line kiln/raw mills.</SUBJECT> <SECTNO>63.1345</SECTNO> <SUBJECT>Standards for clinker coolers.</SUBJECT> <SECTNO>63.1346</SECTNO> <SUBJECT>Standards for new and reconstructed raw material dryers.</SUBJECT> <SECTNO>63.1347</SECTNO> <SUBJECT>Standards for raw and finish mills.</SUBJECT> <SECTNO>63.1348</SECTNO> <SUBJECT>Standards for affected sources other than kilns; in-line kiln raw mills; clinker coolers; new and reconstructed raw material dryers; and raw and finish mills.</SUBJECT> </SUBJGRP> <SUBJGRP> <HD SOURCE="HED">Monitoring and Compliance Provisions</HD> <SECTNO>63.1349</SECTNO> <SUBJECT>Performance testing requirements.</SUBJECT> <SECTNO>63.1350</SECTNO> <SUBJECT>Monitoring requirements.</SUBJECT> <SECTNO>63.1351</SECTNO> <SUBJECT>Compliance dates.</SUBJECT> <SECTNO>63.1352</SECTNO> <SUBJECT>Additional test methods.</SUBJECT> </SUBJGRP> <SUBJGRP> <HD SOURCE="HED">Notification, Reporting and Recordkeeping</HD> <SECTNO>63.1353</SECTNO> <SUBJECT>Notification requirements.</SUBJECT> <SECTNO>63.1354</SECTNO> <SUBJECT>Reporting requirements.</SUBJECT> <SECTNO>63.1355</SECTNO> <SUBJECT>Recordkeeping requirements.</SUBJECT> </SUBJGRP> <SUBJGRP> <HD SOURCE="HED">Other</HD> <SECTNO>63.1356</SECTNO> <SUBJECT>Exemption from new source performance standards.</SUBJECT> <SECTNO>63.1357</SECTNO> <SUBJECT>Temporary, conditioned exemption from particulate and opacity standards.</SUBJECT> <SECTNO>63.1358</SECTNO> <SUBJECT>Delegation of authority.</SUBJECT> <SECTNO>63.1359</SECTNO> <SUBJECT>[Reserved]<PRTPAGE P="7"/> </SUBJECT> <APP>Table 1 to Subpart LLL of Part 63—Applicability of General Provisions</APP> </SUBJGRP> </SUBPART> <SUBPART> <HD SOURCE="HED">Subpart MMM—National Emission Standards for Hazardous Air Pollutants for Pesticide Active Ingredient Production</HD> <SECTNO>63.1360</SECTNO> <SUBJECT>Applicability.</SUBJECT> <SECTNO>63.1361</SECTNO> <SUBJECT>Definitions.</SUBJECT> <SECTNO>63.1362</SECTNO> <SUBJECT>Standards.</SUBJECT> <SECTNO>63.1363</SECTNO> <SUBJECT>Standards for equipment leaks.</SUBJECT> <SECTNO>63.1364</SECTNO> <SUBJECT>Compliance dates.</SUBJECT> <SECTNO>63.1365</SECTNO> <SUBJECT>Test methods and initial compliance procedures.</SUBJECT> <SECTNO>63.1366</SECTNO> <SUBJECT>Monitoring and inspection requirements.</SUBJECT> <SECTNO>63.1367</SECTNO> <SUBJECT>Recordkeeping requirements.</SUBJECT> <SECTNO>63.1368</SECTNO> <SUBJECT>Reporting requirements.</SUBJECT> <SECTNO>63.1369</SECTNO> <SUBJECT>Delegation of authority.</SUBJECT> <APP>Table 1 to Subpart MMM of part 63—General Provisions Applicability to Subpart MMM.</APP> <APP>Table 2 to Subpart MMM of part 63—Standards for New and Existing PAI Sources.</APP> <APP>Table 3 to Subpart MMM of Part 63—Monitoring Requirements for Control Devices.</APP> <APP>Table 4 to Subpart MMM of Part 63—Control Requirements for Items of Equipment that Meet the Criteria of § 63.1362(k).</APP> </SUBPART> <SUBPART> <HD SOURCE="HED">Subpart NNN—National Emission Standards for Hazardous Air Pollutants for Wool Fiberglass Manufacturing</HD> <SECTNO>63.1380</SECTNO> <SUBJECT>Applicability.</SUBJECT> <SECTNO>63.1381</SECTNO> <SUBJECT>Definitions.</SUBJECT> <SECTNO>63.1382</SECTNO> <SUBJECT>Emission standards.</SUBJECT> <SECTNO>63.1383</SECTNO> <SUBJECT>Monitoring requirements.</SUBJECT> <SECTNO>63.1384</SECTNO> <SUBJECT>Performance test requirements.</SUBJECT> <SECTNO>63.1385</SECTNO> <SUBJECT>Test methods and procedures.</SUBJECT> <SECTNO>63.1386</SECTNO> <SUBJECT>Notification, recordkeeping, and reporting requirements.</SUBJECT> <SECTNO>63.1387</SECTNO> <SUBJECT>Compliance dates.</SUBJECT> <SECTNO>63.1388—63.1399</SECTNO> <SUBJECT>[Reserved]</SUBJECT> <APP>Table 1 to Subpart NNN of part 63—Applicability of general provisions (40 CFR part 63, subpart A) to subpart NNN.</APP> <APP>Appendix A to Subpart NNN of part 63—Method for the determination of LOI</APP> <APP>Appendix B to Subpart NNN of part 63—Free formaldehyde analysis of insulation resins by hydroxylamine hydrochloride</APP> <APP>Appendix C to Subpart NNN of part 63—Method for the determination of product density</APP> </SUBPART> <SUBPART> <RESERVED>Subpart OOO[Reserved]</RESERVED> </SUBPART> <SUBPART> <HD SOURCE="HED">Subpart PPP—National Emission Standards for Hazardous Air Pollutant Emissions for Polyether Polyols Production</HD> <SECTNO>63.1420</SECTNO> <SUBJECT>Applicability and designation of affected sources.</SUBJECT> <SECTNO>63.1421</SECTNO> <SUBJECT>Delegation of authority.</SUBJECT> <SECTNO>63.1422</SECTNO> <SUBJECT>Compliance dates and relationship of this rule to existing applicable rules.</SUBJECT> <SECTNO>63.1423</SECTNO> <SUBJECT>Definitions.</SUBJECT> <SECTNO>63.1424</SECTNO> <SUBJECT>Emission standards.</SUBJECT> <SECTNO>63.1425</SECTNO> <SUBJECT>Process vent control requirements.</SUBJECT> <SECTNO>63.1426</SECTNO> <SUBJECT>Process vent requirements for determining organic HAP concentration, control efficiency, and aggregated organic HAP emission reduction for a PMPU.</SUBJECT> <SECTNO>63.1427</SECTNO> <SUBJECT>Process vent requirements for processes using extended cookout as an epoxide emission reduction technique.</SUBJECT> <SECTNO>63.1428</SECTNO> <SUBJECT>Process vent requirements for group determination of PMPUs using a nonepoxide organic HAP to make or modify the product.</SUBJECT> <SECTNO>63.1429</SECTNO> <SUBJECT>Process vent monitoring requirements.</SUBJECT> <SECTNO>63.1430</SECTNO> <SUBJECT>Process vent reporting and recordkeeping requirements.</SUBJECT> <SECTNO>63.1431</SECTNO> <SUBJECT>Process vent annual epoxides emission factor plan requirements.</SUBJECT> <SECTNO>63.1432</SECTNO> <SUBJECT>Storage vessel provisions.</SUBJECT> <SECTNO>63.1433</SECTNO> <SUBJECT>Wastewater provisions.</SUBJECT> <SECTNO>63.1434</SECTNO> <SUBJECT>Equipment leak provisions.</SUBJECT> <SECTNO>63.1435</SECTNO> <SUBJECT>Heat exchanger provisions.</SUBJECT> <SECTNO>63.1436</SECTNO> <SUBJECT>[Reserved]</SUBJECT> <SECTNO>63.1437</SECTNO> <SUBJECT>Additional requirements for performance testing.</SUBJECT> <SECTNO>63.1438</SECTNO> <SUBJECT>Parameter monitoring levels and excursions.</SUBJECT> <SECTNO>63.1439</SECTNO> <SUBJECT>General recordkeeping and reporting provisions.</SUBJECT> <APP>Table 1 to Subpart PPP of Part 63—Applicability of General Provisions to Subpart PPP Affected Sources</APP> <APP>Table 2 to Subpart PPP of Part 63—Applicability of Subparts F, G, H, and U to Subpart PPP Affected Sources</APP> <APP>Table 3 to Subpart PPP of Part 63—Group 1 Storage Vessels at Existing and New Affected Sources</APP> <APP>Table 4 to Subpart PPP of Part 63—Known Organic HAP From Polyether Polyol Products</APP> <APP>Table 5 to Subpart PPP of Part 63—Process Vents From Batch Unit Operations—Monitoring, Recordkeeping, and Reporting Requirements</APP> <APP>Table 6 to Subpart PPP of Part 63—Process Vents From Continuous Unit Operations—Monitoring, Recordkeeping, and Reporting Requirements</APP> <APP>Table 7 to Subpart PPP of Part 63—Operating Parameters for Which Monitoring Levels are Required to be Established for Process Vents Streams</APP> <APP>Table 8 to Subpart PPP of Part 63—Routine Reports Required by This Subpart</APP> </SUBPART> <SUBPART> <PRTPAGE P="8"/> <RESERVED>Subparts QQQ—SSS[Reserved]</RESERVED> </SUBPART> <SUBPART> <HD SOURCE="HED">Subpart TTT—National Emission Standards for Hazardous Air Pollutants for Primary Lead Smelting</HD> <SECTNO>63.1541</SECTNO> <SUBJECT>Applicability.</SUBJECT> <SECTNO>63.1542</SECTNO> <SUBJECT>Definitions.</SUBJECT> <SECTNO>63.1543</SECTNO> <SUBJECT>Standards for process and process fugitive sources.</SUBJECT> <SECTNO>63.1544</SECTNO> <SUBJECT>Standards for fugitive dust sources.</SUBJECT> <SECTNO>63.1545</SECTNO> <SUBJECT>Compliance dates.</SUBJECT> <SECTNO>63.1546</SECTNO> <SUBJECT>Test methods.</SUBJECT> <SECTNO>63.1547</SECTNO> <SUBJECT>Monitoring requirements.</SUBJECT> <SECTNO>63.1548</SECTNO> <SUBJECT>Notification requirements.</SUBJECT> <SECTNO>63.1549</SECTNO> <SUBJECT>Recordkeeping and reporting requirements.</SUBJECT> <SECTNO>63.1550</SECTNO> <SUBJECT>Delegation of authority.</SUBJECT> </SUBPART> <SUBPART> <RESERVED>Subparts UUU—WWW[Reserved]</RESERVED> </SUBPART> <SUBPART> <HD SOURCE="HED">Subpart XXX—National Emission Standards for Hazardous Air Pollutants for Ferroalloys Production: Ferromanganese and Silicomanganese</HD> <SECTNO>63.1620-63.1649</SECTNO> <SUBJECT>[Reserved]</SUBJECT> <SECTNO>63.1650</SECTNO> <SUBJECT>Applicability and compliance dates.</SUBJECT> <SECTNO>63.1651</SECTNO> <SUBJECT>Definitions.</SUBJECT> <SECTNO>63.1652</SECTNO> <SUBJECT>Emission standards.</SUBJECT> <SECTNO>63.1653</SECTNO> <SUBJECT>Opacity standards.</SUBJECT> <SECTNO>63.1654</SECTNO> <SUBJECT>Operational and work practice standards.</SUBJECT> <SECTNO>63.1655</SECTNO> <SUBJECT>Maintenance requirements.</SUBJECT> <SECTNO>63.1656</SECTNO> <SUBJECT>Performance testing, test methods, and compliance demonstrations.</SUBJECT> <SECTNO>63.1657</SECTNO> <SUBJECT>Monitoring requirements.</SUBJECT> <SECTNO>63.1658</SECTNO> <SUBJECT>Notification requirements.</SUBJECT> <SECTNO>63.1659</SECTNO> <SUBJECT>Reporting requirements.</SUBJECT> <SECTNO>63.1660</SECTNO> <SUBJECT>Recordkeeping requirements.</SUBJECT> <SECTNO>63.1661</SECTNO> <SUBJECT>Delegation of authorities.</SUBJECT> <SECTNO>63.1662-63.1679</SECTNO> <SUBJECT>[Reserved]</SUBJECT> <APP>Appendix A to Part 63—Test Methods</APP> <APP>Appendix B to Part 63—Sources Defined for Early Reduction Provisions</APP> <APP>Appendix C to Part 63—Determination of the Fraction Biodegraded (F<E T="52">bio</E>) in a Biological Treatment Unit</APP> <APP>Appendix D to Part 63—Alternative Validation Procedure for EPA Waste and Wastewater Methods</APP> </SUBPART> </CONTENTS> <AUTH> <HD SOURCE="HED">Authority:</HD> <P>42 U.S.C. 7401 <E T="03">et seq.</E> </P> </AUTH> <SOURCE> <HD SOURCE="HED">Source:</HD> <P>57 FR 61992, Dec. 29, 1992, unless otherwise noted.</P> </SOURCE> <SUBPART> <HD SOURCE="HED">Subpart EEE—National Emission Standards for Hazardous Air Pollutants From Hazardous Waste Combustors</HD> <SOURCE> <HD SOURCE="HED">Source:</HD> <P>63 FR 33820, June 19, 1998, unless otherwise noted.</P> </SOURCE> <SECTION> <SECTNO>§ § 63.1200-63.1210</SECTNO> <RESERVED>[Reserved]</RESERVED> </SECTION> <SECTION> <SECTNO>§ 63.1211</SECTNO> <SUBJECT>Notification requirements.</SUBJECT> <P>(a) <E T="03">Notification of Intent To Comply (NIC).</E> (1) All hazardous waste combustors subject to this subpart shall prepare a Notification of Intent to Comply that includes the following information:</P> <P>(i) General information:</P> <P>(A) The name and address of the owner/operator and the source;</P> <P>(B) Whether the source is a major or an area source;</P> <P>(C) Waste minimization and emission control technique(s) being considered;</P> <P>(D) Emission monitoring technique(s) being considered;</P> <P>(E) Waste minimization and emission control technique(s) effectiveness;</P> <P>(F) A description of the evaluation criteria used or to be used to select waste minimization and/or emission control technique(s); and</P> <P>(G) A statement that the source intends to comply with this subpart by controlling emissions from the combustion of hazardous waste pursuant to the standards of this subpart.</P> <P>(ii) Information on key activities and estimated dates for these activities that will bring the source into compliance with emission control requirements of this subpart. The submission of key activities and dates is not intended to be static and may be revised by the source during the period the NIC is in effect. Revisions shall be submitted to the regulatory authority and be made available to the public. The following are the key activities and dates that shall be included:</P> <P>(A) The dates for beginning and completion of engineering studies to evaluate emission control systems or process changes for emissions;</P> <P>(B) The date by which contracts for emission control systems or process changes for emission control will be awarded, or the date by which orders will be issued for the purchase of component parts to accomplish emission control or process changes;</P> <P>(C) The date by which construction applications will be submitted;</P> <P>(D) The date by which on-site construction, installation of emission control equipment, or process change is to be initiated;<PRTPAGE P="9"/> </P> <P>(E) The date by which on-site construction, installation of emission control equipment, or process change is to be completed; and</P> <P>(F) The date by which final compliance is to be achieved. The individual dates and milestones listed in paragraphs (a)(1)(ii)(A) through (F) of this section as part of the NIC are not requirements and therefore are not enforceable deadlines; the Agency is requiring paragraphs (a)(1)(ii)(A) through (F) of this section as part of the NIC only to inform the public of the source's intentions towards coming into compliance.</P> <P>(iii) A summary of the public meeting required under paragraph (b) of this section.</P> <P>(iv) For any source that does not intend to comply, but will not stop burning hazardous waste as required under paragraph (c) of this section, a certification that the designated source will:</P> <P>(A) Stop burning hazardous waste on or before the compliance date of the emission standards of this Subpart; and</P> <P>(B) Be necessary to combust the hazardous waste from another on-site source, during the year prior to the compliance date of the emission standards of this Subpart, because that other source is:</P> <P>(<E T="03">1</E>) Installing equipment to come into compliance with the emission standards of this Subpart; or</P> <P>(<E T="03">2</E>) Installing source reduction modifications to eliminate the need for further combustion of wastes.</P> <P>(2) A draft of the NIC must be made available for public review no later than 30 days prior to the public meeting required under paragraph (b)(1) of this section.</P> <P>(3) The final NIC must be submitted to the permitting agency no later than one year following the effective date of the emission standards of this subpart.</P> <P>(b) <E T="03">NIC Public Meeting and Notice.</E> (1) Prior to the submission of the NIC to the permitting agency, and no later than 10 months after the effective date of the emission standards of this subpart, the source shall hold at least one informal meeting with the public to discuss anticipated activities described in the draft NIC for achieving compliance with the MACT standards promulgated in this subpart. The source must post a sign-in sheet or otherwise provide a voluntary opportunity for attendees to provide their names and addresses.</P> <P>(2) The source shall submit a summary of the meeting, along with the list of attendees and their addresses developed under paragraph (b)(1) of this section, and copies of any written comments or materials submitted at the meeting, to the permitting agency as part of the final NIC, in accordance with paragraph (a)(1)(iii) of this section.</P> <P>(3) The source must provide public notice of the NIC meeting at least 30 days prior to the meeting. The source shall provide public notice in all of the following forms:</P> <P>(i) <E T="03">Newspaper advertisement.</E> The source shall publish a notice in a newspaper of general circulation in the county or equivalent jurisdiction of the source. In addition, the source shall publish the notice in newspapers of general circulation in adjacent counties or equivalent jurisdiction where such publication would be necessary to inform the affected public. The notice must be published as a display advertisement.</P> <P>(ii) <E T="03">Visible and accessible sign.</E> The source shall post a notice on a clearly marked sign at or near the source. If the source places the sign on the source's property, then the sign must be large enough to be readable from the nearest spot where the public would pass by the source.</P> <P>(iii) <E T="03">Broadcast media announcement.</E> The source shall broadcast a notice at least once on at least one local radio station or television station.</P> <P>(iv) <E T="03">Notice to the facility mailing list.</E> The source shall provide a copy of the notice to the facility mailing list in accordance with § 124.10(c)(1)(ix) of this chapter.</P> <P>(4) The notices required under paragraph (b)(3) of this section must include:</P> <P>(i) The date, time, and location of the meeting;</P> <P>(ii) A brief description of the purpose of the meeting;</P> <P>(iii) A brief description of the source and proposed operations, including the address or a map (e.g., a sketched or <PRTPAGE P="10"/>copied street map) of the source location;</P> <P>(iv) A statement encouraging people to contact the source at least 72 hours before the meeting if they need special access to participate in the meeting;</P> <P>(v) A statement describing how the draft NIC can be obtained; and</P> <P>(vi) The name, address, and telephone number of a contact person for the NIC.</P> <P>(c) <E T="03">Sources that do not intend to comply.</E> Those sources subject to the requirements of this subpart, except those sources meeting the requirements of paragraph (a)(1)(iv) of this section:</P> <P>(1) Who signify in their NIC an intent not to comply with the requirements of this Subpart, must stop burning hazardous waste on or before two years after the effective date of the emmission standards of this subpart;</P> <P>(2) Who do not intend to comply with this subpart must include in their NIC a schedule that includes key dates for the steps to be taken to stop burning hazardous waste. Key dates include the date for submittal of RCRA closure documents.</P> </SECTION> <SECTION> <SECTNO>§ 63.1212</SECTNO> <SUBJECT>Progress reports.</SUBJECT> <P>(a) <E T="03">General.</E> Not later than two years after the effective date of the emission standards of this subpart, all sources subject to this Subpart except those hazardous waste combustion sources that comply with paragraph (b)(2) of this section shall:</P> <P>(1) Complete engineering design for any physical modifications to the source needed to comply with the emissions standards of this subpart;</P> <P>(2) Submit applicable construction applications to the applicable regulatory authority; and</P> <P>(3) Enter into a binding contractual commitment to purchase, fabricate, and install any equipment, devices, and ancillary structures needed to comply with the emission requirements of this subpart.</P> <P>(b) <E T="03">Demonstration.</E> (1) Hazardous waste combustion sources shall submit to the regulatory authority a progress report on or before two years after the effective date of the emission standards of this subpart which contains information demonstrating that the source has met the requirements of paragraph (a) of this section. This information will be used by the regulatory authority to determine if the source has made adequate progress towards compliance with the applicable emission standards.</P> <P>(2) Sources that intend to come into compliance with the emissions standards of this subpart, but can do so without undertaking any of the activities described in paragraph (a) of this section, shall submit documentation either:</P> <P>(i) Demonstrating that the source, at the time of the progress report, is in compliance with the emissions requirements; or</P> <P>(ii) Specifying the steps that will be taken to bring the source into compliance, without undertaking any of the activities listed in paragraphs (a)(1) through (3) of this section.</P> <P>(3) Sources that fail to comply with paragraph (a) above or paragraph (b)(2) of this section shall stop burning hazardous waste on or before the date two years after the effective date of the emission standards of this subpart.</P> <P>(c) <E T="03">Schedule.</E> (1) The progress report shall contain a detailed schedule that lists key dates for all projects that will bring the source into compliance with the requirements of this subpart (i.e., key dates for the activities required under paragraphs (b)(1)(i) through (iii) of this section). Dates shall cover the time frame from the progress report through the compliance date of the emission standards of this subpart.</P> <P>(2) The schedule shall contain the following dates:</P> <P>(i) Bid and award dates for construction contracts and equipment supply contractors;</P> <P>(ii) Milestones such as ground breaking, completion of drawings and specifications, equipment deliveries, intermediate construction completions, and testing;</P> <P>(iii) The dates on which applications were submitted for or obtained operating and construction permits or licenses;</P> <P>(iv) The dates by which approvals of any permits or licenses are anticipated; and<PRTPAGE P="11"/> </P> <P>(v) The projected date by which the source will be in compliance with the requirements of this subpart.</P> <P>(d) <E T="03">Notice of intent to comply.</E> The progress report shall contain a statement that the source intends or does not intend to come into compliance with the applicable emission control requirements of this subpart.</P> <P>(e) <E T="03">Sources that do not intend to comply.</E> (1) Sources that: indicated in their NIC their intent not to comply with this subpart and stop burning hazardous waste prior to the submittal of a progress report; or meet the requirements of paragraph (a)(1)(iv) of this section are not required to include the requirements of paragraphs (b) and (c) of this section to their progress report, but shall include in their progress report: the date on which the source stopped burning hazardous waste; and the date(s) on which RCRA closure documents were submitted.</P> <P>(2) Those sources that signify in the progress report, submitted not later than two years after the effective date of the emission standards of this subpart, their intention not to comply with the requirements of this subpart must stop burning hazardous waste on or before the date two years after the effective date of the emission standards of this subpart.</P> </SECTION> <SECTION> <SECTNO>§ 63.1213</SECTNO> <SUBJECT>Certification.</SUBJECT> <P>(a) The Notice of Intent to Comply (NIC) and Progress Report submitted shall contain the following certification signed and dated by an authorized representative of the source: </P> <EXTRACT> <P>I certify under penalty of law that I have personally examined and am familiar with the information submitted in this document and all attachments and that, based on my inquiry of those individuals immediately responsible for obtaining the information, I believe that the information is true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment.</P> </EXTRACT> <P>(b) An authorized representative should be a responsible corporate officer (for a corporation), a general partner (for a partnership), the proprietor (of a sole proprietorship), or a principal executive officer or ranking elected official (for a municipality, State, Federal, or other public agency).</P> </SECTION> <SECTION> <SECTNO>§ 63.1214</SECTNO> <SUBJECT>Extension of the compliance date.</SUBJECT> <P>(a) A source that intends to come into compliance with the requirements of this subpart, but due to the installation of controls will not meet the compliance date, may request an extension of the compliance date for one year.</P> <P>(b) Sources subject to this subpart shall follow the requirements of § 63.6(i)(4) or § 63.1216 to request an extension of the compliance date.</P> </SECTION> <SECTION> <SECTNO>§ 63.1215</SECTNO> <SUBJECT>Sources that become affected sources after the effective date of the emission standards of this subpart.</SUBJECT> <P>(a) A source that begins to burn hazardous waste after the effective date of the emission standards of this subpart, therefore becoming an affected source, but prior to 9 months after the effective date of the emission standards of this subpart shall comply with all the requirements of §§ 63.1211 through 63.1213 and associated time frames for public meetings and document submittals.</P> <P>(b) A source that intends to begin burning hazardous waste more than 9 months after the effective date of the emission standards of this subpart, therefore becoming an affected source, shall meet all the requirements of §§ 63.1211 through 63.1213 prior to burning hazardous waste.</P> <P>(1) Such sources shall make a draft NIC available, notice their public meeting, hold their public meeting, and submit a final NIC prior to burning hazardous waste.</P> <P>(2) Such sources also shall submit their progress report at the time of the submittal of their final NIC.</P> </SECTION> <SECTION> <SECTNO>§ 63.1216</SECTNO> <SUBJECT>Extension of the compliance date to install pollution prevention or waste minimization controls.</SUBJECT> <P>(a) <E T="03">Applicability.</E> The owner or operator of any source subject to the requirements of this subpart may request from the Administrator or State with an approved Title V program an extension of one year to comply with the emission standards in this subpart, if the owner or operator can reasonably <PRTPAGE P="12"/>document that the installation of pollution prevention or waste minimization measures will significantly reduce the amount and/or toxicity of hazardous wastes entering the feedstream(s) of the combustion device(s) subject to this subpart, and that the facility could not otherwise install the necessary control measures and comply within three years after the effective date of the emission standards of this subpart.</P> <P>(b) <E T="03">Requirements for requesting an extension.</E> Requests for a one-year extension must be in writing, must be received not later than 12 months before the affected source's compliance date, and must contain the following information:</P> <P>(1) A description of pollution prevention or waste minimization controls that, when installed, will significantly reduce the amount and/or toxicity of hazardous wastes entering the feedstream(s) of the combustion device(s) subject to this subpart. Pollution prevention or waste minimization measures may include: equipment or technology modifications, reformulation or redesign of products, substitution of raw materials, improvements in work practices, maintenance, training, inventory control, or recycling practices conducted as defined in 40 CFR 261.1(c);</P> <P>(2) A description of other pollution controls to be installed that are necessary to comply with the emission standards;</P> <P>(3) A reduction goal or estimate of the annual reductions in quantity and/or toxicity of hazardous waste(s) entering combustion feedstream(s) that will occur by installing the proposed pollution prevention or waste minimization measures;</P> <P>(4) A comparison of reductions in the amounts and/or toxicity of hazardous wastes combusted after installation of pollution prevention or waste minimization measures to the amounts and/or toxicity of hazardous wastes combusted prior to the installation of these measures; and, if the difference is less than a fifteen percent reduction, a comparison to pollution prevention and waste minimization reductions recorded during the previous five years;</P> <P>(5) Reasonable documentation that installation of the pollution prevention or waste minimization changes will not result in a net increase (except for documented increases in production) of hazardous constituents released to the environment through other emissions, wastes or effluents;</P> <P>(6) Reasonable documentation that the design and installation of waste minimization and other measures that are necessary for compliance cannot otherwise be installed within the three year compliance period, and</P> <P>(7) The information required in 40 CFR 63.6(i)(6)(i)(B) through (D).</P> <P>(8) Documentation prepared under an existing State required pollution prevention program that contains the information may be enclosed with a request for extension in lieu of paragraphs (b)(1) through (7) of this section.</P> <P>(c) <E T="03">Approval of request for extension of compliance.</E> Based on the information provided in any request made under paragraph (a) of this section, the Administrator or State with an approved Title V program may grant an extension of compliance with the emission standards identified in paragraph (a) of this section. The extension will be in writing in accordance with §§ 63.6(i)(10)(i) through 63.6(i)(10)(v)(A). EPA and States must consider the information required in paragraph (a) of this section in approving or denying requests for one-year compliance extensions.</P> </SECTION> </SUBPART> <SUBPART> <RESERVED>Subpart FFF[Reserved]</RESERVED> </SUBPART> <SUBPART> <HD SOURCE="HED">Subpart GGG—National Emission Standards for Pharmaceuticals Production</HD> <SOURCE> <HD SOURCE="HED">Source:</HD> <P>63 FR 50326, Sept. 21, 1998, unless otherwise noted.</P> </SOURCE> <SECTION> <SECTNO>§ 63.1250</SECTNO> <SUBJECT>Applicability.</SUBJECT> <P>(a) <E T="03">Definition of affected source.</E> The affected source subject to this subpart is the pharmaceutical manufacturing operation, as defined in § 63.1251. Except as specified in paragraph (d) of this section, the provisions of this subpart <PRTPAGE P="13"/>apply to pharmaceutical manufacturing operations that meet the criteria specified in paragraphs (a)(1) through (a)(3) of this section as follows:</P> <P>(1) Manufacture a pharmaceutical product, as defined in § 63.1251;</P> <P>(2) Are located at a plant site that is a major source as defined in section 112(a) of the Act; and</P> <P>(3) Process, use, or produce HAP.</P> <P>(b) <E T="03">New source applicability.</E> A new affected source subject to this subpart and to which the requirements for new sources apply is: an affected source for which construction or reconstruction commenced after April 2, 1997 and the standard was applicable at the time of construction or reconstruction; or a pharmaceutical manufacturing process unit (PMPU), dedicated to manufacturing a single product, that has the potential to emit 10 tons per year of any one HAP or 25 tons per year of combined HAP, for which construction commenced after April 2, 1997.</P> <P>(c) <E T="03">General Provisions.</E> Table 1 of this subpart specifies the provisions of subpart A of this part that apply to an owner or operator of an affected source subject to this subpart, and clarifies specific provisions in subpart A of this part as necessary for this subpart.</P> <P>(d) <E T="03">Processes exempted from the affected source.</E> The provisions of this subpart do not apply to research and development facilities.</P> <P>(e) <E T="03">Storage tank ownership determination.</E> The owner or operator shall follow the procedures specified in paragraphs (e)(1) through (e)(5) of this section to determine to which PMPU a storage tank shall belong.</P> <P>(1) If a storage tank is dedicated to a single PMPU, the storage tank shall belong to that PMPU.</P> <P>(2) If a storage tank is shared among PMPU's, then the storage tank shall belong to that PMPU located on the same plant site as the storage tank that has the greatest annual volume input into or output from the storage tank (i.e., said PMPU has the predominant use of the storage tank).</P> <P>(3) If predominant use cannot be determined for a storage tank that is shared among PMPU's and if one of those PMPU's is subject to this subpart, the storage tank shall belong to said PMPU.</P> <P>(4) If the predominant use of a storage tank varies from year to year, then predominant use shall be determined based on the utilization that occurred during the year preceding September 21, 1998 for existing affected sources. For new affected sources, predominant use will be based on the first year after initial startup. The determination of predominant use shall be reported in the Notification of Compliance Status required by § 63.1260(f). If the predominant use changes, the redetermination of predominant use shall be reported in the next Periodic Report.</P> <P>(5) If the storage tank begins receiving material from (or sending material to) another PMPU; or ceases to receive material from (or send material to) a PMPU; or if the applicability of this subpart to a storage tank has been determined according to the provisions of paragraphs (e)(1) through (4) of this section and there is a significant change in the use of the storage tank that could reasonably change the predominant use, the owner or operator shall reevaluate the applicability of this subpart to the storage tank, and report such changes to EPA in the next Periodic report.</P> <P>(f) <E T="03">Compliance dates.</E> The compliance dates for affected sources are as follows:</P> <P>(1) An owner or operator of an existing affected source must comply with the provisions of this subpart within 3 years after September 21, 1998.</P> <P>(2) An owner or operator of a new or reconstructed affected source must comply with the provisions of this subpart on September 21, 1998 or upon startup, whichever is later.</P> <P>(3) Notwithstanding the requirements of paragraphs (f)(1) and (2) of this section, a new source which commences construction or reconstruction after April 2, 1997 and before September 21, 1998 shall not be required to comply with such promulgated standard until 3 years after September 21, 1998 if:</P> <P>(i) The promulgated standard is more stringent than the proposed standard; and</P> <P>(ii) The owner or operator complies with the standard as proposed during the 3-year period immediately after September 21, 1998.<PRTPAGE P="14"/> </P> <P>(4) Pursuant to section 112(i)(3)(B) of the Act, an owner or operator may request an extension allowing the existing source up to 1 additional year to comply with section 112(d) standards.</P> <P>(i) For purposes of this subpart, a request for an extension shall be submitted no later than 120 days prior to the compliance dates specified in paragraphs (f)(1) through (3) of this section, except as provided in paragraph (f)(4)(ii) of this section. The dates specified in § 63.6(i) for submittal of requests for extensions shall not apply to sources subject to this subpart.</P> <P>(ii) An owner or operator may submit a compliance extension request after the date specified in paragraph (f)(4)(i) of this section provided the need for the compliance extension arose after that date and before the otherwise applicable compliance date, and the need arose due to circumstances beyond reasonable control of the owner or operator. This request shall include the data described in § 63.6(i)(6)(i)(A), (B), (C), and (D).</P> <P>(g) <E T="03">Applicability of this subpart except during periods of startup, shutdown, and malfunction.</E> (1) Each provision set forth in this subpart shall apply at all times except that emission limitations shall not apply during periods of: startup; shutdown; and malfunction, if the startup, shutdown, and malfunction precludes the ability of a particular emission point of an affected source to comply with one or more specific emission limitations to which it is subject and the owner or operator follows the provisions for periods of startup, shutdown, and malfunction, as specified in §§ 63.1259(a)(3) and 63.1260(i). Startup, shutdown, and malfunction are defined in § 63.1251.</P> <P>(2) The provisions set forth in § 63.1255 of this subpart shall apply at all times except during periods of nonoperation of the PMPU (or specific portion thereof) in which the lines are drained and depressurized resulting in the cessation of the emissions to which § 63.1255 of this subpart applies.</P> <P>(3) The owner or operator shall not shut down items of equipment that are required or utilized for compliance with the emissions limitations of this subpart during times when emissions (or, where applicable, wastewater streams or residuals) are being routed to such items of equipment, if the shutdown would contravene emissions limitations of this subpart applicable to such items of equipment. This paragraph does not apply if the item of equipment is malfunctioning, or if the owner or operator must shut down the equipment to avoid damage due to a malfunction of the PMPU or portion thereof.</P> <P>(4) During startups, shutdowns, and malfunctions when the emissions limitations of this subpart do not apply pursuant to paragraphs (g)(1) through (3) of this section, the owner or operator shall implement, to the extent reasonably available, measures to prevent or minimize excess emissions to the extent practical. For purposes of this paragraph, “excess emissions” means emissions in excess of those that would have occurred if there were no startup, shutdown, or malfunction and the owner or operator complied with the relevant provisions of this subpart. The measures to be taken shall be identified in the applicable startup, shutdown, and malfunction plan, and may include, but are not limited to, air pollution control technologies, work practices, pollution prevention, monitoring, and/or changes in the manner of operation of the source. Back-up control devices are not required, but may be used if available.</P> <P>(h) <E T="03">Consistency with other regulations.</E> (1) <E T="03">Consistency with other MACT standards.</E> After the compliance dates specified in this section, an affected source subject to the provisions of this subpart that is also subject to the provisions of any other subpart of 40 CFR part 63 may elect, to the extent the subparts are consistent, which subpart under which to maintain records and report to EPA. The affected source shall identify in the Notification of Compliance Status report required by § 63.1260(f) under which authority such records will be maintained.</P> <P>(2) <E T="03">Consistency with 40 CFR parts 264 and 265, subparts AA, BB, and/or CC.</E> After the compliance dates specified in this section, if any affected source subject to this subpart is also subject to monitoring, recordkeeping, and reporting requirements in 40 CFR part 264, subpart AA, BB, or CC, or is subject to <PRTPAGE P="15"/>monitoring and recordkeeping requirements in 40 CFR part 265, subpart AA, BB, or CC and the owner or operator complies with the periodic reporting requirements under 40 CFR part 264, subpart AA, BB, or CC that would apply to the device if the facility had final-permitted status, the owner or operator may elect to comply either with the monitoring, recordkeeping, and reporting requirements of this subpart, or with the monitoring, recordkeeping, and reporting requirements in 40 CFR parts 264 and/or 265, as described in this paragraph, which shall constitute compliance with the monitoring, record keeping, and reporting requirements of this subpart. If the owner or operator elects to comply with the monitoring, recordkeeping, and reporting requirements in 40 CFR parts 264 and/or 265, the owner or operator shall report all information required by § 63.1260(g). The owner or operator shall identify in the Notification of Compliance Status required by § 63.1260(f) the monitoring, recordkeeping, and reporting authority under which the owner or operator will comply.</P> <P>(3) <E T="03">Consistency with 40 CFR 60.112b.</E> After the compliance dates specified in this section, a storage tank controlled with a floating roof and in compliance with the provisions of 40 CFR 60.112b, subpart Kb, constitutes compliance with the provisions of this subpart GGG. A storage tank with a fixed roof, closed vent system, and control device in compliance with the provisions of 40 CFR 60.112b, subpart Kb must comply with the monitoring, recordkeeping, and reporting provisions of this subpart GGG. The owner or operator shall identify in the Notification of Compliance Status report required by § 63.1260(f) which tanks are in compliance with subpart Kb.</P> <P>(4) <E T="03">Consistency with subpart I of this part.</E> After the compliance dates specified in this section, for equipment at an affected source subject to this subpart that is also subject to subpart I of this part, an owner or operator may elect to comply with either the provisions of this subpart GGG or the provisions of subpart I of this part. The owner or operator shall identify in the Notification of Compliance Status report required by § 63.1260(f) the provisions with which the owner elects to comply.</P> <P>(5) <E T="03">Consistency with other regulations for wastewater.</E> After the compliance dates specified in this section, the owner or operator of an affected wastewater that is also subject to provisions in 40 CFR parts 260 through 272 shall comply with the more stringent control requirements (e.g., waste management units, numerical treatment standards, etc.) and the more stringent testing, monitoring, recording, and recordkeeping requirements that overlap between the provisions of this subpart and the provisions of 40 CFR parts 260 through 272. The owner or operator shall keep a record of the information used to determine which requirements were the most stringent and shall submit this information if requested by the Administrator.</P> <P>(i) For the purposes of establishing whether a person is in violation of this subpart, nothing in this subpart shall preclude the use of any credible evidence or information relevant to whether a source would have been in compliance with applicable requirements.</P> </SECTION> <SECTION> <SECTNO>§ 63.1251</SECTNO> <SUBJECT>Definitions.</SUBJECT> <P>Terms used in this subpart are defined in the Act, in subpart A of this part, or in this section. If the same term is defined in subpart A of this part and in this section, it shall have the meaning given in this section for the purposes of this subpart.</P> <P> <E T="03">Active ingredient</E> means any component that is intended to furnish pharmacological activity or other direct effect in the diagnosis, cure, mitigation, treatment, or prevention of disease, or to affect the structure or any function of the body of man or other animals. The term includes those components that may undergo chemical change in the manufacture of the pharmaceutical product and be present in the pharmaceutical product in a modified form intended to furnish the specified activity or effect.</P> <P> <E T="03">Actual HAP emissions</E> means the HAP emitted to the atmosphere from either uncontrolled or controlled emission points.<PRTPAGE P="16"/> </P> <P> <E T="03">Air pollution control device or Control device</E> means equipment installed on a process vent, storage tank, wastewater treatment exhaust stack, or combination thereof that reduces the mass of HAP emitted to the air. The equipment may consist of an individual device or a series of devices. Examples include, but are not limited to, incinerators, carbon adsorption units, condensers, flares, boilers, process heaters, and gas absorbers. Process condensers are not considered air pollution control devices or control devices.</P> <P> <E T="03">Annual average concentration,</E> as used in the wastewater provisions, means the annual average concentration as determined according to the procedures specified in § 63.1257(e)(1).</P> <P> <E T="03">Automated monitoring and recording system</E> means any means of measuring values of monitored parameters and creating a hard copy or computer record of the measured values that does not require manual reading of monitoring instruments and manual transcription of data values. Automated monitoring and recording systems include, but are not limited to, computerized systems and strip charts.</P> <P> <E T="03">Batch emission episode</E> means a discrete venting episode that may be associated with a single unit operation. A unit operation may have more than one batch emission episode. For example, a displacement of vapor resulting from the charging of a vessel with HAP will result in a discrete emission episode that will last through the duration of the charge and will have an average flowrate equal to the rate of the charge. If the vessel is then heated, there will also be another discrete emission episode resulting from the expulsion of expanded vapor. Both emission episodes may occur in the same vessel or unit operation. There are possibly other emission episodes that may occur from the vessel or other process equipment, depending on process operations.</P> <P> <E T="03">Batch operation or Batch process</E> means a noncontinuous operation involving intermittent or discontinuous feed into equipment, and, in general, involves the emptying of the equipment after the batch operation ceases and prior to beginning a new operation. Addition of raw material and withdrawal of product do not occur simultaneously in a batch operation.</P> <P> <E T="03">Bench-scale batch process</E> means a batch process (other than a research and development facility) that is capable of being located on a laboratory bench top. This bench-scale equipment will typically include reagent feed vessels, a small reactor and associated product separator, recovery and holding equipment. These processes are only capable of producing small quantities of product.</P> <P> <E T="03">Block</E> means a time period that comprises a single batch.</P> <P> <E T="03">Cleaning operation</E> means routine rinsing, washing, or boil-off of equipment in batch operations between batches.</P> <P> <E T="03">Closed biological treatment process</E> means a tank or surface impoundment where biological treatment occurs and air emissions from the treatment process are routed to either a control device by means of a closed-vent system or by means of hard-piping. The tank or surface impoundment has a fixed roof, as defined in this section, or a floating flexible membrane cover that meets the requirements specified in § 63.1256(c).</P> <P> <E T="03">Closed-loop system</E> means an enclosed system that returns process fluid to the process and is not vented to the atmosphere except through a closed-vent system.</P> <P> <E T="03">Closed-purge system</E> means a system or combination of system and portable containers, to capture purged liquids. Containers must be covered or closed when not being filled or emptied.</P> <P> <E T="03">Closed-vent system</E> means a system that is not open to the atmosphere and is composed of piping, ductwork, connections, and, if necessary, flow inducing devices that transport gas or vapor from an emission point to a control device.</P> <P> <E T="03">Combustion device</E> means an individual unit of equipment, such as a flare, incinerator, process heater, or boiler, used for the combustion of HAP vapors.</P> <P> <E T="03">Component</E> means any ingredient for use in the manufacture of a drug product, including those that may not appear in such drug product.</P> <P> <E T="03">Connector</E> means flanged, screwed, or other joined fittings used to connect <PRTPAGE P="17"/>two pipe lines or a pipe line and a piece of equipment. A common connector is a flange. Joined fittings welded completely around the circumference of the interface are not considered connectors for the purpose of this regulation. For the purpose of reporting and recordkeeping, connector means joined fittings that are not inaccessible, ceramic, or ceramic-lined as described in § 63.1255(b)(1)(vii) and § 63.1255(f)(3).</P> <P> <E T="03">Construction</E> means the onsite fabrication, erection, or installation of an affected source or a PMPU.</P> <P> <E T="03">Consumption</E> means the quantity of HAP entering a process that is not used as reactant (makeup). If the same HAP component is generated in the process as well as added as makeup, consumption shall include the quantity generated in the process, as calculated assuming 100 theoretical conversion. The quantity of material used as reactant is the theoretical amount needed assuming a 100 percent stoichiometric conversion. Makeup is the net amount of material that must be added to the process to replenish losses.</P> <P> <E T="03">Container,</E> as used in the wastewater provisions, means any portable waste management unit that has a capacity greater than or equal to 0.1 m<E T="51">3</E> in which a material is stored, transported, treated, or otherwise handled. Examples of containers are drums, barrels, tank trucks, barges, dumpsters, tank cars, dump trucks, and ships.</P> <P> <E T="03">Continuous process</E> means a process where the inputs and outputs flow continuously throughout the duration of the process. Continuous processes are typically steady state.</P> <P> <E T="03">Continuous recorder</E> means a data recording device that either records an instantaneous data value at least once every 15 minutes or records 15-minute or more frequent block average values.</P> <P> <E T="03">Continuous seal</E> means a seal that forms a continuous closure that completely covers the space between the wall of the storage tank and the edge of the floating roof. A continuous seal may be a vapor-mounted, liquid-mounted, or metallic shoe seal.</P> <P> <E T="03">Control device,</E> for purposes of this § 63.1255, means any equipment used for recovering or oxidizing organic hazardous air pollutant vapors. Such equipment includes, but is not limited to, absorbers, carbon adsorbers, condensers, flares, boilers, and process heaters.</P> <P> <E T="03">Controlled HAP emissions</E> means the quantity of HAP discharged to the atmosphere from an air pollution control device.</P> <P> <E T="03">Cover,</E> as used in the wastewater provisions, means a device or system which is placed on or over a waste management unit containing wastewater or residuals so that the entire surface area is enclosed to minimize air emissions. A cover may have openings necessary for operation, inspection, and maintenance of the waste management unit such as access hatches, sampling ports, and gauge wells provided that each opening is closed when not in use. Examples of covers include a fixed roof installed on a wastewater tank, a lid installed on a container, and an air-supported enclosure installed over a waste management unit.</P> <P> <E T="03">Dedicated PMPU</E> means a PMPU that is composed of equipment that is used to manufacture the same product for a continuous period of 6 months or greater. The PMPU includes any shared storage tank(s) that are determined to belong to the PMPU according to the procedures in § 63.1250(e).</P> <P> <E T="03">Double block and bleed system</E> means two block valves connected in series with a bleed valve or line that can vent the line between the two block valves.</P> <P> <E T="03">Duct work</E> means a conveyance system such as those commonly used for heating and ventilation systems. It is often made of sheet metal and often has sections connected by screws or crimping. Hard-piping is not ductwork.</P> <P> <E T="03">Enhanced biological treatment system or enhanced biological treatment process</E> means an aerated, thoroughly mixed treatment unit(s) that contains biomass suspended in water followed by a clarifier that removes biomass from the treated water and recycles recovered biomass to the aeration unit. The mixed liquor volatile suspended solids (biomass) is greater than 1 kilogram per cubic meter throughout each aeration unit. The biomass is suspended and aerated in the water of the aeration unit(s) by either submerged air flow or mechanical agitation. A thoroughly mixed treatment unit is a unit <PRTPAGE P="18"/>that is designed and operated to approach or achieve uniform biomass distribution and organic compound concentration throughout the aeration unit by quickly dispersing the recycled biomass and the wastewater entering the unit.</P> <P> <E T="03">Equipment</E>, for purposes of § 63.1255, means each pump, compressor, agitator, pressure relief device, sampling connection system, open-ended valve or line, valve, connector, and instrumentation system in organic hazardous air pollutant service; and any control devices or closed-vent systems required by this subpart.</P> <P> <E T="03">Excipient</E> means any substance other than the active drug or product which have been appropriately evaluated for safety and are included in a drug delivery system to either aid the processing of the drug delivery system during its manufacture; protect, support or enhance stability, bioavailability, or patient acceptability; assist in product identification; or enhance any other attribute of the overall safety and effectiveness of the drug delivery system during storage or use.</P> <P> <E T="03">External floating roof</E> means a pontoon-type or double-deck type cover that rests on the liquid surface in a storage tank or waste management unit with no fixed roof.</P> <P> <E T="03">Fill or filling</E> means the introduction of material into a storage tank or the introduction of a wastewater stream or residual into a waste management unit, but not necessarily to complete capacity.</P> <P> <E T="03">First attempt at repair</E> means to take action for the purpose of stopping or reducing leakage of organic material to the atmosphere.</P> <P> <E T="03">Fixed roof</E> means a cover that is mounted on a waste management unit or storage tank in a stationary manner and that does not move with fluctuations in liquid level.</P> <P> <E T="03">Floating roof</E> means a cover consisting of a double deck, pontoon single deck, internal floating cover or covered floating roof, which rests upon and is supported by the liquid being contained, and is equipped with a closure seal or seals to close the space between the roof edge and waste management unit or storage tank wall.</P> <P> <E T="03">Flow indicator</E> means a device which indicates whether gas flow is, or whether the valve position would allow gas flow to be, present in a line.</P> <P> <E T="03">Formulation</E> means the process of mixing, blending, or diluting one or more active or inert ingredients with one or more active or inert ingredients, without an intended chemical reaction, to obtain a pharmaceutical dosage form. Formulation operations include mixing, compounding, blending, and tablet coating.</P> <P> <E T="03">Group of processes</E> means all of the equipment associated with processes in a building, processing area, or facility-wide. For a dedicated process, a group of processes may consist of a single process.</P> <P> <E T="03">Halogen atoms</E> mean atoms of chlorine or fluorine.</P> <P> <E T="03">Halogenated compounds</E> means organic HAP compounds that contain halogen atoms.</P> <P> <E T="03">Halogenated vent stream or Halogenated stream</E> means a process, storage tank, or waste management unit vent determined to have a concentration of halogenated compounds of greater than 20 ppmv, as determined through process knowledge, test results using Method 18 of 40 CFR part 60, appendix A, or test results using any other test method that has been validated according to the procedures in Method 301 of appendix A of this part.</P> <P> <E T="03">Hard-piping</E> means piping or tubing that is manufactured and properly installed using good engineering judgment and standards, such as ANSI B31-3.</P> <P> <E T="03">Hydrogen halides and halogens</E> means hydrogen chloride (HCl), chlorine (Cl<E T="51">2</E>), and hydrogen fluoride (HF).</P> <P> <E T="03">In gas/vapor service</E> means that a piece of equipment in organic hazardous air pollutant service contains a gas or vapor at operating conditions.</P> <P> <E T="03">In heavy liquid service</E> means that a piece of equipment in organic hazardous air pollutant service is not in gas/vapor service or in light liquid service.</P> <P> <E T="03">In light liquid service</E> means that a piece of equipment in organic hazardous air pollutant service contains a liquid that meets the following conditions:<PRTPAGE P="19"/> </P> <P>(1) The vapor pressure of one or more of the organic compounds is greater than 0.3 kilopascals at 20°C;</P> <P>(2) The total concentration of the pure organic compounds constituents having a vapor pressure greater than 0.3 kilopascals at 20°C is equal to or greater than 20 percent by weight of the total process stream; and</P> <P>(3) The fluid is a liquid at operating conditions. (Note: Vapor pressures may be determined by the methods described in 40 CFR 60.485(e)(1).)</P> <P> <E T="03">In liquid service</E> means that a piece of equipment in organic hazardous air pollutant service is not in gas/vapor service.</P> <P> <E T="03">In organic hazardous air pollutant</E> or in organic HAP service means that a piece of equipment either contains or contacts a fluid (liquid or gas) that is at least 5 percent by weight of total organic HAP's as determined according to the provisions of § 63.180(d). The provisions of § 63.180(d) also specify how to determine that a piece of equipment is not in organic HAP service.</P> <P> <E T="03">In vacuum service</E> means that equipment is operating at an internal pressure which is at least 5 kilopascals below ambient pressure.</P> <P> <E T="03">In-situ sampling systems</E> means nonextractive samplers or in-line samplers.</P> <P> <E T="03">Individual drain system</E> means the stationary system used to convey wastewater streams or residuals to a waste management unit. The term includes hard piping; all process drains and junction boxes; and associated sewer lines, other junction boxes, manholes, sumps, and lift stations conveying wastewater streams or residuals. A segregated stormwater sewer system, which is a drain and collection system designed and operated for the sole purpose of collecting rainfall-runoff at a facility, and which is segregated from all other individual drain systems, is excluded from this definition.</P> <P> <E T="03">Initial startup</E> means the first time a new or reconstructed source begins production. Initial startup does not include operation solely for testing equipment. Initial startup does not include subsequent start ups (as defined in this section) of processes following malfunctions or process shutdowns.</P> <P> <E T="03">Internal floating roof</E> means a cover that rests or floats on the liquid surface (but not necessarily in complete contact with it) inside a storage tank or waste management unit that has a permanently affixed roof.</P> <P> <E T="03">Instrumentation system</E> means a group of equipment components used to condition and convey a sample of the process fluid to analyzers and instruments for the purpose of determining process operating conditions (e.g., composition, pressure, flow, etc.). Valves and connectors are the predominant type of equipment used in instrumentation systems; however, other types of equipment may also be included in these systems. Only valves nominally 0.5 inches and smaller, and connectors nominally 0.75 inches and smaller in diameter are considered instrumentation systems for the purposes of this subpart. Valves greater than nominally 0.5 inches and connectors greater than nominally 0.75 inches associated with instrumentation systems are not considered part of instrumentation systems and must be monitored individually.</P> <P> <E T="03">Junction box</E> means a manhole or access point to a wastewater sewer system line or a lift station.</P> <P> <E T="03">Large control device</E> means a control device that controls process vents with total emissions of greater than or equal to 10 tons of HAP per year, before control.</P> <P> <E T="03">Liquid-mounted seal</E> means a foam- or liquid-filled seal mounted in contact with the liquid between the wall of the storage tank or waste management unit and the floating roof. The seal is mounted continuously around the tank or unit.</P> <P> <E T="03">Liquids dripping</E> means any visible leakage from the seal including dripping, spraying, misting, clouding, and ice formation. Indications of liquid dripping include puddling or new stains that are indicative of an existing evaporated drip.</P> <P> <E T="03">Malfunction</E> means any sudden, infrequent, and not reasonably preventable failure of air pollution control equipment, emissions monitoring equipment, process equipment, or a process to operate in a normal or usual manner. Failures that are caused all or in <PRTPAGE P="20"/>part by poor maintenance or careless operation are not malfunctions.</P> <P> <E T="03">Maximum true vapor pressure</E> means the equilibrium partial pressure exerted by the total organic HAP in the stored or transferred liquid at the temperature equal to the highest calendar-month average of the liquid storage or transferred temperature for liquids stored or transferred above or below the ambient temperature or at the local maximum monthly average temperature as reported by the National Weather Service for liquids stored or transferred at the ambient temperature, as determined:</P> <P>(1) In accordance with methods described in Chapter 19.2 of the American Petroleum Institute's Manual of Petroleum Measurement Standards, Evaporative Loss From Floating-Roof Tanks (incorporated by reference as specified in § 63.14); or</P> <P>(2) As obtained from standard reference texts; or</P> <P>(3) As determined by the American Society for Testing and Materials Method D2879-97, Test Method for Vapor Pressure-Temperature Relationship and Initial Decomposition Temperature of Liquids by Isoteniscope (incorporated by reference as specified in § 63.14); or</P> <P>(4) Any other method approved by the Administrator.</P> <P> <E T="03">Metallic shoe seal or mechanical shoe seal</E> means metal sheets that are held vertically against the wall of the storage tank by springs, weighted levers, or other mechanisms and connected to the floating roof by braces or other means. A flexible coated fabric (envelope) spans the annular space between the metal sheet and the floating roof.</P> <P> <E T="03">Nondedicated formulation operations</E> means equipment used to formulate numerous products.</P> <P> <E T="03">Nondedicated recovery device(s)</E> means a recovery device that receives material from more than one PMPU.</P> <P> <E T="03">Nonrepairable</E> means that it is technically infeasible to repair a piece of equipment from which a leak has been detected without a process shutdown.</P> <P> <E T="03">Open biological treatment process</E> means a biological treatment process that is not a closed biological treatment process as defined in this section.</P> <P> <E T="03">Open-ended valve or line</E> means any valve, except pressure relief valves, having one side of the valve seat in contact with process fluid and one side open to atmosphere, either directly or through open piping.</P> <P> <E T="03">Operating scenario</E> for the purposes of reporting and recordkeeping, means any specific operation of a PMPU and includes for each process:</P> <P>(1) A description of the process and the type of process equipment used;</P> <P>(2) An identification of related process vents and their associated emissions episodes and durations, wastewater PODs, and storage tanks;</P> <P>(3) The applicable control requirements of this subpart, including the level of required control;</P> <P>(4) The control or treatment devices used, as applicable, including a description of operating and/or testing conditions for any associated control device;</P> <P>(5) The process vents, wastewater PODs, and storage tanks (including those from other processes) that are simultaneously routed to the control or treatment device(s);</P> <P>(6) The applicable monitoring requirements of this subpart and any parametric level that assures compliance for all emissions routed to the control or treatment device;</P> <P>(7) Calculations and engineering analyses required to demonstrate compliance; and</P> <P>(8) A verification that the operating conditions for any associated control or treatment device have not been exceeded and that any required calculations and engineering analyses have been performed. For reporting purposes, a change to any of these elements not previously reported, except for paragraph (5) of this definition, shall constitute a new operating scenario.</P> <P> <E T="03">Partially soluble HAP</E> means a HAP listed in Table 2 of this subpart.</P> <P> <E T="03">Pharmaceutical manufacturing operations</E> means the facility-wide collection of PMPU's and any other equipment such as heat exchanger systems, or cooling towers that are not associated with an individual PMPU, but that are located at a facility for the purpose of manufacturing pharmaceutical products and are under common control.<PRTPAGE P="21"/> </P> <P> <E T="03">Pharmaceutical manufacturing process unit (PMPU)</E> means the process, as defined in this subpart, and any associated storage tanks, equipment identified in § 63.1252(f), and components such as pumps, compressors, agitators, pressure relief devices, sampling connection systems, open-ended valves or lines, valves, connectors, and instrumentation systems that are used in the manufacturing of a pharmaceutical product.</P> <P> <E T="03">Pharmaceutical product</E> means:</P> <P>(1) Any material described by the standard industrial classification (SIC) code 2833 or 2834;</P> <P>(2) Any material whose manufacturing process is described by north american industrial classification system (NAICS) code 325411 or 325412;</P> <P>(3) A finished dosage form of a drug, for example, a tablet, capsule, solution, etc., that contains an active ingredient generally, but not necessarily, in association with inactive ingredients; or</P> <P>(4) Any component whose intended primary use is to furnish pharmacological activity or other direct effect in the diagnosis, cure, mitigation, treatment, or prevention of disease, or to affect the structure or any function of the body of man or other animals (the term does not include excipients, but includes drug components such as raw starting materials or precursors that undergo chemical change or processing before they become active ingredients).</P> <P> <E T="03">Plant site</E> means all contiguous or adjoining property that is under common control, including properties that are separated only by a road or other public right-of-way. Common control includes properties that are owned, leased, or operated by the same entity, parent entity, subsidiary, or any combination thereof.</P> <P> <E T="03">Point of determination (POD)</E> means the point where a wastewater stream exits the process, storage tank, or last recovery device. If soluble and/or partially soluble HAP compounds are not recovered from water before discharge, the discharge point from the process equipment or storage tank is a POD. If water streams are routed to a recovery device, the discharge from the recovery device is a POD. There can be more than 1 POD per process or PMPU.</P> <P> <E T="03">Pressure release</E> means the emission of materials resulting from the system pressure being greater than the set pressure of the pressure relief device. This release can be one release or a series of releases over a short time period due to a malfunction in the process.</P> <P> <E T="03">Pressure relief device or valve</E> means a safety device used to prevent operating pressures from exceeding the maximum allowable working pressure of the process equipment. A common pressure relief device is a spring-loaded pressure relief valve. Devices that are actuated either by a pressure of less than or equal to 2.5 psig or by a vacuum are not pressure relief devices.</P> <P> <E T="03">Primary use</E> means the single largest use of a material.</P> <P> <E T="03">Process</E> means all equipment which collectively function to produce a pharmaceutical product. A process may consist of one or more unit operations. For the purposes of this subpart, process includes all or a combination of reaction, recovery, separation, purification, or other activity, operation, manufacture, or treatment which are used to produce a pharmaceutical product. Cleaning operations conducted are considered part of the process. The holding of the pharmaceutical product in tanks or other holding equipment for more than 30 consecutive days, or transfer of the pharmaceutical product to containers for shipment, marks the end of a process, and the tanks are considered part of the PMPU that produced the stored material. When material from one unit operation is used as the feedstock for the production of two or more different pharmaceutical products, the unit operation is considered the endpoint of the process that produced the material, and the unit operations into which the material is routed mark the beginning of the other processes. Nondedicated recovery devices located within a contiguous area within the affected source are considered single processes. Nondedicated formulation operations occurring within a contiguous area are considered a single process that is used to formulate numerous materials and/or products. Quality Assurance and Quality Control laboratories are not considered part of any process.<PRTPAGE P="22"/> </P> <P> <E T="03">Process condenser</E> means a condenser whose primary purpose is to recover material as an integral part of a process. The condenser must support a vapor-to-liquid phase change for periods of source equipment operation that are at or above the boiling or bubble point of substance(s) at the liquid surface. Examples of process condensers include distillation condensers, reflux condensers, and condensers used in stripping or flashing operations. In a series of condensers, all condensers up to and including the first condenser with an exit gas temperature below the boiling or bubble point of the substance(s) at the liquid surface are considered to be process condensers. All condensers in line prior to a vacuum source are included in this definition.</P> <P> <E T="03">Process shutdown</E> means a work practice or operational procedure that stops production from a process or part of a process during which it is technically feasible to clear process material from a process or part of a process consistent with safety constraints and during which repairs can be effected. An unscheduled work practice or operational procedure that stops production from a process or part of a process for less than 24 hours is not a process shutdown. An unscheduled work practice or operational procedure that would stop production from a process or part of a process for a shorter period of time than would be required to clear the process or part of the process of materials and start up the process, and would result in greater emissions than delay of repair of leaking components until the next scheduled process shutdown, is not a process shutdown. The use of spare equipment and technically feasible bypassing of equipment without stopping production are not process shutdowns.</P> <P> <E T="03">Process tank</E> means a tank that is used to collect material discharged from a feedstock storage tank or unit operation within the process and transfer this material to another unit operation within the process or to a product storage tank. Surge control vessels and bottoms receivers that fit these conditions are considered process tanks.</P> <P> <E T="03">Process vent</E> means a vent from a unit operation or vents from multiple unit operations within a process that are manifolded together into a common header, through which a HAP-containing gas stream is, or has the potential to be, released to the atmosphere. Examples of process vents include, but are not limited to, vents on condensers used for product recovery, bottom receivers, surge control vessels, reactors, filters, centrifuges, and process tanks. Emission streams that are undiluted and uncontrolled containing less than 50 ppmv HAP, as determined through process knowledge that no HAP are present in the emission stream or using an engineering assessment as discussed in § 63.1257(d)(2)(ii), test data using Methods 18 of 40 CFR part 60, appendix A, or any other test method that has been validated according to the procedures in Method 301 of appendix A of this part, are not considered process vents. Process vents do not include vents on storage tanks regulated under § 63.1253, vents on wastewater emission sources regulated under § 63.1256, or pieces of equipment regulated under § 63.1255.</P> <P> <E T="03">Production-indexed HAP consumption factor</E> is the result of dividing the annual consumption of total HAP by the annual production rate, per process.</P> <P> <E T="03">Production-indexed volatile organic compound (VOC) consumption factor</E> is the result of dividing the annual consumption of total VOC by the annual production rate, per process.</P> <P> <E T="03">Publicly owned treatment works (POTW)</E> means any devices and systems used in the storage, treatment, recycling, and reclamation of municipal sewage or industrial wastes of a liquid nature as defined in section 212(2)(A) of the Clean Water Act, as amended [33 U.S.C. § 1292(2)(A)]. A POTW includes the treatment works, intercepting sewers, outfall sewers, sewage collection systems, pumping, power, and other equipment. The POTW is defined at 40 CFR 403.3(o).</P> <P> <E T="03">Reactor</E> means a device or vessel in which one or more chemicals or reactants, other than air, are combined or decomposed in such a way that their molecular structures are altered and one or more new organic compounds are formed.</P> <P> <E T="03">Recovery device,</E> as used in the wastewater provisions, means an individual <PRTPAGE P="23"/>unit of equipment used for the purpose of recovering chemicals for fuel value (i.e., net positive heating value), use, reuse, or for sale for fuel value, use or reuse. Examples of equipment that may be recovery devices include organic removal devices such as decanters, strippers, or thin-film evaporation units. To be a recovery device, a decanter and any other equipment based on the operating principle of gravity separation must receive only two-phase liquid streams.</P> <P> <E T="03">Repaired</E> means that equipment is adjusted, or otherwise altered, to eliminate a leak as defined in the applicable sections of § 63.1255.</P> <P> <E T="03">Research and development facility</E> means any stationary source whose primary purpose is to conduct research and development into new processes and products, where such source is operated under the close supervision of technically trained personnel, and is not engaged in the manufacture of products for commercial sale in commerce, except in a de minimis manner.</P> <P> <E T="03">Residual</E> means any HAP-containing liquid or solid material that is removed from a wastewater stream by a waste management unit or treatment process that does not destroy organics (nondestructive unit). Examples of residuals from nondestructive waste management units are: the organic layer and bottom residue removed by a decanter or organic-water separator and the overheads from a steam stripper or air stripper. Examples of materials which are not residuals are: silt; mud; leaves; bottoms from a steam stripper or air stripper; and sludges, ash, or other materials removed from wastewater being treated by destructive devices such as biological treatment units and incinerators.</P> <P> <E T="03">Safety device</E> means a closure device such as a pressure relief valve, frangible disc, fusible plug, or any other type of device which functions exclusively to prevent physical damage or permanent deformation to a unit or its air emission control equipment by venting gases or vapors directly to the atmosphere during unsafe conditions resulting from an unplanned, accidental, or emergency event. For the purposes of this subpart, a safety device is not used for routine venting of gases or vapors from the vapor headspace underneath a cover such as during filling of the unit or to adjust the pressure in this vapor headspace in response to normal daily diurnal ambient temperature fluctuations. A safety device is designed to remain in a closed position during normal operations and open only when the internal pressure, or another relevant parameter, exceeds the device threshold setting applicable to the air emission control equipment as determined by the owner or operator based on manufacturer recommendations, applicable regulations, fire protection and prevention codes, standard engineering codes and practices, or other requirements for the safe handling of flammable, combustible, explosive, reactive, or hazardous materials.</P> <P> <E T="03">Sampling connection system</E> means an assembly of equipment within a process unit used during periods of representative operation to take samples of the process fluid. Equipment used to take nonroutine grab samples is not considered a sampling connection system.</P> <P> <E T="03">Sensor</E> means a device that measures a physical quantity or the change in a physical quantity, such as temperature, pressure, flow rate, pH, or liquid level.</P> <P> <E T="03">Set pressure</E> means the pressure at which a properly operating pressure relief device begins to open to relieve atypical process system operating pressure.</P> <P> <E T="03">Sewer line</E> means a lateral, trunk line, branch line, or other conduit including, but not limited to, grates, trenches, etc., used to convey wastewater streams or residuals to a downstream waste management unit.</P> <P> <E T="03">Shutdown</E> means the cessation of operation of a PMPU or an individual piece of equipment required or used to comply with this part or for emptying and degassing storage tanks. Shutdown occurs for purposes including but not limited to: periodic maintenance, replacement of equipment, or repair. Shutdown does not apply to routine batch operations or the rinsing or washing of equipment in batch operations between batches.</P> <P> <E T="03">Single-seal system</E> means a floating roof having one continuous seal that completely covers the space between <PRTPAGE P="24"/>the wall of the storage tank and the edge of the floating roof. This seal may be a vapor-mounted, liquid-mounted, or metallic shoe seal.</P> <P> <E T="03">Small control device</E> means a control device that controls process vents with total emissions of less than 10 tons of HAP per year, before control.</P> <P> <E T="03">Soluble HAP</E> means a HAP listed in Table 3 of this subpart.</P> <P> <E T="03">Startup</E> means the first time a new or reconstructed source begins production, or, for new equipment added, including equipment used to comply with this subpart, the first time the equipment is put into operation, or for the introduction of a new product/process, the first time the product or process is run in equipment. As used in § 63.1255, startup means the setting in operation of a piece of equipment or a control device that is subject to this subpart.</P> <P> <E T="03">Storage tank</E> means a tank or other vessel that is used to store organic liquids that contain one or more HAP as feedstocks or products of a PMPU. The following are not considered storage tanks for the purposes of this subpart:</P> <P>(1) Vessels permanently attached to motor vehicles such as trucks, railcars, barges, or ships;</P> <P>(2) Pressure vessels designed to operate in excess of 204.9 kilopascals and without emissions to the atmosphere;</P> <P>(3) Vessels storing organic liquids that contain HAP only as impurities;</P> <P>(4) Wastewater storage tanks; and</P> <P>(5) Process tanks.</P> <P> <E T="03">Surface impoundment</E> means a waste management unit which is a natural topographic depression, manmade excavation, or diked area formed primarily of earthen materials (although it may be lined with manmade materials), which is designed to hold an accumulation of liquid wastes or waste containing free liquids. A surface impoundment is used for the purpose of treating, storing, or disposing of wastewater or residuals, and is not an injection well. Examples of surface impoundments are equalization, settling, and aeration pits, ponds, and lagoons.</P> <P> <E T="03">Total organic compounds (TOC)</E> means those compounds measured according to the procedures of Method 18 or Method 25A, 40 CFR part 60, appendix A.</P> <P> <E T="03">Treatment process</E> means a specific technique that removes or destroys the organics in a wastewater or residual stream such as a steam stripping unit, thin-film evaporation unit, waste incinerator, biological treatment unit, or any other process applied to wastewater streams or residuals to comply with § 63.1256. Most treatment processes are conducted in tanks. Treatment processes are a subset of waste management units.</P> <P> <E T="03">Uncontrolled HAP emissions</E> means a gas stream containing HAP which has exited the process (or process condenser, if any), but which has not yet been introduced into an air pollution control device to reduce the mass of HAP in the stream. If the process vent is not routed to an air pollution control device, uncontrolled emissions are those HAP emissions released to the atmosphere.</P> <P> <E T="03">Unit operation</E> means those processing steps that occur within distinct equipment that are used, among other things, to prepare reactants, facilitate reactions, separate and purify products, and recycle materials. Equipment used for these purposes includes but is not limited to reactors, distillation columns, extraction columns, absorbers, decanters, dryers, condensers, and filtration equipment.</P> <P> <E T="03">Vapor-mounted seal</E> means a continuous seal that completely covers the annular space between the wall, the storage tank or waste management unit and the edge of the floating roof and is mounted such that there is a vapor space between the stored liquid and the bottom of the seal.</P> <P> <E T="03">Volatile organic compounds (VOC)</E> means those materials defined in 40 CFR 51.100.</P> <P> <E T="03">Waste management unit</E> means the equipment, structure(s),and or devices used to convey, store, treat, or dispose of wastewater streams or residuals. Examples of waste management units include wastewater tanks, air flotation units, surface impoundments, containers, oil-water or organic-water separators, individual drain systems, biological wastewater treatment units, waste incinerators, and organic removal devices such as steam and air stripper units, and thin film evaporation units. If such equipment is used <PRTPAGE P="25"/>for recovery then it is part of a pharmaceutical process and is not a waste management unit.</P> <P> <E T="03">Wastewater</E> means any portion of an individual wastewater stream or any aggregation of wastewater streams.</P> <P> <E T="03">Wastewater stream</E> means water that is discarded from a PMPU through a single POD, that contains an annual average concentration of partially soluble and/or soluble HAP compounds of at least 5 parts per million by weight and a load of at least 0.05 kg/yr, and that is not exempted by the provisions of § 63.1256(a)(3). For the purposes of this subpart, noncontact cooling water is not considered a wastewater stream. Wastewater streams are generated by both process operations and maintenance activities.</P> <P> <E T="03">Wastewater tank</E> means a stationary waste management unit that is designed to contain an accumulation of wastewater or residuals and is constructed primarily of nonearthen materials (e.g., wood, concrete, steel, plastic) which provide structural support. Wastewater tanks used for flow equalization are included in this definition.</P> <P> <E T="03">Water seal controls</E> means a seal pot, p-leg trap, or other type of trap filled with water (e.g., flooded sewers that maintain water levels adequate to prevent air flow through the system) that creates a water barrier between the sewer line and the atmosphere. The water level of the seal must be maintained in the vertical leg of a drain in order to be considered a water seal.</P> </SECTION> <SECTION> <SECTNO>§ 63.1252</SECTNO> <SUBJECT>Standards: General.</SUBJECT> <P>Each owner or operator of any affected source subject to the provisions of this subpart shall control HAP emissions to the level specified in this section on and after the compliance dates specified in § 63.1250(f). Compliance with the emission limits may be demonstrated initially through the provisions of § 63.1257 (Test methods and compliance procedures) and continuously through the provisions of § 63.1258 (Monitoring requirements).</P> <P>(a) <E T="03">Opening of a safety device.</E> Opening of a safety device, as defined in § 63.1251, is allowed at any time conditions require it to do so to avoid unsafe conditions.</P> <P>(b) <E T="03">Closed-vent systems.</E> The owner or operator of a closed-vent system that contains bypass lines that could divert a vent stream away from a control device used to comply with the requirements in §§ 63.1253, 63.1254, and 63.1256 shall comply with the requirements of Table 4 to this subpart and paragraph (b)(1) or (2) of this section. Equipment such as low leg drains, high point bleeds, analyzer vents, open-ended valves or lines, rupture disks and pressure relief valves needed for safety purposes are not subject to this paragraph.</P> <P>(1) Install, calibrate, maintain, and operate a flow indicator that determines whether vent stream flow is present at least once every 15 minutes. Records shall be maintained as specified in § 63.1259(i)(6)(i). The flow indicator shall be installed at the entrance to any bypass line that could divert the vent stream away from the control device to the atmosphere; or</P> <P>(2) Secure the bypass line valve in the closed position with a car seal or lock and key type configuration. A visual inspection of the seal or closure mechanism shall be performed at least once every month to ensure that the valve is maintained in the closed position and the vent stream is not diverted through the bypass line. Records shall be maintained as specified in § 63.1259(i)(6)(ii).</P> <P>(c) <E T="03">Heat exchange systems.</E> Except as provided in paragraph (c)(2) of this section, owners and operators of affected sources shall comply with the requirements in paragraph (c)(1) of this section for heat exchange systems that cool process equipment or materials used in pharmaceutical manufacturing operations.</P> <P>(1) The heat exchange system shall be treated according to the provisions of § 63.104, except that the monitoring frequency shall be no less than quarterly.</P> <P>(2) For identifying leaking equipment, the owner or operator of heat exchange systems on equipment which meet current good manufacturing practice (CGMP) requirements of 21 CFR part 211 may elect to use the physical integrity of the reactor as the surrogate indicator of heat exchange system leaks around the reactor.</P> <P>(d) <E T="03">Emissions averaging provisions.</E> Except as specified in paragraphs (d)(1) <PRTPAGE P="26"/>through (5) of this section, owners or operators of storage tanks or processes subject to the provisions of §§ 63.1253 and 63.1254 may choose to comply by using emissions averaging requirements specified in § 63.1257(g) or (h) for any storage tank or process.</P> <P>(1) A State may prohibit averaging of HAP emissions and require the owner or operator of an existing source to comply with the provisions in §§ 63.1253 and 63.1254.</P> <P>(2) Only emission sources subject to the requirements of § 63.1253(b)(1) and (c)(1) or § 63.1254(a)(2), (a)(3)(ii)(A) or (a)(3)(iii) may be included in any averaging group.</P> <P>(3) Processes which have been permanently shutdown or storage tanks permanently taken out of HAP service may not be included in any averaging group.</P> <P>(4) Processes and storage tanks already controlled on or before November 15, 1990 may not be included in an emissions averaging group, except where the level of control is increased after November 15, 1990. In these cases, the uncontrolled emissions shall be the controlled emissions as calculated on November 15, 1990 for the purpose of determining the uncontrolled emissions as specified in § 63.1257(g) and (h).</P> <P>(5) Emission points controlled to comply with a State or Federal rule other than this subpart may not be included in an emission averaging group, unless the level of control has been increased after November 15, 1990 above what is required by the other State or Federal rule. Only the control above what is required by the other State or Federal rule will be credited. However, if an emission point has been used to generate emissions averaging credit in an approved emissions average, and the point is subsequently made subject to a State or Federal rule other than this subpart, the point can continue to generate emissions averaging credit for the purpose of complying with the previously approved average.</P> <P>(6) Not more than 20 processes subject to § 63.1254(a)(2)(i), 20 storage tanks subject to § 63.1253(b)(1), and 20 storage tanks subject to § 63.1253(c)(1)(i) at an affected source may be included in an emissions averaging group.</P> <P>(7) Compliance with the emissions standards in § 63.1253 shall be satisfied when the annual percent reduction efficiency is greater than or equal to 90 percent for those tanks meeting the requirements of § 63.1253(a)(1) and 95 percent for those tanks meeting the requirements of § 63.1253(a)(2), as demonstrated using the test methods and compliance procedures specified in § 63.1257(g).</P> <P>(8) Compliance with the emissions standards in § 63.1254(a)(2) shall be satisfied when the annual percent reduction efficiency is greater than or equal to 93 percent, as demonstrated using the test methods and compliance procedures specified in § 63.1257(h).</P> <P>(e) <E T="03">Pollution prevention alternative.</E> Except as provided in paragraph (e)(1) of this section, owners and operators may choose to meet the pollution prevention alternative requirement specified in either paragraph (e)(2) or (3) of this section for any PMPU, in lieu of the requirements specified in §§ 63.1253, 63.1254, 63.1255, and 63.1256. Compliance with paragraphs (e)(2) and (3) of this section shall be demonstrated through the procedures in § 63.1257(f).</P> <P>(1) The HAP that are generated in the PMPU that are not part of the production-indexed consumption factor must be controlled according to the requirements of §§ 63.1253, 63.1254, 63.1255, and 63.1256. The HAP that are generated as a result of combustion control of emissions must be controlled according to the requirements of paragraph (g) of this section.</P> <P>(2) The production-indexed HAP consumption factor (kg HAP consumed/kg produced) shall be reduced by at least 75 percent from a 3 year average baseline established no earlier than the 1987 calendar year, or for the time period from startup of the process until the present in which the PMPU was operational and data are available, whichever is the lesser time period. If a time period less than 3 years is used to set the baseline, the data must represent at least 1 year's worth of data. For any reduction in the HAP factor achieved by reducing a HAP that is also a VOC, an equivalent reduction in the VOC factor is also required. For any reduction in the HAP factor that is achieved <PRTPAGE P="27"/>by reducing a HAP that is not a VOC, the VOC factor may not be increased.</P> <P>(3) Both requirements specified in paragraphs (e)(3)(i) and (ii) of this section are met.</P> <P>(i) The production-indexed HAP consumption factor (kg HAP consumed/kg produced) shall be reduced by at least 50 percent from a 3-year average baseline established no earlier than the 1987 calendar year, or for the time period from startup of the process until the present in which the PMPU was operational and data are available, whichever is less. If a time period less than 3 years is used to set the baseline, the data must represent at least 1 year's worth of data. For any reduction in the HAP factor achieved by reducing a HAP that is also a VOC, an equivalent reduction in the VOC factor is also required. For any reduction in the HAP factor that is achieved by reducing a HAP that is not a VOC, the VOC factor may not be increased.</P> <P>(ii) The total PMPU HAP emissions shall be reduced by an amount, in kg/yr, that, when divided by the annual production rate, in kg/yr, and added to the reduction of the production-indexed HAP consumption factor, in kg/kg, yields a value of at least 75 percent of the average baseline HAP production-indexed consumption factor established according to paragraph (e)(3)(i) of this section according to the equation provided in § 63.1257(f)(2)(ii)(A). The total PMPU VOC emissions shall be reduced by an amount calculated according to the equation provided in § 63.1257(f)(2)(ii)(B). The annual reduction in HAP and VOC air emissions must be due to the use of the following control devices:</P> <P>(A) Combustion control devices such as incinerators, flares or process heaters.</P> <P>(B) Control devices such as condensers and carbon adsorbers whose recovered product is destroyed or shipped offsite for destruction.</P> <P>(C) Any control device that does not ultimately allow for recycling of material back to the PMPU.</P> <P>(D) Any control device for which the owner or operator can demonstrate that the use of the device in controlling HAP emissions will have no effect on the production-indexed consumption factor for the PMPU.</P> <P>(f) <E T="03">Control requirements for certain liquid streams in open systems within a PMPU.</E> (1) The owner or operator shall comply with the provisions of Table 5 of this subpart, for each item of equipment meeting all the criteria specified in paragraphs (f)(2) through (4) and either paragraph (f)(5)(i) or (ii) of this section.</P> <P>(2) The item of equipment is of a type identified in Table 5 of this subpart;</P> <P>(3) The item of equipment is part of a PMPU, as defined in § 63.1251;</P> <P>(4) The item of equipment is controlled less stringently than in Table 5 of this subpart and the item of equipment is not otherwise exempt from controls by the provisions of this subpart or subpart A of this part; and</P> <P>(5) The item of equipment:</P> <P>(i) Is a drain, drain hub, manhole, lift station, trench, pipe, or oil/water separator that conveys water with an annual average concentration greater than or equal to 1,300 parts per million by weight (ppmw) of partially soluble HAP compounds; or an annual average concentration greater than or equal to 5,200 ppmw of partially soluble and/or soluble HAP compounds. The annual average concentration shall be determined according to the procedures in § 63.1257(e)(1)(ii).</P> <P>(ii) Is a tank that receives one or more streams that contain water with an annual average concentration greater than or equal to 1,300 ppmw of partially soluble HAP compounds, or greater than or equal to 5,200 ppmw of total partially soluble and/or soluble HAP compounds. The owner or operator of the source shall determine the average concentration of the stream at the inlet to the tank and according to the procedures in § 63.1257(e)(1)(ii).</P> <P>(g) <E T="03">Control requirements for halogenated vent streams that are controlled by combustion devices.</E> If a combustion device is used to comply with the provisions of §§ 63.1253 (storage tanks), 63.1254 (process vents), 63.1256(h) (wastewater vent streams) for a halogenated vent stream, then the vent stream shall be ducted to a halogen reduction device such as, but not limited to, a scrubber, before it is discharged <PRTPAGE P="28"/>to the atmosphere. The halogen reduction device must reduce emissions by the amounts specified in either paragraph (g)(1) or (2) of this section.</P> <P>(1) A halogen reduction device after the combustion control device must reduce overall emissions of hydrogen halides and halogens, as defined in § 63.1251, by 95 percent or to a concentration less than or equal to 20 ppmv.</P> <P>(2) A halogen reduction device located before the combustion control device must reduce the halogen atom content of the vent stream to a concentration less than or equal to 20 ppmv.</P> </SECTION> <SECTION> <SECTNO>§ 63.1253</SECTNO> <SUBJECT>Standards: Storage tanks.</SUBJECT> <P>(a) Except as provided in paragraphs (d) and (e) of this section, the owner or operator of a storage tank meeting the criteria of paragraph (a)(1) of this section is subject to the requirements of paragraph (b) of this section. Except as provided in paragraphs (d) and (e) of this section, the owner or operator of a storage tank meeting the criteria of paragraph (a)(2) of this section is subject to the requirements of paragraph (c) of this section. Compliance with the provisions of paragraphs (b) and (c) of this section is demonstrated using the initial compliance procedures in § 63.1257(c) and the monitoring requirements in § 63.1258.</P> <P>(1) A storage tank with a design capacity greater than or equal to 38 m<E T="51">3</E> (10,000 gallons [gal]) but less than 75 m<E T="51">3</E> (20,000 gal), and storing a liquid for which the maximum true vapor pressure of total HAP is greater than or equal to 13.1 kPa (1.9 psia).</P> <P>(2) A storage tank with a design capacity greater than or equal to 75 m<E T="51">3</E> (20,000 gal) storing a liquid for which the maximum true vapor pressure of total HAP is greater than or equal to 13.1 kPa (1.9 psia).</P> <P>(b) The owner or operator of a storage tank shall equip the affected storage tank with either a fixed roof with internal floating roof, an external floating roof, an external floating roof converted to an internal floating roof, or a closed-vent system meeting the conditions of § 63.1252(b) with a control device that meets any of the following conditions:</P> <P>(1) Reduces inlet emissions of total HAP by 90 percent by weight or greater;</P> <P>(2) Is an enclosed combustion device that provides a minimum residence time of 0.5 seconds at a minimum temperature of 760° C;</P> <P>(3) Is a flare that meets the requirements of § 63.11(b); or</P> <P>(4) Is a control device specified in § 63.1257(a)(4).</P> <P>(c) The owner or operator of a storage tank shall equip the affected storage tank with either a fixed roof with internal floating roof, an external floating roof, an external floating roof converted to an internal floating roof, or a closed-vent system meeting the conditions of § 63.1252(b) with a control device that meets any of the following conditions:</P> <P>(1) Reduces inlet emissions of total HAP as specified in paragraph (c)(1) (i) or (ii) of this section:</P> <P>(i) By 95 percent by weight or greater; or (ii) If the owner or operator can demonstrate that a control device installed on a storage tank on or before April 2, 1997 is designed to reduce inlet emissions of total HAP by greater than or equal to 90 percent by weight but less than 95 percent by weight, then the control device is required to be operated to reduce inlet emissions of total HAP by 90 percent or greater.</P> <P>(2) Is an enclosed combustion device that provides a minimum residence time of 0.5 seconds at a minimum temperature of 760° C;</P> <P>(3) Is a flare that meets the requirements of § 63.11(b); or</P> <P>(4) Is a control device specified in § 63.1257(a)(4).</P> <P>(d) As an alternative standard, the owner or operator of an existing or new affected source may comply with the storage tank standards by routing storage tank vents to a control device achieving an outlet TOC concentration, as calibrated on methane or the predominant HAP, of 20 ppmv or less, and an outlet concentration of hydrogen halides and halogens of 20 ppmv or less. Compliance with the outlet concentrations shall be determined by the initial compliance procedures of § 63.1257(c)(4) and the continuous emission monitoring requirements of § 63.1258(b)(5).<PRTPAGE P="29"/> </P> <P>(e) <E T="03">Planned routine maintenance.</E> The specifications and requirements in paragraphs (b) through (d) of this section for control devices do not apply during periods of planned routine maintenance. Periods of planned routine maintenance of the control devices, during which the control device does not meet the specifications of paragraphs (b) through (d) of this section, as applicable, shall not exceed 240 hours per year.</P> </SECTION> <SECTION> <SECTNO>§ 63.1254</SECTNO> <SUBJECT>Standards: Process vents.</SUBJECT> <P>(a) <E T="03">Existing sources.</E> Except as provided in paragraph (c) of this section, the owner or operator of an existing affected source must control the collection of all gas streams originating from processes subject to this standard so as to comply with the requirements in paragraph (a)(1) or the requirements of paragraphs (a)(2) and (a)(3) of this section. If any vent within a process meets the criteria of paragraph (a)(3)(i) of this section, the owner or operator must comply with the provisions in paragraphs (a)(2) and (a)(3) for that process. The requirements of paragraphs (a) (1) and (2) of this section apply to all process vents within a process, as a group, and do not apply to individual vents. An owner or operator may switch from compliance with paragraph (a)(1) of this section to compliance with paragraphs (a) (2) and (3) of this section only after at least 1 year of operation in compliance with paragraph (a)(1) of this section. An owner or operator may switch from compliance with paragraphs (a) (2) and (3) of this section to compliance with paragraph (a)(1) of this section at any time. Notification of such a change in the compliance method shall be reported according to the procedures in § 63.1260(h) of this subpart. Compliance with the required emission limits or reductions in paragraphs (a) (1) through (3) of this section may be demonstrated using the initial compliance procedures described in § 63.1257(d) and the monitoring requirements described in § 63.1258.</P> <P>(1) Except for processes with a vent that meets the conditions in paragraph (a)(3)(i) of this section, actual HAP emissions shall not exceed 900 kilograms (kg) per year [2,000 pounds per year] from the sum of all process vents within a process.</P> <P>(i) Except as provided in paragraph (a)(1)(ii) of this section, the owner or operator is limited to 7 processes in any 365-day period that can be selected to comply with paragraph (a)(1) of this section.</P> <P>(ii) The owner or operator may exclude processes with less than 100 lb/yr HAP, on an uncontrolled basis, from the 7-process limit described in paragraph (a)(1)(i) of this section.</P> <P>(2) Uncontrolled HAP emissions from the sum of all process vents within a process that do not meet the conditions in paragraph (a)(3)(i) of this section or are not controlled according to any of the requirements of paragraphs (a)(2)(i), (a)(2)(ii), (a)(2)(iii), or (c) of this section shall be reduced by 93 percent or greater by weight.</P> <P>(i) To outlet concentrations less than or equal to 20 ppmv as TOC and less than or equal to 20 ppmv as hydrogen halides and halogens;</P> <P>(ii) By a flare that meets the requirements of § 63.11(b); or (iii) By a control device specified in § 63.1257(a)(4).</P> <P>(3) Except as provided in paragraph (a)(3)(iii) of this section, uncontrolled HAP emissions from each process vent that meets the conditions in paragraph (a)(3)(i) of this section shall be reduced as specified in paragraph (a)(3)(ii) of this section.</P> <P>(i) Uncontrolled HAP emissions from a process vent shall be reduced as specified in paragraph (a)(3)(ii) if the vent meets either of the criteria described in paragraph (a)(3)(i) (A) or (B) of this section:</P> <P>(A) The flow-weighted average flowrate calculated using Equation 1 of this subpart is less than or equal to the flowrate calculated using Equation 2 of this subpart.</P> <GPH DEEP="59" SPAN="1"> <GID>ER21SE98.000</GID> </GPH> <GPH DEEP="12" SPAN="1"> <GID>ER21SE98.001</GID> </GPH> <FP SOURCE="FP-2">Where:</FP> <PRTPAGE P="30"/> <FP SOURCE="FP-2">FR<E T="52">a</E> = flow-weighted average flowrate for the vent, scfm</FP> <FP SOURCE="FP-2">D<E T="52">i</E> = duration of each emission event, min</FP> <FP SOURCE="FP-2">FR<E T="52">i</E> = flowrate of each emission event, scfm</FP> <FP SOURCE="FP-2">n = number of emission events</FP> <FP SOURCE="FP-2">FR = flowrate, scfm</FP> <FP SOURCE="FP-2">HL = annual uncontrolled HAP emissions, lb/yr, as defined in § 63.1251</FP> <P>(B) As an alternative to the criteria described in paragraph (a)(3)(i)(A) of this section, uncontrolled HAP emissions from a process vent shall be reduced or controlled as specified in paragraph (a)(3)(ii) of this section if the process vent meets the criteria specified in paragraphs (a)(3)(i)(B)(<E T="03">1</E>) and (<E T="03">2</E>) of this section or the criteria specified in paragraphs (a)(3)(i)(B)(<E T="03">1</E>) and (<E T="03">3</E>) of this section.</P> <P>(<E T="03">1</E>) Uncontrolled HAP emissions from the process vent exceed 25 tons per year.</P> <P>(<E T="03">2</E>) The flow-weighted average flowrate for the vent, as calculated in Equation 1 of this section, is less than or equal to 100 scfm.</P> <P>(<E T="03">3</E>) The flow weighted average is greater than 100 scfm and less than or equal to the flowrate calculated using Equation 2 of this section.</P> <P>(ii) Uncontrolled HAP emissions shall be reduced:</P> <P>(A) By 98 percent by weight or greater; or</P> <P>(B) To outlet concentrations less than or equal to 20 ppmv as TOC and less than or equal to 20 ppmv as hydrogen halides and halogens; or</P> <P>(C) By a flare that meets the requirements of § 63.11(b); or</P> <P>(D) By a control device specified in § 63.1257(a)(4).</P> <P>(iii) If the owner or operator can demonstrate that a control device, installed on a process vent that meets the conditions of paragraph (a)(3)(i) of this section on or before April 2, 1997, was designed to reduce uncontrolled HAP emissions of total HAP by greater than or equal to 93 percent by weight, but less than 98 percent by weight, then the control device is required to be operated to reduce inlet emissions of total HAP by 93 percent by weight or greater.</P> <P>(b) <E T="03">New sources.</E> Uncontrolled HAP emissions from the sum of all process vents within a process at a new affected source that are not controlled according to any of the requirements of paragraphs (b)(1), (2), or (3) of this section or paragraph (c) of this section shall be reduced by 98 percent or greater by weight if the uncontrolled HAP emissions from the sum of all process vents within a process is greater than 180 kg/yr (400 lb/yr). Compliance with the required emission limit or reduction is demonstrated using the initial compliance procedures in § 63.1257(d) and the monitoring requirements described in § 63.1258.</P> <P>(1) To outlet concentrations less than or equal to 20 ppmv as TOC and less than or equal to 20 ppmv as hydrogen halides and halogens;</P> <P>(2) By a flare that meets the requirements of § 63.11(b); or</P> <P>(3) By a control device specified in § 63.1257(a)(4).</P> <P>(c) As an alternative standard, the owner or operator of an existing or new affected source may comply with the process vent standards by routing all vents from a process to a control device achieving an outlet TOC concentration, as calibrated on methane or the predominant HAP, of 20 ppmv or less, and an outlet concentration of hydrogen halides and halogens of 20 ppmv or less. Any process vents within a process that are not routed to this control device must be controlled in accordance with the provisions of paragraphs (a)(2),(a)(3), and (b) of this section, as applicable. Compliance with the outlet concentrations shall be determined by the initial compliance procedures described in § 63.1257(d)(1)(iv) and the continuous emission monitoring requirements described in § 63.1258(b)(5).</P> </SECTION> <SECTION> <SECTNO>§ 63.1255</SECTNO> <SUBJECT>Standards: Equipment leaks.</SUBJECT> <P>(a) <E T="03">General Equipment Leak Requirements.</E> (1) The provisions of this section apply to pumps, compressors, agitators, pressure relief devices, sampling connection systems, open-ended valves or lines, valves, connectors, instrumentation systems, control devices, and closed-vent systems required by this subpart that are intended to operate in organic hazardous air pollutant service 300 hours or more during <PRTPAGE P="31"/>the calendar year within a source subject to the provisions of this subpart.</P> <P>(2) <E T="03">Consistency with other regulations.</E> After the compliance date for a process, equipment subject to both this section and either of the following will be required to comply only with the provisions of this subpart:</P> <P>(i) 40 CFR part 60.</P> <P>(ii) 40 CFR part 61.</P> <P>(3) [Reserved]</P> <P>(4) The provisions in § 63.1(a)(3) of subpart A of this part do not alter the provisions in paragraph (a)(2) of this section.</P> <P>(5) Lines and equipment not containing process fluids are not subject to the provisions of this section. Utilities, and other nonprocess lines, such as heating and cooling systems which do not combine their materials with those in the processes they serve, are not considered to be part of a process.</P> <P>(6) The provisions of this section do not apply to bench-scale processes, regardless of whether the processes are located at the same plant site as a process subject to the provisions of this subpart.</P> <P>(7) Each piece of equipment to which this section applies shall be identified such that it can be distinguished readily from equipment that is not subject to this section. Identification of the equipment does not require physical tagging of the equipment. For example, the equipment may be identified on a plant site plan, in log entries, or by designation of process boundaries by some form of weatherproof identification. If changes are made to the affected source subject to the leak detection requirements, equipment identification for each type of component shall be updated, if needed, within 15 calendar days of the end of each monitoring period for that component.</P> <P>(8) Equipment that is in vacuum service is excluded from the requirements of this section.</P> <P>(9) Equipment that is in organic HAP service, but is in such service less than 300 hours per calendar year, is excluded from the requirements of this section if it is identified as required in paragraph (g)(9) of this section.</P> <P>(10) When each leak is detected by visual, audible, or olfactory means, or by monitoring as described in § 63.180(b) or (c), the following requirements apply:</P> <P>(i) A weatherproof and readily visible identification, marked with the equipment identification number, shall be attached to the leaking equipment.</P> <P>(ii) The identification on a valve or connector in light liquid or gas/vapor service may be removed after it has been monitored as specified in paragraph (e)(7)(iii) of this section and § 63.174(e), and no leak has been detected during the follow-up monitoring.</P> <P>(iii) The identification on equipment, except on a valve or connector in light liquid or gas/vapor service, may be removed after it has been repaired.</P> <P>(b) <E T="03">References.</E> (1) The owner or operator of a source subject to this section shall comply with the following sections of subpart H, except for § 63.160, § 63.161, § 63.162, § 63.163, § 63.167, § 63.168, § 63.170, § 63.171, § 63.172, § 63.173, § 63.181, and § 63.182 of this subpart. In place of § 63.160 and § 63.162, the owner or operator shall comply with paragraph (a) of this section; in place of § 63.161, the owner or operator shall comply with § 63.1251 of this subpart; in place of § 63.163 and § 63.173, the owner or operator shall comply with paragraph (c) of this section; in place of § 63.167, the owner or operator shall comply with paragraph (d) of this section; in place of § 63.168, the owner or operator shall comply with paragraph (e) of this section; in place of § 63.170, the owner or operator shall comply with § 63.1254 of this subpart; in place of § 63.171, the owner or operator shall comply with paragraph (b)(1)(v) of this section; in place of § 63.172, the owner or operator shall comply with paragraph (b)(1)(vi) of this section; in place of § 63.181, the owner or operator shall comply with paragraph (g) of this section; in place of § 63.182, the owner or operator shall comply with paragraph (h) of this section. The term “process unit” as used in subpart H shall be considered to be defined the same as “group of processes” for sources subject to this subpart GGG.</P> <P>(i) Section 63.164, Compressors;</P> <P>(ii) Section 63.165, Pressure relief devices in gas/vapor service;</P> <P>(iii) Section 63.166, Sampling connection systems;<PRTPAGE P="32"/> </P> <P>(iv) Section 63.169, Pumps, valves, connectors, and agitators in heavy liquid service; instrumentation systems; and pressure relief devices in liquid service;</P> <P>(v) Section 63.171, Delay of repair, shall apply except § 63.171(a) shall not apply. Instead, delay of repair of equipment for which leaks have been detected is allowed if one of the following conditions exist:</P> <P>(A) The repair is technically infeasible without a process shutdown. Repair of this equipment shall occur by the end of the next scheduled process shutdown.</P> <P>(B) The owner or operator determines that repair personnel would be exposed to an immediate danger if attempting to repair without a process shutdown. Repair of this equipment shall occur by the end of the next scheduled process shutdown.</P> <P>(vi) Section 63.172, Closed-vent systems and control devices, for closed-vent systems used to comply with this subpart, and for control devices used to comply with this section only, except</P> <P>(A) Sections 63.172(k) and (l) shall not apply. In place of § 63.172(k) and (l), the owner or operator shall comply with paragraph (f) of this section.</P> <P>(B) Owners or operators may, instead of complying with the provisions of § 63.172(f), design a closed-vent system to operate at a pressure below atmospheric pressure. The system shall be equipped with at least one pressure gage or other pressure measurement device that can be read from a readily accessible location to verify that negative pressure is being maintained in the closed-vent system when the associated control device is operating.</P> <P>(vii) Section 63.174, Connectors, except:</P> <P>(A) Sections 63.174(f) and (g) shall not apply. In place of § 63.174(f) and (g), the owner or operator shall comply with paragraph (f) of this section.</P> <P>(B) Days that the connectors are not in organic HAP service shall not be considered part of the 3 month period in § 63.174(e).</P> <P>(C) Section 63.174(b)(3)(ii) shall not apply. Instead, if the percent leaking connectors in the process unit was less than 0.5 percent, but equal to or greater than 0.25 percent, during the last required monitoring period, monitoring shall be performed once every 4 years. An owner or operator may comply with the requirements of this paragraph by monitoring at least 40 percent of the connectors in the first 2 years and the remainder of the connectors within the next 2 years. The percent leaking connectors will be calculated for the total of all monitoring performed during the 4 year period.</P> <P>(D) Section 63.174(b)(3)(iv) shall not apply. Instead, the owner or operator shall increase the monitoring frequency to once every 2 years for the next monitoring period if leaking connectors comprise at least 0.5 percent but less than 1.0 percent of the connectors monitored within the 4 years specified in paragraph (b)(1)(vii)(C) of this section or the first 4 years specified in § 63.174(b)(3)(iii). At the end of that 2 year monitoring period, the owner or operator shall monitor once per year while the percent leaking connectors is greater than or equal to 0.5 percent; if the percent leaking connectors is less than 0.5 percent, the owner or operator may return to monitoring once every 4 years or may monitor in accordance with § 63.174(b)(3)(iii), if appropriate.</P> <P>(E) Section 63.174(b)(3)(v) shall not apply. Instead, if an owner or operator complying with the requirements of paragraph (b)(1)(vii)(C) and (D) of this section or § 63.174 (b)(3)(iii) for a group of processes determines that 1 percent or greater of the connectors are leaking, the owner or operator shall increase the monitoring frequency to one time per year. The owner or operator may again elect to use the provisions of paragraphs (b)(1)(vii)(C) or (D) of this section after a monitoring period in which less than 0.5 percent of the connectors are determined to be leaking.</P> <P>(F) Section 63.174(b)(3)(iii) shall not apply. Instead, monitoring shall be required once every 8 years, if the percent leaking connectors in the process unit was less than 0.25 percent during the last required monitoring period. An owner or operator shall monitor at least 50 percent of the connectors in the first 4 years and the remainder of the connectors within the next 4 years. If the percent leaking connectors in the first 4 years is equal to or greater <PRTPAGE P="33"/>than 0.35 percent, the monitoring program shall revert at that time to the appropriate monitoring frequency specified in paragraphs (b)(1)(vii)(C), (D), or (E) of this section.</P> <P>(viii) Section 63.177, Alternative means of emission limitation: General;</P> <P>(ix) Section 63.178, Alternative means of emission limitation: Batch processes, except that § 63.178(b), requirements for pressure testing, shall apply to all processes, not just batch processes;</P> <P>(x) Section 63.179, Alternative means of emission limitation: Enclosed-vented process units;</P> <P>(xi) Section 63.180, Test methods and procedures, except § 63.180(b)(4)(ii)(A) through (C) shall not apply. Instead calibration gases shall be a mixture of methane and air at a concentration of approximately, but less than, 10,000 parts per million methane for agitators; 2,000 parts per million for pumps; and 500 parts per million for all other equipment, except as provided in section 63.180(b)(4)(iii).</P> <P>(2) [Reserved]</P> <P>(c) <E T="03">Standards for Pumps in Light Liquid Service and Agitators in Gas/Vapor Service and in Light Liquid Service.</E> (1) The provisions of this section apply to each pump that is in light organic HAP liquid service, and to each agitator in organic HAP gas/vapor service or in light organic HAP liquid service.</P> <P>(2)(i) <E T="03">Monitoring.</E> Each pump and agitator subject to this section shall be monitored quarterly to detect leaks by the method specified in § 63.180(b) of subpart H, except as provided in § 63.177 of subpart H, paragraph (f) of this section, and paragraphs (c)(5) through (c)(9) of this section.</P> <P>(ii) <E T="03">Leak definition.</E> The instrument reading, as determined by the method as specified in § 63.180(b), that defines a leak is:</P> <P>(A) For agitators, an instrument reading of 10,000 parts per million or greater.</P> <P>(B) For pumps, an instrument reading of 2,000 parts per million or greater.</P> <P>(iii) <E T="03">Visual Inspections.</E> Each pump and agitator shall be checked by visual inspection each calendar week for indications of liquids dripping from the pump or agitator seal. If there are indications of liquids dripping from the seal, a leak is detected.</P> <P>(3) <E T="03">Repair provisions.</E> (i) When a leak is detected, it shall be repaired as soon as practicable, but not later than 15 calendar days after it is detected, except as provided in paragraph (b)(1)(v) of this section.</P> <P>(ii) A first attempt at repair shall be made no later than 5 calendar days after the leak is detected. First attempts at repair include, but are not limited to, the following practices where practicable:</P> <P>(A) Tightening of packing gland nuts.</P> <P>(B) Ensuring that the seal flush is operating at design pressure and temperature.</P> <P>(4) <E T="03">Calculation of percent leakers.</E> (i) The owner or operator shall decide no later than the end of the first monitoring period what groups of processes will be developed. Once the owner or operator has decided, all subsequent percent calculations shall be made on the same basis.</P> <P>(ii) If, calculated on a 1 year rolling average, the greater of either 10 percent or three of the pumps in a group of processes leak, the owner or operator shall monitor each pump once per month.</P> <P>(iii) The number of pumps in a group of processes shall be the sum of all the pumps in organic HAP service, except that pumps found leaking in a continuous process within 1 quarter after startup of the pump shall not count in the percent leaking pumps calculation for that one monitoring period only.</P> <P>(iv) Percent leaking pumps shall be determined by the following Equation 3: </P> <FP SOURCE="FP-2">%P<E T="52">L</E> = [(P<E T="52">L</E>—P<E T="52">S</E>)/(P<E T="52">T</E>—P<E T="52">S</E>)] × 100 (Eq. 3)</FP> <FP SOURCE="FP-2">Where:</FP> <FP SOURCE="FP-2">%P<E T="52">L</E> = percent leaking pumps</FP> <FP SOURCE="FP-2">P<E T="52">L</E> = number of pumps found leaking as determined through quarterly monitoring as required in paragraphs (c)(2)(i) and (c)(2)(ii) of this section.</FP> <FP SOURCE="FP-2">P<E T="52">T</E> = total pumps in organic HAP service, including those meeting the criteria in paragraphs (c)(5) and (c)(6) of this section</FP> <FP SOURCE="FP-2">PS = number of pumps in a continuous process leaking within 1 quarter of startup during the current monitoring period</FP> <PRTPAGE P="34"/> <P>(5) <E T="03">Exemptions.</E> Each pump or agitator equipped with a dual mechanical seal system that includes a barrier fluid system is exempt from the requirements of paragraphs (c)(1) through (c)(4)(iii) of this section, provided the following requirements are met:</P> <P>(i) Each dual mechanical seal system is:</P> <P>(A) Operated with the barrier fluid at a pressure that is at all times greater than the pump/agitator stuffing box pressure; or</P> <P>(B) Equipped with a barrier fluid degassing reservoir that is connected by a closed-vent system to a control device that complies with the requirements of paragraph (b)(1)(vi) of this section; or</P> <P>(C) Equipped with a closed-loop system that purges the barrier fluid into a process stream.</P> <P>(ii) The barrier fluid is not in light liquid service.</P> <P>(iii) Each barrier fluid system is equipped with a sensor that will detect failure of the seal system, the barrier fluid system, or both.</P> <P>(iv) Each pump/agitator is checked by visual inspection each calendar week for indications of liquids dripping from the pump/agitator seal.</P> <P>(A) If there are indications of liquids dripping from the pump/agitator seal at the time of the weekly inspection, the pump/agitator shall be monitored as specified in § 63.180(b) to determine if there is a leak of organic HAP in the barrier fluid.</P> <P>(B) If an instrument reading of 2,000 parts per million or greater is measured for pumps, or 10,000 parts per million or greater is measured for agitators, a leak is detected.</P> <P>(v) Each sensor as described in paragraph (c)(5)(iii) of this section is observed daily or is equipped with an alarm unless the pump is located within the boundary of an unmanned plant site.</P> <P>(vi)(A) The owner or operator determines, based on design considerations and operating experience, criteria applicable to the presence and frequency of drips and to the sensor that indicate failure of the seal system, the barrier fluid system, or both.</P> <P>(B) If indications of liquids dripping from the pump/agitator seal exceed the criteria established in paragraph (c)(5)(vi)(A) of this section, or if, based on the criteria established in paragraph (c)(5)(vi)(A) of this section, the sensor indicates failure of the seal system, the barrier fluid system, or both, a leak is detected.</P> <P>(C) When a leak is detected, it shall be repaired as soon as practicable, but not later than 15 calendar days after it is detected, except as provided in paragraph (b)(1)(v) of this section.</P> <P>(D) A first attempt at repair shall be made no later than 5 calendar days after each leak is detected.</P> <P>(6) Any pump/agitator that is designed with no externally actuated shaft penetrating the pump/agitator housing is exempt from the requirements of paragraphs (c)(1) through (c)(4) of this section, except for the requirements of paragraph (c)(2)(iii) and, for pumps, paragraph (c)(4)(iv).</P> <P>(7) Any pump/agitator equipped with a closed-vent system capable of capturing and transporting any leakage from the seal or seals back to the process or to a control device that complies with the requirements of paragraph (b)(1)(vi) of this section is exempt from the requirements of paragraphs (c)(2) through (c)(5) of this section.</P> <P>(8) Any pump/agitator that is located within the boundary of an unmanned plant site is exempt from the weekly visual inspection requirement of paragraphs (c)(2)(iii) and (c)(5)(iv) of this section, and the daily requirements of paragraph (c)(5)(v) of this section, provided that each pump/agitator is visually inspected as often as practicable and at least monthly.</P> <P>(9) If more than 90 percent of the pumps in a group of processes meet the criteria in either paragraph (c)(5) or (c)(6) of this section, the process is exempt from the requirements of paragraph (c)(4) of this section.</P> <P>(d) <E T="03">Standards: Open-Ended Valves or Lines.</E> (1)(i) Each open-ended valve or line shall be equipped with a cap, blind flange, plug, or a second valve, except as provided in § 63.177 and paragraphs (d)(4) through (6) of this section.</P> <P>(ii) The cap, blind flange, plug, or second valve shall seal the open end at all times except during operations requiring process fluid flow through the open-ended valve or line, or during <PRTPAGE P="35"/>maintenance or repair. The cap, blind flange, plug, or second valve shall be in place within 1 hour of cessation of operations requiring process fluid flow through the open-ended valve or line, or within 1 hour of cessation of maintenance or repair.</P> <P>(2) Each open-ended valve or line equipped with a second valve shall be operated in a manner such that the valve on the process fluid end is closed before the second valve is closed.</P> <P>(3) When a double block and bleed system is being used, the bleed valve or line may remain open during operations that require venting the line between the block valves but shall comply with paragraph (d)(1) of this section at all other times.</P> <P>(4) Open-ended valves or lines in an emergency shutdown system which are designed to open automatically in the event of a process upset are exempt from the requirements of paragraphs (d)(1) through (d)(3) of this section.</P> <P>(5) Open-ended valves or lines containing materials which would autocatalytically polymerize are exempt from the requirements of paragraphs (d)(1) through (d)(3) of this section.</P> <P>(6) Open-ended valves or lines containing materials which could cause an explosion, serious overpressure, or other safety hazard if capped or equipped with a double block and bleed system as specified in paragraphs (d)(1) through (d)(3) of this section are exempt from the requirements of paragraphs (d)(1) through (d)(3) of this section.</P> <P>(e) <E T="03">Standards: Valves in Gas/Vapor Service and in Light Liquid Service.</E> (1) The provisions of this section apply to valves that are either in gas organic HAP service or in light liquid organic HAP service.</P> <P>(2) For existing and new affected sources, all valves subject to this section shall be monitored, except as provided in paragraph (f) of this section and in § 63.177, by no later than 1 year after the compliance date.</P> <P>(3) <E T="03">Monitoring.</E> The owner or operator of a source subject to this section shall monitor all valves, except as provided in paragraph (f) of this section and in § 63.177, at the intervals specified in paragraph (e)(4) of this section and shall comply with all other provisions of this section, except as provided in paragraph (b)(1)(v) of this section, § 63.178, and § 63.179.</P> <P>(i) The valves shall be monitored to detect leaks by the method specified in § 63.180(b).</P> <P>(ii) An instrument reading of 500 parts per million or greater defines a leak.</P> <P>(4) <E T="03">Subsequent monitoring frequencies.</E> After conducting the initial survey required in paragraph (e)(2) of this section, the owner or operator shall monitor valves for leaks at the intervals specified below:</P> <P>(i) For a group of processes with 2 percent or greater leaking valves, calculated according to paragraph (e)(6) of this section, the owner or operator shall monitor each valve once per month, except as specified in paragraph (e)(9) of this section.</P> <P>(ii) For a group of processes with less than 2 percent leaking valves, the owner or operator shall monitor each valve once each quarter, except as provided in paragraphs (e)(4)(iii) through (e)(4)(v) of this section.</P> <P>(iii) For a group of processes with less than 1 percent leaking valves, the owner or operator may elect to monitor each valve once every 2 quarters.</P> <P>(iv) For a group of processes with less than 0.5 percent leaking valves, the owner or operator may elect to monitor each valve once every 4 quarters.</P> <P>(v) For a group of processes with less than 0.25 percent leaking valves, the owner or operator may elect to monitor each valve once every 2 years.</P> <P>(5) <E T="03">Calculation of percent leakers.</E> For a group of processes to which this subpart applies, an owner or operator may choose to subdivide the valves in the applicable group of processes and apply the provisions of paragraph (e)(4) of this section to each subgroup. If the owner or operator elects to subdivide the valves in the applicable group of processes, then the provisions of paragraphs (e)(5)(i) through (e)(5)(viii) of this section apply.</P> <P>(i) The overall performance of total valves in the applicable group of processes must be less than 2 percent leaking valves, as detected according to paragraphs (e)(3) (i) and (ii) of this section and as calculated according to <PRTPAGE P="36"/>paragraphs (e)(6) (ii) and (iii) of this section.</P> <P>(ii) The initial assignment or subsequent reassignment of valves to subgroups shall be governed by the provisions of paragraphs (e)(5)(ii) (A) through (C) of this section.</P> <P>(A) The owner or operator shall determine which valves are assigned to each subgroup. Valves with less than 1 year of monitoring data or valves not monitored within the last 12 months must be placed initially into the most frequently monitored subgroup until at least 1 year of monitoring data has been obtained.</P> <P>(B) Any valve or group of valves can be reassigned from a less frequently monitored subgroup to a more frequently monitored subgroup provided that the valves to be reassigned were monitored during the most recent monitoring period for the less frequently monitored subgroup. The monitoring results must be included with the less frequently monitored subgroup's monitoring event and associated next percent leaking valves calculation for that group.</P> <P>(C) Any valve or group of valves can be reassigned from a more frequently monitored subgroup to a less frequently monitored subgroup provided that the valves to be reassigned have not leaked for the period of the less frequently monitored subgroup (e.g., for the last 12 months, if the valve or group of valves is to be reassigned to a subgroup being monitored annually). Nonrepairable valves may not be reassigned to a less frequently monitored subgroup.</P> <P>(iii) The owner or operator shall determine every 6 months if the overall performance of total valves in the applicable group of processes is less than 2 percent leaking valves and so indicate the performance in the next periodic report. If the overall performance of total valves in the applicable group of processes is 2 percent leaking valves or greater, the owner or operator shall revert to the program required in paragraphs (e)(2) through (e)(4) of this section. The overall performance of total valves in the applicable group of processes shall be calculated as a weighted average of the percent leaking valves of each subgroup according to the following Equation 4:</P> <GPH DEEP="59" SPAN="1"> <GID>ER21SE98.002</GID> </GPH> <FP SOURCE="FP-2">where:</FP> <FP SOURCE="FP-2">%V<E T="52">LO</E> = overall performance of total valves in the applicable process or group of processes</FP> <FP SOURCE="FP-2">%V<E T="52">Li</E> = percent leaking valves in subgroup I, most recent value calculated according to the procedures in paragraphs (e)(6) (ii) and (iii) of this section</FP> <FP SOURCE="FP-2">V<E T="52">i</E> = number of valves in subgroup I</FP> <FP SOURCE="FP-2">n = number of subgroups</FP> <P>(iv) <E T="03">Records.</E> In addition to records required by paragraph (g) of this section, the owner or operator shall maintain records specified in paragraphs (e)(5)(iv)(A) through (D) of this section.</P> <P>(A) Which valves are assigned to each subgroup,</P> <P>(B) Monitoring results and calculations made for each subgroup for each monitoring period,</P> <P>(C) Which valves are reassigned and when they were reassigned, and</P> <P>(D) The results of the semiannual overall performance calculation required in paragraph (e)(5)(iii) of this section.</P> <P>(v) The owner or operator shall notify the Administrator no later than 30 days prior to the beginning of the next monitoring period of the decision to subgroup valves. The notification shall identify the participating processes and the valves assigned to each subgroup.</P> <P>(vi) <E T="03">Semiannual reports.</E> In addition to the information required by paragraph (h)(3) of this section, the owner or operator shall submit in the periodic reports the information specified in paragraphs (e)(5)(vi)(A) and (B) of this section.</P> <P>(A) Valve reassignments occurring during the reporting period, and</P> <P>(B) Results of the semiannual overall performance calculation required by paragraph (e)(5)(iii) of this section.<PRTPAGE P="37"/> </P> <P>(vii) To determine the monitoring frequency for each subgroup, the calculation procedures of paragraph (e)(6)(iii) of this section shall be used.</P> <P>(viii) Except for the overall performance calculations required by paragraphs (e)(5)(i) and (e)(5)(iii) of this section, each subgroup shall be treated as if it were a process for the purposes of applying the provisions of this section.</P> <P>(6)(i) The owner or operator shall decide no later than the implementation date of this subpart or upon revision of an operating permit how to group the processes. Once the owner or operator has decided, all subsequent percentage calculations shall be made on the same basis.</P> <P>(ii) Percent leaking valves for each group of processes or subgroup shall be determined by the following Equation 5: </P> <FP SOURCE="FP-2">%V<E T="52">L</E> = [V<E T="52">L</E>/V<E T="52">T</E>] × 100</FP> <SUBJECT>(Eq. 5)</SUBJECT> <FP SOURCE="FP-2">Where:</FP> <FP SOURCE="FP-2">%V<E T="52">L</E> = percent leaking valves</FP> <FP SOURCE="FP-2">V<E T="52">L</E> = number of valves found leaking excluding nonrepairables as provided in paragraph (e)(6)(iv)(A) of this section</FP> <FP SOURCE="FP-2">V<E T="52">T</E> = total valves monitored, in a monitoring period excluding valves monitored as required by (e)(7)(iii) of this section</FP> <P>(iii) When determining monitoring frequency for each group of processes or subgroup subject to monthly, quarterly, or semiannual monitoring frequencies, the percent leaking valves shall be the arithmetic average of the percent leaking valves from the last two monitoring periods. When determining monitoring frequency for each group of processes or subgroup subject to annual or biennial (once every 2 years) monitoring frequencies, the percent leaking valves shall be the arithmetic average of the percent leaking valves from the last three monitoring periods.</P> <P>(iv)(A) Nonrepairable valves shall be included in the calculation of percent leaking valves the first time the valve is identified as leaking and nonrepairable and as required to comply with paragraph (e)(6)(iv)(B) of this section. Otherwise, a number of nonrepairable valves (identified and included in the percent leaking calculation in a previous period) up to a maximum of 1 percent of the total number of valves in organic HAP service at a process may be excluded from calculation of percent leaking valves for subsequent monitoring periods.</P> <P>(B) If the number of nonrepairable valves exceeds 1 percent of the total number of valves in organic HAP service at a process, the number of nonrepairable valves exceeding 1 percent of the total number of valves in organic HAP service shall be included in the calculation of percent leaking valves.</P> <P>(7) <E T="03">Repair provisions.</E> (i) When a leak is detected, it shall be repaired as soon as practicable, but no later than 15 calendar days after the leak is detected, except as provided in paragraph (b)(1)(v) of this section.</P> <P>(ii) A first attempt at repair shall be made no later than 5 calendar days after each leak is detected.</P> <P>(iii) When a leak is repaired, the valve shall be monitored at least once within the first 3 months after its repair. Days that the valve is not in organic HAP service shall not be considered part of this 3 month period.</P> <P>(8) First attempts at repair include, but are not limited to, the following practices where practicable:</P> <P>(i) Tightening of bonnet bolts,</P> <P>(ii) Replacement of bonnet bolts,</P> <P>(iii) Tightening of packing gland nuts, and</P> <P>(iv) Injection of lubricant into lubricated packing.</P> <P>(9) Any equipment located at a plant site with fewer than 250 valves in organic HAP service in the affected source is exempt from the requirements for monthly monitoring specified in paragraph (e)(4)(i) of this section. Instead, the owner or operator shall monitor each valve in organic HAP service for leaks once each quarter, or comply with paragraphs (e)(4)(iii) or (e)(4)(iv) of this section.</P> <P>(f) <E T="03">Unsafe to Monitor, Difficult to Monitor, and Inaccessible Equipment.</E> (1) Equipment that is designated as unsafe to monitor, difficult to monitor, or inaccessible is exempt from the monitoring requirements specified in paragraphs (f)(1)(i) through (iv) of this section provided the owner or operator meets the requirements specified in paragraph (f)(2), (f)(3), or (f)(4) of this <PRTPAGE P="38"/>section, as applicable. Ceramic or ceramic-lined connectors are subject to the same requirements as inaccessible connectors.</P> <P>(i) For pumps and agitators, paragraphs (c)(2), (c)(3), and (c)(4) of this section do not apply.</P> <P>(ii) For valves, paragraphs (e)(2) through (e)(7) of this section do not apply.</P> <P>(iii) For closed-vent systems, § 63.172(f)(1) and (2), and (g) do not apply.</P> <P>(iv) For connectors, § 63.174(b) through (e) do not apply.</P> <P>(2) <E T="03">Equipment that is unsafe to monitor.</E> (i) Equipment may be designated as unsafe to monitor if the owner or operator determines that monitoring personnel would be exposed to an immediate danger as a consequence of complying with the monitoring requirements in paragraphs (f)(1)(i) through (iv) of this section.</P> <P>(ii) The owner or operator of equipment that is designated as unsafe-to-monitor must have a written plan that requires monitoring of the equipment as frequently as practicable during safe-to-monitor times, but not more frequently than the periodic monitoring schedule otherwise applicable.</P> <P>(3) <E T="03">Equipment that is difficult to monitor.</E> (i) Equipment may be designated as difficult to monitor if the owner or operator determines that the equipment cannot be monitored without elevating the monitoring personnel more than 2 meters above a support surface or it is not accessible at anytime in a safe manner;</P> <P>(ii) At an existing source, any equipment within a group of processes that meets the criteria of paragraph (f)(3)(i) of this section may be designated as difficult to monitor. At a new affected source, an owner or operator may designate no more than 3 percent of each type of equipment as difficult to monitor.</P> <P>(iii) The owner or operator of equipment designated as difficult to monitor must follow a written plan that requires monitoring of the equipment at least once per calendar year.</P> <P>(4) <E T="03">Inaccessible equipment and ceramic or ceramic-lined connectors.</E> (i) A connector, agitator, or valve may be designated as inaccessible if it is:</P> <P>(A) Buried;</P> <P>(B) Insulated in a manner that prevents access to the equipment by a monitor probe;</P> <P>(C) Obstructed by equipment or piping that prevents access to the equipment by a monitor probe;</P> <P>(D) Unable to be reached from a wheeled scissor-lift or hydraulic-type scaffold which would allow access to equipment up to 7.6 meters (25 feet) above the ground; or</P> <P>(E) Not able to be accessed at any time in a safe manner to perform monitoring. Unsafe access includes, but is not limited to, the use of a wheeled scissor-lift on unstable or uneven terrain, the use of a motorized man-lift basket in areas where an ignition potential exists, or access would require near proximity to hazards such as electrical lines, or would risk damage to equipment.</P> <P>(ii) At an existing source, any connector, agitator, or valve that meets the criteria of paragraph (f)(4)(i) of this section may be designated as inaccessible. At a new affected source, an owner or operator may designate no more than 3 percent of each type of equipment as inaccessible.</P> <P>(iii) If any inaccessible equipment or ceramic or ceramic-lined connector is observed by visual, audible, olfactory, or other means to be leaking, the leak shall be repaired as soon as practicable, but no later than 15 calendar days after the leak is detected, except as provided in paragraph (g) of this section.</P> <P>(g) <E T="03">Recordkeeping Requirements.</E> (1) An owner or operator of more than one group of processes subject to the provisions of this section may comply with the recordkeeping requirements for the groups of processes in one recordkeeping system if the system identifies with each record the program being implemented (e.g., quarterly monitoring) for each type of equipment. All records and information required by this section shall be maintained in a manner that can be readily accessed at the plant site. This could include physically locating the records at the plant site or accessing the records from a central location by computer at the plant site.<PRTPAGE P="39"/> </P> <P>(2) <E T="03">General recordkeeping.</E> Except as provided in paragraph (e) of this section and in paragraph (a)(9) of this section, the following information pertaining to all equipment subject to the requirements in this section shall be recorded:</P> <P>(i)(A) A list of identification numbers for equipment (except connectors that are not subject to paragraph (f) of this section and instrumentation systems) subject to the requirements of this section. Connectors, except those subject to paragraph (f) of this section, need not be individually identified if all connectors in a designated area or length of pipe subject to the provisions of this section are identified as a group, and the number of subject connectors is indicated. The list for each type of equipment shall be completed no later than the completion of the initial survey required for that component. The list of identification numbers shall be updated, if needed, to incorporate equipment changes within 15 calendar days of the completion of each monitoring survey for the type of equipment component monitored.</P> <P>(B) A schedule for monitoring connectors subject to the provisions of § 63.174(a) and valves subject to the provisions of paragraph (e)(4) of this section.</P> <P>(C) Physical tagging of the equipment to indicate that it is in organic HAP service is not required. Equipment subject to the provisions of this section may be identified on a plant site plan, in log entries, or by other appropriate methods.</P> <P>(ii)(A) A list of identification numbers for equipment that the owner or operator elects to equip with a closed-vent system and control device, under the provisions of paragraph (c)(7) of this section, § 63.164(h), or § 63.165(c).</P> <P>(B) A list of identification numbers for compressors that the owner or operator elects to designate as operating with an instrument reading of less than 500 parts per million above background, under the provisions of § 63.164(i).</P> <P>(iii)(A) A list of identification numbers for pressure relief devices subject to the provisions in § 63.165(a).</P> <P>(B) A list of identification numbers for pressure relief devices equipped with rupture disks, under the provisions of § 63.165(d).</P> <P>(iv) Identification of instrumentation systems subject to the provisions of this section. Individual components in an instrumentation system need not be identified.</P> <P>(v) The owner or operator may develop a written procedure that identifies the conditions that justify a delay of repair. The written procedures may be included as part of the startup/shutdown/malfunction plan, required by § 63.1260(i), for the source or may be part of a separate document that is maintained at the plant site. Reasons for delay of repair may be documented by citing the relevant sections of the written procedure.</P> <P>(vi) The following information shall be recorded for each dual mechanical seal system:</P> <P>(A) Design criteria required by paragraph (c)(5)(vi)(A) of this section and § 63.164(e)(2), and an explanation of the design criteria; and</P> <P>(B) Any changes to these criteria and the reasons for the changes.</P> <P>(vii) A list of equipment designated as unsafe to monitor, difficult to monitor, or inaccessible under paragraphs (f) or (b)(1)(v)(B) of this section and a copy of the plan for monitoring or inspecting this equipment.</P> <P>(viii) A list of connectors removed from and added to the process, as described in § 63.174(i)(1), and documentation of the integrity of the weld for any removed connectors, as required in § 63.174(j). This is not required unless the net credits for removed connectors is expected to be used.</P> <P>(ix) For batch processes that the owner or operator elects to monitor as provided under § 63.178(c), a list of equipment added to batch product processes since the last monitoring period required in §§ 63.178(c)(3)(ii) and (3)(iii). This list must be completed for each type of equipment within 15 calendar days of the completion of each monitoring survey for the type of equipment monitored.</P> <P>(3) <E T="03">Records of visual inspections.</E> For visual inspections of equipment subject to the provisions of paragraphs <PRTPAGE P="40"/>(c)(2)(iii) and (c)(5)(iv)(A) of this section, the owner or operator shall document that the inspection was conducted and the date of the inspection. The owner or operator shall maintain records as specified in paragraph (g)(4) of this section for leaking equipment identified in this inspection, except as provided in paragraph (g)(5) of this section. These records shall be retained for 2 years.</P> <P>(4) <E T="03">Monitoring records.</E> When each leak is detected as specified in paragraph (c) of this section and § 63.164; paragraph (e) of this section and § 63.169; and §§ 63.172 and 63.174 of subpart H, the following information shall be recorded and kept for 2 years onsite and 3 years offsite (5 years total):</P> <P>(i) The instrument and the equipment identification number and the operator name, initials, or identification number.</P> <P>(ii) The date the leak was detected and the date of the first attempt to repair the leak.</P> <P>(iii) The date of successful repair of the leak.</P> <P>(iv) If postrepair monitoring is required, the maximum instrument reading measured by Method 21 of 40 CFR part 60, appendix A after the leak is successfully repaired or determined to be nonrepairable.</P> <P>(v) “Repair delayed” and the reason for the delay if a leak is not repaired within 15 calendar days after discovery of the leak.</P> <P>(A) The owner or operator may develop a written procedure that identifies the conditions that justify a delay of repair. In such cases, reasons for delay of repair may be documented by citing the relevant sections of the written procedure.</P> <P>(B) If delay of repair was caused by depletion of stocked parts, there must be documentation that the spare parts were sufficiently stocked onsite before depletion and the reason for depletion.</P> <P>(vi) If repairs were delayed, dates of process shutdowns that occur while the equipment is unrepaired.</P> <P>(vii)(A) If the alternative in § 63.174(c)(1)(ii) is not in use for the monitoring period, identification, either by list, location (area or grouping), or tagging of connectors disturbed since the last monitoring period required in § 63.174(b), as described in § 63.174(c)(1).</P> <P>(B) The date and results of follow-up monitoring as required in § 63.174(c). If identification of disturbed connectors is made by location, then all connectors within the designated location shall be monitored.</P> <P>(viii) The date and results of the monitoring required in § 63.178(c)(3)(i) for equipment added to a batch process since the last monitoring period required in §§ 63.178(c)(3)(ii) and (c)(3)(iii). If no leaking equipment is found in this monitoring, the owner or operator shall record that the inspection was performed. Records of the actual monitoring results are not required.</P> <P>(ix) Copies of the periodic reports as specified in paragraph (h)(3) of this section, if records are not maintained on a computerized data base capable of generating summary reports from the records.</P> <P>(5) <E T="03">Records of pressure tests</E>. The owner or operator who elects to pressure test a process equipment train and supply lines between storage and processing areas to demonstrate compliance with this section is exempt from the requirements of paragraphs (g)(2), (g)(3), (g)(4), and (g)(6) of this section. Instead, the owner or operator shall maintain records of the following information:</P> <P>(i) The identification of each product, or product code, produced during the calendar year. It is not necessary to identify individual items of equipment in the process equipment train.</P> <P>(ii) Records demonstrating the proportion of the time during the calendar year the equipment is in use in the process that is subject to the provisions of this subpart. Examples of suitable documentation are records of time in use for individual pieces of equipment or average time in use for the process unit. These records are not required if the owner or operator does not adjust monitoring frequency by the time in use, as provided in § 63.178(c)(3)(iii).</P> <P>(iii) Physical tagging of the equipment to identify that it is in organic HAP service and subject to the provisions of this section is not required. Equipment in a process subject to the provisions of this appendix may be <PRTPAGE P="41"/>identified on a plant site plan, in log entries, or by other appropriate methods.</P> <P>(iv) The dates of each pressure test required in § 63.178(b), the test pressure, and the pressure drop observed during the test.</P> <P>(v) Records of any visible, audible, or olfactory evidence of fluid loss.</P> <P>(vi) When a process equipment train does not pass two consecutive pressure tests, the following information shall be recorded in a log and kept for 2 years:</P> <P>(A) The date of each pressure test and the date of each leak repair attempt.</P> <P>(B) Repair methods applied in each attempt to repair the leak.</P> <P>(C) The reason for the delay of repair.</P> <P>(D) The expected date for delivery of the replacement equipment and the actual date of delivery of the replacement equipment.</P> <P>(E) The date of successful repair.</P> <P>(6) <E T="03">Records of compressor compliance tests</E>. The dates and results of each compliance test required for compressors subject to the provisions in § 63.164(i) and the dates and results of the monitoring following a pressure release for each pressure relief device subject to the provisions in §§ 63.165(a) and (b). The results shall include:</P> <P>(i) The background level measured during each compliance test.</P> <P>(ii) The maximum instrument reading measured at each piece of equipment during each compliance test.</P> <P>(7) <E T="03">Records for closed-vent systems</E>. The owner or operator shall maintain records of the information specified in paragraphs (g)(7)(i) through (g)(7)(iii) of this section for closed-vent systems and control devices subject to the provisions of paragraph (b)(1)(vi) of this section. The records specified in paragraph (g)(7)(i) of this section shall be retained for the life of the equipment. The records specified in paragraphs (g)(7)(ii) and (g)(7)(iii) of this section shall be retained for 2 years.</P> <P>(i) The design specifications and performance demonstrations specified in paragraphs (g)(7)(i)(A) through (g)(7)(i)(D) of this section.</P> <P>(A) Detailed schematics, design specifications of the control device, and piping and instrumentation diagrams.</P> <P>(B) The dates and descriptions of any changes in the design specifications.</P> <P>(C) The flare design (i.e., steam assisted, air assisted, or nonassisted) and the results of the compliance demonstration required by § 63.11(b).</P> <P>(D) A description of the parameter or parameters monitored, as required in paragraph (b)(1)(vi) of this section, to ensure that control devices are operated and maintained in conformance with their design and an explanation of why that parameter (or parameters) was selected for the monitoring.</P> <P>(ii) Records of operation of closed-vent systems and control devices.</P> <P>(A) Dates and durations when the closed-vent systems and control devices required in paragraph (c) of this section and §§ 63.164 through 63.166 are not operated as designed as indicated by the monitored parameters, including periods when a flare pilot light system does not have a flame.</P> <P>(B) Dates and durations during which the monitoring system or monitoring device is inoperative.</P> <P>(C) Dates and durations of startups and shutdowns of control devices required in paragraph (c)(7) of this section and §§ 63.164 through 63.166.</P> <P>(iii) Records of inspections of closed-vent systems subject to the provisions of § 63.172.</P> <P>(A) For each inspection conducted in accordance with the provisions of § 63.172(f)(1) or (f)(2) during which no leaks were detected, a record that the inspection was performed, the date of the inspection, and a statement that no leaks were detected.</P> <P>(B) For each inspection conducted in accordance with the provisions of § 63.172(f)(1) or (f)(2) during which leaks were detected, the information specified in paragraph (g)(4) of this section shall be recorded.</P> <P>(8) <E T="03">Records for components in heavy liquid service</E>. Information, data, and analysis used to determine that a piece of equipment or process is in heavy liquid service shall be recorded. Such a determination shall include an analysis or demonstration that the process fluids do not meet the criteria of “in light liquid or gas service.” Examples of information that could document this include, but are not limited to, records of chemicals purchased for the process, <PRTPAGE P="42"/>analyses of process stream composition, engineering calculations, or process knowledge.</P> <P>(9) <E T="03">Records of exempt components</E>. Identification, either by list, location (area or group) of equipment in organic HAP service less than 300 hours per year subject to the provisions of this section.</P> <P>(10) <E T="03">Records of alternative means of compliance determination</E>. Owners and operators choosing to comply with the requirements of § 63.179 shall maintain the following records:</P> <P>(i) Identification of the process(es) and the organic HAP they handle.</P> <P>(ii) A schematic of the process, enclosure, and closed-vent system.</P> <P>(iii) A description of the system used to create a negative pressure in the enclosure to ensure that all emissions are routed to the control device.</P> <P>(h) <E T="03">Reporting Requirements.</E> (1) Each owner or operator of a source subject to this section shall submit the reports listed in paragraphs (h)(1)(i) through (ii) of this section.</P> <P>(i) A Notification of Compliance Status Report described in paragraph (h)(2) of this section,</P> <P>(ii) Periodic Reports described in paragraph (h)(3) of this section, and</P> <P>(2) <E T="03">Notification of compliance report</E>. Each owner or operator of a source subject to this section shall submit the information specified in paragraphs (h)(2)(i) through (iii) of this section in the Notification of Compliance Status Report described in § 63.1260(f).</P> <P>(i) The notification shall provide the information listed in paragraphs (h)(2)(i)(A) through (C) of this section for each process subject to the requirements of paragraphs (b) through (g) of this section.</P> <P>(A) Process group identification.</P> <P>(B) Approximate number of each equipment type (e.g., valves, pumps) in organic HAP service, excluding equipment in vacuum service.</P> <P>(C) Method of compliance with the standard (for example, “monthly leak detection and repair” or “equipped with dual mechanical seals”).</P> <P>(ii) The notification shall provide the information listed in paragraphs (h)(2)(ii)(A) and (B) of this section for each process subject to the requirements of paragraph (b)(1)(ix) of this section and § 63.178(b).</P> <P>(A) Products or product codes subject to the provisions of this section, and</P> <P>(B) Planned schedule for pressure testing when equipment is configured for production of products subject to the provisions of this section.</P> <P>(iii) The notification shall provide the information listed in paragraphs (h)(2)(iii)(A) and (B) of this section for each process subject to the requirements in § 63.179.</P> <P>(A) Process identification.</P> <P>(B) A description of the system used to create a negative pressure in the enclosure and the control device used to comply with the requirements of paragraph (b)(1)(vi) of this section.</P> <P>(iv) Any change in the information submitted under paragraph (h) of this section shall be provided to the Administrator as a part of subsequent Periodic Reports. Section 63.9(j) shall not apply to the Notification of Compliance Status Report described in this paragraph (h)(2) of this section.</P> <P>(3) <E T="03">Periodic reports</E>. The owner or operator of a source subject to this section shall submit Periodic Reports.</P> <P>(i) A report containing the information in paragraphs (h)(3)(ii), (h)(3)(iii), and (h)(3)(iv) of this section shall be submitted semiannually starting 6 months after the Notification of Compliance Status Report, as required in paragraph (h)(2) of this section. The first periodic report shall cover the first 6 months after the compliance date specified in § 63.1250(e). Each subsequent periodic report shall cover the 6 month period following the preceding period.</P> <P>(ii) For equipment complying with the provisions of paragraphs (b) through (g) of this section, the summary information listed in paragraphs (h)(3)(ii)(A) through (L) of this section for each monitoring period during the 6-month period.</P> <P>(A) The number of valves for which leaks were detected as described in paragraph (e)(3) of this section, the percent leakers, and the total number of valves monitored;</P> <P>(B) The number of valves for which leaks were not repaired as required in <PRTPAGE P="43"/>paragraph (e)(7) of this section, identifying the number of those that are determined nonrepairable;</P> <P>(C) The number of pumps and agitators for which leaks were detected as described in paragraph (c)(2) of this section, the percent leakers, and the total number of pumps and agitators monitored;</P> <P>(D) The number of pumps and agitators for which leaks were not repaired as required in paragraph (c)(3) of this section;</P> <P>(E) The number of compressors for which leaks were detected as described in § 63.164(f);</P> <P>(F) The number of compressors for which leaks were not repaired as required in § 63.164(g);</P> <P>(G) The number of connectors for which leaks were detected as described in § 63.174(a), the percent of connectors leaking, and the total number of connectors monitored;</P> <P>(H) The number of connectors for which leaks were not repaired as required in § 63.174(d), identifying the number of those that are determined nonrepairable;</P> <P>(I) The facts that explain any delay of repairs and, where appropriate, why a process shutdown was technically infeasible.</P> <P>(J) The results of all monitoring to show compliance with §§ 63.164(i), 63.165(a), and 63.172(f) conducted within the semiannual reporting period.</P> <P>(K) If applicable, the initiation of a monthly monitoring program under either paragraph (c)(4)(ii) or paragraph (e)(4)(i) of this section.</P> <P>(L) If applicable, notification of a change in connector monitoring alternatives as described in § 63.174(c)(1).</P> <P>(iii) For owners or operators electing to meet the requirements of § 63.178(b), the report shall include the information listed in paragraphs (h)(3)(iii)(A) through (E) of this paragraph for each process.</P> <P>(A) Product process equipment train identification;</P> <P>(B) The number of pressure tests conducted;</P> <P>(C) The number of pressure tests where the equipment train failed either the retest or two consecutive pressure tests;</P> <P>(D) The facts that explain any delay of repairs; and</P> <P>(E) The results of all monitoring to determine compliance with § 63.172(f) of subpart H.</P> <P>(iv) Any revisions to items reported in earlier Notification of Compliance Status Report, if the method of compliance has changed since the last report or any other changes to the information reported has occurred.</P> </SECTION> <SECTION> <SECTNO>§ 63.1256</SECTNO> <SUBJECT>Standards: Wastewater.</SUBJECT> <P>(a) <E T="03">General</E>. Each owner or operator of any affected source (existing or new) shall comply with the general wastewater requirements in paragraphs (a)(1) and (2) of this section.</P> <P>(1) <E T="03">Identify wastewater that requires control</E>. For each POD, the owner or operator shall comply with the requirements in either paragraph (a)(1)(i), or (ii) of this section to determine whether a wastewater stream is an affected wastewater stream that requires control for soluble and/or partially soluble HAP compounds or to designate the wastewater stream as an affected wastewater stream, respectively. The owner or operator may use a combination of the approaches in paragraphs (a)(1)(i) and (ii) of this section for different affected wastewater generated at the source. The owner or operator shall also comply with the requirements for multiphase discharges in paragraph (a)(4) of this section. Wastewater identified in paragraph (a)(3) of this section is exempt from the provisions of this subpart.</P> <P>(i) <E T="03">Determine characteristics of a wastewater stream</E>. At new and existing sources, a wastewater stream is an affected wastewater stream if the annual average concentration and annual load exceed any of the criteria specified in paragraph (a)(1)(i)(A) through (C) of this section. At new sources, a wastewater stream is subject to additional control requirements if the annual average concentration and annual load exceed the criteria specified in paragraphs (a)(1)(i)(D) of this section. The owner or operator shall comply with the provisions of § 63.1257(e)(1) to determine the annual average concentrations and annual load of partially soluble and soluble HAP compounds.<PRTPAGE P="44"/> </P> <P>(A) The wastewater stream contains partially soluble HAP compounds at an annual average concentration greater than 1,300 ppmw, and the total soluble and partially soluble HAP load in all wastewater from the PMPU exceeds 1 Mg/yr.</P> <P>(B) The wastewater stream contains partially soluble and/or soluble HAP compounds at an annual average concentration of 5,200 ppmw, and the total soluble and partially soluble HAP load in all wastewater from the PMPU exceeds 1 Mg/yr.</P> <P>(C) The wastewater stream contains partially soluble and/or soluble HAP at an annual average concentration of greater than 10,000 ppmw, and the total partially soluble and/or soluble HAP load in all wastewater from the affected source is greater than 1 Mg/yr.</P> <P>(D) The wastewater stream contains soluble HAP compounds at an annual average concentration greater than 110,000 ppmw, and the total soluble and partially soluble HAP load in all wastewater from the PMPU exceeds 1 Mg/yr.</P> <P>(ii) <E T="03">Designate wastewater as affected wastewater</E>. For existing sources, the owner or operator may elect to designate wastewater streams as meeting the criteria of either paragraphs (a)(1)(i)(A),(B), or (C) of this section. For new sources, the owner or operator may elect to designate wastewater streams meeting the criterion in paragraph (a)(1)(i)(D) or for wastewater known to contain no soluble HAP, as meeting the criterion in paragraph (a)(1)(i)(A) of this section. For designated wastewater the procedures specified in paragraphs (a)(1)(ii)(A) and (B) of this section shall be followed, except as specified in paragraphs (g)(8)(i), (g)(9)(i), and (g)(10) of this section. The owner or operator is not required to determine the annual average concentration or load for each designated wastewater stream for the purposes of this section.</P> <P>(A) From the POD for the wastewater stream that is designated as an affected wastewater stream to the location where the owner or operator elects to designate such wastewater stream as an affected wastewater stream, the owner or operator shall comply with all applicable emission suppression requirements specified in paragraphs (b) through (f) of this section.</P> <P>(B) From the location where the owner or operator designates a wastewater stream as an affected wastewater stream, such wastewater stream shall be managed in accordance with all applicable emission suppression requirements specified in paragraphs (b) through (f) of this section and with the treatment requirements in paragraph (g) of this section.</P> <P>(iii) <E T="03">Scrubber Effluent.</E> Effluent from a water scrubber that has been used to control Table 2 HAP-containing vent streams that are controlled in order to meet the process vent requirements in § 63.1254 of this subpart is considered an affected wastewater stream.</P> <P>(2) <E T="03">Requirements for affected wastewater.</E> (i) An owner or operator of a facility shall comply with the applicable requirements for wastewater tanks, surface impoundments, containers, individual drain systems, and oil/water separators as specified in paragraphs (b) through (f) of this section, except as provided in paragraph (g)(3) of this section.</P> <P>(ii) Comply with the applicable requirements for control of soluble and partially soluble compounds as specified in paragraph (g) of this section. Alternatively, the owner or operator may elect to comply with the treatment provisions specified in paragraph (a)(5) of this section.</P> <P>(iii) Comply with the applicable monitoring and inspection requirements specified in § 63.1258.</P> <P>(iv) Comply with the applicable recordkeeping and reporting requirements specified in §§ 63.1259 and 63.1260.</P> <P>(3) <E T="03">Exempt wastewater.</E> The following wastewaters are not subject to the wastewater provisions of this part:</P> <P>(i) Stormwater from segregated sewers;</P> <P>(ii) Water from fire-fighting and deluge systems, including testing of such systems;</P> <P>(iii) Spills; and</P> <P>(iv) Water from safety showers.</P> <P>(4) <E T="03">Requirements for multiphase discharges.</E> The owner or operator shall not discharge a separate phase that can be isolated through gravity separation from the aqueous phase to a waste management or treatment unit, unless <PRTPAGE P="45"/>the stream is discharged to a treatment unit in compliance with paragraph (g)(13) of this section.</P> <P>(5) <E T="03">Offsite treatment or onsite treatment not owned or operated by the source.</E> The owner or operator may elect to transfer affected wastewater streams that contain less than 50 ppmw of partially soluble HAP or a residual removed from such affected wastewater to an onsite treatment operation not owned or operated by the owner or operator of the source generating the wastewater or residual, or to an offsite treatment operation, provided that the waste management units up to the activated sludge unit are covered or the owner or operator demonstrates that less than 5 percent of the total soluble HAP is emitted from the these units.</P> <P>(i) The owner or operator transferring the wastewater or residual shall:</P> <P>(A) Comply with the provisions specified in paragraphs (b) through (f) of this section for each waste management unit that receives or manages affected wastewater or a residual removed from affected wastewater prior to shipment or transport.</P> <P>(B) Include a notice with each shipment or transport of affected wastewater or residual removed from affected wastewater. The notice shall state that the affected wastewater or residual contains organic HAP that are to be treated in accordance with the provisions of this subpart. When the transport is continuous or ongoing (for example, discharge to a publicly-owned treatment works), the notice shall be submitted to the treatment operator initially and whenever there is a change in the required treatment. The owner or operator shall keep a record of the notice in accordance with § 63.1259(g).</P> <P>(ii) The owner or operator may not transfer the affected wastewater or residual unless the transferee has submitted to the EPA a written certification that the transferee will manage and treat any affected wastewater or residual removed from affected wastewater received from a source subject to the requirements of this subpart in accordance with the requirements of either:</P> <P>(A) Paragraphs (b) through (i) of this section; or</P> <P>(B) Subpart D of this part if alternative emission limitations have been granted the transferor in accordance with those provisions; or</P> <P>(C) Section 63.6(g).</P> <P>(iii) The certifying entity may revoke the written certification by sending a written statement to the EPA and the owner or operator giving at least 90 days notice that the certifying entity is rescinding acceptance of responsibility for compliance with the regulatory provisions listed in this paragraph. Upon expiration of the notice period, the owner or operator may not transfer the wastewater stream or residual to the treatment operation.</P> <P>(iv) By providing this written certification to the EPA, the certifying entity accepts responsibility for compliance with the regulatory provisions listed in paragraph (a)(5)(ii) of this section with respect to any shipment of wastewater or residual covered by the written certification. Failure to abide by any of those provisions with respect to such shipments may result in enforcement action by the EPA against the certifying entity in accordance with the enforcement provisions applicable to violations of these provisions by owners or operators of sources.</P> <P>(v) Written certifications and revocation statements, to the EPA from the transferees of wastewater or residuals shall be signed by the responsible official of the certifying entity, provide the name and address of the certifying entity, and be sent to the appropriate EPA Regional Office at the addresses listed in § 63.13. Such written certifications are not transferable by the treater.</P> <P>(b) <E T="03">Wastewater tanks.</E> For each wastewater tank that receives, manages, or treats affected wastewater or a residual removed from affected wastewater, the owner or operator shall comply with the requirements of either paragraph (b)(1) or (2) of this section as specified in Table 6 of this subpart.</P> <P>(1) The owner or operator shall operate and maintain a fixed roof except when the contents of the wastewater tank are heated, treated by means of an exothermic reaction, or sparged, during which time the owner or operator shall comply with the requirements specified in paragraph (b)(2) of <PRTPAGE P="46"/>this section. For the purposes of this paragraph, the requirements of paragraph (b)(2) of this section are satisfied by operating and maintaining a fixed roof if the owner or operator demonstrates that the total soluble and partially soluble HAP emissions from the wastewater tank are no more than 5 percent higher than the emissions would be if the contents of the wastewater tank were not heated, treated by an exothermic reaction, or sparged.</P> <P>(2) The owner or operator shall comply with the requirements in paragraphs (b)(3) through (9) of this section and shall operate and maintain one of the emission control techniques listed in paragraphs (b)(2)(i) through (iii) of this section.</P> <P>(i) A fixed roof and a closed-vent system that routes the organic HAP vapors vented from the wastewater tank to a control device; or</P> <P>(ii) A fixed roof and an internal floating roof that meets the requirements specified in § 63.119(b), with the differences noted in § 63.1257(c)(3)(i) through (iii) for the purposes of this subpart; or</P> <P>(iii) An external floating roof that meets the requirements specified in §§ 63.119(c), 63.120(b)(5), and 63.120(b)(6), with the differences noted in § 63.1257(c)(3)(i) through (v) for the purposes of this subpart.</P> <P>(3) If the owner or operator elects to comply with the requirements of paragraph (b)(2)(i) of this section, the fixed roof shall meet the requirements of paragraph (b)(3)(i) of this section, the control device shall meet the requirements of paragraph (b)(3)(ii) of this section, and the closed-vent system shall meet the requirements of paragraph (b)(3)(iii) of this section.</P> <P>(i) The fixed roof shall meet the following requirements:</P> <P>(A) Except as provided in paragraph (b)(3)(iv) of this section, the fixed roof and all openings (e.g., access hatches, sampling ports, and gauge wells) shall be maintained in accordance with the requirements specified in § 63.1258(h).</P> <P>(B) Each opening shall be maintained in a closed position (e.g., covered by a lid) at all times that the wastewater tank contains affected wastewater or residual removed from affected wastewater except when it is necessary to use the opening for wastewater sampling, removal, or for equipment inspection, maintenance, or repair.</P> <P>(ii) The control device shall be designed, operated, and inspected in accordance with the requirements of paragraph (h) of this section.</P> <P>(iii) Except as provided in paragraph (b)(3)(iv) of this section, the closed-vent system shall be inspected in accordance with the requirements of § 63.1258(h).</P> <P>(iv) For any fixed roof tank and closed-vent system that is operated and maintained under negative pressure, the owner or operator is not required to comply with the requirements specified in § 63.1258(h).</P> <P>(4) If the owner or operator elects to comply with the requirements of paragraph (b)(2)(ii) of this section, the floating roof shall be inspected according to the procedures specified in § 63.120(a)(2) and (3), with the differences noted in § 63.1257(c)(3)(iv) for the purposes of this subpart.</P> <P>(5) Except as provided in paragraph (b)(6) of this section, if the owner or operator elects to comply with the requirements of paragraph (b)(2)(iii) of this section, seal gaps shall be measured according to the procedures specified in § 63.120(b)(2)(i) through (b)(4) and the wastewater tank shall be inspected to determine compliance with § 63.120(b)(5) and (6) according to the schedule specified in § 63.120(b)(1)(i) through (iii).</P> <P>(6) If the owner or operator determines that it is unsafe to perform the seal gap measurements specified in § 63.120(b)(2)(i) through (b)(4) or to inspect the wastewater tank to determine compliance with § 63.120(b)(5) and (6) because the floating roof appears to be structurally unsound and poses an imminent or potential danger to inspecting personnel, the owner or operator shall comply with the requirements in either paragraph (b)(6)(i) or (ii) of this section.</P> <P>(ii) The owner or operator shall empty and remove the wastewater tank from service within 45 calendar days of determining that the roof is unsafe. If the wastewater tank cannot be emptied within 45 calendar days, the owner or operator may utilize up to two extensions of up to 30 additional <PRTPAGE P="47"/>calendar days each. Documentation of a decision to utilize an extension shall include an explanation of why it was unsafe to perform the inspection or seal gap measurement, shall document that alternate storage capacity is unavailable, and shall specify a schedule of actions that will ensure that the wastewater tank will be emptied as soon as possible.</P> <P>(7) Except as provided in paragraph (b)(6) of this section, each wastewater tank shall be inspected initially, and semiannually thereafter, for improper work practices in accordance with § 63.1258(g). For wastewater tanks, improper work practice includes, but is not limited to, leaving open any access door or other opening when such door or opening is not in use.</P> <P>(8) Except as provided in paragraph (b)(6) of this section, each wastewater tank shall be inspected for control equipment failures as defined in paragraph (b)(8)(i) of this section according to the schedule in paragraphs (b)(8)(ii) and (iii) of this section in accordance with § 63.1258(g).</P> <P>(i) Control equipment failures for wastewater tanks include, but are not limited to, the conditions specified in paragraphs (b)(8)(i)(A) through (I) of this section.</P> <P>(A) The floating roof is not resting on either the surface of the liquid or on the leg supports.</P> <P>(B) There is stored liquid on the floating roof.</P> <P>(C) A rim seal is detached from the floating roof.</P> <P>(D) There are holes, tears, cracks or gaps in the rim seal or seal fabric of the floating roof.</P> <P>(E) There are visible gaps between the seal of an internal floating roof and the wall of the wastewater tank.</P> <P>(F) There are gaps between the metallic shoe seal or the liquid mounted primary seal of an external floating roof and the wall of the wastewater tank that exceed 212 square centimeters per meter of tank diameter or the width of any portion of any gap between the primary seal and the tank wall exceeds 3.81 centimeters.</P> <P>(G) There are gaps between the secondary seal of an external floating roof and the wall of the wastewater tank that exceed 21.2 square centimeters per meter of tank diameter or the width of any portion of any gap between the secondary seal and the tank wall exceeds 1.27 centimeters.</P> <P>(H) Where a metallic shoe seal is used on an external floating roof, one end of the metallic shoe does not extend into the stored liquid or one end of the metallic shoe does not extend a minimum vertical distance of 61 centimeters above the surface of the stored liquid.</P> <P>(I) A gasket, joint, lid, cover, or door has a crack or gap, or is broken.</P> <P>(ii) The owner or operator shall inspect for the control equipment failures in paragraphs (b)(8)(i)(A) through (H) according to the schedule specified in paragraphs (b)(4) and (5) of this section.</P> <P>(iii) The owner or operator shall inspect for the control equipment failures in paragraph (b)(8)(i)(I) of this section initially, and semiannually thereafter.</P> <P>(9) Except as provided in paragraph (i) of this section, when an improper work practice or a control equipment failure is identified, first efforts at repair shall be made no later than 5 calendar days after identification and repair shall be completed within 45 calendar days after identification. If a failure that is detected during inspections required by this section cannot be repaired within 45 calendar days and if the tank cannot be emptied within 45 calendar days, the owner or operator may utilize up to two extensions of up to 30 additional calendar days each. Documentation of a decision to utilize an extension shall include a description of the failure, shall document that alternate storage capacity is unavailable, and shall specify a schedule of actions that will ensure that the control equipment will be repaired or the tank will be emptied as soon as practical.</P> <P>(c) <E T="03">Surface impoundments.</E> For each surface impoundment that receives, manages, or treats affected wastewater or a residual removed from affected wastewater, the owner or operator shall comply with the requirements of paragraphs (c)(1), (2), and (3) of this section.</P> <P>(1) The owner or operator shall operate and maintain on each surface impoundment either a cover (e.g., air-supported structure or rigid cover) and a <PRTPAGE P="48"/>closed-vent system that routes the organic hazardous air pollutants vapors vented from the surface impoundment to a control device in accordance with paragraphs (c)(1)(i), (iii), (iv), and (v) of this section, or a floating flexible membrane cover as specified in paragraph (c)(1)(ii) of this section.</P> <P>(i) The cover and all openings shall meet the following requirements:</P> <P>(A) Except as provided in paragraph (c)(1)(iv) of this section, the cover and all openings (e.g., access hatches, sampling ports, and gauge wells) shall be maintained in accordance with the requirements specified in § 63.1258(h).</P> <P>(B) Each opening shall be maintained in a closed position (e.g., covered by a lid) at all times that affected wastewater or residual removed from affected wastewater is in the surface impoundment except when it is necessary to use the opening for sampling, removal, or for equipment inspection, maintenance, or repair.</P> <P>(C) The cover shall be used at all times that affected wastewater or residual removed from affected wastewater is in the surface impoundment except during removal of treatment residuals in accordance with 40 CFR 268.4 or closure of the surface impoundment in accordance with 40 CFR 264.228.</P> <P>(ii) Floating flexible membrane covers shall meet the requirements specified in paragraphs (c)(1)(ii)(A) through (F) of this section.</P> <P>(A) The floating flexible cover shall be designed to float on the liquid surface during normal operations, and to form a continuous barrier over the entire surface area of the liquid.</P> <P>(B) The cover shall be fabricated from a synthetic membrane material that is either:</P> <P>(<E T="03">1</E>) High density polyethylene (HDPE) with a thickness no less than 2.5 millimeters (100 mils); or</P> <P>(<E T="03">2</E>) A material or a composite of different materials determined to have both organic permeability properties that are equivalent to those of the material listed in paragraph (c)(1)(ii)(B)(<E T="03">1</E>) of this section, and chemical and physical properties that maintain the material integrity for the intended service life of the material.</P> <P>(C) The cover shall be installed in a manner such that there are no visible cracks, holes, gaps, or other open spaces between cover section seams or between the interface of the cover edge and its foundation mountings.</P> <P>(D) Except as provided for in paragraph (c)(1)(ii)(E) of this section, each opening in the floating membrane cover shall be equipped with a closure device designed to operate such that when the closure device is secured in the closed position there are no visible cracks, holes, gaps, or other open spaces in the closure device or between the perimeter of the cover opening and the closure device.</P> <P>(E) The floating membrane cover may be equipped with one or more emergency cover drains for removal of stormwater. Each emergency cover drain shall be equipped with a slotted membrane fabric cover that covers at least 90 percent of the area of the opening or a flexible fabric sleeve seal.</P> <P>(F) The closure devices shall be made of suitable materials that will minimize exposure of organic HAP to the atmosphere, to the extent practical, and will maintain the integrity of the equipment throughout its intended service life. Factors to be considered in designing the closure devices shall include: the effects of any contact with the liquid and its vapor managed in the surface impoundment; the effects of outdoor exposure to wind, moisture, and sunlight; and the operating practices used for the surface impoundment on which the floating membrane cover is installed.</P> <P>(G) Whenever affected wastewater or residual from affected wastewater is in the surface impoundment, the floating membrane cover shall float on the liquid and each closure device shall be secured in the closed position. Opening of closure devices or removal of the cover is allowed to provide access to the surface impoundment for performing routine inspection, maintenance, or other activities needed for normal operations and/or to remove accumulated sludge or other residues from the bottom of surface impoundment. Openings shall be maintained in accordance with § 63.1258(h).</P> <P>(iii) The control device shall be designed, operated, and inspected in accordance with paragraph (h) of this section.<PRTPAGE P="49"/> </P> <P>(iv) Except as provided in paragraph (c)(1)(v) of this section, the closed-vent system shall be inspected in accordance with § 63.1258(h).</P> <P>(v) For any cover and closed-vent system that is operated and maintained under negative pressure, the owner or operator is not required to comply with the requirements specified in § 63.1258(h).</P> <P>(2) Each surface impoundment shall be inspected initially, and semiannually thereafter, for improper work practices and control equipment failures in accordance with § 63.1258(g).</P> <P>(i) For surface impoundments, improper work practice includes, but is not limited to, leaving open any access hatch or other opening when such hatch or opening is not in use.</P> <P>(ii) For surface impoundments, control equipment failure includes, but is not limited to, any time a joint, lid, cover, or door has a crack or gap, or is broken.</P> <P>(3) Except as provided in paragraph (i) of this section, when an improper work practice or a control equipment failure is identified, first efforts at repair shall be made no later than 5 calendar days after identification and repair shall be completed within 45 calendar days after identification.</P> <P>(d) <E T="03">Containers.</E> For each container that receives, manages, or treats affected wastewater or a residual removed from affected wastewater, the owner or operator shall comply with the requirements of paragraphs (d)(1) through (5) of this section.</P> <P>(1) The owner or operator shall operate and maintain a cover on each container used to handle, transfer, or store affected wastewater or a residual removed from affected wastewater in accordance with the following requirements:</P> <P>(i) Except as provided in paragraph (d)(3)(iv) of this section, if the capacity of the container is greater than 0.42 m<E T="51">3</E>, the cover and all openings (e.g., bungs, hatches, sampling ports, and pressure relief devices) shall be maintained in accordance with the requirements specified in § 63.1258(h).</P> <P>(ii) If the capacity of the container is less than or equal to 0.42 m<E T="51">3</E>, the owner or operator shall comply with either paragraph (d)(1)(ii)(A) or (B) of this section.</P> <P>(A) The container must meet existing Department of Transportation specifications and testing requirements under 49 CFR part 178; or</P> <P>(B) Except as provided in paragraph (d)(3)(iv) of this section, the cover and all openings shall be maintained without leaks as specified in § 63.1258(h).</P> <P>(iii) The cover and all openings shall be maintained in a closed position (e.g., covered by a lid) at all times that affected wastewater or a residual removed from affected wastewater is in the container except when it is necessary to use the opening for filling, removal, inspection, sampling, or pressure relief events related to safety considerations.</P> <P>(2) For containers with a capacity greater than or equal to 0.42 m<E T="51">3</E>, either a submerged fill pipe shall be used when a container is being filled by pumping with affected wastewater or a residual removed from affected wastewater or the container shall be located within an enclosure with a closed-vent system that routes the organic HAP vapors vented from the container to a control device.</P> <P>(i) The submerged fill pipe outlet shall extend to no more than 6 inches or within two fill pipe diameters of the bottom of the container while the container is being filled.</P> <P>(ii) The cover shall remain in place and all openings shall be maintained in a closed position except for those openings required for the submerged fill pipe and for venting of the container to prevent physical damage or permanent deformation of the container or cover.</P> <P>(3) During treatment of affected wastewater or a residual removed from affected wastewater, including aeration, thermal or other treatment, in a container, whenever it is necessary for the container to be open, the container shall be located within an enclosure with a closed-vent system that routes the organic HAP vapors vented from the container to a control device.</P> <P>(i) Except as provided in paragraph (d)(3)(iv) of this section, the enclosure and all openings (e.g., doors, hatches) shall be maintained in accordance with the requirements specified in § 63.1258(h).<PRTPAGE P="50"/> </P> <P>(ii) The control device shall be designed, operated, and inspected in accordance with paragraph (h) of this section.</P> <P>(iii) Except as provided in paragraph (d)(3)(iv) of this section, the closed-vent system shall be inspected in accordance with § 63.1258(h).</P> <P>(iv) For any enclosure and closed-vent system that is operated and maintained under negative pressure, the owner or operator is not required to comply with the requirements specified in § 63.1258(h).</P> <P>(4) Each container shall be inspected initially, and semiannually thereafter, for improper work practices and control equipment failures in accordance with § 63.1258(g).</P> <P>(i) For containers, improper work practice includes, but is not limited to, leaving open any access hatch or other opening when such hatch or opening is not in use.</P> <P>(ii) For containers, control equipment failure includes, but is not limited to, any time a cover or door has a gap or crack, or is broken.</P> <P>(5) Except as provided in paragraph (i) of this section, when an improper work practice or a control equipment failure is identified, first efforts at repair shall be made no later than 5 calendar days after identification and repair shall be completed within 15 calendar days after identification.</P> <P>(e) <E T="03">Individual drain systems.</E> For each individual drain system that receives or manages affected wastewater or a residual removed from affected wastewater, the owner or operator shall comply with the requirements of paragraphs (e) (1), (2), and (3) or with paragraphs (e) (4), (5), and (6) of this section.</P> <P>(1) If the owner or operator elects to comply with this paragraph, the owner or operator shall operate and maintain on each opening in the individual drain system a cover and if vented, route the vapors to a process or through a closed-vent system to a control device. The owner or operator shall comply with the requirements of paragraphs (e)(1) (i) through (v) of this section.</P> <P>(i) The cover and all openings shall meet the following requirements:</P> <P>(A) Except as provided in paragraph (e)(1)(iv) of this section, the cover and all openings (e.g., access hatches, sampling ports) shall be maintained in accordance with the requirements specified in § 63.1258(h).</P> <P>(B) The cover and all openings shall be maintained in a closed position at all times that affected wastewater or a residual removed from affected wastewater is in the drain system except when it is necessary to use the opening for sampling or removal, or for equipment inspection, maintenance, or repair.</P> <P>(ii) The control device shall be designed, operated, and inspected in accordance with paragraph (h) of this section.</P> <P>(iii) Except as provided in paragraph (e)(1)(iv) of this section, the closed-vent system shall be inspected in accordance with § 63.1258(h).</P> <P>(iv) For any cover and closed-vent system that is operated and maintained under negative pressure, the owner or operator is not required to comply with the requirements specified in § 63.1258(h).</P> <P>(v) The individual drain system shall be designed and operated to segregate the vapors within the system from other drain systems and the atmosphere.</P> <P>(2) Each individual drain system shall be inspected initially, and semiannually thereafter, for improper work practices and control equipment failures, in accordance with § 63.1258(g).</P> <P>(i) For individual drain systems, improper work practice includes, but is not limited to, leaving open any access hatch or other opening when such hatch or opening is not in use for sampling or removal, or for equipment inspection, maintenance, or repair.</P> <P>(ii) For individual drain systems, control equipment failure includes, but is not limited to, any time a joint, lid, cover, or door has a gap or crack, or is broken.</P> <P>(3) Except as provided in paragraph (i) of this section, when an improper work practice or a control equipment failure is identified, first efforts at repair shall be made no later than 5 calendar days after identification and repair shall be completed within 15 calendar days after identification.</P> <P>(4) If the owner or operator elects to comply with this paragraph, the owner <PRTPAGE P="51"/>or operator shall comply with the requirements in paragraphs (e)(4) (i) through (iii) of this section:</P> <P>(i) Each drain shall be equipped with water seal controls or a tightly fitting cap or plug. The owner or operator shall comply with paragraphs (e)(4)(i)(A) and (B) of this section.</P> <P>(A) For each drain equipped with a water seal, the owner or operator shall ensure that the water seal is maintained. For example, a flow-monitoring device indicating positive flow from a main to a branch water line supplying a trap or water being continuously dripped into the trap by a hose could be used to verify flow of water to the trap. Visual observation is also an acceptable alternative.</P> <P>(B) If a water seal is used on a drain receiving affected wastewater, the owner or operator shall either extend the pipe discharging the wastewater below the liquid surface in the water seal of the receiving drain, or install a flexible shield (or other enclosure which restricts wind motion across the open area between the pipe and the drain) that encloses the space between the pipe discharging the wastewater to the drain receiving the wastewater. (Water seals which are used on hubs receiving wastewater that is not subject to the provisions of this subpart for the purpose of eliminating cross ventilation to drains carrying affected wastewater are not required to have a flexible cap or extended subsurface discharging pipe.)</P> <P>(ii) Each junction box shall be equipped with a tightly fitting solid cover (i.e., no visible gaps, cracks, or holes) which shall be kept in place at all times except during inspection and maintenance. If the junction box is vented, the owner or operator shall comply with the requirements in paragraph (e)(4)(ii) (A) or (B) of this section.</P> <P>(A) The junction box shall be vented to a process or through a closed-vent system to a control device. The closed-vent system shall be inspected in accordance with the requirements of § 63.1258(h) and the control device shall be designed, operated, and inspected in accordance with the requirements of paragraph (h) of this section.</P> <P>(B) If the junction box is filled and emptied by gravity flow (i.e., there is no pump) or is operated with no more than slight fluctuations in the liquid level, the owner or operator may vent the junction box to the atmosphere provided that the junction box complies with the requirements in paragraphs (e)(4)(ii)(B) (<E T="03">1</E>) and (<E T="03">2</E>) of this section.</P> <P>(<E T="03">1</E>) The vent pipe shall be at least 90 centimeters in length and no greater than 10.2 centimeters in nominal inside diameter.</P> <P>(<E T="03">2</E>) Water seals shall be installed and maintained at the wastewater entrance(s) to or exit from the junction box restricting ventilation in the individual drain system and between components in the individual drain system. The owner or operator shall demonstrate (e.g., by visual inspection or smoke test) upon request by the Administrator that the junction box water seal is properly designed and restricts ventilation.</P> <P>(iii) Each sewer line shall not be open to the atmosphere and shall be covered or enclosed in a manner so as to have no visible gaps or cracks in joints, seals, or other emission interfaces. (Note: This provision applies to sewers located inside and outside of buildings.)</P> <P>(5) Equipment used to comply with paragraphs (e)(4) (i), (ii), or (iii) of this section shall be inspected as follows:</P> <P>(i) Each drain using a tightly fitting cap or plug shall be visually inspected initially, and semiannually thereafter, to ensure caps or plugs are in place and that there are no gaps, cracks, or other holes in the cap or plug.</P> <P>(ii) Each junction box shall be visually inspected initially, and semiannually thereafter, to ensure that there are no gaps, cracks, or other holes in the cover.</P> <P>(iii) The unburied portion of each sewer line shall be visually inspected initially, and semiannually thereafter, for indication of cracks or gaps that could result in air emissions.</P> <P>(6) Except as provided in paragraph (i) of this section, when a gap, hole, or crack is identified in a joint or cover, first efforts at repair shall be made no later than 5 calendar days after identification, and repair shall be completed <PRTPAGE P="52"/>within 15 calendar days after identification.</P> <P>(f) <E T="03">Oil-water separators.</E> For each oil-water separator that receives, manages, or treats affected wastewater or a residual removed from affected wastewater, the owner or operator shall comply with the requirements of paragraphs (f)(1) through (6) of this section.</P> <P>(1) The owner or operator shall maintain one of the following:</P> <P>(i) A fixed roof and a closed-vent system that routes the organic HAP vapors vented from the oil-water separator to a control device. The fixed roof, closed-vent system, and control device shall meet the requirements specified in paragraph (f)(2) of this section;</P> <P>(ii) A floating roof that meets the requirements in 40 CFR 60.693-2(a)(1)(i), (a)(1)(ii), (a)(2), (a)(3), and (a)(4). For portions of the oil-water separator where it is infeasible to construct and operate a floating roof, such as over the weir mechanism, the owner or operator shall operate and maintain a fixed roof, closed-vent system, and control device that meet the requirements specified in paragraph (f)(2) of this section.</P> <P>(2) A fixed roof shall meet the requirements of paragraph (f)(2)(i) of this section, a control device shall meet the requirements of paragraph (f)(2)(ii) of this section, and a closed-vent system shall meet the requirements of (f)(2)(iii) of this section.</P> <P>(i) The fixed roof shall meet the following requirements:</P> <P>(A) Except as provided in (f)(2)(iv) of this section, the fixed roof and all openings (e.g., access hatches, sampling ports, and gauge wells) shall be maintained in accordance with the requirements specified in § 63.1258(h).</P> <P>(B) Each opening shall be maintained in a closed, sealed position (e.g., covered by a lid that is gasketed and latched) at all times that the oil-water separator contains affected wastewater or a residual removed from affected wastewater except when it is necessary to use the opening for sampling or removal, or for equipment inspection, maintenance, or repair.</P> <P>(ii) The control device shall be designed, operated, and inspected in accordance with the requirements of paragraph (h) of this section.</P> <P>(iii) Except as provided in paragraph (f)(2)(iv) of this section, the closed-vent system shall be inspected in accordance with the requirements of § 63.1258(h).</P> <P>(iv) For any fixed-roof and closed-vent system that is operated and maintained under negative pressure, the owner or operator is not required to comply with the requirements of § 63.1258(h).</P> <P>(3) If the owner or operator elects to comply with the requirements of paragraph (f)(1)(ii) of this section, seal gaps shall be measured according to the procedures specified in 40 CFR part 60, subpart QQQ § 60.696(d)(1) and the schedule specified in paragraphs (f)(3)(i) and (ii) of this section.</P> <P>(i) Measurement of primary seal gaps shall be performed within 60 calendar days after installation of the floating roof and introduction of affected wastewater or a residual removed from affected wastewater and once every 5 years thereafter.</P> <P>(ii) Measurement of secondary seal gaps shall be performed within 60 calendar days after installation of the floating roof and introduction of affected wastewater or a residual removed from affected wastewater and once every year thereafter.</P> <P>(4) Each oil-water separator shall be inspected initially, and semiannually thereafter, for improper work practices in accordance with § 63.1258(g). For oil-water separators, improper work practice includes, but is not limited to, leaving open or ungasketed any access door or other opening when such door or opening is not in use.</P> <P>(5) Each oil-water separator shall be inspected for control equipment failures as defined in paragraph (f)(5)(i) of this section according to the schedule specified in paragraphs (f)(5)(ii) and (iii) of this section.</P> <P>(i) For oil-water separators, control equipment failure includes, but is not limited to, the conditions specified in paragraphs (f)(5)(i)(A) through (G) of this section.</P> <P>(A) The floating roof is not resting on either the surface of the liquid or on the leg supports.<PRTPAGE P="53"/> </P> <P>(B) There is stored liquid on the floating roof.</P> <P>(C) A rim seal is detached from the floating roof.</P> <P>(D) There are holes, tears, or other open spaces in the rim seal or seal fabric of the floating roof.</P> <P>(E) There are gaps between the primary seal and the separator wall that exceed 67 square centimeters per meter of separator wall perimeter or the width of any portion of any gap between the primary seal and the separator wall exceeds 3.8 centimeters.</P> <P>(F) There are gaps between the secondary seal and the separator wall that exceed 6.7 square centimeters per meter of separator wall perimeter or the width of any portion of any gap between the secondary seal and the separator wall exceeds 1.3 centimeters.</P> <P>(G) A gasket, joint, lid, cover, or door has a gap or crack, or is broken.</P> <P>(ii) The owner or operator shall inspect for the control equipment failures in paragraphs (f)(5)(i)(A) through (F) according to the schedule specified in paragraph (f)(3) of this section.</P> <P>(iii) The owner or operator shall inspect for control equipment failures in paragraph (f)(5)(i)(G) of this section initially, and semiannually thereafter.</P> <P>(6) Except as provided in paragraph (i) of this section, when an improper work practice or a control equipment failure is identified, first efforts at repair shall be made no later than 5 calendar days after identification and repair shall be completed within 45 calendar days after identification.</P> <P>(g) <E T="03">Performance standards for treatment processes managing wastewater and/or residuals removed from wastewater.</E> This section specifies the performance standards for treating affected wastewater. The owner or operator shall comply with the requirements as specified in paragraphs (g)(1) through (6) of this section. Where multiple compliance options are provided, the options may be used in combination for different wastewater and/or for different compounds (e.g., soluble versus partially soluble compounds) in the same wastewater, except where otherwise provided in this section. Once affected wastewater or a residual removed from affected wastewater has been treated in accordance with this subpart, it is no longer subject to the requirements of this subpart.</P> <P>(1) <E T="03">Existing source.</E> For a wastewater stream at an existing source that exceeds or is designated to exceed the concentration and load criteria in paragraph (a)(1)(i)(A) of this section, the owner or operator shall comply with a control option in paragraph (g)(8) of this section. For a wastewater stream at an existing source that exceeds the concentration and load criteria in either paragraph (a)(1)(i)(B) or (C) of this section, the owner or operator shall comply with a control option in paragraph (g)(8) of this section and a control option in paragraph (g)(9) of this section. As an alternative to the control options in paragraphs (g)(8) and (g)(9) of this section, the owner or operator may comply with a control option in either paragraph (g)(10), (11) or (13) of this section, as applicable.</P> <P>(2) <E T="03">New source.</E> For a wastewater stream at a new source that exceeds or is designated to exceed the concentration and load criteria in paragraph (a)(1)(i)(A) of this section, the owner or operator shall comply with a control option in paragraph (g)(8) of this section. For wastewater at a new source that exceeds the concentration and load criteria in either paragraph (a)(1)(i)(B) or (C) of this section, but does not exceed the criteria in paragraph (a)(1)(i)(D) of this section, the owner or operator shall comply with a control option in paragraph (g)(8) of this section and a control option in paragraph (g)(9) of this section. As an alternative to the control options in paragraphs (g)(8) and/or (9) of this section, the owner or operator may comply with a control option in either paragraph (g)(10), (11), or (13) of this section, as applicable. For a wastewater stream at a new source that exceeds or is designated to exceed the concentration and load criteria in paragraph (a)(1)(i)(D) of this section, the owner or operator shall comply with a control option in paragraph (g)(12) or (13) of this section.</P> <P>(3) <E T="03">Biological treatment processes.</E> Biological treatment processes in compliance with this section may be either open or closed biological treatment processes as defined in § 63.1251. An open biological treatment process in <PRTPAGE P="54"/>compliance with this section need not be covered and vented to a control device. An open or a closed biological treatment process in compliance with this section and using § 63.1257(e)(2)(iii)(E) or (F) to demonstrate compliance is not subject to the requirements of paragraphs (b) and (c) of this section. A closed biological treatment process in compliance with this section and using § 63.1257(e)(2)(iii)(G) to demonstrate compliance shall comply with the requirements of paragraphs (b) and (c) of this section. Waste management units upstream of an open or closed biological treatment process shall meet the requirements of paragraphs (b) through (f) of this section, as applicable.</P> <P>(4) <E T="03">Performance tests and design evaluations.</E> If the Resource Conservation and Recovery Act (RCRA) option [paragraph (g)(13) of this section] or the enhanced biological treatment process for soluble HAP compounds option [paragraph (g)(10) of this section] is selected to comply with this section, neither a design evaluation nor a performance test is required. For any other nonbiological treatment process, and for closed biological treatment processes as defined in § 63.1251, the owner or operator shall conduct either a design evaluation as specified in § 63.1257(e)(2)(ii) or performance test as specified in § 63.1257(e)(2)(iii). For each open biological treatment process as defined in § 63.1251, the owner or operator shall conduct a performance test as specified in § 63.1257(e)(2)(iii)(E) or (F).</P> <P>(5) <E T="03">Control device requirements.</E> When gases are vented from the treatment process, the owner or operator shall comply with the applicable control device requirements specified in paragraph (h) of this section and § 63.1257(e)(3), and the applicable leak inspection provisions specified in § 63.1258(h). This requirement is in addition to the requirements for treatment systems specified in paragraphs (g)(8) through (14) of this section. This requirement does not apply to any open biological treatment process that meets the mass removal requirements.</P> <P>(6) <E T="03">Residuals: general.</E> When residuals result from treating affected wastewater, the owner or operator shall comply with the requirements for residuals specified in paragraph (g)(14) of this section.</P> <P>(7) <E T="03">Treatment using a series of treatment processes.</E> In all cases where the wastewater provisions in this subpart allow or require the use of a treatment process or control device to comply with emissions limitations, the owner or operator may use multiple treatment processes or control devices, respectively. For combinations of treatment processes where the wastewater stream is conveyed by hard-piping, the owner or operator shall comply with either the requirements of paragraph (g)(7)(i) or (ii) of this section. For combinations of treatment processes where the wastewater stream is not conveyed by hard-piping, the owner or operator shall comply with the requirements of paragraph (g)(7)(ii) of this section. For combinations of control devices, the owner or operator shall comply with the requirements of paragraph (g)(7)(i) of this section.</P> <P>(i) <E T="03">Compliance across the combination of all treatment units or control devices in series.</E> (A) For combinations of treatment processes, the wastewater stream shall be conveyed by hard-piping between the treatment processes. For combinations of control devices, the vented gas stream shall be conveyed by hard-piping between the control devices.</P> <P>(B) For combinations of treatment processes, each treatment process shall meet the applicable requirements of paragraphs (b) through (f) of this section, except as provided in paragraph (g)(3) of this section.</P> <P>(C) The owner or operator shall identify, and keep a record of, the combination of treatment processes or of control devices, including identification of the first and last treatment process or control device. The owner or operator shall include this information as part of the treatment process description reported in the Notification of Compliance Status.</P> <P>(D) The performance test or design evaluation shall determine compliance across the combination of treatment processes or control devices. If a performance test is conducted, the “inlet” shall be the point at which the wastewater stream or residual enters the <PRTPAGE P="55"/>first treatment process, or the vented gas stream enters the first control device. The “outlet” shall be the point at which the treated wastewater stream exits the last treatment process, or the vented gas stream exits the last control device.</P> <P>(ii)<E T="03"> Compliance across individual units.</E> (A) For combinations of treatment processes, each treatment process shall meet the applicable requirements of paragraphs (b) through (f) of this section except as provided in paragraph (g)(3) of this section.</P> <P>(B) The owner or operator shall identify, and keep a record of, the combination of treatment processes, including identification of the first and last treatment process. The owner or operator shall include this information as part of the treatment process description reported in the Notification of Compliance Status report.</P> <P>(C) The owner or operator shall determine the mass removed or destroyed by each treatment process. The performance test or design evaluation shall determine compliance for the combination of treatment processes by adding together the mass removed or destroyed by each treatment process and determine the overall control efficiency of the treatment system.</P> <P>(8) <E T="03">Control options: Wastewater containing partially soluble HAP compounds.</E> The owner or operator shall comply with either paragraph (g)(8)(i) or (ii) of this section for the control of partially soluble HAP compounds at new or existing sources.</P> <P>(i) <E T="03">50 ppmw concentration option.</E> The owner or operator shall comply with paragraphs (g)(8)(i)(A) and (B) of this section.</P> <P>(A) Reduce, by removal or destruction, the concentration of total partially soluble HAP compounds to a level less than 50 ppmw as determined by the procedures specified in § 63.1257(e)(2)(iii)(B).</P> <P>(B) This option shall not be used when the treatment process is a biological treatment process. This option shall not be used when the wastewater is designated as an affected wastewater as specified in paragraph (a)(1)(ii) of this section. Dilution shall not be used to achieve compliance with this option.</P> <P>(ii) <E T="03">Percent mass removal/destruction option.</E> The owner or operator shall reduce, by removal or destruction, the mass of total partially soluble HAP compounds by 99 percent or more. The removal destruction efficiency shall be determined by the procedures specified in § 63.1257(e)(2)(iii)(C), for noncombustion, nonbiological treatment processes; § 63.1257(e)(2)(iii)(D), for combustion processes; and § 63.1257(e)(2)(iii)(F) or (G) for biological treatment processes.</P> <P>(9) <E T="03">Control options: Wastewater containing soluble HAP compounds.</E> The owner or operator shall comply with either paragraph (g)(9)(i) or (ii) of this section for the control of soluble HAP compounds at new or existing sources.</P> <P>(i) <E T="03">520 ppmw concentration option.</E> The owner or operator shall comply with paragraphs (g)(9)(i)(A) and (B) of this section.</P> <P>(A) Reduce, by removal or destruction, the concentration of total soluble HAP compounds to a level less than 520 ppmw as determined in the procedures specified in § 63.1257(e)(2)(iii)(B).</P> <P>(B) This option shall not be used when the treatment process is a biological treatment process. This option shall not be used when the wastewater is designated as an affected wastewater as specified in paragraph (a)(1)(ii) of this section. Dilution shall not be used to achieve compliance with this option.</P> <P>(ii) <E T="03">Percent mass removal/destruction option.</E> The owner or operator shall reduce, by removal or destruction, the mass of total soluble HAP by 90 percent or more. The removal/destruction efficiency shall be determined by the procedures in § 63.1257(e)(2)(iii)(C), for noncombustion, nonbiological treatment processes; § 63.1257(e)(2)(iii)(D), for combustion processes; and § 63.1257(e)(2)(iii)(F) or (G) for biological treatment processes.</P> <P>(10) <E T="03">Control option: Enhanced biotreatment for wastewater containing soluble HAP.</E> The owner or operator may elect to treat affected wastewater streams containing soluble HAP and less than 50 ppmw partially soluble HAP in an enhanced biological treatment system, as defined in § 63.1251. This option shall not be used when the wastewater is designated as an affected wastewater as specified in paragraph (a)(1)(ii) of <PRTPAGE P="56"/>this section. These treatment processes are exempt from the design evaluation or performance tests requirements specified in paragraph (g)(4) of this section.</P> <P>(11) <E T="03">95-percent mass reduction option, for biological treatment processes.</E> The owner or operator of a new or existing source using biological treatment for any affected wastewater shall reduce the mass of total soluble and partially soluble HAP sent to that biological treatment unit by at least 95 percent. All wastewater as defined in § 63.1251 entering such a biological treatment unit from PMPU's subject to this subpart shall be included in the demonstration of the 95-percent mass removal. The owner or operator shall comply with paragraphs (g)(11)(i) through (iv) of this section.</P> <P>(i) Except as provided in paragraph (g)(11)(iv) of this section, the owner or operator shall ensure that all wastewater from PMPU's subject to this subpart entering a biological treatment unit are treated to destroy at least 95-percent total mass of all soluble and partially soluble HAP compounds.</P> <P>(ii) For open biological treatment processes, compliance shall be determined using the procedures specified in § 63.1257(e)(2)(iii)(E). For closed aerobic biological treatment processes compliance shall be determined using the procedures specified in § 63.1257(e)(2)(iii)(E) or (G). For closed anaerobic biological treatment processes compliance shall be determined using the procedures specified in § 63.1257(e)(2)(iii)(G).</P> <P>(iii) For each treatment process or waste management unit that receives, manages, or treats wastewater subject to this paragraph, from the POD to the biological treatment unit, the owner or operator shall comply with paragraphs (b) through (f) of this section for control of air emissions. When complying with this paragraph, the term affected wastewater in paragraphs (b) through (f) of this section shall mean all wastewater from PMPU's, not just affected wastewater.</P> <P>(iv) If wastewater is in compliance with the requirements in paragraph (g)(8), (9), or (12) of this section before entering the biological treatment unit, the hazardous air pollutants mass of that wastewater is not required to be included in the total mass flow rate entering the biological treatment unit for the purpose of demonstrating compliance.</P> <P>(12) <E T="03">Percent mass removal/destruction option for soluble HAP compounds at new sources.</E> The owner or operator of a new source shall reduce, by removal or destruction, the mass flow rate of total soluble HAP from affected wastewater by 99 percent or more. The removal/destruction efficiency shall be determined by the procedures in § 63.1257(e)(2)(iii)(C), for noncombustion, nonbiological treatment processes; § 63.1257(e)(2)(iii)(D), for combustion processes; and § 63.1257(e)(2)(iii)(F) or (G) for biological treatment processes.</P> <P>(13) <E T="03">Treatment in a RCRA unit option.</E> The owner or operator shall treat the affected wastewater or residual in a unit identified in, and complying with, paragraph (g)(13)(i), (ii), or (iii) of this section. These units are exempt from the design evaluation or performance tests requirements specified in paragraph (g)(4) of this section and § 63.1257(e)(2), and from the monitoring requirements specified in paragraph (a)(2)(iii) of this section, as well as recordkeeping and reporting requirements associated with monitoring and performance tests.</P> <P>(i) The wastewater or residual is discharged to a hazardous waste incinerator for which the owner or operator has been issued a final permit under 40 CFR part 270 and complies with the requirements of 40 CFR part 264, subpart O, or has certified compliance with the interim status requirements of 40 CFR part 265, subpart O;</P> <P>(ii) The wastewater or residual is discharged to a process heater or boiler burning hazardous waste for which the owner or operator:</P> <P>(A) Has been issued a final permit under 40 CFR part 270 and complies with the requirements of 40 CFR part 266, subpart H; or</P> <P>(B) Has certified compliance with the interim status requirements of 40 CFR part 266, subpart H.</P> <P>(iii) The wastewater or residual is discharged to an underground injection well for which the owner or operator has been issued a final permit under 40 CFR part 270 or 40 CFR part 144 and <PRTPAGE P="57"/>complies with the requirements of 40 CFR part 122. The owner or operator shall comply with all applicable requirements of this subpart prior to the point where the wastewater enters the underground portion of the injection well.</P> <P>(14) <E T="03">Residuals.</E> For each residual removed from affected wastewater, the owner or operator shall control for air emissions by complying with paragraphs (b) through (f) of this section and by complying with one of the provisions in paragraphs (g)(14)(i) through (iv) of this section.</P> <P>(i) Recycle the residual to a production process or sell the residual for the purpose of recycling. Once a residual is returned to a production process, the residual is no longer subject to this section.</P> <P>(ii) Return the residual to the treatment process.</P> <P>(iii) Treat the residual to destroy the total combined mass flow rate of soluble and/or partially soluble HAP compounds by 99 percent or more, as determined by the procedures specified in § 63.1257(e)(2)(iii)(C) or (D).</P> <P>(iv) Comply with the requirements for RCRA treatment options specified in paragraph (g)(13) of this section.</P> <P>(h) <E T="03">Control devices.</E> For each control device or combination of control devices used to comply with the provisions in paragraphs (b) through (f) and (g)(5) of this section, the owner or operator shall operate and maintain the control device or combination of control devices in accordance with the requirements of paragraphs (h) (1) through (4) of this section.</P> <P>(1) Whenever organic HAP emissions are vented to a control device which is used to comply with the provisions of this subpart, such control device shall be operating.</P> <P>(2) The control device shall be designed and operated in accordance with paragraph (h)(2) (i), (ii), (iii), (iv), or (v) of this section, as demonstrated by the provisions in § 63.1257(e)(3).</P> <P>(i) An enclosed combustion device (including but not limited to a vapor incinerator, boiler, or process heater) shall meet the conditions in paragraph (h)(2)(i) (A), (B), or (C) of this section, alone or in combination with other control devices. If a boiler or process heater is used as the control device, then the vent stream shall be introduced into the flame zone of the boiler or process heater.</P> <P>(A) Reduce the organic HAP emissions vented to the control device by 95 percent by weight or greater;</P> <P>(B) Achieve an outlet TOC concentration of 20 ppmv on a dry basis corrected to 3 percent oxygen. The owner or operator shall use either Method 18 of 40 CFR part 60, appendix A, or any other method or data that has been validated according to the applicable procedures in Method 301 of appendix A of this part; or</P> <P>(C) Provide a minimum residence time of 0.5 seconds at a minimum temperature of 760°C.</P> <P>(ii) A vapor recovery system (including but not limited to a carbon adsorption system or condenser), alone or in combination with other control devices, shall reduce the organic HAP emissions vented to the control device by 95 percent by weight or greater or achieve an outlet TOC concentration of 20 ppmv. The 20 ppmv performance standard is not applicable to compliance with the provisions of paragraphs (c) or (d) of this section.</P> <P>(iii) A flare shall comply with the requirements of § 63.11(b).</P> <P>(iv) A scrubber, alone or in combination with other control devices, shall reduce the organic HAP emissions in such a manner that 95 weight-percent is either removed, or destroyed by chemical reaction with the scrubbing liquid, or achieve an outlet TOC concentration of 20 ppmv. The 20 ppmv performance standard is not applicable to compliance with the provisions of paragraphs (c) or (d) of this section.</P> <P>(v) Any other control device used shall, alone or in combination with other control devices, reduce the organic HAP emissions vented to the control device by 95 percent by weight or greater or achieve an outlet TOC concentration of 20 ppmv. The 20 ppmv performance standard is not applicable to compliance with the provisions of paragraphs (c) or (d) of this section.</P> <P>(3) If the control device is a combustion device, the owner or operator shall comply with the requirements in § 63.1252(g) to control halogenated vent streams.<PRTPAGE P="58"/> </P> <P>(4) Except as provided in paragraph (i) of this section, if gaps, cracks, tears, or holes are observed in ductwork, piping, or connections to covers and control devices during an inspection, a first effort to repair shall be made as soon as practical but no later than 5 calendar days after identification. Repair shall be completed no later than 15 calendar days after identification or discovery of the defect.</P> <P>(i) <E T="03">Delay of repair.</E> Delay of repair of equipment for which a control equipment failure or a gap, crack, tear, or hole has been identified, is allowed if the repair is technically infeasible without a shutdown, as defined in § 63.1251, or if the owner or operator determines that emissions of purged material from immediate repair would be greater than the emissions likely to result from delay of repair. Repair of this equipment shall occur by the end of the next shutdown.</P> <P>(1) Delay of repair of equipment for which a control equipment failure or a gap, crack, tear, or hole has been identified, is allowed if the equipment is emptied or is no longer used to treat or manage affected wastewater or residuals removed from affected wastewater.</P> <P>(2) Delay of repair of equipment for which a control equipment failure or a gap, crack, tear, or hole has been identified is also allowed if additional time is necessary due to the unavailability of parts beyond the control of the owner or operator. Repair shall be completed as soon as practical. The owner or operator who uses this provision shall comply with the requirements of § 63.1259(h) to document the reasons that the delay of repair was necessary.</P> </SECTION> <SECTION> <SECTNO>§ 63.1257</SECTNO> <SUBJECT> Test methods and compliance procedures.</SUBJECT> <P>(a) <E T="03">General.</E> Except as specified in paragraph (a)(5) of this section, the procedures specified in paragraphs (c), (d), (e), and (f) of this section are required to demonstrate initial compliance with §§ 63.1253, 63.1254, 63.1256, and 63.1252(e), respectively. The provisions in paragraphs (a) (2) through (3) apply to performance tests that are specified in paragraphs (c), (d), and (e) of this section. The provisions in paragraph (a)(5) of this section are used to demonstrate initial compliance with the alternative standards specified in §§ 63.1253(d) and 63.1254(c). The provisions in paragraph (a)(6) of this section are used to comply with the outlet concentration requirements specified in §§ 63.1253(c), 63.1254 (a)(2)(i) and (a)(3)(ii)(B), 63.1254(b)(i) and 63.1256(h)(2).</P> <P>(1) <E T="03">Design evaluation.</E> To demonstrate that a control device meets the required control efficiency, a design evaluation must address the composition and organic HAP concentration of the vent stream entering the control device. A design evaluation also must address other vent stream characteristics and control device operating parameters as specified in any one of paragraphs (a)(1) (i) through (vi) of this section, depending on the type of control device that is used. If the vent stream is not the only inlet to the control device, the efficiency demonstration also must consider all other vapors, gases, and liquids, other than fuels, received by the control device.</P> <P>(i) For an enclosed combustion device used to comply with the provisions of 63.1253 (b)(2) or (c)(2), or 63.1256(h)(2)(i)(C) with a minimum residence time of 0.5 seconds and a minimum temperature of 760°C, the design evaluation must document that these conditions exist.</P> <P>(ii) For a combustion control device that does not satisfy the criteria in paragraph (a)(1)(i) of this section, the design evaluation must document control efficiency and address the following characteristics, depending on the type of control device:</P> <P>(A) For a thermal vapor incinerator, the design evaluation must consider the autoignition temperature of the organic HAP, must consider the vent stream flow rate, and must establish the design minimum and average temperature in the combustion zone and the combustion zone residence time.</P> <P>(B) For a catalytic vapor incinerator, the design evaluation shall consider the vent stream flow rate and shall establish the design minimum and average temperatures across the catalyst bed inlet and outlet.</P> <P>(C) For a boiler or process heater, the design evaluation shall consider the vent stream flow rate; shall establish the design minimum and average flame <PRTPAGE P="59"/>zone temperatures and combustion zone residence time; and shall describe the method and location where the vent stream is introduced into the flame zone.</P> <P>(iii) For a condenser, the design evaluation shall consider the vent stream flow rate, relative humidity, and temperature and shall establish the design outlet organic HAP compound concentration level, design average temperature of the condenser exhaust vent stream, and the design average temperatures of the coolant fluid at the condenser inlet and outlet. The temperature of the gas stream exiting the condenser must be measured and used to establish the outlet organic HAP concentration.</P> <P>(iv) For a carbon adsorption system that regenerates the carbon bed directly onsite in the control device such as a fixed-bed adsorber, the design evaluation shall consider the vent stream flow rate, relative humidity, and temperature and shall establish the design exhaust vent stream organic compound concentration level, adsorption cycle time, number and capacity of carbon beds, type and working capacity of activated carbon used for carbon beds, design total regeneration stream mass or volumetric flow over the period of each complete carbon bed regeneration cycle, design carbon bed temperature after regeneration, design carbon bed regeneration time, and design service life of carbon. For vacuum desorption, the pressure drop shall be included.</P> <P>(v) For a carbon adsorption system that does not regenerate the carbon bed directly onsite in the control device such as a carbon canister, the design evaluation shall consider the vent stream mass or volumetric flow rate, relative humidity, and temperature and shall establish the design exhaust vent stream organic compound concentration level, capacity of carbon bed, type and working capacity of activated carbon used for carbon bed, and design carbon replacement interval based on the total carbon working capacity of the control device and source operating schedule.</P> <P>(vi) For a scrubber, the design evaluation shall consider the vent stream composition; constituent concentrations; liquid-to-vapor ratio; scrubbing liquid flow rate and concentration; temperature; and the reaction kinetics of the constituents with the scrubbing liquid. The design evaluation shall establish the design exhaust vent stream organic compound concentration level and will include the additional information in paragraphs (a)(1)(vi)(A) and (B) of this section for trays and a packed column scrubber.</P> <P>(A) Type and total number of theoretical and actual trays;</P> <P>(B) Type and total surface area of packing for entire column, and for individual packed sections if column contains more than one packed section.</P> <P>(2) <E T="03">Calculation of TOC or total organic HAP concentration.</E> The TOC concentration or total organic HAP concentration is the sum of the concentrations of the individual components. If compliance is being determined based on TOC, the owner or operator shall compute TOC for each run using Equation 6 of this subpart. If compliance with the wastewater provisions is being determined based on total organic HAP, the owner or operator shall compute total organic HAP using Equation 6 of this subpart, except that only the organic HAP compounds shall be summed; when determining compliance with paragraph (e)(3)(i) of this section, only the soluble and partially soluble HAP compounds shall be summed.</P> <GPH DEEP="33" SPAN="1"> <GID>ER21SE98.003</GID> </GPH> <FP SOURCE="FP-2">where:</FP> <P>CG<E T="52">T</E>=total concentration of TOC in vented gas stream, average of samples, dry basis, ppmv</P> <FP SOURCE="FP-2">CGS<E T="52">i,j</E>=concentration of sample components in vented gas stream for sample j, dry basis, ppmv</FP> <FP SOURCE="FP-2">i=identifier for a compound</FP> <FP SOURCE="FP-2">n=number of components in the sample</FP> <FP SOURCE="FP-2">j=identifier for a sample</FP> <FP SOURCE="FP-2">m=number of samples in the sample run</FP> <P>(3) <E T="03">Percent oxygen correction for combustion control devices.</E> If the control device is a combustion device, the TOC or total organic HAP concentrations must be corrected to 3 percent oxygen. The <PRTPAGE P="60"/>integrated sampling and analysis procedures of Method 3B of 40 CFR part 60, appendix A shall be used to determine the actual oxygen concentration (%0<E T="52">2d</E>). The samples shall be taken during the same time that the TOC or total organic HAP samples are taken. The concentration corrected to 3 percent oxygen (C<E T="52">d</E>) shall be computed using Equation 7 of this subpart:</P> <GPH DEEP="31" SPAN="1"> <GID>ER21SE98.004</GID> </GPH> <FP SOURCE="FP-2">where:</FP> <FP SOURCE="FP-2">C<E T="52">c</E> = concentration of TOC or total organic HAP corrected to 3 percent oxygen, dry basis, ppmv</FP> <FP SOURCE="FP-2">C<E T="52">m</E> = total concentration of TOC in vented gas stream, average of samples, dry basis, ppmv</FP> <FP SOURCE="FP-2">%0<E T="52">2d</E> = concentration of oxygen measured in vented gas stream, dry basis, percent by volume</FP> <P>(4) <E T="03">Exemptions from compliance demonstrations.</E> An owner or operator using any control device specified in paragraphs (a)(4)(i) through (iv) of this section is exempt from the initial compliance provisions in paragraphs (c), (d), and (e) of this section.</P> <P>(i) A boiler or process heater with a design heat input capacity of 44 megawatts or greater.</P> <P>(ii) A boiler or process heater into which the emission stream is introduced with the primary fuel.</P> <P>(iii) A boiler or process heater burning hazardous waste for which the owner or operator:</P> <P>(A) Has been issued a final permit under 40 CFR part 270 and complies with the requirements of 40 CFR part 266, subpart H, or</P> <P>(B) Has certified compliance with the interim status requirements of 40 CFR part 266, subpart H.</P> <P>(iv) A hazardous waste incinerator for which the owner or operator has been issued a final permit under 40 CFR part 270 and complies with the requirements of 40 CFR part 264, subpart O, or has certified compliance with the interim status requirements of 40 CFR part 265, subpart O.</P> <P>(5) <E T="03">Initial compliance with alternative standard.</E> Initial compliance with the alternative standards in §§ 63.1253(d) and 63.1254(c) is demonstrated when the outlet TOC concentration is 20 ppmv or less, and the outlet hydrogen halide and halogen concentration is 20 ppmv or less. To demonstrate initial compliance, the owner or operator shall be in compliance with the monitoring provisions in § 63.1258(b)(5) on the initial compliance date. The owner or operator shall use Method 18 to determine the predominant organic HAP in the emission stream if the TOC monitor is calibrated on the predominant HAP.</P> <P>(6) <E T="03">Initial compliance with the 20 ppmv outlet limit.</E> Initial compliance with the 20 ppmv TOC and hydrogen halide and halogen concentration is demonstrated when the outlet TOC concentration is 20 ppmv or less, and the outlet hydrogen halide and halogen concentration is 20 ppmv or less. To demonstrate initial compliance, the operator shall use test methods described in paragraph (b) of this section. The owner or operator shall comply with the monitoring provisions in § 63.1258(b)(1) through (5) of this subpart on the initial compliance date.</P> <P>(b) <E T="03">Test methods.</E> When testing is conducted to measure emissions from an affected source, the test methods specified in paragraphs (b)(1) through (10) of this section shall be used.</P> <P>(1) EPA Method 1 or 1A of appendix A of part 60 is used for sample and velocity traverses.</P> <P>(2) EPA Method 2, 2A, 2C, or 2D of appendix A of part 60 is used for velocity and volumetric flow rates.</P> <P>(3) EPA Method 3 of appendix A of part 60 is used for gas analysis.</P> <P>(4) EPA Method 4 of appendix A of part 60 is used for stack gas moisture.</P> <P>(5) [Reserved]</P> <P>(6) Concentration measurements shall be adjusted to negate the dilution effects of introducing nonaffected gaseous streams into the vent streams prior to control or measurement. The following methods are specified for concentration measurements:</P> <P>(i) Method 18 may be used to determine HAP concentration in any control device efficiency determination.</P> <P>(ii) Method 25 of appendix A of part 60 may be used to determine total gaseous nonmethane organic concentration for control efficiency determinations in combustion devices.<PRTPAGE P="61"/> </P> <P>(iii) Method 26 of appendix A of part 60 shall be used to determine hydrogen chloride concentrations in control device efficiency determinations or in the 20 ppmv outlet hydrogen halide concentration standard.</P> <P>(iv) Method 25A of appendix A of part 60 may be used to determine the HAP or TOC concentration for control device efficiency determinations under the conditions specified in Method 25 of appendix A for direct measurement of an effluent with a flame ionization detector, or in demonstrating compliance with the 20 ppmv TOC outlet standard. If Method 25A is used to determine the concentration of TOC for the 20 ppmv standard, the instrument shall be calibrated on methane or the predominant HAP. If calibrating on the predominant HAP, the use of Method 25A shall comply with paragraphs (b)(6)(iv)(A) through (C) of this section.</P> <P>(A) The organic HAP used as the calibration gas for Method 25A, 40 CFR part 60, appendix A, shall be the single organic HAP representing the largest percent by volume.</P> <P>(B) The use of Method 25A, 40 CFR part 60, appendix A, is acceptable if the response from the high level calibration gas is at least 20 times the standard deviation of the response from the zero calibration gas when the instrument is zeroed on the most sensitive scale.</P> <P>(C) The span value of the analyzer must be less than 100 ppmv.</P> <P>(7) <E T="03">Testing conditions for continuous processes.</E> Testing of emissions on equipment operating as part of a continuous process will consist of three l-hour runs. Gas stream volumetric flow rates shall be measured every 15 minutes during each 1-hour run. The HAP concentration shall be determined from samples collected in an integrated sample over the duration of each l-hour test run, or from grab samples collected simultaneously with the flow rate measurements (every 15 minutes). If an integrated sample is collected for laboratory analysis, the sampling rate shall be adjusted proportionally to reflect variations in flow rate. For continuous gas streams, the emission rate used to determine compliance shall be the average emission rate of the three test runs.</P> <P>(8) <E T="03">Testing and compliance determination conditions for batch processes.</E> Testing of emissions on equipment where the flow of gaseous emissions is intermittent (batch operations) shall be conducted as specified in paragraphs (b)(8)(i) through (iii) of this section.</P> <P>(i) Except as provided in paragraph (b)(9) of this section for condensers, testing shall be conducted at absolute worst-case conditions or hypothetical worst-case conditions. Gas stream volumetric flow rates shall be measured at 15-minute intervals. The HAP or TOC concentration shall be determined from samples collected in an integrated sample over the duration of the test, or from grab samples collected simultaneously with the flow rate measurements (every 15 minutes). If an integrated sample is collected for laboratory analysis, the sampling rate shall be adjusted proportionally to reflect variations in flow rate. The absolute worst-case or hypothetical worst-case conditions shall be characterized by the criteria presented in paragraphs (b)(8)(i)(A) and (B)of this section. In all cases, a site-specific plan shall be submitted to the Administrator for approval prior to testing in accordance with § 63.7(c) and § 63.1260(l). The test plan shall include the emission profile described in paragraph (b)(8)(ii) of this section.</P> <P>(A) Absolute worst-case conditions are defined by the criteria presented in paragraph (b)(8)(i)(A)(<E T="03">1</E>) or (<E T="03">2</E>) of this section if the maximum load is the most challenging condition for the control device. Otherwise, absolute worst-case conditions are defined by the conditions in paragraph (b)(8)(i)(A)(<E T="03">3</E>) of this section.</P> <P>(<E T="03">1</E>) The period in which the inlet to the control device will contain at least 50 percent of the maximum HAP load (in lb) capable of being vented to the control device over any 8 hour period. An emission profile as described in paragraph (b)(8)(ii)(A) of this section shall be used to identify the 8-hour period that includes the maximum projected HAP load.</P> <P>(<E T="03">2</E>) A 1-hour period of time in which the inlet to the control device will contain the highest HAP mass loading rate, in lb/hr, capable of being vented <PRTPAGE P="62"/>to the control device. An emission profile as described in paragraph (b)(8)(ii)(A) of this section shall be used to identify the 1-hour period of maximum HAP loading.</P> <P>(<E T="03">3</E>) The period of time when the HAP loading or stream composition (including non-HAP) is most challenging for the control device. These conditions include, but are not limited to the following:</P> <P>(<E T="03">i</E>) Periods when the stream contains the highest combined VOC and HAP load, in lb/hr, described by the emission profiles in (b)(8)(ii);</P> <P>(<E T="03">ii</E>) Periods when the streams contain HAP constituents that approach limits of solubility for scrubbing media;</P> <P>(<E T="03">iii</E>) Periods when the streams contain HAP constituents that approach limits of adsorptivity for carbon adsorption systems.</P> <P>(B) Hypothetical worst-case conditions are simulated test conditions that, at a minimum, contain the highest hourly HAP load of emissions that would be predicted to be vented to the control device from the emissions profile described in paragraph (b)(8)(ii)(B) or (C) of this section.</P> <P>(ii) <E T="03">Emissions profile.</E> The owner or operator may choose to perform tests only during those periods of the worst-case conditions that the owner or operator selects to control as part of achieving the required emission reduction. The owner or operator must develop an emission profile for the vent to the control device that describes the characteristics of the vent stream at the inlet to the control device under worst case conditions. The emission profile shall be developed based on any one of the procedures described in (b)(8)(ii)(A) through (C) of this section, as required by paragraph (b)(8)(i).</P> <P>(A) <E T="03">Emission profile by process.</E> The emission profile must consider all emission episodes that could contribute to the vent stack for a period of time that is sufficient to include all processes venting to the stack and shall consider production scheduling. The profile shall describe the HAP load to the device that equals the highest sum of emissions from the episodes that can vent to the control device in any given hour. Emissions per episode shall be calculated using the procedures specified in paragraph (d)(2) of this section. Emissions per episode shall be divided by the duration of the episode only if the duration of the episode is longer than 1 hour.</P> <P>(B) <E T="03">Emission profile by equipment.</E> The emission profile must consist of emissions that meet or exceed the highest emissions, in lb/hr, that would be expected under actual processing conditions. The profile shall describe equipment configurations used to generate the emission events, volatility of materials processed in the equipment, and the rationale used to identify and characterize the emission events. The emissions may be based on using a compound more volatile than compounds actually used in the process(es), and the emissions may be generated from all equipment in the process(es) or only selected equipment.</P> <P>(C) <E T="03">Emission profile by capture and control device limitation.</E> The emission profile shall consider the capture and control system limitations and the highest emissions, in lb/hr, that can be routed to the control device, based on maximum flowrate and concentrations possible because of limitations on conveyance and control equipment (e.g., fans, LEL alarms and safety bypasses).</P> <P>(iii) Three runs, at a minimum of 1 hour each and a maximum of 8 hours each, are required for performance testing. Each run must occur over the same worst-case conditions, as defined in paragraph (b)(8)(i) of this section.</P> <P>(9) <E T="03">Testing requirements for condensers.</E> For emission streams controlled using condensers, continuous direct measurement of condenser outlet gas temperature to be used in determining concentrations per the design evaluation described in § 63.1257(a)(1)(iii) is required.</P> <P>(10) <E T="03">Wastewater testing.</E> Wastewater analysis shall be conducted in accordance with paragraph (b)(10)(i), (ii), (iii), or (iv) of this section.</P> <P>(i) <E T="03">Method 305.</E> Use procedures specified in Method 305 of 40 CFR part 63, appendix A and comply with requirements specified in paragraph (b)(10)(v) of this section.</P> <P>(ii) <E T="03">Method 624, 625, 1624, 1625, or 8270.</E> Use procedures specified in Method 624, 625, 1624, 1625, or 8270 of 40 CFR part 136, <PRTPAGE P="63"/>appendix A and comply with requirements in paragraph (b)(10)(v) of this section.</P> <P>(iii) <E T="03">Other EPA Methods.</E> Use procedures specified in the method, validate the method using the procedures in paragraph (b)(10)(iii)(A) or (B) of this section, and comply with the procedures in paragraph (b)(10)(v) of this section.</P> <P>(A) Validate the method according to section 5.1 or 5.3 of Method 301 of 40 CFR part 63, appendix A.</P> <P>(B) Follow the procedure as specified in “Alternative Validation Procedure for EPA Waste Methods” 40 CFR part 63, appendix D.</P> <P>(iv) <E T="03">Methods other than an EPA method.</E> Use procedures specified in the method, validate the method using the procedures in paragraph (b)(10)(iii)(A) of this section, and comply with the requirements in paragraph (b)(10)(v) of this section.</P> <P>(v) <E T="03">Sampling plan.</E> The owner or operator shall prepare a sampling plan. Wastewater samples shall be collected using sampling procedures which minimize loss of organic compounds during sample collection and analysis and maintain sample integrity. The sample plan shall include procedures for determining recovery efficiency of the relevant partially soluble and soluble HAP compounds. An example of an acceptable sampling plan would be one that incorporates similar sampling and sample handling requirements to those of Method 25D of 40 CFR part 60, appendix A. The sampling plan shall be maintained at the facility.</P> <P>(c) <E T="03">Initial compliance with storage tank provisions.</E> The owner or operator of an affected storage tank shall demonstrate initial compliance with § 63.1253(b) or (c), as applicable, by fulfilling the requirements of paragraph (c)(1),or (c)(2), or (c)(3) of this section.</P> <P>(1) <E T="03">Performance test.</E> If this option is chosen to demonstrate initial compliance with the percent reduction requirement of § 63.1253(b)(1) or (c)(1)(i), the efficiency of the control device shall be calculated using performance test data as specified in paragraphs (c)(1)(i) through (iii) of this section. Initial compliance with the outlet concentration requirement of § 63.1253(b)(2) or (c)(1)(ii) is demonstrated by fulfilling the requirements of paragraph (a)(6) of this section.</P> <P>(i) Equations 8 and 9 of this subpart shall be used to calculate the mass rate of total HAP reasonably expected maximum filling rate at the inlet and outlet of the control device for standard conditions of 20°C: where:</P> <GPH DEEP="35" SPAN="1"> <GID>ER21SE98.005</GID> </GPH> <GPH DEEP="35" SPAN="1"> <GID>ER21SE98.006</GID> </GPH> <FP SOURCE="FP-2">where:</FP> <FP SOURCE="FP-2">C<E T="52">ij</E>, C<E T="52">oj</E> = concentration of sample component j of the gas stream at the inlet and outlet of the control device, respectively, dry basis, ppmv</FP> <FP SOURCE="FP-2">E<E T="52">i</E>, E<E T="52">o</E> = mass rate of total HAP at the inlet and outlet of the control device, respectively, dry basis, kg/hr</FP> <FP SOURCE="FP-2">M<E T="52">ij</E>, M<E T="52">oj</E> = molecular weight of sample component j of the gas stream at the inlet and outlet of the control device, respectively, gram/gram-mole</FP> <FP SOURCE="FP-2">Q<E T="52">i</E>, Q<E T="52">o</E> = flow rate of gas stream at the inlet and outlet of the control device, respectively, dry standard cubic meter per minute</FP> <FP SOURCE="FP-2">K<E T="52">2</E> = constant, 2.494 × 10<E T="51">−6</E> (parts per million) <E T="51">−1</E> (gram-mole per standard cubic meter) (kilogram/gram) (minute/hour), where standard temperature is 20°C</FP> <FP SOURCE="FP-2">n = number of sample components in the gas stream</FP> <P>(ii) The percent reduction in total HAP shall be calculated using Equation 10 of this subpart:</P> <GPH DEEP="27" SPAN="1"> <GID>ER21SE98.007</GID> </GPH> <FP SOURCE="FP-2">where:</FP> <FP SOURCE="FP-2">R = control efficiency of control device, percent</FP> <FP SOURCE="FP-2">E<E T="52">i</E> = mass rate of total HAP at the inlet to the control device as calculated under paragraph (c)(1)(i) of this section, kilograms organic HAP per hour<PRTPAGE P="64"/> </FP> <FP SOURCE="FP-2">E<E T="52">o</E> = mass rate of total HAP at the outlet of the control device, as calculated under paragraph (c)(1)(i) of this section, kilograms organic HAP per hour</FP> <P>(iii) A performance test is not required to be conducted if the control device used to comply with § 63.1253 (storage tank provisions) is also used to comply with § 63.1254 (process vent provisions), and compliance with § 63.1254 has been demonstrated in accordance with paragraph (d) of this section.</P> <P>(2) <E T="03">Design evaluation.</E> If this option is chosen to demonstrate initial compliance with the percent reduction requirement of § 63.1253(b) or (c), a design evaluation shall be prepared in accordance with the provisions in paragraph (a)(1) of this section. The design evaluation shall include documentation demonstrating that the control device being used achieves the required control efficiency during reasonably expected maximum filling rate.</P> <P>(3) <E T="03">Floating roof.</E> If the owner or operator of an affected source chooses to comply with the provisions of § 63.1253(b) or (c) by installing a floating roof, the owner or operator shall comply with the procedures described in §§ 63.119(b), (c), (d), and 63.120(a), (b), and (c), with the differences noted in paragraphs (c)(3)(i) through (v) of this section for the purposes of this subpart.</P> <P>(i) When the term “storage vessel” is used in §§ 63.119 and 63.120, the definition of “storage tank” in § 63.1251 shall apply for the purposes of this subpart.</P> <P>(ii) When December 31, 1992 is referred to in § 63.119, April 2, 1997 shall apply instead for the purposes of this subpart.</P> <P>(iii) When April 22, 1994 is referred to in § 63.119, September 21, 1998 shall apply instead for the purposes of this subpart.</P> <P>(iv) When the phrase “the compliance date specified in § 63.100 of subpart F of this part” is referred to in § 63.120, the phrase “the compliance date specified in § 63.1250” shall apply for the purposes of this subpart.</P> <P>(v) When the phrase “the maximum true vapor pressure of the total organic HAP's in the stored liquid falls below the values defining Group 1 storage vessels specified in table 5 or table 6 of this subpart” is referred to in § 63.120(b)(1)(iv), the phrase “the maximum true vapor pressure of the total organic HAP in the stored liquid falls below 13.1 kPa (1.9 psia)” shall apply for the purposes of this subpart.</P> <P>(4) <E T="03">Initial compliance with alternative standard.</E> Initial compliance with § 63.1253(d) is demonstrated by fulfilling the requirements of paragraph (a)(5) of this section.</P> <P>(5) <E T="03">Planned maintenance.</E> The owner or operator shall demonstrate compliance with the requirements of § 63.1253(e) by including the periods of planned routine maintenance specified by date and time in each Periodic Report required by § 63.1260.</P> <P>(d) <E T="03">Initial compliance with process vent provisions.</E> An owner or operator of an affected source complying with the process vent standards in § 63.1254 shall demonstrate compliance using the procedures described in paragraphs (d)(1) through (4) of this section.</P> <P>(1) Except as provided in paragraph (a)(4) of this section, initial compliance with the process vent standards in § 63.1254 shall be demonstrated using the procedures specified in paragraphs (d)(1)(i) through (iv), as applicable.</P> <P>(i) Initial compliance with § 63.1254(a)(1)(i) is demonstrated when the actual emissions of HAP from the sum of all process vents within a process that do not meet the criteria specified in § 63.1254(a)(3) is less than or equal to 2,000 lb/yr. Initial compliance with § 63.1254(a)(1)(ii) is demonstrated when the uncontrolled emissions of HAP from the sum of all process vents within a process is less than or equal to 100 lb/yr. Uncontrolled HAP emissions and controlled HAP emissions shall be determined using the procedures described in paragraphs (d)(2) and (3) of this section.</P> <P>(ii) Initial compliance with the percent reduction requirements in §§ 63.1254(a)(2), (a)(3), and (b) is demonstrated by:</P> <P>(A) Determining controlled HAP emissions using the procedures described in paragraph (d)(3) of this section and uncontrolled HAP emissions <PRTPAGE P="65"/>determined using the procedures described in paragraph (d)(2) of this section and demonstrating that the reductions required by §§ 63.1254(a)(2), (a)(3), and (b) are met; or</P> <P>(B) Controlling the process vents using a device meeting the criteria specified in paragraph (a)(4) of this section.</P> <P>(iii) Initial compliance with the outlet concentration requirements in § 63.1254(a)(2)(ii) and (3) is demonstrated when the outlet TOC concentration is 20 ppmv or less and the outlet hydrogen halide and halogen concentration is 20 ppmv or less. The owner or operator shall demonstrate compliance by fulfilling the requirements in paragraph (a)(6) of this section.</P> <P>(iv) Initial compliance with § 63.1254(c) is demonstrated by fulfilling the requirements of paragraph (a)(5) of this section.</P> <P>(2) <E T="03">Uncontrolled emissions.</E> An owner or operator of an affected source complying with the emission limitation required by § 63.1254(a)(1), or emissions reductions specified in § 63.1254(a)(2), (a)(3), or (b), for each process vent within a process, shall calculate uncontrolled emissions from all equipment in the process according to the procedures described in paragraph (d)(2)(i) or (ii) of this section, as appropriate.</P> <P>(i) <E T="03">Emission estimation procedures.</E> Owners or operators shall determine uncontrolled emissions of HAP using measurements and/or calculations for each batch emission episode within each unit operation according to the engineering evaluation methodology in paragraphs (d)(2)(i)(A) through (H) of this section. Except where variations are noted, individual HAP partial pressures in multicomponent systems shall be determined by the following methods: If the components are miscible in one another, use Raoult's law to calculate the partial pressures; if the solution is a dilute aqueous mixture, use Henry's law to calculate partial pressures; if Raoult's law or Henry's law are not appropriate or available, use experimentally obtained activity coefficients or models such as the group-contribution models, to predict activity coefficients, or assume the components of the system behave independently and use the summation of all vapor pressures from the HAP as the total HAP partial pressure. Chemical property data can be obtained from standard reference texts.</P> <P>(A) <E T="03">Vapor displacement.</E> Emissions from vapor displacement due to transfer of material shall be calculated using Equation 11 of this subpart. The individual HAP partial pressures may be calculated using Raoult's law.</P> <GPH DEEP="29" SPAN="1"> <GID>ER21SE98.008</GID> </GPH> <FP SOURCE="FP-2">where:</FP> <FP SOURCE="FP-2">E = mass of HAP emitted</FP> <FP SOURCE="FP-2">V = volume of gas displaced from the vessel</FP> <FP SOURCE="FP-2">R = ideal gas law constant</FP> <FP SOURCE="FP-2">T = temperature of the vessel vapor space; absolute</FP> <FP SOURCE="FP-2">P<E T="52">i</E> = partial pressure of the individual HAP</FP> <FP SOURCE="FP-2">MW<E T="52">i</E> = molecular weight of the individual HAP</FP> <FP SOURCE="FP-2">n = number of HAP compounds in the emission stream i = identifier for a HAP compound</FP> <P>(B) <E T="03">Purging.</E> Emissions from purging shall be calculated using Equation 12 of this subpart. The partial pressures of individual condensable compounds may be calculated using Raoult's law, the pressure of the vessel vapor space may be set equal to 760 mmHg, and the partial pressure of HAP shall be assumed to be 25 percent of the saturated value if the purge flow rate is greater than 100 standard cubic feet per minute (scfm).</P> <GPH DEEP="45" SPAN="2"> <GID>ER21SE98.009</GID> </GPH> <PRTPAGE P="66"/> <FP SOURCE="FP-2">Where:</FP> <FP SOURCE="FP-2">E = mass of HAP emitted</FP> <FP SOURCE="FP-2">V = purge flow rate at the temperature and pressure of the vessel vapor space</FP> <FP SOURCE="FP-2">R = ideal gas law constant</FP> <FP SOURCE="FP-2">T = temperature of the vessel vapor space; absolute</FP> <FP SOURCE="FP-2">P<E T="52">i</E> = partial pressure of the individual HAP</FP> <FP SOURCE="FP-2">P<E T="52">j</E> = partial pressure of individual condensable VOC compounds (including HAP)</FP> <FP SOURCE="FP-2">P<E T="52">T</E> = pressure of the vessel vapor space</FP> <FP SOURCE="FP-2">MW<E T="52">i</E> = molecular weight of the individual HAP</FP> <FP SOURCE="FP-2">t = time of purge</FP> <FP SOURCE="FP-2">n = number of HAP compounds in the emission stream</FP> <FP SOURCE="FP-2">i = identifier for a HAP compound</FP> <FP SOURCE="FP-2">j = identifier for a condensable compound</FP> <FP SOURCE="FP-2">m = number of condensable compounds (including HAP) in the emission stream</FP> <P>(C) <E T="03">Heating.</E> Emissions caused by the heating of a vessel to a temperature equal to or lower than 10 K below the boiling point shall be calculated using the procedures in either paragraph (d)(2)(i)(C)(<E T="03">1</E>) or (<E T="03">3</E>) of this section. Emissions caused by heating a vessel to a temperature that is higher than 10 K below the boiling point and less than the boiling point, must be calculated using the procedures in either paragraph (d)(2)(i)(C) (<E T="03">2</E>) or (<E T="03">3</E>) of this section. If the contents of a vessel are heated to the boiling point, emissions must be calculated using the procedures in paragraph (d)(2)(i)(C)(<E T="03">4</E>) of this section.</P> <P>(<E T="03">1</E>) This paragraph describes procedures to calculate emissions if the final temperature to which the vessel contents are heated is 10 K below the boiling point of the HAP in the vessel, or lower. The owner or operator shall calculate the mass of HAP emitted per episode using either Equation 13 or 14 of this subpart. The moles of noncondensable gas displaced are calculated using Equation 15 of this subpart. The initial and final pressure of the noncondensable gas in the vessel shall be calculated using Equation 16 of this subpart. The average molecular weight of HAP in the displaced gas shall be calculated using Equation 17 of this subpart.</P> <GPH DEEP="60" SPAN="2"> <GID>ER21SE98.010</GID> </GPH> <GPH DEEP="55" SPAN="2"> <GID>ER21SE98.011</GID> </GPH> <GPH DEEP="33" SPAN="2"> <GID>ER21SE98.012</GID> </GPH> <GPH DEEP="31" SPAN="2"> <GID>ER21SE98.013</GID> </GPH> <GPH DEEP="52" SPAN="2"> <PRTPAGE P="67"/> <GID>ER21SE98.014</GID> </GPH> <FP SOURCE="FP-2">Where:</FP> <FP SOURCE="FP-2">E = mass of HAP vapor displaced from the vessel being heated</FP> <FP SOURCE="FP-2">x<E T="52">i</E> = mole fraction of each HAP in the liquid phase</FP> <FP SOURCE="FP-2">x<E T="52">j</E> = mole fraction of each condensable VOC (including HAP) in the liquid phase</FP> <FP SOURCE="FP-2">(P<E T="52">i</E>*) = vapor pressure of each HAP in the vessel headspace at any temperature between the initial and final heatup temperatures, mmHg</FP> <FP SOURCE="FP-2">(P<E T="52">j</E>*) = vapor pressure of each condensable VOC (including HAP) in the vessel headspace at any temperature between the initial and final heatup temperatures, mmHg</FP> <FP SOURCE="FP-2">760 = atmospheric pressure, mmHg</FP> <FP SOURCE="FP-2">MW<E T="52">HAP</E> = the average molecular weight of HAP present in the displaced gas</FP> <FP SOURCE="FP-2"> <E T="61">Dh</E> = number of moles of noncondensable gas displaced</FP> <FP SOURCE="FP-2">V = volume of free space in the vessel</FP> <FP SOURCE="FP-2">R = ideal gas law constant</FP> <FP SOURCE="FP-2">T<E T="52">1</E> = initial temperature of vessel contents, absolute</FP> <FP SOURCE="FP-2">T<E T="52">2</E> = final temperature of vessel contents, absolute</FP> <FP SOURCE="FP-2">Pa<E T="52">n</E> = partial pressure of noncondensable gas in the vessel headspace at initial (n=1) and final (n=2) temperature</FP> <FP SOURCE="FP-2">P<E T="52">atm</E> = atmospheric pressure (when <E T="61">Dh</E> is used in Equation 13 of this subpart, P<E T="52">atm</E> may be set equal to 760 mmHg for any vessel)</FP> <FP SOURCE="FP-2">(P<E T="52">j</E>)<E T="52">Tn</E> = partial pressure of each condensable compound (including HAP) in the vessel headspace at the initial temperature (n=1) and final (n=2) temperature</FP> <FP SOURCE="FP-2">m = number of condensable compounds (including HAP) in the displaced vapor</FP> <FP SOURCE="FP-2">j = identifier for a condensable compound</FP> <FP SOURCE="FP-2">(P<E T="52">i</E>)<E T="52">Tn</E> = partial pressure of each HAP in the vessel headspace at initial (T<E T="52">1</E>) and final (T<E T="52">2</E>) temperature; [for use in Equation 13, replace (P<E T="52">i</E>)<E T="52">T1</E>+(P<E T="52">i</E>)<E T="52">T2</E> with P<E T="52">i</E> at the temperature used to calculate vapor pressure of HAP in Equation 13]</FP> <FP SOURCE="FP-2">MW<E T="52">i</E> = molecular weight of each HAP</FP> <FP SOURCE="FP-2">n = number of HAP compounds in the emission stream</FP> <FP SOURCE="FP-2">i = identifier for a HAP compound</FP> <P>(<E T="03">2</E>) If the vessel contents are heated to a temperature that is higher than 10 K below the boiling point and less than the boiling point, emissions must be calculated using the procedures in paragraph (d)(2)(i)(C)(<E T="03">2</E>)(<E T="03">i</E>), or (<E T="03">ii</E>), or (<E T="03">iii</E>) of this section.</P> <P>(<E T="03">i</E>) Use Equation 13 of this subpart. In Equation 13 of this subpart, the HAP vapor pressures must be determined at the temperature 10 K below the boiling point. In the calculation of <E T="61">Dh</E> for Equation 13 of this subpart, T<E T="52">2</E> must be the temperature 10 K below the boiling point, and Pa<E T="52">2</E> must be determined at the temperature 10 K below the boiling point. In the calculation of MW<E T="52">HAP</E>, the HAP partial pressures must be determined at the temperature 10 K below the boiling point.</P> <P>(<E T="03">ii</E>) Use Equation 14 of this subpart. In Equation 14 of this subpart, the HAP partial pressures must be deter mined at the temperature 10 K below the boiling point. In the calculation of <E T="61">Dh</E> for Equation 14 of this subpart, T<E T="52">2</E> must be the temperature 10 K below the boiling point, and Pa<E T="52">2</E> must be determined at the temperature 10 K below the boiling point. In the calculation of MW<E T="52">HAP</E>, the HAP partial pressures must be determined at the temperature 10 K below the boiling point.</P> <P>(<E T="03">iii</E>) Use Equation 14 of this subpart over specific temperature increments. If the initial temperature is lower than 10 K below the boiling point, emissions must be calculated as the sum over two increments; one increment is from the initial temperature to 10 K below the boiling point, and the second is from 10 K below the boiling point to the lower of either the final temperature or the temperature 5 K below the boiling <PRTPAGE P="68"/>point. If the initial temperature is higher than 10 K below the boiling point, emissions are calculated over one increment from the initial temperature to the lower of either the final temperature or the temperature 5 K below the boiling point.</P> <P>(<E T="03">3</E>)(<E T="03">i</E>) Emissions caused by heating a vessel are calculated using Equation 18 of this subpart.</P> <GPH DEEP="63" SPAN="2"> <GID>ER21SE98.015</GID> </GPH> <FP SOURCE="FP-2">Where:</FP> <FP SOURCE="FP-2">E = mass of HAP vapor displaced from the vessel being heated</FP> <FP SOURCE="FP-2">N<E T="52">avg</E> = average gas space molar volume during the heating process</FP> <FP SOURCE="FP-2">P<E T="52">T</E>= total pressure in the vessel</FP> <FP SOURCE="FP-2">P<E T="52">i,1</E> = partial pressure of the individual HAP compounds at T<E T="52">1</E> </FP> <FP SOURCE="FP-2">P<E T="52">i,2</E> = partial pressure of the individual HAP compounds at T<E T="52">2</E> </FP> <FP SOURCE="FP-2">MW<E T="52">HAP</E> = average molecular weight of the HAP compounds</FP> <FP SOURCE="FP-2">n<E T="52">i,1</E> = number of moles of condensable in the vessel headspace at T<E T="52">1</E> </FP> <FP SOURCE="FP-2">n<E T="52">i,2</E> = number of moles of condensable in the vessel headspace at T<E T="52">2</E> </FP> <FP SOURCE="FP-2">n = number of HAP compounds in the emission stream</FP> <P>(<E T="03">ii</E>) The average gas space molar volume during the heating process is calculated using Equation 19 of this subpart.</P> <GPH DEEP="31" SPAN="2"> <GID>ER21SE98.016</GID> </GPH> <FP SOURCE="FP-2">Where:</FP> <FP SOURCE="FP-2">N<E T="52">avg</E> = average gas space molar volume during the heating process</FP> <FP SOURCE="FP-2">V = volume of free space in vessel</FP> <FP SOURCE="FP-2">P<E T="52">T</E> = total pressure in the vessel</FP> <FP SOURCE="FP-2">R = ideal gas law constant</FP> <FP SOURCE="FP-2">T<E T="52">1</E> = initial temperature of the vessel</FP> <FP SOURCE="FP-2">T<E T="52">2</E> = final temperature of the vessel</FP> <P>(<E T="03">iii</E>) The difference in the number of moles of condensable in the vessel headspace between the initial and final temperatures is calculated using Equation 20 of this subpart.</P> <GPH DEEP="29" SPAN="2"> <GID>ER21SE98.017</GID> </GPH> <FP SOURCE="FP-2">Where:</FP> <FP SOURCE="FP-2">V = volume of free space in vessel</FP> <FP SOURCE="FP-2">R = ideal gas law constant</FP> <FP SOURCE="FP-2">T<E T="52">1</E> = initial temperature in the vessel</FP> <FP SOURCE="FP-2">T<E T="52">2</E> = final temperature in the vessel</FP> <FP SOURCE="FP-2">P<E T="52">i,1</E> = partial pressure of the individual HAP compounds at T<E T="52">1</E> </FP> <FP SOURCE="FP-2">P<E T="52">i,2</E> = partial pressure of the individual HAP compounds at T<E T="52">2</E> </FP> <FP SOURCE="FP-2">n = number of HAP compounds in the emission stream</FP> <P>(<E T="03">4</E>) If the vessel contents are heated to the boiling point, emissions must be <PRTPAGE P="69"/>calculated using the procedure in paragraphs (d)(2)(i)(c)(4)(<E T="03">i</E>) and (<E T="03">ii</E>) of this section.</P> <P>(<E T="03">i</E>) Use either of the procedures in paragraph (d)(3)(i)(B)(<E T="03">3</E>) of this section to calculate the emissions from heating to the boiling point (note that Pa<E T="52">2</E>=0 in the calculation of; and</P> <P>(<E T="03">ii</E>) While boiling, the vessel must be operated with a properly operated process condenser. An initial demonstration that a process condenser is properly operated is required for vessels that operate process condensers without secondary condensers that are air pollution control devices. The owner or operator must either measure the condenser exhaust gas temperature and show it is less than the boiling point of the substance(s) in the vessel, or perform a material balance around the vessel and condenser to show that at least 99 percent of the material vaporized while boiling is condensed. Uncontrolled emissions are assumed to be zero under these conditions. The initial demonstration shall be conducted for all appropriate operating scenarios and documented in the Notification of Compliance report described in § 63.1260(f).</P> <P>(D) <E T="03">Depressurization.</E> Emissions from depressurization shall be calculated using the procedures in either paragraphs (d)(2)(i)(D)(<E T="03">1</E>) through (<E T="03">4</E>), paragraphs (d)(2)(i)(D)(<E T="03">5</E>) through (<E T="03">9</E>), or paragraph (d)(2)(i)(D)(<E T="03">10</E>) of this section.</P> <P>(<E T="03">1</E>) Equations 21 and 22 of this subpart are used to calculate the initial and final volumes of noncondensable gas present in the vessel, adjusted to atmospheric pressure. The HAP partial pressures may be calculated using Raoult's law.</P> <GPH DEEP="26" SPAN="1"> <GID>ER21SE98.018</GID> </GPH> <GPH DEEP="26" SPAN="1"> <GID>ER21SE98.019</GID> </GPH> <FP SOURCE="FP-2">Where:</FP> <FP SOURCE="FP-2">V<E T="52">nc1</E> = initial volume of noncondensable gas in the vessel</FP> <FP SOURCE="FP-2">V<E T="52">nc2</E> = final volume of noncondensable gas in the vessel</FP> <FP SOURCE="FP-2">V = free volume in the vessel being depressurized</FP> <FP SOURCE="FP-2">P<E T="52">nc1</E> = initial partial pressure of the noncondensable gas, as calculated using Equation 23 of this subpart, mmHg</FP> <FP SOURCE="FP-2">P<E T="52">nc2</E> = final partial pressure of the noncondensable gas, as calculated using Equation 24 of this subpart, mmHg</FP> <FP SOURCE="FP-2">760 = atmospheric pressure, mmHg</FP> <P>(<E T="03">2</E>) The initial and final partial pressures of the noncondensable gas in the vessel are determined using Equations 23 and 24 of this subpart:</P> <GPH DEEP="31" SPAN="1"> <GID>ER21SE98.020</GID> </GPH> <GPH DEEP="31" SPAN="1"> <GID>ER21SE98.021</GID> </GPH> <FP SOURCE="FP-2">Where:</FP> <FP SOURCE="FP-2">P<E T="52">nc1</E> = initial partial pressure of the noncondensable gas</FP> <FP SOURCE="FP-2">P<E T="52">nc2</E> = final partial pressure of the noncondensable gas</FP> <FP SOURCE="FP-2">P<E T="52">1</E> = initial vessel pressure</FP> <FP SOURCE="FP-2">P<E T="52">2</E> = final vessel pressure</FP> <FP SOURCE="FP-2">P<E T="52">j</E>* = vapor pressure of each condensable (including HAP) in the emission stream</FP> <FP SOURCE="FP-2">x<E T="52">j</E> = mole fraction of each condensable (including HAP) in the emission stream</FP> <FP SOURCE="FP-2">m = number of condensable compounds (including HAP) in the emission stream</FP> <FP SOURCE="FP-2">j = identifier for a condensable compound</FP> <FP SOURCE="FP-2">(<E T="03">3</E>) The average ratio of moles of noncondensable to moles of HAP is calculated using Equation 25 of this subpart:</FP> <GPH DEEP="72" SPAN="2"> <PRTPAGE P="70"/> <GID>ER21SE98.022</GID> </GPH> <FP SOURCE="FP-2">Where:</FP> <FP SOURCE="FP-2">n<E T="52">R</E> = average ratio of moles of noncondensable to moles of HAP</FP> <FP SOURCE="FP-2">P<E T="52">nc1</E> = initial partial pressure of the noncondensable gas, as calculated using Equation 23 of this subpart</FP> <FP SOURCE="FP-2">P<E T="52">nc2</E> = final partial pressure of the noncondensable gas, as calculated using Equation 24 of this subpart</FP> <FP SOURCE="FP-2">P<E T="52">i</E>* = vapor pressure of each individual HAP</FP> <FP SOURCE="FP-2">x<E T="52">i</E> = mole fraction of each individual HAP in the liquid phase</FP> <FP SOURCE="FP-2">n = number of HAP compounds</FP> <FP SOURCE="FP-2">i = identifier for a HAP compound</FP> <P>(<E T="03">4</E>) The mass of HAP emitted shall be calculated using Equation 26 of this subpart:</P> <GPH DEEP="27" SPAN="2"> <GID>ER21SE98.023</GID> </GPH> <FP SOURCE="FP-2">Where:</FP> <FP SOURCE="FP-2">E = mass of HAP emitted</FP> <FP SOURCE="FP-2">V<E T="52">nc1</E> = initial volume of noncondensable gas in the vessel, as calculated using Equation 21 of this subpart</FP> <FP SOURCE="FP-2">V<E T="52">nc2</E> = final volume of noncondensable gas in the vessel, as calculated using Equation 22 of this subpart n<E T="52">R</E> = average ratio of moles of noncondensable to moles of HAP, as calculated using Equation 25 of this subpart</FP> <FP SOURCE="FP-2">P<E T="52">atm</E> = atmospheric pressure, standard</FP> <FP SOURCE="FP-2">R = ideal gas law constant</FP> <FP SOURCE="FP-2">T = temperature of the vessel, absolute</FP> <FP SOURCE="FP-2">MW<E T="52">HAP</E> = average molecular weight of the HAP, as calculated using Equation 17 of this subpart</FP> <P>(<E T="03">5</E>) The moles of HAP vapor initially in the vessel are calculated using the ideal gas law using Equation 27 of this subpart:</P> <GPH DEEP="29" SPAN="1"> <GID>ER21SE98.024</GID> </GPH> <FP SOURCE="FP-2">Where:</FP> <FP SOURCE="FP-2">Y<E T="52">HAP</E> = mole fraction of HAP (the sum of the individual HAP fractions, <E T="61">S</E>Y<E T="52">i</E>)</FP> <FP SOURCE="FP-2">V = free volume in the vessel being depressurized</FP> <FP SOURCE="FP-2">P<E T="52">1</E> = initial vessel pressure</FP> <FP SOURCE="FP-2">R = ideal gas law constant</FP> <FP SOURCE="FP-2">T = vessel temperature, absolute</FP> <P>(<E T="03">6</E>) The initial and final moles of noncondensable gas present in the vessel are calculated using Equations 28 and 29 of this subpart:</P> <GPH DEEP="26" SPAN="1"> <GID>ER21SE98.025</GID> </GPH> <GPH DEEP="26" SPAN="1"> <GID>ER21SE98.026</GID> </GPH> <FP SOURCE="FP-2">Where:</FP> <FP SOURCE="FP-2">n<E T="52">1</E> = initial number of moles of noncondensable gas in the vessel</FP> <FP SOURCE="FP-2">n<E T="52">2</E> = final number of moles of noncondensable gas in the vessel</FP> <FP SOURCE="FP-2">V = free volume in the vessel being depressurized</FP> <FP SOURCE="FP-2">P<E T="52">nc1</E> = initial partial pressure of the noncondensable gas, as calculated using Equation 23 of this subpart</FP> <FP SOURCE="FP-2">P<E T="52">nc2</E> = final partial pressure of the noncondensable gas, as calculated using Equation 24 of this subpart</FP> <FP SOURCE="FP-2">R = ideal gas law constant<PRTPAGE P="71"/> </FP> <FP SOURCE="FP-2">T = temperature, absolute</FP> <P>(<E T="03">7</E>) The initial and final partial pressures of the noncondensable gas in the vessel are determined using Equations 23 and 24 of this subpart.</P> <P>(<E T="03">8</E>) The moles of HAP emitted during the depressurization are calculated by taking an approximation of the average ratio of moles of HAP to moles of noncondensable and multiplying by the total moles of noncondensables released during the depressurization, using Equation 30 of this subpart:</P> <FP SOURCE="FP-2">where:</FP> <GPH DEEP="42" SPAN="2"> <GID>ER21SE98.027</GID> </GPH> <FP SOURCE="FP-2">n<E T="52">HAP</E> = moles of HAP emitted</FP> <FP SOURCE="FP-2">n<E T="52">1</E> = initial number of moles of noncondensable gas in the vessel, as calculated using Equation 28 of this subpart</FP> <FP SOURCE="FP-2">n<E T="52">2</E> = final number of moles of noncondensable gas in the vessel, as calculated using Equation 29 of this subpart</FP> <P>(<E T="03">9</E>) The mass of HAP emitted can be calculated using Equation 31 of this subpart: </P> <FP SOURCE="FP-2">E =N<E T="52">HAP</E> * MW<E T="52">HAP</E>(Eq. 31)</FP> <FP SOURCE="FP-2">where:</FP> <FP SOURCE="FP-2">E = mass of HAP emitted</FP> <FP SOURCE="FP-2">n<E T="52">HAP</E> = moles of HAP emitted, as calculated using Equation 30 of this subpart</FP> <FP SOURCE="FP-2">MW<E T="52">HAP</E> = average molecular weight of the HAP as calculated using Equation 17 of this subpart</FP> <P>(<E T="03">10</E>) Emissions from depressurization may be calculated using Equation 32 of this subpart:</P> <GPH DEEP="61" SPAN="2"> <GID>ER21SE98.028</GID> </GPH> <FP SOURCE="FP-2">where:</FP> <FP SOURCE="FP-2">V = free volume in vessel being depressurized</FP> <FP SOURCE="FP-2">R = ideal gas law constant</FP> <FP SOURCE="FP-2">T = temperature of the vessel, absolute</FP> <FP SOURCE="FP-2">P<E T="52">1</E> = initial pressure in the vessel</FP> <FP SOURCE="FP-2">P<E T="52">2</E> = final pressure in the vessel</FP> <FP SOURCE="FP-2">P<E T="52">i</E> = partial pressure of the individual HAP compounds</FP> <P>MW<E T="52">i</E> = molecular weight of the individual HAP compounds</P> <FP SOURCE="FP-2">n = number of HAP compounds in the emission stream</FP> <FP SOURCE="FP-2">i = identifier for a HAP compound</FP> <P>(E) <E T="03">Vacuum systems.</E> Emissions from vacuum systems may be calculated using Equation 33 of this subpart if the air leakage rate is known or can be approximated.</P> <GPH DEEP="33" SPAN="2"> <GID>ER21SE98.029</GID> </GPH> <PRTPAGE P="72"/> <FP SOURCE="FP-2">where:</FP> <FP SOURCE="FP-2">E = mass of HAP emitted</FP> <FP SOURCE="FP-2">P<E T="52">system</E> = absolute pressure of receiving vessel or ejector outlet conditions, if there is no receiver</FP> <FP SOURCE="FP-2">P<E T="52">i</E>* = vapor pressure of the HAP at the receiver temperature or the ejector outlet conditions</FP> <FP SOURCE="FP-2">La = total air leak rate in the system, mass/time</FP> <FP SOURCE="FP-2">MW<E T="52">nc</E> = molecular weight of noncondensable gas</FP> <FP SOURCE="FP-2">t = time of vacuum operation</FP> <FP SOURCE="FP-2">MW<E T="52">HAP</E> = average molecular weight of HAP in the emission stream, as calculated using Equation 17 of this subpart, with HAP partial pressures calculated at the temperature of the receiver or ejector outlet, as appropriate</FP> <P>(F) <E T="03">Gas evolution.</E> Emissions from gas evolution shall be calculated using Equation 12 of this subpart with V calculated using Equation 34 of this subpart:</P> <GPH DEEP="37" SPAN="2"> <GID>ER21SE98.030</GID> </GPH> <FP SOURCE="FP-2">Where:</FP> <FP SOURCE="FP-2">V = volumetric flow rate of gas evolution</FP> <FP SOURCE="FP-2">W<E T="52">g</E> = mass flow rate of gas evolution</FP> <FP SOURCE="FP-2">R = ideal gas law constant</FP> <FP SOURCE="FP-2">T = temperature at the exit, absolute</FP> <FP SOURCE="FP-2">P<E T="52">T</E> = vessel pressure</FP> <FP SOURCE="FP-2">MW<E T="52">g</E> = molecular weight of the evolved gas</FP> <P>(G) <E T="03">Air drying.</E> Emissions from air drying shall be calculated using Equation 35 of this subpart:</P> <GPH DEEP="31" SPAN="2"> <GID>ER21SE98.031</GID> </GPH> <FP SOURCE="FP-2">Where:</FP> <FP SOURCE="FP-2">E = mass of HAP emitted</FP> <FP SOURCE="FP-2">B = mass of dry solids</FP> <FP SOURCE="FP-2">PS<E T="52">1</E> = HAP in material entering dryer, weight percent</FP> <FP SOURCE="FP-2">PS<E T="52">2</E> = HAP in material exiting dryer, weight percent</FP> <P>(H) <E T="03">Empty vessel purging.</E> Emissions from empty vessel purging shall be calculated using Equation (36) of this subpart (Note: The term -Ft/v can be assumed to be 1):</P> <GPH DEEP="34" SPAN="2"> <GID>ER21SE98.032</GID> </GPH> <FP SOURCE="FP-2">Where:</FP> <FP SOURCE="FP-2">V = volume of empty vessel</FP> <FP SOURCE="FP-2">R = ideal gas law constant</FP> <FP SOURCE="FP-2">T = temperature of the vessel vapor space; absolute</FP> <FP SOURCE="FP-2">P<E T="52">i</E> = partial pressure of the individual HAP at the beginning of the purge</FP> <FP SOURCE="FP-2">(MW<E T="52">i</E>) = molecular weight of the individual HAP</FP> <FP SOURCE="FP-2">F = flowrate of the purge gas</FP> <FP SOURCE="FP-2">t = duration of the purge</FP> <FP SOURCE="FP-2">n = number of HAP compounds in the emission stream</FP> <FP SOURCE="FP-2">i = identifier for a HAP compound</FP> <PRTPAGE P="73"/> <P>(ii) <E T="03">Engineering assessments.</E> The owner or operator shall conduct an engineering assessment to calculate uncontrolled HAP emissions for each emission episode that is not due to vapor displacement, purging, heating, depressurization, vacuum operations, gas evolution, or air drying. For emission episodes caused by any of these types of activities, the owner or operator also may calculate uncontrolled HAP emissions based on an engineering assessment if the owner or operator can demonstrate to the Administrator that the methods in paragraph (d)(2)(i) of this section are not appropriate. One criterion the owner or operator could use to demonstrate that the methods in paragraph (d)(2)(i) of this section are not appropriate is if previous test data are available that show a greater than 20 percent discrepancy between the test value and the estimated value. An engineering assessment includes, but is not limited to, the following:</P> <P>(A) Previous test results, provided the tests are representative of current operating practices at the process unit.</P> <P>(B) Bench-scale or pilot-scale test data representative of the process under representative operating conditions.</P> <P>(C) Maximum flow rate, HAP emission rate, concentration, or other relevant parameter specified or implied within a permit limit applicable to the process vent.</P> <P>(D) Design analysis based on accepted chemical engineering principles, measurable process parameters, or physical or chemical laws or properties. Examples of analytical methods include, but are not limited to:</P> <P>(<E T="03">1</E>) Use of material balances based on process stoichiometry to estimate maximum organic HAP concentrations.</P> <P>(<E T="03">2</E>) Estimation of maximum flow rate based on physical equipment design such as pump or blower capacities.</P> <P>(<E T="03">3</E>) Estimation of HAP concentrations based on saturation conditions.</P> <P>(E) All data, assumptions, and procedures used in the engineering assessment shall be documented in accordance with § 63.1260(e). Data or other information supporting a finding that the emissions estimation equations are inappropriate shall be reported in the Precompliance report.</P> <P>(3) <E T="03">Controlled emissions.</E> An owner or operator shall determine controlled emissions using the procedures in either paragraph (d)(3)(i) or (ii) of this section. For condensers, controlled emissions shall be calculated using the emission estimation equations described in paragraph (d)(3)(i)(B) of this section.</P> <P>(i) <E T="03">Small control devices.</E> Except for condensers, controlled emissions for each process vent that is controlled using a small control device shall be determined by using the design evaluation described in paragraph (d)(3)(i)(A) of this section, or conducting a performance test in accordance with paragraph (d)(3)(ii) of this section. Whenever a small control device becomes a large control device, the owner or operator must comply with the provisions in paragraph (d)(3)(ii) of this section and submit the test report in the next Periodic report.</P> <P>(A) <E T="03">Design evaluation.</E> The design evaluation shall include documentation demonstrating that the control device being used achieves the required control efficiency under worst-case conditions, as determined from the emission profile described in § 63.1257(b)(8)(ii). The control efficiency determined from this design evaluation shall be applied to uncontrolled emissions to estimate controlled emissions. The documentation must be conducted in accordance with the provisions in paragraph (a)(1) of this section. The design evaluation shall also include the value(s) and basis for the parameter(s) monitored under § 63.1258.</P> <P>(B) <E T="03">Emission estimation equations.</E> An owner or operator using a condenser as a control device shall determine controlled emissions using exhaust gas temperature measurements and calculations for each batch emission episode within each unit operation according to the engineering methodology in paragraphs (d)(3)(i)(B)(<E T="03">1</E>) through (<E T="03">8</E>) of this section. Individual HAP partial pressures shall be calculated as specified in paragraph (d)(2)(i) of this section.</P> <P>(<E T="03">1</E>) Emissions from vapor displacement shall be calculated using Equation 11 of this subpart with T set equal to the temperature of the receiver and <PRTPAGE P="74"/>the HAP partial pressures determined at the temperature of the receiver.</P> <P>(<E T="03">2</E>) Emissions from purging shall be calculated using Equation 12 of this subpart with T set equal to the temperature of the receiver and the HAP partial pressures determined at the temperature of the receiver.</P> <P>(<E T="03">3</E>) Emissions from heating shall be calculated using either Equation 13 of this subpart or Equation 37 of this subpart. In Equation 13, the HAP vapor pressures shall be determined at the temperature of the receiver. In Equations 13 and 37 of this subpart, <E T="61">Dh</E> is equal to the number of moles of noncondensable displaced from the vessel, as calculated using Equation 15 of this subpart. In Equations 13 and 37 of this subpart, the HAP average molecular weight shall be calculated using Equation 17 with the HAP partial pressures determined at the temperature of the receiver.</P> <GPH DEEP="60" SPAN="1"> <GID>ER21SE98.033</GID> </GPH> <FP SOURCE="FP-2">Where:</FP> <FP SOURCE="FP-2">E = mass of HAP emitted</FP> <FP SOURCE="FP-2"> <E T="61">Dh</E> = moles of noncondensable gas displaced</FP> <FP SOURCE="FP-2">P<E T="52">T</E> = pressure in the receiver</FP> <FP SOURCE="FP-2">P<E T="52">i</E> = partial pressure of the individual HAP at the receiver temperature</FP> <FP SOURCE="FP-2">P<E T="52">j</E> = partial pressure of the individual condensable (including HAP) at the receiver temperature</FP> <FP SOURCE="FP-2">n = number of HAP compounds in the emission stream</FP> <FP SOURCE="FP-2">i = identifier for a HAP compound</FP> <FP SOURCE="FP-2">MW<E T="52">HAP</E> = the average molecular weight of HAP in vapor exiting the receiver, as calculated using Equation 17 of this subpart</FP> <FP SOURCE="FP-2">m = number of condensable compounds (including HAP) in the emission stream</FP> <P>(<E T="03">4</E>)(<E T="03">i</E>) Emissions from depressurization shall be calculated using Equation 38 of this subpart.</P> <GPH DEEP="60" SPAN="2"> <GID>ER21SE98.034</GID> </GPH> <FP SOURCE="FP-2">Where:</FP> <FP SOURCE="FP-2">E = mass of HAP vapor emitted</FP> <FP SOURCE="FP-2">V<E T="52">nc1</E> = initial volume of noncondensable in the vessel, corrected to the final pressure, as calculated using Equation 39 of this subpart</FP> <FP SOURCE="FP-2">V<E T="52">nc2</E> = final volume of noncondensable in the vessel, as calculated using Equation 40 of this subpart</FP> <FP SOURCE="FP-2">P<E T="52">i</E> = partial pressure of each individual HAP at the receiver temperature</FP> <FP SOURCE="FP-2">P<E T="52">j</E> = partial pressure of each condensable (including HAP) at the receiver temperature</FP> <FP SOURCE="FP-2">P<E T="52">T</E> = receiver pressure</FP> <FP SOURCE="FP-2">T = temperature of the receiver</FP> <FP SOURCE="FP-2">R = ideal gas law constant</FP> <FP SOURCE="FP-2">MW<E T="52">HAP</E> = the average molecular weight of HAP calculated using Equation 17 of this subpart with partial pressures determined at the receiver temperature</FP> <FP SOURCE="FP-2">i = identifier for a HAP compound</FP> <FP SOURCE="FP-2">n = number of HAP compounds in the emission stream</FP> <FP SOURCE="FP-2">m = number of condensable compounds (including HAP) in the emission stream</FP> <FP SOURCE="FP-2">j = identifier for a condensable compound</FP> <PRTPAGE P="75"/> <P>(<E T="03">ii</E>) The initial and final volumes of noncondensable gas present in the vessel, adjusted to the pressure of the receiver, are calculated using Equations 39 and 40 of this subpart.</P> <GPH DEEP="29" SPAN="1"> <GID>ER21SE98.035</GID> </GPH> <GPH DEEP="29" SPAN="1"> <GID>ER21SE98.036</GID> </GPH> <FP SOURCE="FP-2">Where:</FP> <FP SOURCE="FP-2">V<E T="52">nc1</E> = initial volume of noncondensable gas in the vessel</FP> <FP SOURCE="FP-2">V<E T="52">nc2</E> = final volume of noncondensable gas in the vessel</FP> <FP SOURCE="FP-2">V = free volume in the vessel being depressurized</FP> <FP SOURCE="FP-2">P<E T="52">nc1</E> = initial partial pressure of the noncondensable gas, as calculated using Equation 41 of this subpart</FP> <FP SOURCE="FP-2">P<E T="52">nc2</E> = final partial pressure of the noncondensable gas, as calculated using Equation 42 of this subpart</FP> <FP SOURCE="FP-2">P<E T="52">T</E> = pressure of the receiver</FP> <P>(<E T="03">iii</E>) Initial and final partial pressures of the noncondensable gas in the vessel are determined using Equations 41 and 42 of this subpart.</P> <GPH DEEP="31" SPAN="1"> <GID>ER21SE98.037</GID> </GPH> <GPH DEEP="31" SPAN="1"> <GID>ER21SE98.038</GID> </GPH> <FP SOURCE="FP-2">Where:</FP> <FP SOURCE="FP-2">P<E T="52">nc1</E> = initial partial pressure of the noncondensable gas in the vessel</FP> <FP SOURCE="FP-2">P<E T="52">nc2</E> = final partial pressure of the noncondensable gas in the vessel</FP> <FP SOURCE="FP-2">P<E T="52">1</E> = initial vessel pressure</FP> <FP SOURCE="FP-2">P<E T="52">2</E> = final vessel pressure</FP> <FP SOURCE="FP-2">P<E T="52">j</E> = partial pressure of each condensable compound (including HAP) in the vessel</FP> <FP SOURCE="FP-2">m = number of condensable compounds (including HAP) in the emission stream</FP> <FP SOURCE="FP-2">j = identifier for a condensable compound</FP> <P>(<E T="03">5</E>) Emissions from vacuum systems shall be calculated using Equation 33 of this subpart.</P> <P>(<E T="03">6</E>) Emissions from gas evolution shall be calculated using Equation 12 with V calculated using Equation 34 of this subpart, T set equal to the receiver temperature, and the HAP partial pressures determined at the receiver temperature. The term for time, t, in Equation 12 of this subpart is not needed for the purposes of this calculation.</P> <P>(<E T="03">7</E>) Emissions from air drying shall be calculated using Equation 11 of this subpart with V equal to the air flow rate and P<E T="52">i</E> determined at the receiver temperature.</P> <P>(<E T="03">8</E>) Emissions from empty vessel purging shall be calculated using equation 43 of this subpart:</P> <GPH DEEP="59" SPAN="2"> <GID>ER21SE98.039</GID> </GPH> <FP SOURCE="FP-2">Where:</FP> <FP SOURCE="FP-2">V = volume of empty vessel</FP> <FP SOURCE="FP-2">R = ideal gas law constant</FP> <FP SOURCE="FP-2">T<E T="52">1</E> = temperature of the vessel vapor space at beginning of purge</FP> <FP SOURCE="FP-2">T<E T="52">2</E> = temperature of the receiver, absolute</FP> <FP SOURCE="FP-2">(P<E T="52">i</E>)<E T="52">T1</E> = partial pressure of the individual HAP at the beginning of the purge</FP> <FP SOURCE="FP-2">(P<E T="52">i</E>)<E T="52">T2</E> = partial pressure of the individual HAP at the receiver temperature<PRTPAGE P="76"/> </FP> <FP SOURCE="FP-2">MW<E T="52">i</E> = molecular weight of the individual HAP</FP> <FP SOURCE="FP-2">F = flowrate of the purge gas</FP> <FP SOURCE="FP-2">t = duration of the purge</FP> <FP SOURCE="FP-2">n = number of HAP compounds in the emission stream</FP> <FP SOURCE="FP-2">i = identifier for a HAP compound</FP> <P>(ii) <E T="03">Large control devices</E>. Except for condensers, controlled emissions for each process vent that is controlled using a large control device shall be determined by applying the control efficiency of the large control device to the estimated uncontrolled emissions. The control efficiency shall be determined by conducting a performance test on the control device as described in paragraphs (d)(3)(ii)(A) through (C) of this section, or by using the results of a previous performance test as described in paragraph (d)(4) of this section. If the control device is intended to control only hydrogen halides and halogens, the owner or operator may assume the control efficiency of organic HAP is zero percent. If the control device is intended to control only organic HAP, the owner or operator may assume the control efficiency for hydrogen halides and halogen is zero percent. Owners and operators are not required to conduct performance tests for devices described in paragraphs (a)(4) and (d)(4) of this section that are large control devices, as defined in § 63.1251.</P> <P>(A) The performance test shall be conducted by performing emission testing on the inlet and outlet, or, if complying with the provisions of § 63.1254(c), on the outlet of the control device, following the test methods and procedures of § 63.1257(b). Concentrations shall be calculated from the data obtained through emission testing according to the procedures in paragraph (a)(2) of this section. If the control device is a combustion device that uses supplemental combustion air, the concentrations shall be corrected to 3 percent oxygen according to the procedures in paragraph (a)(3) of this section.</P> <P>(B) Performance testing shall be conducted under absolute, or hypothetical worst-case conditions, as defined in paragraphs (b)(8)(i)(A) through (B) of this section.</P> <P>(C) The owner or operator may elect to conduct more than one performance test on the control device for the purpose of establishing more than one operating condition at which the control device achieves the required control efficiency.</P> <P>(4) An owner or operator is not required to conduct a performance test for the following:</P> <P>(i) Any control device for which a previous performance test was conducted, provided the test was conducted using the same procedures specified in § 63.1257(b) over conditions typical of the appropriate worst-case, as defined in § 63.1257(b)(8)(i). The results of the previous performance test shall be used to demonstrate compliance.</P> <P>(e) <E T="03">Compliance with wastewater provisions.</E> (1) <E T="03">Determining annual average concentration and annual load.</E> To determine the annual average concentration and annual load of partially soluble and/or soluble HAP compounds in a wastewater stream, as required by § 63.1256(a)(1), an owner or operator shall comply with the provisions in paragraphs (e)(1)(i) through (iii) of this section. A wastewater stream is exempt from the requirements of § 63.1256(a)(2) if the owner or operator determines the annual average concentration and annual load are below all of the applicability cutoffs specified in § 63.1256(a)(1)(i)(A) through (D). For annual average concentration, only initial rinses are included. Concentration measurements based on Method 305 shall be adjusted by dividing each concentration by the compound-specific Fm factor listed in Table 8 of this subpart. Concentration measurements based on methods other than Method 305 may not be adjusted by the compound-specific Fm factor listed in Table 8 of this subpart.</P> <P>(i) <E T="03">Annual average concentration definition.</E> (A) When complying with § 63.1256(a)(1)(i)(A), the annual average concentration means the total mass of partially soluble HAP compounds occurring in the wastewater stream during the calendar year divided by the total mass of the wastewater stream discharged during the same calendar year.</P> <P>(B) When complying with § 63.1256(a)(1)(i) (B) or (C), the annual <PRTPAGE P="77"/>average concentration means the total mass of partially soluble and/or soluble HAP compounds occurring in the wastewater stream during the calendar year divided by the total mass of the wastewater stream discharged during the same calendar year.</P> <P>(C) When complying with § 63.1256(a)(1)(i)(D), the annual average concentration means the total mass of soluble HAP compounds occurring in the wastewater stream during the calendar year divided by the total mass of the wastewater stream discharged during the same calendar year.</P> <P>(ii) <E T="03">Determination of annual average concentration.</E> An owner or operator shall determine annual average concentrations of partially soluble and/or soluble HAP compounds in accordance with the provisions specified in paragraph (e)(1)(ii)(A), (B), or (C) of this section. The owner or operator may determine annual average concentrations by process simulation. Data and other information supporting the simulation shall be reported in the Precompliance Report for approval by the Administrator. The annual average concentration shall be determined either at the POD or downstream of the POD with adjustment for concentration changes made according to paragraph (e)(1)(ii)(D) of this section.</P> <P>(A) <E T="03">Test methods.</E> The concentration of partially soluble HAP, soluble HAP, or total HAP shall be measured using any of the methods described in paragraphs (b)(10)(i) through (iv) of this section.</P> <P>(B) <E T="03">Knowledge of the wastewater stream.</E> The concentration of partially soluble HAP, soluble HAP, or total HAP shall be calculated based on knowledge of the wastewater stream according to the procedures in paragraphs (e)(1)(ii)(B)(<E T="03">1</E>) and (<E T="03">2</E>) of this section. The owner or operator shall document concentrations in the Notification of Compliance Status report described in § 63.1260(f).</P> <P>(<E T="03">1</E>) <E T="03">Mass balance.</E> The owner or operator shall calculate the concentrations of HAP compounds in wastewater considering the total quantity of HAP discharged to the water, the amount of water at the POD, and the amounts of water and solvent lost to other mechanisms such as reactions, air emissions, or uptake in product or other processing materials. The quantities of HAP and water shall be based on batch sheets, manufacturing tickets, or FDA bills of materials. In cases where a chemical reaction occurs that generates or consumes HAP, the amount of HAP remaining after a reaction shall be based on stoichometry assuming 100 percent theoretical consumption or yield, as applicable.</P> <P>(2) <E T="03">Published water solubility data.</E> For single components in water, owners and operators may use the water solubilities published in standard reference texts at the POD temperature to determine maximum HAP concentration.</P> <P>(C) <E T="03">Bench scale or pilot-scale test data.</E> The concentration of partially soluble HAP, soluble HAP, or total HAP shall be calculated based on bench scale or pilot-scale test data. The owner or operator shall provide sufficient information to demonstrate that the bench-scale or pilot-scale test concentration data are representative of actual HAP concentrations. The owner or operator shall also provide documentation describing the testing protocol, and the means by which sample variability and analytical variability were accounted for in the determination of HAP concentrations. Documentation of the pilot-scale or bench scale analysis shall be provided in the precompliance report.</P> <P>(D) <E T="03">Adjustment for concentrations determined downstream of the POD.</E> The owner or operator shall make corrections to the annual average concentration when the concentration is determined downstream of the POD at a location where: two or more wastewater streams have been mixed; one or more wastewater streams have been treated; or, losses to the atmosphere have occurred. The owner or operator shall make the adjustments either to the individual data points or to the final annual average concentration.</P> <P>(iii) <E T="03">Determination of annual load.</E> An owner or operator shall calculate the partially soluble and/or soluble HAP load in a wastewater stream based on the annual average concentration determined in paragraph (e)(1)(ii) (A), (B), or (C) of this section and the total volume of the wastewater stream, based <PRTPAGE P="78"/>on knowledge of the wastewater stream in accordance with paragraphs (e)(1)(ii)(B) of this section. The owner or operator shall maintain records of the total liters of wastewater discharged per year as specified in § 63.1259(b).</P> <P>(2) <E T="03">Compliance with treatment unit control provisions.</E> (i) <E T="03">Performance tests and design evaluations-general.</E> To comply with the control options in § 63.1256(g) (10) or (13), neither a design evaluation nor a performance test is required. For any other nonbiological treatment process, the owner or operator shall conduct either a design evaluation as specified in paragraph (e)(2)(ii) of this section, or a performance test as specified in paragraph (e)(2)(iii) of this section to demonstrate that each nonbiological treatment process used to comply with § 63.1256(g) (8), (9), and/or (12) achieves the conditions specified for compliance. The owner or operator shall demonstrate by the procedures in either paragraph (e)(2) (ii) or (iii) of this section that each closed biological treatment process used to comply with § 63.1256 (g)(8)(ii), (g)(9)(ii), (g)(11), or (g)(12) achieves the conditions specified for compliance. If an open biological treatment unit is used to comply with § 63.1256 (g)(8)(ii), (g)(9)(ii), (g)(11), or (g)(12), the owner or operator shall comply with the performance test requirements in paragraph (e)(2)(iii) of this section.</P> <P>(ii) <E T="03">Design evaluation.</E> A design evaluation and supporting documentation that addresses the operating characteristics of the treatment process and that is based on operation at a wastewater stream flow rate and a concentration under which it would be most difficult to demonstrate compliance. For closed biological treatment processes, the percent reduction from removal/destruction in the treatment unit and control device shall be determined by a mass balance over the unit. The mass flow rate of soluble and/or partially soluble HAP compounds exiting the treatment process shall be the sum of the mass flow rate of soluble and/or partially soluble HAP compounds in the wastewater stream exiting the biological treatment process and the mass flow rate of the vented gas stream exiting the control device. The mass flow rate entering the treatment process minus the mass flow rate exiting the process determines the actual mass removal. Compounds that meet the requirements specified in paragraph (e)(2)(iii)(A)(<E T="03">4</E>) of this section are not required to be included in the design evaluation; the term “performance test” in paragraph (e)(2)(iii)(A)(<E T="03">4</E>) of this section shall mean “design evaluation” for the purposes of this paragraph.</P> <P>(iii) <E T="03">Performance tests.</E> Performance tests shall be conducted using test methods and procedures that meet the applicable requirements specified in paragraphs (e)(2)(iii)(A) through (G) of this section.</P> <P>(A) <E T="03">General.</E> This paragraph specifies the general procedures for performance tests that are conducted to demonstrate compliance of a treatment process with the control requirements specified in § 63.1256(g).</P> <P>(<E T="03">1</E>) <E T="03">Representative process unit operating conditions.</E> Compliance shall be demonstrated for representative operating conditions. Operations during periods of malfunction and periods of nonoperation shall not constitute representative conditions. The owner or operator shall record the process information that is necessary to document operating conditions during the test.</P> <P>(<E T="03">2</E>) <E T="03">Representative treatment process operating conditions.</E> Performance tests shall be conducted when the treatment process is operating at a representative inlet flow rate and concentration. If the treatment process will be operating at several different sets of representative operating conditions, the owner or operator shall comply with paragraphs (e)(2)(iii)(A)(<E T="03">2</E>)(<E T="03">i</E>) and (<E T="03">ii</E>) of this section. The owner or operator shall record information that is necessary to document treatment process or control device operating conditions during the test.</P> <P>(<E T="03">i</E>) <E T="03">Range of operating conditions.</E> If the treatment process will be operated at several different sets of representative operating conditions, performance testing over the entire range is not required. In such cases, the performance test results shall be supplemented with modeling and/or engineering assessments to demonstrate performance over the operating range.<PRTPAGE P="79"/> </P> <P>(<E T="03">ii</E>) <E T="03">Consideration of residence time.</E> If concentration and/or flow rate to the treatment process are not relatively constant (i.e., comparison of inlet and outlet data will not be representative of performance), the owner or operator shall consider residence time, when determining concentration and flow rate.</P> <P>(<E T="03">3</E>) <E T="03">Testing equipment.</E> All testing equipment shall be prepared and installed as specified in the applicable test methods, or as approved by the Administrator.</P> <P>(<E T="03">4</E>) <E T="03">Compounds not required to be considered in performance tests.</E> Compounds that meet the requirements specified in (e)(2)(iii)(A)(<E T="03">4</E>)(<E T="03">i</E>), (<E T="03">ii</E>), or (<E T="03">iii</E>) of this section are not required to be included in the performance test. Concentration measurements based on Method 305 shall be adjusted by dividing each concentration by the compound-specific Fm factor listed in Table 8 of this subpart. Concentration measurements based on methods other than Method 305 shall not be adjusted by the compound-specific Fm factor listed in Table 8 of this subpart.</P> <P>(<E T="03">i</E>) Compounds not used or produced by the PMPU; or</P> <P>(<E T="03">ii</E>) Compounds with concentrations at the POD that are below 1 ppmw; or</P> <P>(<E T="03">iii</E>) Compounds with concentrations at the POD that are below the lower detection limit where the lower detection limit is greater than 1 ppmw. The method shall be an analytical method for wastewater which has the compound of interest as a target analyte.</P> <P>(<E T="03">5</E>) <E T="03">Treatment using a series of treatment processes.</E> In all cases where the wastewater provisions in this subpart allow or require the use of a treatment process to comply with emissions limitations, the owner or operator may use multiple treatment processes. The owner or operator complying with the requirements of § 63.1256(g)(7)(i), when wastewater is conveyed by hard-piping, shall comply with either paragraph (e)(2)(iii)(A)(<E T="03">5</E>)(<E T="03">i</E>) or (<E T="03">ii</E>) of this section. The owner or operator complying with the requirements of § 63.1256(g)(7)(ii) shall comply with the requirements of paragraph (e)(2)(iii)(A)(<E T="03">5</E>)(<E T="03">ii</E>) of this section.</P> <P>(<E T="03">i</E>) The owner or operator shall conduct the performance test across each series of treatment processes. For each series of treatment processes, inlet concentration and flow rate shall be measured either where the wastewater enters the first treatment process in a series of treatment processes, or prior to the first treatment process as specified in paragraph (e)(2)(iii)(A)(<E T="03">6</E>) of this section. For each series of treatment processes, outlet concentration and flow rate shall be measured where the wastewater exits the last treatment process in the series of treatment processes, except when the last treatment process is an open or a closed aerobic biological treatment process demonstrating compliance by using the procedures in paragraphs (e)(2)(iii)(E) or (F) of this section. When the last treatment process is either an open or a closed aerobic biological treatment process demonstrating compliance by using the procedures in paragraphs (e)(2)(iii)(E) or (F) of this section, inlet and outlet concentrations and flow rates shall be measured at the inlet and outlet to the series of treatment processes prior to the biological treatment process and at the inlet to the biological treatment process, except as provided in paragraph (e)(2)(iii)(A)(6)(ii) of this section. The mass flow rate destroyed in the biological treatment process for which compliance is demonstrated using paragraph (e)(2)(iii)(E) or (F) of this section shall be added to the mass flow rate removed or destroyed in the series of treatment units before the biological treatment unit. This sum shall be used to calculate the overall control efficiency.</P> <P>(<E T="03">ii</E>) The owner or operator shall conduct the performance test across each treatment process in the series of treatment processes. The mass flow rate removed or destroyed by each treatment process shall be added together and the overall control efficiency calculated to determine whether compliance has been demonstrated using paragraphs (e)(2)(iii)(C), (D), (E), (F), or (G) of this section, as applicable. If a biological treatment process is one of the treatment processes in the series of treatment processes, the inlet to the biological treatment process shall be the point at which the wastewater enters the biological treatment process, or the inlet to the equalization tank if <PRTPAGE P="80"/>all the criteria of paragraph (e)(2)(iii)(A)(<E T="03">6</E>)(<E T="03">ii</E>) of this section are met.</P> <P>(<E T="03">6</E>) The owner or operator determining the inlet for purposes of demonstrating compliance with paragraph (e)(2)(iii)(E), or (F)of this section may elect to comply with paragraph (e)(2)(iii)(A)(<E T="03">6</E>)(<E T="03">i</E>) or (<E T="03">ii</E>) of this section.</P> <P>(<E T="03">i</E>) When wastewater is conveyed exclusively by hard-piping from the point of determination to a treatment process that is either the only treatment process or the first in a series of treatment processes (i.e., no treatment processes or other waste management units are used upstream of this treatment process to store, handle, or convey the wastewater), the inlet to the treatment process shall be at any location from the point of determination to where the wastewater stream enters the treatment process. When samples are taken upstream of the treatment process and before wastewater streams have converged, the owner or operator shall ensure that the mass flow rate of all affected wastewater is accounted for when using § 63.1256(g)(8)(ii), (g)(9)(ii) or (g)(12) of this subpart to comply and that the mass flow rate of all wastewater, not just affected wastewater, is accounted for when using § 63.1256(g)(11) to comply, except as provided in paragraph (e)(2)(iii)(A)(<E T="03">4</E>) of this section.</P> <P>(<E T="03">ii</E>) The owner or operator may consider the inlet to the equalization tank as the inlet to the biological treatment process if the wastewater is conveyed by hard-piping from either the last previous treatment process or the point of determination to the equalization tank; or the wastewater is conveyed from the equalization tank exclusively by hard-piping to the biological treatment process and no treatment processes or other waste management units are used to store, handle, or convey the wastewater between the equalization tank and the biological treatment process; or the equalization tank is equipped with a fixed roof and a closed-vent system that routes emissions to a control device that meets the requirements of § 63.1256(b)(1)(i) through (iv) and § 63.1256(b)(2)(i). The outlet from the series of treatment processes prior to the biological treatment process is the point at which the wastewater exits the last treatment process in the series prior to the equalization tank, if the equalization tank and biological treatment process are part of a series of treatment processes. The owner or operator shall ensure that the mass flow rate of all affected wastewater is accounted for when using § 63.1256(g)(9)(ii) or (12) to comply and that the mass flow rate of all wastewater, not just affected wastewater is accounted for when using § 63.1256(g)(11) to comply, except as provided in paragraph (e)(2)(iii)(A)(<E T="03">4</E>) of this section.</P> <P>(B) <E T="03">Noncombustion treatment process—concentration limits.</E> This paragraph applies to performance tests that are conducted to demonstrate compliance of a noncombustion treatment process with the ppmw wastewater stream concentration limits at the outlet of the treatment process. This compliance option is specified in § 63.1256(g)(8)(i) and (9)(i). Wastewater samples shall be collected using sampling procedures which minimize loss of organic compounds during sample collection and analysis and maintain sample integrity per paragraph (b)(10)(iii) of this section. Samples shall be collected and analyzed using the procedures specified in paragraphs (b)(10)(i), (ii), and (iii) of this section. Samples may be grab samples or composite samples. Samples shall be taken at approximately equally spaced time intervals over a 1-hour period. Each 1-hour period constitutes a run, and the performance test shall consist of a minimum of three runs. Concentration measurements based on methods other than Method 305 may be adjusted by multiplying each concentration by the compound-specific Fm factor listed in Table 8 of this subpart. (For affected wastewater streams that contains both partially soluble and soluble HAP compounds, compliance is demonstrated only if the sum of the concentrations of partially soluble HAP compounds is less than 50 ppmw, and the sum of the concentrations of soluble HAP compounds is less than 520 ppmw.)</P> <P>(C) <E T="03">Noncombustion, nonbiological treatment process: percent mass removal/destruction option.</E> This paragraph applies to performance tests that are conducted to demonstrate compliance of a <PRTPAGE P="81"/>noncombustion, nonbiological treatment process with the percent mass removal limits specified in § 63.1256(g)(8)(ii) and (9)(ii) for partially soluble and soluble HAP compounds, respectively. The owner or operator shall comply with the requirements specified in paragraphs (e)(2)(iii)(C)(<E T="03">1</E>) through (<E T="03">5</E>) of this section.</P> <P>(<E T="03">1</E>) <E T="03">Concentration.</E> The concentration of partially soluble and/or soluble HAP compounds entering and exiting the treatment process shall be determined as provided in this paragraph. Wastewater samples shall be collected using sampling procedures which minimize loss of organic compounds during sample collection and analysis and maintain sample integrity per paragraph (b)(10)(v) of this section. The method shall be an analytical method for wastewater which has the compound of interest as a target analyte. Samples may be grab samples or composite samples. Samples shall be taken at approximately equally spaced time intervals over a 1-hour period. Each 1-hour period constitutes a run, and the performance test shall consist of a minimum of three runs. Concentration measurements based on Method 305 shall be adjusted by dividing each concentration by the compound-specific Fm factor listed in Table 8 of this subpart. Concentration measurements based on methods other than Method 305 shall not be adjusted by the compound-specific Fm factor listed in Table 8 of this subpart.</P> <P>(<E T="03">2</E>) <E T="03">Flow rate.</E> The flow rate of the entering and exiting wastewater streams shall be determined using inlet and outlet flow meters, respectively. Where the outlet flow is not greater than the inlet flow, a single flow meter may be used, and may be used at either the inlet or outlet. Flow rate measurements shall be taken at the same time as the concentration measurements.</P> <P>(<E T="03">3</E>) <E T="03">Calculation of mass flow rate—for noncombustion, nonbiological treatment processes.</E> The mass flow rates of partially soluble and/or soluble HAP compounds entering and exiting the treatment process are calculated using Equations 44 and 45 of this subpart.</P> <GPH DEEP="32" SPAN="2"> <GID>ER21SE98.040</GID> </GPH> <GPH DEEP="32" SPAN="2"> <GID>ER21SE98.041</GID> </GPH> <FP SOURCE="FP-2">Where:</FP> <FP SOURCE="FP-2">QMW<E T="52">a</E>, QMW<E T="52">b</E> = mass flow rate of partially soluble or soluble HAP compounds, average of all runs, in wastewater entering (QMW<E T="52">a</E>) or exiting (QMW<E T="52">b</E>) the treatment process, kg/hr</FP> <FP SOURCE="FP-2"> <E T="61">R</E> = density of the wastewater, kg/m<E T="51">3</E> </FP> <FP SOURCE="FP-2">Q<E T="52">a,k</E>, Qb<E T="52">b,k</E> = volumetric flow rate of wastewater entering (Q<E T="52">a,k</E>) or exiting (Q<E T="52">b,k</E>) the treatment process during each run k, m<E T="51">3</E>/hr</FP> <FP SOURCE="FP-2">C<E T="52">T,a,k</E>, C<E T="52">T,b,k</E> = total concentration of partially soluble or soluble HAP compounds in wastewater entering (C<E T="52">T,a,k</E>) or exiting (C<E T="52">T,b,k</E>) the treatment process during each run k, ppmw</FP> <FP SOURCE="FP-2">p = number of runs</FP> <FP SOURCE="FP-2">k = identifier for a run</FP> <FP SOURCE="FP-2">10<E T="51">6</E> = conversion factor, mg/kg</FP> <P>(<E T="03">4</E>) <E T="03">Percent removal calculation for mass flow rate.</E> The percent mass removal across the treatment process shall be calculated as follows:</P> <GPH DEEP="27" SPAN="1"> <GID>ER21SE98.042</GID> </GPH> <FP SOURCE="FP-2">Where:</FP> <FP SOURCE="FP-2">E = removal or destruction efficiency of the treatment process, percent</FP> <FP SOURCE="FP-2">QMW<E T="52">a</E>, QMW<E T="52">b</E> = mass flow rate of partially soluble or soluble HAP compounds in wastewater entering (QMW<E T="52">a</E>) and exiting (QMW<E T="52">b</E>) the <PRTPAGE P="82"/>treatment process, kg/hr (as calculated using Equations 44 and 45 of this subpart)</FP> <P>(<E T="03">5</E>) <E T="03">Compare mass removal efficiency to required efficiency.</E> Compare the mass removal efficiency (calculated in Equation 44 of this subpart) to the required efficiency as specified in § 63.1256(g)(8)(ii) or (9)(ii). If complying with § 63.1256(g)(8)(ii), compliance is demonstrated if the mass removal efficiency is 99 percent or greater. If complying with § 63.1256(g)(9)(ii), compliance is demonstrated if the mass removal efficiency is 90 percent or greater.</P> <P>(D) <E T="03">Combustion treatment processes: percent mass removal/destruction option.</E> This paragraph applies to performance tests that are conducted to demonstrate compliance of a combustion treatment process with the percent mass destruction limits specified in § 63.1256(g)(8)(ii) for partially soluble HAP compounds, and/or § 63.1256(g)(9)(ii) for soluble HAP compounds. The owner or operator shall comply with the requirements specified in paragraphs (e)(2)(iii)(D)(<E T="03">1</E>) through (<E T="03">8</E>) of this section.</P> <P>(<E T="03">1</E>) <E T="03">Concentration in wastewater stream entering the combustion treatment process.</E> The concentration of partially soluble and/or soluble HAP compounds entering the treatment process shall be determined as provided in this paragraph. Wastewater samples shall be collected using sampling procedures which minimize loss of organic compounds during sample collection and analysis and maintain sample integrity per paragraph (b)(10)(v) of this section. The method shall be an analytical method for wastewater which has the compound of interest as a target analyte. Samples may be grab samples or composite samples. Samples shall be taken at approximately equally spaced time intervals over a 1-hour period. Each 1-hour period constitutes a run, and the performance test shall consist of a minimum of three runs. Concentration measurements based on Method 305 of appendix A of this part shall be adjusted by dividing each concentration by the compound-specific Fm factor listed in Table 8 of this subpart. Concentration measurements based on methods other than Method 305 shall not be adjusted by the compound-specific Fm factor listed in Table 8 of this subpart.</P> <P>(<E T="03">2</E>) <E T="03">Flow rate of wastewater entering the combustion treatment process.</E> The flow rate of the wastewater stream entering the combustion treatment process shall be determined using an inlet flow meter. Flow rate measurements shall be taken at the same time as the concentration measurements.</P> <P>(<E T="03">3</E>) <E T="03">Calculation of mass flow rate in wastewater stream entering combustion treatment processes.</E> The mass flow rate of partially soluble and/or soluble HAP compounds entering the treatment process is calculated as follows:</P> <GPH DEEP="32" SPAN="2"> <GID>ER21SE98.043</GID> </GPH> <FP SOURCE="FP-2">Where:</FP> <FP SOURCE="FP-2">QMW<E T="52">a</E> = mass flow rate of partially soluble or soluble HAP compounds entering the combustion unit, kg/hr</FP> <FP SOURCE="FP-2"> <E T="61">p</E>= density of the wastewater stream, kg/m3</FP> <FP SOURCE="FP-2">Q<E T="52">a,k</E> = volumetric flow rate of wastewater entering the combustion unit during run k, m<E T="51">3</E>/hr</FP> <FP SOURCE="FP-2">C<E T="52">T,a,k</E> = total concentration of partially soluble or soluble HAP compounds in the wastewater stream entering the combustion unit during run k, ppmw</FP> <FP SOURCE="FP-2"> <E T="61">r</E> = number of runs</FP> <FP SOURCE="FP-2">k = identifier for a run</FP> <P>(<E T="03">4</E>) <E T="03">Concentration in vented gas stream exiting the combustion treatment process.</E> The concentration of partially soluble and/or soluble HAP compounds (or TOC) exiting the combustion treatment process in any vented gas stream shall be determined as provided in this <PRTPAGE P="83"/>paragraph. Samples may be grab samples or composite samples. Samples shall be taken at approximately equally spaced time intervals over a 1-hour period. Each 1-hour period constitutes a run, and the performance test shall consist of a minimum of three runs. Concentration measurements shall be determined using Method 18 of 40 CFR part 60, appendix A. Alternatively, any other test method validated according to the procedures in Method 301 of appendix A of this part may be used.</P> <P>(<E T="03">5</E>) <E T="03">Volumetric flow rate of vented gas stream exiting the combustion treatment process.</E> The volumetric flow rate of the vented gas stream exiting the combustion treatment process shall be determined using Method 2, 2A, 2C, or 2D of 40 CFR part 60, appendix A, as appropriate. Volumetric flow rate measurements shall be taken at the same time as the concentration measurements.</P> <P>(<E T="03">6</E>) <E T="03">Calculation of mass flow rate of vented gas stream exiting combustion treatment processes.</E> The mass flow rate of partially soluble and/or soluble HAP compounds in a vented gas stream exiting the combustion treatment process shall be calculated as follows:</P> <GPH DEEP="32" SPAN="2"> <GID>ER21SE98.044</GID> </GPH> <FP SOURCE="FP-2">where:</FP> <FP SOURCE="FP-2">QMG<E T="52">b</E> = mass rate of TOC (minus methane and ethane) or total partially soluble and/or soluble HAP, in vented gas stream, exiting (QMG<E T="52">b</E>) the combustion device, dry basis, kg/hr</FP> <FP SOURCE="FP-2">CG<E T="52">b,i</E> = concentration of TOC (minus methane and ethane) or total partially soluble and/or soluble HAP, in vented gas stream, exiting (CG<E T="52">b,i</E>) the combustion device, dry basis, ppmv</FP> <FP SOURCE="FP-2">MW<E T="52">i</E> = molecular weight of a component, kilogram/kilogram-mole</FP> <FP SOURCE="FP-2">QG<E T="52">b</E> = flow rate of gas stream exiting (QG<E T="52">b</E>) the combustion device, dry standard cubic meters per hour</FP> <FP SOURCE="FP-2">K<E T="52">2</E> = constant, 41.57 x 10<E T="51">−9</E> (parts per million)<E T="51">−1</E> (gram-mole per standard cubic meter) (kilogram/gram), where standard temperature (gram-mole per standard cubic meter) is 20°C</FP> <FP SOURCE="FP-2">i = identifier for a compound</FP> <FP SOURCE="FP-2">n = number of components in the sample</FP> <P>(<E T="03">7</E>) <E T="03">Destruction efficiency calculation.</E> The destruction efficiency of the combustion unit for partially soluble and/or soluble HAP compounds shall be calculated as follows:</P> <GPH DEEP="27" SPAN="1"> <GID>ER21SE98.045</GID> </GPH> <FP SOURCE="FP-2">Where:</FP> <FP SOURCE="FP-2">E = destruction efficiency of partially soluble or soluble HAP compounds for the combustion unit, percent</FP> <FP SOURCE="FP-2">QMW<E T="51">2a</E> = mass flow rate of partially soluble or soluble HAP compounds entering the combustion unit, kg/hr</FP> <FP SOURCE="FP-2">QMG<E T="52">b</E> = mass flow rate of TOC (minus methane and ethane) or partially soluble and/or soluble HAP compounds in vented gas stream exiting the combustion treatment process, kg/hr</FP> <P>(<E T="03">8</E>) <E T="03">Compare mass destruction efficiency to required efficiency.</E> Compare the mass destruction efficiency (calculated in Equation 49 of this subpart) to the required efficiency as specified in § 63.1256(g)(8)(ii) or (g)(9)(ii). If complying with § 63.1256(g)(8)(ii), compliance is demonstrated if the mass destruction efficiency is 99 percent or greater. If complying with § 63.1256(g)(9)(ii), compliance is demonstrated if the mass destruction efficiency is 90 percent or greater.</P> <P>(E) <E T="03">Open or closed aerobic biological treatment processes: 95-percent mass destruction option.</E> This paragraph applies <PRTPAGE P="84"/>to performance tests that are conducted for open or closed aerobic biological treatment processes to demonstrate compliance with the 95-percent mass destruction provisions in § 63.1256(g)(11) for partially soluble and/or soluble HAP compounds.</P> <P>(<E T="03">1</E>) <E T="03">Concentration in wastewater stream.</E> The concentration of partially soluble and/or soluble HAP as provided in this paragraph. Concentration measurements to determine E shall be taken as provided in paragraph (e)(2)(iii)(A)(<E T="03">5</E>) of this section for a series of treatment processes. Wastewater samples shall be collected using sampling procedures which minimize loss of organic compounds during sample collection and analysis and maintain sample integrity per paragraph (b)(10)(v) of this section. The method shall be an analytical method for wastewater which has the compound of interest as a target analyte. Samples may be grab samples or composite samples. Samples shall be taken at approximately equally spaced time intervals over a 1-hour period. Each 1-hour period constitutes a run, and the performance test shall consist of a minimum of three runs. Concentration measurements based on Method 305 shall be adjusted by dividing each concentration by the compound-specific Fm factor listed in Table 8 of this subpart. Concentration measurements based on methods other than Method 305 shall not be adjusted by the compound-specific Fm factor listed in Table 8 of this subpart.</P> <P>(<E T="03">2</E>) <E T="03">Flow rate.</E> Flow rate measurements to determine E shall be taken as provided in paragraph (e)(2)(iii)(A)(<E T="03">5</E>) of this section for a series of treatment processes. Flow rate shall be determined using inlet and outlet flow measurement devices. Where the outlet flow is not greater than the inlet flow, a single flow measurement device may be used, and may be used at either the inlet or outlet. Flow rate measurements shall be taken at the same time as the concentration measurements.</P> <P>(3) <E T="03">Destruction efficiency.</E> The owner or operator shall comply with the provisions in either paragraph (e)(2)(iii)(E)(<E T="03">3</E>)(<E T="03">i</E>), (<E T="03">ii</E>) or (<E T="03">iii</E>) of this section. Compliance is demonstrated if the destruction efficiency, E, is equal to or greater than 95 percent.</P> <P>(<E T="03">i</E>) If the performance test is performed across the open or closed biological treatment system only, compliance is demonstrated if E is equal to F<E T="52">bio</E>, where E is the destruction efficiency of partially soluble and/or soluble HAP compounds and F<E T="52">bio</E> is the site-specific fraction of partially soluble and/or soluble HAP compounds biodegraded. F<E T="52">bio</E> shall be determined as specified in paragraph (e)(2)(iii)(E)(<E T="03">4</E>) of this section and appendix C of subpart G of this part.</P> <P>(<E T="03">ii</E>) If compliance is being demonstrated in accordance with paragraphs (e)(2)(iii)(A)(<E T="03">5</E>)(<E T="03">i</E>) or (<E T="03">ii</E>) of this section, the removal efficiency shall be calculated using Equation 49 of this subpart. When complying with paragraph (e)(2)(iii)(A)(<E T="03">5</E>)(<E T="03">i</E>) of this section, the series of nonbiological treatment processes comprise one treatment process segment. When complying with paragraph (e)(2)(iii)(A)(<E T="03">5</E>)(<E T="03">ii</E>) of this section, each nonbiological treatment process is a treatment process segment.</P> <GPH DEEP="30" SPAN="2"> <GID>ER21SE98.046</GID> </GPH> <FP SOURCE="FP-2">Where:</FP> <FP SOURCE="FP-2">QMW<E T="52">a,i</E> = the soluble and/or partially soluble HAP load entering a treatment process segment</FP> <FP SOURCE="FP-2">QMW<E T="52">b,i</E> = the soluble and/or partially soluble HAP load exiting a treatment process segment</FP> <FP SOURCE="FP-2">n = the number of treatment process segments</FP> <FP SOURCE="FP-2">i = identifier for a treatment process element</FP> <FP SOURCE="FP-2">QMW<E T="52">bio</E> = the inlet load of soluble and/or partially soluble HAP to the biological treatment process. The inlet is defined in accordance with <PRTPAGE P="85"/>paragraph (e)(2)(iii)(A)(<E T="03">6</E>) of this section. If complying with paragraph (e)(2)(iii)(A)(<E T="03">6</E>)(<E T="03">ii</E>) of this section, QMW<E T="52">bio</E> is equal to QMW<E T="52">b,n</E> </FP> <FP SOURCE="FP-2">F<E T="52">bio</E> = site-specific fraction of soluble and/or partially soluble HAP compounds biodegraded. F<E T="52">bio</E> shall be determined as specified in paragraph (e)(2)(iii)(E)(<E T="03">4</E>) of this section and Appendix C of subpart G of this part.</FP> <FP SOURCE="FP-2">QMW<E T="52">all</E> = the total soluble and/or partially soluble HAP load to be treated.</FP> <P>(<E T="03">4</E>) <E T="03">Site-specific fraction biodegraded</E> (F<E T="52">bio</E> <E T="03">).</E> The procedures used to determine the compound-specific kinetic parameters for use in calculating F<E T="52">bio</E> differ for the compounds listed in Tables 2 and 3 of this subpart. An owner or operator shall calculate F<E T="52">bio</E> as specified in either paragraph (e)(2)(iii)(E)(<E T="03">4</E>)(<E T="03">i</E>) or (<E T="03">ii</E>) of this section.</P> <P>(<E T="03">i</E>) For biological treatment processes that do not meet the definition for enhanced biological treatment in § 63.1251, the owner or operator shall determine the F<E T="52">bio</E> for the compounds in Tables 2 and 3 of this subpart using any of the procedures in appendix C to part 63, except procedure 3 (inlet and outlet concentration measurements). (The symbol “F<E T="52">bio</E>” represents the site-specific fraction of an individual partially soluble or soluble HAP compound that is biodegraded.)</P> <P>(<E T="03">ii</E>) If the biological treatment process meets the definition of “enhanced biological treatment process” in § 63.1251, the owner or operator shall determine F<E T="52">bio</E> for the compounds in Table 2 of this subpart using any of the procedures specified in appendix C to part 63. The owner or operator shall calculate F<E T="52">bio</E> for the compounds in Table 3 of this subpart using the defaults for first order biodegradation rate constants (K<E T="52">1</E>) in Table 9 of this subpart and follow the procedure explained in Form III of appendix C, 40 CFR part 63, or any of the procedures specified in appendix C of 40 CFR part 63.</P> <P>(F) <E T="03">Open or closed aerobic biological treatment processes: percent removal for partially soluble or soluble HAP compounds.</E> This paragraph applies to the use of performance tests that are conducted for open or closed aerobic biological treatment processes to demonstrate compliance with the percent removal provisions for either partially soluble HAP compounds in § 63.1256(g)(8)(ii) or soluble HAP compounds in § 63.1256(g)(9)(ii) or (g)(12). The owner or operator shall comply with the provisions in paragraph (e)(2)(iii)(E) of this section, except that compliance with § 63.1256(g)(8)(ii) shall be demonstrated when E is equal to or greater than 99 percent, compliance with § 63.1256(g)(9)(ii) shall be demonstrated when E is equal to or greater than 90 percent, and compliance with § 63.1256(g)(12) shall be demonstrated when E is equal to or greater than 99 percent.</P> <P>(G) <E T="03">Closed biological treatment processes: percent mass removal option.</E> This paragraph applies to the use of performance tests that are conducted for closed biological treatment processes to demonstrate compliance with the percent removal provisions in §§ 63.1256(g)(8)(ii), (g)(9)(ii), (g)(11), or (g)(12). The owner or operator shall comply with the requirements specified in paragraphs (e)(2)(iii)(G) (<E T="03">1</E>) through (<E T="03">4</E>) of this section.</P> <P>(<E T="03">1</E>) Comply with the procedures specified in paragraphs (e)(2)(iii)(C) (<E T="03">1</E>) through (<E T="03">3</E>) of this section to determine characteristics of the wastewater entering the biological treatment unit, except that the term “partially soluble and/or soluble HAP” shall mean “soluble HAP” for the purposes of this section if the owner or operator is complying with § 63.1256(g)(9)(ii) or (g)(12), and it shall mean “partially soluble HAP” if the owner or operator is complying with § 63.1256(g)(8)(ii).</P> <P>(<E T="03">2</E>) Comply with the procedures specified in paragraphs (e)(2)(iii)(D) (<E T="03">4</E>) through (<E T="03">6</E>) of this section to determine the characteristics of gas vent streams exiting a control device, with the differences noted in paragraphs (e)(2)(iii)(G)(<E T="03">3</E>) (<E T="03">i</E>) and (<E T="03">ii</E>) of this section.</P> <P>(<E T="03">i</E>) The term “partially soluble and/or soluble HAP” shall mean “soluble HAP” for the purposes of this section if the owner or operator is complying with § 63.1256(g)(9)(ii) or (g)(12), and it shall mean “partially soluble HAP” if the owner or operator is complying with § 63.1256(g)(8)(ii).<PRTPAGE P="86"/> </P> <P>(<E T="03">ii</E>) The term “combustion treatment process” shall mean “control device” for the purposes of this section.</P> <P>(<E T="03">3</E>) <E T="03">Percent removal/destruction calculation.</E> The percent removal and destruction across the treatment unit and any control device(s) shall be calculated using Equation 51 of this subpart:</P> <GPH DEEP="32" SPAN="2"> <GID>ER21SE98.047</GID> </GPH> <FP SOURCE="FP-2">Where:</FP> <FP SOURCE="FP-2">E = removal and destruction efficiency of the treatment unit and control device(s), percent</FP> <FP SOURCE="FP-2">QMW<E T="52">a</E>, QMW<E T="52">b</E> = mass flow rate of partially soluble or soluble HAP compounds in wastewater entering (QMW<E T="52">a</E>) and exiting (QMW<E T="52">b</E>) the treatment process, kilograms per hour (as calculated using Equations WW1 and WW2)</FP> <FP SOURCE="FP-2">QMG<E T="52">b</E> = mass flow rate of partially soluble or soluble HAP compounds in vented gas stream exiting the combustion treatment process, kg/hr</FP> <P>(<E T="03">4</E>) <E T="03">Compare mass removal/destruction efficiency to required efficiency.</E> Compare the mass removal/destruction efficiency (calculated using Equation 51 of this subpart) to the required efficiency as specified in § 63.1256(g)(8)(ii), (g)(9)(ii), (g)(11), or (g)(12). If complying with § 63.1256(g)(8)(ii), compliance is demonstrated if the mass removal/destruction is 99 percent or greater. If complying with § 63.1256(g)(9)(ii), compliance is demonstrated if the mass removal/destruction efficiency is 90 percent or greater. If complying with § 63.1256(g)(11), compliance is demonstrated if the mass removal/destruction efficiency is 95 percent or greater. If complying with § 63.1256(g)(12), compliance is demonstrated if the mass removal/destruction efficiency is 99 percent or greater.</P> <P>(3) <E T="03">Compliance with control device provisions.</E> Except as provided in paragraph (e)(3)(iv) of this section, an owner or operator shall demonstrate that each control device or combination of control devices achieves the appropriate conditions specified in § 63.1256(h)(2) by using one or more of the methods specified in paragraphs (e)(3)(i), (ii), or (iii) of this section.</P> <P>(i) <E T="03">Performance test for control devices other than flares.</E> This paragraph applies to performance tests that are conducted to demonstrate compliance of a control device with the efficiency limits specified in § 63.1256(h)(2). If complying with the 95-percent reduction efficiency requirement, comply with the requirements specified in paragraphs (e)(3)(i) (A) through (J) of this section. If complying with the 20 ppm by volume requirement, comply with the requirements specified in paragraphs (e)(3)(i) (A) through (G) and (e)(3)(i)(J) of this section.</P> <P>(A) <E T="03">General.</E> The owner or operator shall comply with the general performance test provisions in paragraphs (e)(2)(iii)(A) (<E T="03">1</E>) through (<E T="03">4</E>) of this section, except that the term “treatment unit” shall mean “control device” for the purposes of this section.</P> <P>(B) <E T="03">Sampling sites.</E> Sampling sites shall be selected using Method 1 or 1A of 40 CFR part 60, appendix A, as appropriate. For determination of compliance with the 95 percent reduction requirement, sampling sites shall be located at the inlet and the outlet of the control device. For determination of compliance with the 20 ppmv limit, the sampling site shall be located at the outlet of the control device.</P> <P>(C) <E T="03">Concentration in gas stream entering or exiting the control device.</E> The concentration of total organic HAP or TOC in a gas stream shall be determined as provided in this paragraph. Samples may be grab samples or composite samples (i.e., integrated samples). Samples shall be taken at approximately equally spaced time intervals over a 1-hour period. Each 1-hour <PRTPAGE P="87"/>period constitutes a run, and the performance test shall consist of a minimum of three runs. Concentration measurements shall be determined using Method 18 of 40 CFR part 60, appendix A. Alternatively, any other test method validated according to the procedures in Method 301 of appendix A of this part may be used.</P> <P>(D) <E T="03">Volumetric flow rate of gas stream entering or exiting the control device.</E> The volumetric flow rate of the gas stream shall be determined using Method 2, 2A, 2C, or 2D of 40 CFR part 60, appendix A, as appropriate. Volumetric flow rate measurements shall be taken at the same time as the concentration measurements.</P> <P>(E) <E T="03">Calculation of TOC concentration.</E> The owner or operator shall compute TOC in accordance with the procedures in paragraph (a)(2) of this section.</P> <P>(F) <E T="03">Calculation of total organic HAP concentration.</E> The owner or operator determining compliance based on total organic HAP concentration shall compute the total organic HAP concentration in accordance with the provisions in paragraph (a)(2) of this section.</P> <P>(G) <E T="03">Requirements for combustion control devices.</E> If the control device is a combustion device, the owner or operator shall correct TOC and organic HAP concentrations to 3 percent oxygen in accordance with the provisions in paragraph (a)(3) of this section, and demonstrate initial compliance with the requirements for halogenated streams in accordance with paragraph (a)(6) of this section.</P> <P>(H) <E T="03">Mass rate calculation.</E> The mass rate of either TOC (minus methane and ethane) or total organic HAP for each sample run shall be calculated using the following equations. Where the mass rate of TOC is being calculated, all organic compounds (minus methane and ethane) measured by methods specified in paragraph (e)(3)(i)(C) of this section are summed using Equations 52 and 53 of this subpart. Where the mass rate of total organic HAP is being calculated, only soluble and partially soluble HAP compounds shall be summed using Equations 52 and 53.</P> <GPH DEEP="32" SPAN="2"> <GID>ER21SE98.048</GID> </GPH> <GPH DEEP="32" SPAN="2"> <GID>ER21SE98.049</GID> </GPH> <FP SOURCE="FP-2">Where:</FP> <FP SOURCE="FP-2">CG<E T="52">a,i</E>, CG<E T="52">b,i</E> = concentration of TOC or total organic HAP, in vented gas stream, entering (CG<E T="52">a,i</E>) and exiting (CG<E T="52">b,i</E>) the control device, dry basis, ppmv</FP> <FP SOURCE="FP-2">QMG<E T="52">a</E>, QMG<E T="52">b</E> = mass rate of TOC or total organic HAP, in vented gas stream, entering (QMG<E T="52">a</E>) and exiting (QMG<E T="52">b</E>) the control device, dry basis, kg/hr</FP> <FP SOURCE="FP-2">M<E T="52">wi</E> = molecular weight of a component, kilogram/kilogram-mole</FP> <FP SOURCE="FP-2">QG<E T="52">a</E>,QG<E T="52">b</E> = flow rate of gas stream entering (QG<E T="52">a</E>) and exiting (QG<E T="52">b</E>) the control device, dry standard cubic meters per hour</FP> <FP SOURCE="FP-2">K<E T="52">2</E> = constant, 41.57 × 10<E T="51">−9</E> (parts per million)<E T="51">−1</E> (gram-mole per standard cubic meter) (kilogram/gram), where standard temperature (gram-mole per standard cubic meter) is 20°C</FP> <FP SOURCE="FP-2">i = identifier for a compound</FP> <FP SOURCE="FP-2">n = number of components in the sample</FP> <P>(I) <E T="03">Percent reduction calculation.</E> The percent reduction in TOC or total organic HAP for each sample run shall be calculated using Equation 54 of this subpart:</P> <GPH DEEP="27" SPAN="1"> <GID>ER21SE98.050</GID> </GPH> <PRTPAGE P="88"/> <FP SOURCE="FP-2">where:</FP> <FP SOURCE="FP-2">E = destruction efficiency of control device, percent</FP> <FP SOURCE="FP-2">QMG<E T="52">a</E>,QMG<E T="52">b</E> = mass rate of TOC or total organic HAP, in vented gas stream entering and exiting (QMG<E T="52">b</E>) the control device, dry basis, kilograms per hour</FP> <P>(J) <E T="03">Compare mass destruction efficiency to required efficiency.</E> If complying with the 95-percent reduction efficiency requirement, compliance is demonstrated if the mass destruction efficiency (calculated in Equation 51 of this subpart) is 95 percent or greater. If complying with the 20 ppmv limit, compliance is demonstrated if the outlet TOC concentration is 20 ppmv, or less.</P> <P>(ii) <E T="03">Design evaluation.</E> A design evaluation conducted in accordance with the provisions in paragraph (a)(1) of this section. Compounds that meet the requirements specified in paragraph (e)(2)(iii)(A)(4) of this section are not required to be included in the design evaluation.</P> <P>(iii) <E T="03">Compliance demonstration for flares.</E> When a flare is used to comply with § 63.1256(h), the owner or operator shall comply with the flare provisions in § 63.11(b). An owner or operator is not required to conduct a performance test to determine percent emission reduction or outlet organic HAP or TOC concentration when a flare is used.</P> <P>(iv) <E T="03">Exemptions from compliance demonstrations.</E> An owner or operator using any control device specified in paragraph (a)(4) of this section is exempt from the requirements in paragraphs (e)(3)(i) through (e)(3)(iii) of this section and from the requirements in § 63.6(f).</P> <P>(f) <E T="03">Pollution prevention alternative standard.</E> The owner or operator shall demonstrate compliance with § 63.1252(e)(2) using the procedures described in paragraph (f)(1) and (f)(3) of this section. The owner or operator shall demonstrate compliance with § 63.1252(e)(3) using the procedures described in paragraphs (f)(2) and (f)(3) of this section.</P> <P>(1) Compliance is demonstrated when the annual kg/kg factor, calculated according to the procedure in paragraphs (f)(1)(i) and (iii) of this section, is reduced by at least 75 percent as calculated according to the procedure in paragraph (f)(1)(i) and (ii) of this section.</P> <P>(i) The production-indexed HAP consumption factors shall be calculated by dividing annual consumption of total HAP by the annual production rate, per process. The production-indexed total VOC consumption factor shall be calculated by dividing annual consumption of total VOC by the annual production rate, per process.</P> <P>(ii) The baseline factor is calculated from yearly production and consumption data for the first 3-year period in which the PMPU was operational, beginning no earlier than the 1987 calendar year, or for a minimum period of 12 months from startup of the process until the present in which the PMPU was operational and data are available, beginning no earlier than the 1987 calendar year.</P> <P>(iii) The annual factor is calculated on the following bases:</P> <P>(A) For continuous processes, the annual factor shall be calculated every 30 days for the 12-month period preceding the 30th day (30-day rolling average).</P> <P>(B) For batch processes, the annual factor shall be calculated every 10 batches for the 12-month period preceding the 10th batch (10-batch rolling average). The annual factor shall be calculated every 5 batches if the number of batches is less than 10 for the 12-month period preceding the 10th batch and shall be calculated every year if the number of batches is less than 5 for the 12-month period preceding the 5th batch.</P> <P>(2) Compliance is demonstrated when the requirements of paragraphs (f)(2)(i) through (iv) of this section are met.</P> <P>(i) The annual kg/kg factor, calculated according to the procedure in paragraphs (f)(1)(i) and (f)(1)(iii) of this section, is reduced to a value equal to or less than 50 percent of the baseline factor calculated according to the procedure in paragraphs (f)(1)(i) and (ii) of this section.</P> <P>(ii) The yearly reductions associated with add-on controls that meet the criteria of §§ 63.1252(h)(3)(ii)(A) through (D) must be equal to or greater than the amounts calculated in paragraphs (f)(2)(ii)(A) and (B) of this section:</P> <P>(A) The mass of HAP calculated using Equation 55 of this subpart: <PRTPAGE P="89"/> </P> <FP SOURCE="FP-2">[kg reduced]<E T="52">a</E> = [kg/kg]<E T="52">b</E>(0.75−P<E T="52">R</E>)[kg produced]<E T="52">a</E>(Eq. 55)</FP> <FP SOURCE="FP-2">Where:</FP> <FP SOURCE="FP-2">[kg/kg]<E T="52">b</E> = the baseline production-indexed HAP consumption factor, in kg/kg</FP> <FP SOURCE="FP-2">[kg produced]<E T="52">a</E> = the annual HAP production rate, in kg/yr</FP> <FP SOURCE="FP-2">[kg reduced]<E T="52">a</E> = the annual reduction required by add-on controls, in kg/yr</FP> <FP SOURCE="FP-2">P<E T="52">R</E> = the fractional reduction in the annual kg/kg factor achieved using pollution prevention where P<E T="52">R</E> is ≥0.5</FP> <P>(B) The mass of VOC calculated using Equation 56 of this subpart: </P> <FP SOURCE="FP-2">VOC <E T="52">reduced</E> = (VF<E T="52">base</E> − VF<E T="52">P</E> − VF<E T="52">annual</E>) × M<E T="52">prod</E>(Eq. 56)</FP> <FP SOURCE="FP-2">Where:</FP> <FP SOURCE="FP-2">VOC<E T="52">reduced</E> = required VOC emission reduction from add-on controls, kg/yr</FP> <FP SOURCE="FP-2">VF<E T="52">base</E> = baseline VOC factor, kg VOC emitted/kg production</FP> <FP SOURCE="FP-2">VF<E T="52">p</E> = reduction in VOC factor achieved by pollution prevention, kg VOC emitted/kg production</FP> <FP SOURCE="FP-2">VF<E T="52">annual</E> = target annual VOC factor, kg VOC emitted/kg production</FP> <FP SOURCE="FP-2">M<E T="52">prod</E> = production rate, kg/yr</FP> <P>(iii) Demonstration that the criteria in § 63.1252(e)(3)(ii)(A) through (D) are met shall be accomplished through a description of the control device and of the material streams entering and exiting the control device.</P> <P>(iv) The annual reduction achieved by the add-on control shall be quantified using the methods described in § 63.1257(d).</P> <P>(3) Each owner or operator of a PMPU complying with the P2 standard shall prepare a P2 demonstration summary that shall contain, at a minimum, the following information:</P> <P>(i) Descriptions of the methodologies and forms used to measure and record daily consumption of HAP compounds reduced as part of the P2 standard.</P> <P>(ii) Descriptions of the methodologies and forms used to measure and record daily production of products which are included in the P2 standard.</P> <P>(iii) Supporting documentation for the descriptions provided in paragraphs (f)(3)(i) and (ii) including, but not limited to, operator log sheets and copies of daily, monthly, and annual inventories of materials and products.</P> <P>(g) <E T="03">Compliance with storage tank provisions by using emissions averaging. </E>An owner or operator with two or more affected storage tanks may demonstrate compliance with § 63.1253, as applicable, by fulfilling the requirements of paragraphs (g)(1) through (4) of this section.</P> <P>(1) The owner or operator shall develop and submit for approval an Implementation Plan containing all the information required in § 63.1259(e) 6 months prior to the compliance date of the standard. The Administrator shall have 90 days to approve or disapprove the emissions averaging plan after which time the plan shall be considered approved.</P> <P>(2) The annual mass rate of total organic HAP (E<E T="51">Ti</E>, E<E T="51">To</E>) shall be calculated for each storage tank included in the emissions average using the procedures specified in paragraph (c)(1), (2), or (3) of this section.</P> <P>(3) Equations 57 and 58 of this subpart shall be used to calculate total HAP emissions for those tanks subject to § 63.1253(b) or (c):</P> <GPH DEEP="31" SPAN="1"> <GID>ER21SE98.051</GID> </GPH> <GPH DEEP="31" SPAN="1"> <GID>ER21SE98.052</GID> </GPH> <FP SOURCE="FP-2">Where:</FP> <FP SOURCE="FP-2">E<E T="52">ij</E> = yearly mass rate of total HAP at the inlet of the control device for tank j</FP> <FP SOURCE="FP-2">E<E T="52">oj</E> = yearly mass rate of total HAP at the outlet of the control device for tank j</FP> <FP SOURCE="FP-2">ET<E T="52">i</E> = total yearly uncontrolled HAP emissions</FP> <FP SOURCE="FP-2">E<E T="52">To</E> = total yearly actual HAP emissions</FP> <FP SOURCE="FP-2"> <E T="52">n</E> = number of tanks included in the emissions average</FP> <P>(4) The overall percent reduction efficiency shall be calculated as follows:</P> <GPH DEEP="27" SPAN="1"> <GID>ER21SE98.053</GID> </GPH> <FP SOURCE="FP-2">where:</FP> <PRTPAGE P="90"/> <FP SOURCE="FP-2">R = overall percent reduction efficiency</FP> <FP SOURCE="FP-2">D = discount factor = 1.1 for all controlled storage tanks</FP> <P>(h) <E T="03">Compliance with process vent provisions by using emissions averaging. </E>An owner or operator with two or more affected processes complying with § 63.1254 by using emissions averaging shall demonstrate compliance with paragraphs (h)(1), (2) and (3) of this section.</P> <P>(1) The owner or operator shall develop and submit for approval an Implementation Plan at least 6 months prior to the compliance date of the standard containing all the information required in § 63.1259(e). The Administrator shall have 90 days to approve or disapprove the emissions averaging plan. The plan shall be considered approved if the Administrator either approves the plan in writing, or fails to disapprove the plan in writing. The 90-day period shall begin when the Administrator receives the request. If the request is denied, the owner or operator must still be in compliance with the standard by the compliance date.</P> <P>(2) Owners or operators shall calculate uncontrolled and controlled emissions of HAP by using the methods specified in paragraph (d)(2) and (3) of this section for each process included in the emissions average.</P> <P>(i) Equations 60 and 61 of this subpart shall be used to calculate total HAP emissions:</P> <GPH DEEP="31" SPAN="1"> <GID>ER21SE98.054</GID> </GPH> <FP SOURCE="FP-2">where:</FP> <FP SOURCE="FP-2">E<E T="52">Ui</E> = yearly uncontrolled emissions from process I</FP> <FP SOURCE="FP-2">E<E T="52">Ci</E> = yearly actual emissions for process I</FP> <FP SOURCE="FP-2">E<E T="52">TU</E> = total yearly uncontrolled emissions</FP> <P>E<E T="52">TC</E> = total yearly actual emissions</P> <FP SOURCE="FP-2">n = number of processes included in the emissions average</FP> <P>(3) The overall percent reduction efficiency shall be calculated using Equation 62 of this subpart:</P> <GPH DEEP="31" SPAN="1"> <GID>ER21SE98.055</GID> </GPH> <GPH DEEP="27" SPAN="1"> <GID>ER21SE98.056</GID> </GPH> <FP SOURCE="FP-2">where:</FP> <FP SOURCE="FP-2">R = overall percent reduction efficiency</FP> <FP SOURCE="FP-2">D = discount factor = 1.1 for all controlled emission points</FP> </SECTION> <SECTION> <SECTNO>§ 63.1258</SECTNO> <SUBJECT>Monitoring Requirements.</SUBJECT> <P>(a) The owner or operator of any existing, new, or reconstructed affected source shall provide evidence of continued compliance with the standard as specified in this section. During the initial compliance demonstration, maximum or minimum operating parameter levels, as appropriate, shall be established for emission sources that will indicate the source is in compliance. Test data, calculations, or information from the evaluation of the control device design shall be used to establish the operating parameter level.</P> <P>(b) <E T="03">Monitoring for control devices.</E> (1) <E T="03">Parameters to monitor.</E> Except as specified in paragraph (b)(1)(i) of this section, for each control device, the owner or operator shall install and operate monitoring devices and operate within the established parameter levels to ensure continued compliance with the standard. Monitoring parameters are specified for control scenarios in Table 4 of this subpart and in paragraphs (b)(1)(ii) through (xi) of this section.</P> <P>(i) <E T="03">Periodic verification.</E> For control devices that control vent streams totaling less than 1 ton/yr HAP emissions, before control, monitoring shall consist of a daily verification that the device is operating properly. If the control device is used to control batch process vents alone or in combination with other streams, the verification may be on a per batch basis. This verification shall include, but not be limited to, a daily or per batch demonstration that the unit is working as designed and may include the daily measurements of the parameters described in (b)(1)(ii) through (x) of this section. This demonstration shall be included in the Precompliance report, <PRTPAGE P="91"/>to be submitted 6 months prior to the compliance date of the standard.</P> <P>(ii) <E T="03">Scrubbers.</E> For affected sources using liquid scrubbers, the owner or operator shall establish a minimum scrubber liquid flow rate or pressure drop as a site-specific operating parameter which must be measured and recorded every 15 minutes during the period in which the scrubber is functioning in achieving the HAP removal required by this subpart. If the scrubber uses a caustic solution to remove acid emissions, the owner or operator shall establish a minimum pH of the effluent scrubber liquid as a site-specific operating parameter which must be monitored at least once a day. The minimum scrubber flowrate or pressure drop shall be based on the conditions anticipated under worst-case conditions, as defined in § 63.1257(b)(8)(i).</P> <P>(A) The monitoring device used to determine the pressure drop shall be certified by the manufacturer to be accurate to within a gage pressure of <E T="61">±</E>10 percent of the maximum pressure drop measured.</P> <P>(B) The monitoring device used for measurement of scrubber liquid flowrate shall be certified by the manufacturer to be accurate within <E T="61">±</E>10 percent of the design scrubber liquid flowrate.</P> <P>(C) The monitoring device shall be calibrated annually.</P> <P>(iii) <E T="03">Condensers.</E> For each condenser, the owner or operator shall establish the maximum condenser outlet gas temperature as a site-specific operating parameter which must be measured and recorded at least every 15 minutes during the period in which the condenser is functioning in achieving the HAP removal required by this subpart.</P> <P>(A) The temperature monitoring device must be accurate to within <E T="61">±</E>2 percent of the temperature measured in degrees Celsius or <E T="61">±</E>2.5°C, whichever is greater.</P> <P>(B) The temperature monitoring device must be calibrated annually.</P> <P>(iv) <E T="03">Regenerative carbon adsorbers.</E> For each regenerative carbon adsorber, the owner or operator shall comply with the provisions in paragraphs (b)(1)(iv)(A) through (F) of this section.</P> <P>(A) Establish the regeneration cycle characteristics specified in paragraphs (b)(1)(iv)(A)(<E T="03">1</E>) through (<E T="03">4</E>) of this section under worst-case conditions, as defined in § 63.1257(b)(8)(i).</P> <P>(<E T="03">1</E>) Minimum regeneration frequency (i.e., operating time since last regeneration);</P> <P>(<E T="03">2</E>) Minimum temperature to which the bed is heated during regeneration;</P> <P>(<E T="03">3</E>) Maximum temperature to which the bed is cooled, measured within 15 minutes of completing the cooling phase; and</P> <P>(<E T="03">4</E>) Minimum regeneration stream flow.</P> <P>(B) Monitor and record the regeneration cycle characteristics specified in paragraphs (b)(1)(iv)(B)(<E T="03">1</E>) through (<E T="03">4</E>) of this section for each regeneration cycle.</P> <P>(<E T="03">1</E>) Regeneration frequency (operating time since end of last regeneration);</P> <P>(<E T="03">2</E>) Temperature to which the bed is heated during regeneration;</P> <P>(<E T="03">3</E>) Temperature to which the bed is cooled, measured within 15 minutes of the completion of the cooling phase; and</P> <P>(<E T="03">4</E>) Regeneration stream flow.</P> <P>(C) Use a temperature monitoring device that is accurate to within <E T="61">±</E>2 percent of the temperature measured in degrees Celsius or <E T="61">±</E> 2.5 °C, whichever is greater.</P> <P>(D) Use a regeneration stream flow monitoring device capable of recording the total regeneration stream flow to within <E T="61">±</E> 10 percent of the established value (i.e., accurate to within <E T="61">±</E> 10 percent of the reading).</P> <P>(E) Calibrate the temperature and flow monitoring devices annually.</P> <P>(F) Conduct an annual check for bed poisoning in accordance with manufacturer's specifications.</P> <P>(v) <E T="03">Nonregenerative carbon adsorbers.</E> For each nonregenerative carbon adsorber, the owner or operator shall establish and monitor the maximum time interval between replacement based on the conditions anticipated under worst-case, as defined in § 63.1257(b)(8)(i).</P> <P>(vi) <E T="03">Flares.</E> For each flare, the presence of the pilot flame shall be monitored every 15 minutes during the period in which the flare is functioning in <PRTPAGE P="92"/>achieving the HAP removal required by this subpart.</P> <P>(vii) <E T="03">Thermal incinerators.</E> For each thermal incinerator, the owner or operator shall establish the minimum temperature of the gases exiting the combustion chamber as the site-specific operating parameter which must be measured and recorded at least once every 15 minutes during the period in which the combustion device is functioning in achieving the HAP removal required by this subpart.</P> <P>(A) The temperature monitoring device must be accurate to within <E T="61">±</E> 0.75 percent of the temperature measured in degrees Celsius or <E T="61">±</E> 2.5 °C, whichever is greater.</P> <P>(B) The monitoring device must be calibrated annually.</P> <P>(viii) <E T="03">Catalytic incinerators.</E> For each catalytic incinerator, the owner or operator shall monitor the temperature of the gas stream immediately before and after the catalyst bed. The owner or operator shall establish the minimum temperature of the gas stream immediately before the catalyst bed and the minimum temperature difference across the catalyst bed as the site-specific operating parameter which must be monitored and recorded at leastonce every 15 minutes during the period in which the catalytic incinerator is functioning in achieving the HAP removal required by this subpart.</P> <P>(A) The temperature monitoring devices must be accurate to within <E T="61">±</E> 0.75 percent of the temperature measured in degrees Celsius or <E T="61">±</E> 2.5 °C, whichever is greater.</P> <P>(B) The temperature monitoring devices must be calibrated annually.</P> <P>(ix) <E T="03">Process heaters and boilers.</E> (A) Except as specified in paragraph (b)(1)(ix)(B) of this section, for each boiler or process heater, the owner or operator shall establish the minimum temperature of the gases exiting the combustion chamber as the site-specific operating parameter which must be monitored and recorded at least once every 15 minutes during the period in which the boiler or process heater is functioning in achieving the HAP removal required by this subpart.</P> <P>(<E T="03">1</E>) The temperature monitoring device must be accurate to within <E T="61">±</E>0.75 percent of the temperature measured in degrees Celsius or <E T="61">±</E>2.5°C, whichever is greater.</P> <P>(<E T="03">2</E>) The temperature monitoring device must be calibrated annually.</P> <P>(B) The owner or operator is exempt from the monitoring requirements specified in paragraph (b)(1)(ix)(A) of this section if either:</P> <P>(<E T="03">1</E>) All vent streams are introduced with primary fuel; or</P> <P>(<E T="03">2</E>) The design heat input capacity of the boiler or process heater is 44 megawatts or greater.</P> <P>(x) <E T="03">Continuous emission monitor.</E> As an alternative to the parameters specified in paragraphs (b)(1)(ii) through (ix) of this section, an owner or operator may monitor and record the outlet HAP concentration or both the outlet TOC concentration and outlet hydrogen halide and halogen concentration every 15 minutes during the period in which the control device is functioning in achieving the HAP removal required by this subpart. The owner or operator need not monitor the hydrogen halide and halogen concentration if, based on process knowledge, the owner or operator determines that the emission stream does not contain hydrogen halides or halogens. The HAP or TOC monitor must meet the requirements of Performance Specification 8 or 9 of appendix B of part 60 and must be installed, calibrated, and maintained, according to § 63.8. As part of the QA/QC Plan, calibration of the device must include, at a minimum, quarterly cylinder gas audits.</P> <P>(xi) <E T="03">CVS visual inspections.</E> The owner or operator shall perform monthly visual inspections of each closed vent system as specified in § 63.1252(b).</P> <P>(2) <E T="03">Averaging periods.</E> Averaging periods for parametric monitoring levels shall be established according to paragraphs (b)(2)(i) through (iii) of this section.</P> <P>(i) Except as provided in paragraph (b)(2)(iii) of this section, a daily (24-hour) or block average shall be calculated as the average of all values for a monitored parameter level set according to the procedures in (b)(3)(iii) of this section recorded during the operating day or block.<PRTPAGE P="93"/> </P> <P>(ii) The operating day or block shall be defined in the Notification of Compliance Status report. The daily average may be from midnight to midnight or another continuous 24-hour period. The block average is limited to a period of time that is, at a maximum, equal to the time from the beginning to end of a batch process.</P> <P>(iii) Monitoring values taken during periods in which the control devices are not functioning in controlling emissions, as indicated by periods of no flow, shall not be considered in the averages. Where flow to the device could be intermittent, the owner or operator shall install, calibrate and operate a flow indicator at the inlet or outlet of the control device to identify periods of no flow.</P> <P>(3) <E T="03">Procedures for setting parameter levels for control devices used to control emissions from process vents.</E> (i) <E T="03">Small control devices.</E> Except as provided in paragraph (b)(1)(i) of this section, for devices controlling less than 10 tons per year of HAP for which a performance test is not required, the parametric levels shall be set based on the design evaluation required in § 63.1257(d)(3)(i). If a performance test is conducted, the monitoring parameter level shall be established according to the procedures in (b)(3)(ii) of this section.</P> <P>(ii) <E T="03">Large control devices.</E> For devices controlling greater than 10 tons per year of HAP for which a performance test is required, the parameter level must be established as follows:</P> <P>(A) If the operating parameter level to be established is a maximum, it must be based on the average of the values from each of the three test runs.</P> <P>(B) If the operating parameter level to be established is a minimum, it must be based on the average of the values from each of the three test runs.</P> <P>(C) The owner or operator may establish the parametric monitoring level(s) based on the performance test supplemented by engineering assessments and manufacturer's recommendations. Performance testing is not required to be conducted over the entire range of expected parameter values. The rationale for the specific level for each parameter, including any data and calculations used to develop the level(s) and a description of why the level indicates proper operation of the control device shall be provided in the Precompliance report. The procedures specified in this section have not been approved by the Administrator and determination of the parametric monitoring level using these procedures is subject to review and approval by the Administrator.</P> <P>(iii) <E T="03">Parameters for control devices controlling batch process vents.</E> For devices controlling batch process vents alone or in combination with other streams, the parameter level(s) shall be established in accordance with paragraph (b)(3)(iii)(A) or (B) of this section.</P> <P>(A) If more than one batch emission episode has been selected to be controlled, a single level for the batch process(es) shall be determined from the initial compliance demonstration.</P> <P>(B) Instead of establishing a single level for the batch process(es), as described in paragraph (b)(3)(iii)(A) of this section, an owner or operator may establish separate levels for each batch emission episode, selected to be controlled. If separate monitoring levels are established, the owner or operator must provide a record indicating at what point in the daily schedule or log of processes required to be recorded per the requirements of § 63.1259(b)(9) the parameter being monitored changes levels and must record at least one reading of the new parameter level, even if the duration of monitoring for the new parameter is less than 15-minutes.</P> <P>(4) <E T="03">Request approval to monitor alternative parameters.</E> An owner or operator may request approval to monitor parameters other than those required by paragraphs (b)(1)(ii) through (ix) of this section. The request shall be submitted according to the procedures specified in § 63.8(f) or included in the Precompliance report.</P> <P>(5) <E T="03">Monitoring for the alternative standards.</E> For control devices that are used to comply with the provisions of § 63.1253(d) or 63.1254(c), the owner or operator shall monitor and record the outlet TOC concentration and the outlet hydrogen halide and halogen concentration every 15 minutes during the period in which the device is functioning in achieving the HAP removal <PRTPAGE P="94"/>required by this subpart. A TOC monitor meeting the requirements of Performance Specification 8 or 9 of appendix B of part 60 shall be installed, calibrated, and maintained, according to § 63.8. The owner or operator need notmonitor the hydrogen halide and halogen concentration if, based on process knowledge, the owner or operator determines that the emission stream does not contain hydrogen halides or halogens.</P> <P>(6) <E T="03">Exceedances of operating parameters.</E> An exceedance of an operating parameter is defined as one of the following:</P> <P>(i) If the parameter, averaged over the operating day or block, is below a minimum value established during the initial compliance demonstration.</P> <P>(ii) If the parameter, averaged over the operating day or block, is above the maximum value established during the initial compliance demonstration.</P> <P>(iii) Each loss of pilot flame for flares.</P> <P>(7) <E T="03">Excursions.</E> Excursions are defined by either of the two cases listed in paragraphs (b)(7)(i) or (ii) of this section.</P> <P>(i) When the period of control device operation is 4 hours or greater in an operating day and monitoring data are insufficient to constitute a valid hour of data, as defined in paragraph (b)(7)(iii) of this section, for at least 75 percent of the operating hours.</P> <P>(ii) When the period of control device operation is less than 4 hours in an operating day and more than one of the hours during the period of operation does not constitute a valid hour of data due to insufficient monitoring data.</P> <P>(iii) Monitoring data are insufficient to constitute a valid hour of data, as used in paragraphs (b)(7)(i) and (ii) of this section, if measured values are unavailable for any of the required 15-minute periods within the hour.</P> <P>(8) <E T="03">Violations.</E> Exceedances of parameters monitored according to the provisions of paragraphs (b)(1)(ii) and (iv) through (ix) of this section or excursions as defined by paragraphs (b)(7)(i) through (iii) of this section constitute violations of the operating limit according to paragraphs (b)(8)(i), (ii), and (iv) of this section. Exceedances of the temperature limit monitored according to the provisions of paragraph (b)(1)(iii) of this section or exceedances of the outlet concentrations monitored according to the provisions of paragraph (b)(1)(x) of this section constitute violations of the emission limit according to paragraphs (b)(8)(i), (ii), and (iv) of this section. Exceedances of the outlet concentrations monitored according to the provisions of paragraph (b)(5) of this section constitute violations of the emission limit according to the provisions of paragraphs (b)(8)(iii) and (iv) of this section.</P> <P>(i) Except as provided in paragraph (b)(8)(iv) of this section, for episodes occurring more than once per day, exceedances of established parameter limits or excursions will result in no more than one violation per operating day for each monitored item of equipment utilized in the process.</P> <P>(ii) Except as provided in paragraph (b)(8)(iv) of this section, for control devices used for more than one process in the course of an operating day, exceedances or excursions will result in no more than one violation per operating day, per control device, for each process for which the control device is in service.</P> <P>(iii) Except as provided in paragraph (b)(8)(iv) of this section, exceedances of the 20 ppmv TOC outlet emission limit, averaged over the operating day, will result in no more than one violation per day per control device. Except as provided in paragraph (b)(8)(iv) of this section, exceedances of the 20 ppmv hydrogen halide or halogen outlet emission limit, averaged over the operating day, will result in no more than one violation per day per control device.</P> <P>(iv) Periods of time when monitoring measurements exceed the parameter values as well as periods of inadequate monitoring data do not constitute a violation if they occur during a startup, shutdown, or malfunction, and the facility follows its startup, shutdown, and malfunction plan.</P> <P>(c) <E T="03">Monitoring for emission limits.</E> The owner or operator of any affected source complying with the provisions of § 63.1254(a)(1) shall demonstrate continuous compliance with the 2,000 lb/yr emission limits by calculating daily a 365-day rolling summation of emissions. For owners and operators opting <PRTPAGE P="95"/>to switch compliance strategy from the 93 percent control requirement to the 2,000 lb/yr compliance method, as decribed in § 63.1254(a), the rolling average must include emissions from the past 365 days. Each day that the total emissions per process exceeds 2,000 lb/yr will be considered a violation of the emission limit.</P> <P>(d) <E T="03">Monitoring for equipment leaks.</E> The owner or operator of any affected source complying with the requirements of § 63.1255 of this subpart shall meet the monitoring requirements described § 63.1255 of this subpart.</P> <P>(e) <E T="03">Pollution prevention.</E> The owner or operator of any affected source that chooses to comply with the requirements of §§ 63.1252(e)(2) and (3) shall calculate a yearly rolling average of kg HAP consumption per kg production and kg VOC consumption per kg production every month or every 10 batches. Each rolling average kg/kg factor that exceeds the value established in § 63.1257(f)(1)(ii) will be considered a violation of the emission limit.</P> <P>(f) <E T="03">Emissions averaging.</E> The owner or operator of any affected source that chooses to comply with the requirements of § 63.1252(d) shall meet all monitoring requirements specified in paragraphs (b)(1) and (3) of this section, as applicable, for all processes and storage tanks included in the emissions average.</P> <P>(g) <E T="03">Inspection and monitoring of waste management units and treatment processes.</E> (1) For each wastewater tank, surface impoundment, container, individual drain system, and oil-water separator that receives, manages, or treats wastewater, a residual removed from wastewater, a recycled wastewater, or a recycled residual removed from wastewater, the owner or operator shall comply with the inspection requirements specified in Table 7 of this subpart.</P> <P>(2) For each biological treatment unit used to comply with § 63.1256(g), the owner or operator shall monitor TSS, BOD, and the biomass concentration at a frequency approved by the permitting authority and using methods approved by the permitting authority. The owner or operator may request approval to monitor other parameters. The request shall be submitted in the Precompliance report according to the procedures specified in § 63.1260(e), and shall include a description of planned reporting and recordkeeping procedures. The owner or operator shall include as part of the submittal the basis for the selected monitoring frequencies and the methods that will be used. The Administrator will specify appropriate reporting and recordkeeping requirements as part of the review of the permit application or by other appropriate means.</P> <P>(3) For nonbiological treatment units, the owner or operator shall request approval to monitor appropriate parameters that demonstrate proper operation of the selected treatment process. The request shall be submitted in the Precompliance report according to the procedures specified in § 63.1260(e), and shall include a description of planned reporting and recordkeeping procedures. The Administrator will specify appropriate reporting and recordkeeping requirements as part of the review of the permit application or by other appropriate means.</P> <P>(h) <E T="03">Leak inspection provisions for vapor suppression equipment.</E> (1) Except as provided in paragraph (h)(9) of this section, for each vapor collection system, closed-vent system, fixed roof, cover, or enclosure required to comply with this section, the owner or operator shall comply with the requirements of paragraphs (h)(2) through (8) of this section.</P> <P>(2) Except as provided in paragraphs (h)(6) and (7) of this section, each vapor collection system and closed-vent system shall be inspected according to the procedures and schedule specified in paragraphs (h)(2)(i) and (ii) of this section and each fixed roof, cover, and enclosure shall be inspected according to the procedures and schedule specified in paragraph (h)(2)(iii) of this section.</P> <P>(i) If the vapor collection system or closed-vent system is constructed of hard-piping, the owner or operator shall:</P> <P>(A) Conduct an initial inspection according to the procedures in paragraph (h)(3) of this section, and</P> <P>(B) Conduct annual visual inspections for visible, audible, or olfactory indications of leaks.<PRTPAGE P="96"/> </P> <P>(ii) If the vapor collection system or closed-vent system is constructed of ductwork, the owner or operator shall:</P> <P>(A) Conduct an initial inspection according to the procedures in paragraph (h)(3) of this section, and</P> <P>(B) Conduct annual inspections according to the procedures in paragraph (h)(3) of this section.</P> <P>(C) Conduct annual visual inspections for visible, audible, or olfactory indications of leaks.</P> <P>(iii) For each fixed roof, cover, and enclosure, the owner or operator shall:</P> <P>(A) Conduct an initial inspection according to the procedures in paragraph (h)(3) of this section, and</P> <P>(B) Conduct semiannual visual inspections for visible, audible, or olfactory indications of leaks.</P> <P>(3) Each vapor collection system, closed-vent system, fixed roof, cover, and enclosure shall be inspected according to the procedures specified in paragraphs (h)(3)(i) through (v) of this section.</P> <P>(i) Inspections shall be conducted in accordance with Method 21 of 40 CFR part 60, appendix A.</P> <P>(ii) <E T="03">Detection instrument performance criteria.</E> (A) Except as provided in paragraph (h)(3)(ii)(B) of this section, the detection instrument shall meet the performance criteria of Method 21 of 40 CFR part 60, appendix A, except the instrument response factor criteria in section 3.1.2(a) of Method 21 shall be for the average composition of the process fluid not each individual VOC in the stream. For process streams that contain nitrogen, air, or other inerts which are not organic HAP or VOC, the average stream response factor shall be calculated on an inert-free basis.</P> <P>(B) If no instrument is available at the plant site that will meet the performance criteria specified in paragraph (h)(3)(ii)(A) of this section, the instrument readings may be adjusted by multiplying by the average response factor of the process fluid, calculated on an inert-free basis as described in paragraph (h)(3)(ii)(A) of this section.</P> <P>(iii) The detection instrument shall be calibrated before use on each day of its use by the procedures specified in Method 21 of 40 CFR part 60, appendix A.</P> <P>(iv) Calibration gases shall be as follows:</P> <P>(A) Zero air (less than 10 parts per million hydrocarbon in air); and</P> <P>(B) Mixtures of methane in air at a concentration less than 10,000 parts per million. A calibration gas other than methane in air may be used if the instrument does not respond to methane or if the instrument does not meet the performance criteria specified in paragraph (h)(2)(ii)(A) of this section. In such cases, the calibration gas may be a mixture of one or more of the compounds to be measured in air.</P> <P>(v) An owner or operator may elect to adjust or not adjust instrument readings for background. If an owner or operator elects to not adjust readings for background, all such instrument readings shall be compared directly to the applicable leak definition to determine whether there is a leak. If an owner or operator elects to adjust instrument readings for background, the owner or operator shall measure background concentration using the procedures in § 63.180(b) and (c). The owner or operator shall subtract background reading from the maximum concentration indicated by the instrument.</P> <P>(vi) The background level shall be determined according to the procedures in Method 21 of 40 CFR part 60 appendix A.</P> <P>(vii) The arithmetic difference between the maximum concentration indicated by the instrument and the background level shall be compared with 500 parts per million for determining compliance.</P> <P>(4) Leaks, as indicated by an instrument reading greater than 500 parts per million above background or by visual inspections, shall be repaired as soon as practicable, except as provided in paragraph (h)(5) of this section.</P> <P>(i) A first attempt at repair shall be made no later than 5 calendar days after the leak is detected.</P> <P>(ii) Repair shall be completed no later than 15 calendar days after the leak is detected, except as provided in paragraph (h)(4)(iii) of this section.</P> <P>(iii) For leaks found in vapor collection systems used for transfer operations, repairs shall be completed no later than 15 calendar days after the leak is detected or at the beginning of <PRTPAGE P="97"/>the next transfer loading operation, whichever is later.</P> <P>(5) Delay of repair of a vapor collection system, closed-vent system, fixed roof, cover, or enclosure for which leaks have been detected is allowed if the repair is technically infeasible without a shutdown, as defined in § 63.1251, or if the owner or operator determines that emissions resulting from immediate repair would be greater than the fugitive emissions likely to result from delay of repair. Repair of such equipment shall be complete by the end of the next shutdown.</P> <P>(6) Any parts of the vapor collection system, closed-vent system, fixed roof, cover, or enclosure that are designated, as described in paragraph (h)(8)(i) of this section, as unsafe to inspect are exempt from the inspection requirements of paragraphs (h)(2)(i), (ii), and (iii) of this section if:</P> <P>(i) The owner or operator determines that the equipment is unsafe to inspect because inspecting personnel would be exposed to an imminent or potential danger as a consequence of complying with paragraphs (h)(2)(i), (ii), or (iii) of this section; and</P> <P>(ii) The owner or operator has a written plan that requires inspection of the equipment as frequently as practicable during safe-to-inspect times.</P> <P>(7) Any parts of the vapor collection system, closed-vent system, fixed roof, cover, or enclosure that are designated, as described in paragraph (h)(8)(ii) of this section, as difficult to inspect are exempt from the inspection requirements of paragraphs (h)(2)(i), (ii), and (iii)(A) of this section if:</P> <P>(i) The owner or operator determines that the equipment cannot be inspected without elevating the inspecting personnel more than 2 meters above a support surface; and</P> <P>(ii) The owner or operator has a written plan that requires inspection of the equipment at least once every 5 years.</P> <P>(8) Records shall be maintained as specified in § 63.1259(i) (4) through (9).</P> <P>(9) If a closed-vent system subject to this section is also subject to the equipment leak provisions of § 63.1255, the owner or operator shall comply with the provisions of § 63.1255 and is exempt from the requirements of this section.</P> </SECTION> <SECTION> <SECTNO>§ 63.1259</SECTNO> <SUBJECT>Recordkeeping requirements.</SUBJECT> <P>(a) <E T="03">Requirements of subpart A of this part.</E> The owner or operator of an affected source shall comply with the recordkeeping requirements in subpart A of this part as specified in Table 1 of this subpart and in paragraphs (a)(1) through (5) of this section.</P> <P>(1) <E T="03">Data retention.</E> Each owner or operator of an affected source shall keep copies of all records and reports required by this subpart for at least 5 years, as specified in § 63.10(b)(1).</P> <P>(2) <E T="03">Records of applicability determinations.</E> The owner or operator of a stationary source that is not subject to this subpart shall keep a record of the applicability determination, as specified in § 63.10(b)(3).</P> <P>(3) <E T="03">Startup, shutdown, and malfunction plan.</E> The owner or operator of an affected source shall develop and implement a written startup, shutdown, and malfunction plan as specified in § 63.6(e)(3). This plan shall describe, in detail, procedures for operating and maintaining the affected source during periods of startup, shutdown, and malfunction and a program for corrective action for malfunctioning process, air pollution control, and monitoring equipment used to comply with this subpart. The owner or operator of an affected source shall keep the current and superseded versions of this plan onsite, as specified in § 63.6(e)(3)(v). The owner or operator shall keep the startup, shutdown, and malfunction records specified in paragraphs (b)(3)(i) through (iii) of this section. Reports related to the plan shall be submitted as specified in § 63.1260(i).</P> <P>(i) The owner or operator shall record the occurrence and duration of each malfunction of air pollution control equipment used to comply with this subpart, as specified in § 63.6(e)(3)(iii).</P> <P>(ii) The owner or operator shall record the occurrence and duration of each malfunction of continuous monitoring systems used to comply with this subpart.</P> <P>(iii) For each startup, shutdown, or malfunction, the owner or operator shall record all information necessary to demonstrate that the procedures specified in the affected source's startup, shutdown, and malfunction plan were followed, as specified in <PRTPAGE P="98"/>§ 63.6(e)(3)(iii); alternatively, the owner or operator shall record any actions taken that are not consistent with the plan, as specified in § 63.6(e)(3)(iv).</P> <P>(4) <E T="03">Recordkeeping requirements for sources with continuous monitoring systems.</E> The owner or operator of an affected source who elects to install a continuous monitoring system shall maintain records specified in § 63.10(c)(1) through (14).</P> <P>(5) <E T="03">Application for approval of construction or reconstruction.</E> For new affected sources, each owner or operator shall comply with the provisions in § 63.5 regarding construction and reconstruction, excluding the provisions specified in § 63.5(d)(1)(ii)(H), (d)(2), and (d)(3)(ii).</P> <P>(b) <E T="03">Records of equipment operation.</E> The owner or operator must keep the following records up-to-date and readily accessible:</P> <P>(1) Each measurement of a control device operating parameter monitored in accordance with § 63.1258 and each measurement of a treatment process parameter monitored in accordance with § 63.1258(g)(2) and (3).</P> <P>(2) For processes subject to § 63.1252(e), records of consumption, production, and the rolling average values of the production-indexed HAP and VOC consumption factors.</P> <P>(3) For each continuous monitoring system used to comply with this subpart, records documenting the completion of calibration checks and maintenance of continuous monitoring systems.</P> <P>(4) For processes in compliance with the 2,000 lb/yr emission limit of § 63.1254(a)(1), records of the rolling annual total emissions.</P> <P>(5) Records of the following, as appropriate:</P> <P>(i) The number of batches per year for each batch process.</P> <P>(ii) The operating hours per year for continuous processes.</P> <P>(6) Uncontrolled and controlled emissions per batch for each process.</P> <P>(7) Wastewater concentration per POD or process.</P> <P>(8) Number of storage tank turnovers per year, if used in an emissions average.</P> <P>(9) Daily schedule or log of each operating scenario prior to its operation.</P> <P>(10) Description of worst-case operating conditions as determined using the procedures described in § 63.1257(b)(8) for control devices.</P> <P>(11) Periods of planned routine maintenance as described in § 63.1257 (c)(5).</P> <P>(c) <E T="03">Records of operating scenarios.</E> The owner or operator of an affected source shall keep records of each operating scenario which demonstrates compliance with this subpart.</P> <P>(d) <E T="03">Records of equipment leak detection and repair programs.</E> The owner or operator of any affected source implementing the leak detection and repair (LDAR) program specified in § 63.1255 of this subpart, shall implement the recordkeeping requirements in § 63.1255 of this subpart.</P> <P>(e) <E T="03">Records of emissions averaging.</E> The owner or operator of any affected source that chooses to comply with the requirements of § 63.1252(d) shall maintain up-to-date records of the following information:</P> <P>(1) An Implementation Plan which shall include in the plan, for all process vents and storage tanks included in each of the averages, the information listed in paragraphs (e)(1)(i) through (v) of this section.</P> <P>(i) The identification of all process vents and storage tanks in each emissions average.</P> <P>(ii) The uncontrolled and controlled emissions of HAP and the overall percent reduction efficiency as determined in §§ 63.1257(g)(1) through (4) or 63.1257(h)(1) through (3) as applicable.</P> <P>(iii) The calculations used to obtain the uncontrolled and controlled HAP emissions and the overall percent reduction efficiency.</P> <P>(iv) The estimated values for all parameters required to be monitored under § 63.1258(f) for each process and storage tank included in an average.</P> <P>(v) A statement that the compliance demonstration, monitoring, inspection, recordkeeping and reporting provisions in §§ 63.1257(g) and (h), 63.1258(f), and 63.1260(k) that are applicable to each emission point in the emissions average will be implemented beginning on the date of compliance.</P> <P>(2) The Implementation Plan must demonstrate that the emissions from the processes and storage tanks proposed to be included in the average will <PRTPAGE P="99"/>not result in greater hazard or, at the option of the operating permit authority, greater risk to human health or the environment than if the storage tanks and process vents were controlled according to the provisions in §§ 63.1253 and 63.1254, respectively.</P> <P>(i) This demonstration of hazard or risk equivalency shall be made to the satisfaction of the operating permit authority.</P> <P>(A) The Administrator may require owners and operators to use specific methodologies and procedures for making a hazard or risk determination.</P> <P>(B) The demonstration and approval of hazard or risk equivalency shall be made according to any guidance that the Administrator makes available for use or any other technically sound information or methods.</P> <P>(ii) An emissions averaging plan that does not demonstrate hazard or risk equivalency to the satisfaction of the Administrator shall not be approved. The Administrator may require such adjustments to the emissions averaging plan as are necessary in order to ensure that the average will not result in greater hazard or risk to human health or the environment than would result if the emission points were controlled according to §§ 63.1253 and 63.1254.</P> <P>(iii) A hazard or risk equivalency demonstration must:</P> <P>(A) Be a quantitative, comparative chemical hazard or risk assessment;</P> <P>(B) Account for differences between averaging and non-averaging options in chemical hazard or risk to human health or the environment; and</P> <P>(C) Meet any requirements set by the Administrator for such demonstrations.</P> <P>(3) Records as specified in paragraphs (a), (b) and (d) of this section.</P> <P>(4) A rolling quarterly calculation of the annual percent reduction efficiency as specified in § 63.1257(g) and (h).</P> <P>(f) <E T="03">Records of delay of repair.</E> Documentation of a decision to use a delay of repair due to unavailability of parts, as specified in § 63.1256(i), shall include a description of the failure, the reason additional time was necessary (including a statement of why replacement parts were not kept onsite and when delivery from the manufacturer is scheduled), and the date when the repair was completed.</P> <P>(g) <E T="03">Record of wastewater stream or residual transfer.</E> The owner or operator transferring an affected wastewater stream or residual removed from an affected wastewater stream in accordance with § 63.1256(a)(5) shall keep a record of the notice sent to the treatment operator stating that the wastewater stream or residual contains organic HAP which are required to be managed and treated in accordance with the provisions of this subpart.</P> <P>(h) <E T="03">Records of extensions.</E> The owner or operator shall keep documentation of a decision to use an extension, as specified in § 63.1256(b)(6)(ii) or (b)(9), in a readily accessible location. The documentation shall include a description of the failure, documentation that alternate storage capacity is unavailable, and specification of a schedule of actions that will ensure that the control equipment will be repaired and the tank will be emptied as soon as practical.</P> <P>(i) <E T="03">Records of inspections.</E> The owner or operator shall keep records specified in paragraphs (i)(1) through (9) of this section.</P> <P>(1) A record that each waste management unit inspection required by § 63.1256(b) through (f) was performed.</P> <P>(2) A record that each inspection for control devices required by § 63.1256(h) was performed.</P> <P>(3) A record of the results of each seal gap measurement required by § 63.1256(b)(5) and (f)(3). The records shall include the date of measurement, the raw data obtained in the measurement, and the calculations described in § 63.120(b)(2) through (4).</P> <P>(4) Records identifying all parts of the vapor collection system, closed-vent system, fixed roof, cover, or enclosure that are designated as unsafe to inspect in accordance with § 63.1258(h)(6), an explanation of why the equipment is unsafe to inspect, and the plan for inspecting the equipment.</P> <P>(5) Records identifying all parts of the vapor collection system, closed-vent system, fixed roof, cover, or enclosure that are designated as difficult to inspect in accordance with § 63.1258(h)(7), an explanation of why the equipment is difficult to inspect, <PRTPAGE P="100"/>and the plan for inspecting the equipment.</P> <P>(6) For each vapor collection system or closed-vent system that contains bypass lines that could divert a vent stream away from the control device and to the atmosphere, the owner or operator shall keep a record of the information specified in either paragraph (i)(6)(i) or (ii) of this section.</P> <P>(i) Hourly records of whether the flow indicator specified under § 63.1252(b)(1) was operating and whether a diversion was detected at any time during the hour, as well as records of the times and durations of all periods when the vent stream is diverted from the control device or the flow indicator is not operating.</P> <P>(ii) Where a seal mechanism is used to comply with § 63.1252(b)(2), hourly records of flow are not required. In such cases, the owner or operator shall record that the monthly visual inspection of the seals or closure mechanisms has been done, and shall record the occurrence of all periods when the seal mechanism is broken, the bypass line valve position has changed, or the key for a lock-and-key type lock has been checked out, and records of any car-seal that has broken.</P> <P>(7) For each inspection conducted in accordance with § 63.1258(h)(2) and (3) during which a leak is detected, a record of the information specified in paragraphs (i)(7)(i) through (viii) of this section.</P> <P>(i) The instrument identification numbers; operator name or initials; and identification of the equipment.</P> <P>(ii) The date the leak was detected and the date of the first attempt to repair the leak.</P> <P>(iii) Maximum instrument reading measured by the method specified in § 63.1258(h)(4) after the leak is successfully repaired or determined to be nonrepairable.</P> <P>(iv) “Repair delayed” and the reason for the delay if a leak is not repaired within 15 calendar days after discovery of the leak.</P> <P>(v) The name, initials, or other form of identification of the owner or operator (or designee) whose decision it was that repair could not be effected without a shutdown.</P> <P>(vi) The expected date of successful repair of the leak if a leak is not repaired within 15 calendar days.</P> <P>(vii) Dates of shutdowns that occur while the equipment is unrepaired. (viii) The date of successful repair of the leak.</P> <P>(8) For each inspection conducted in accordance with § 63.1258(h)(3) during which no leaks are detected, a record that the inspection was performed, the date of the inspection, and a statement that no leaks were detected.</P> <P>(9) For each visual inspection conducted in accordance with § 63.1258(h)(2)(i)(B) or (h)(2)(iii)(B) of this section during which no leaks are detected, a record that the inspection was performed, the date of the inspection, and a statement that no leaks were detected.</P> </SECTION> <SECTION> <SECTNO>§ 63.1260</SECTNO> <SUBJECT>Reporting requirements.</SUBJECT> <P>(a) The owner or operator of an affected source shall comply with the reporting requirements of paragraphs (b) through (l) of this section. Applicable reporting requirements of §§ 63.9 and 63.10 are also summarized in Table 1 of this subpart.</P> <P>(b) <E T="03">Initial notification.</E> The owner or operator shall submit the applicable initial notification in accordance with § 63.9(b) or (d).</P> <P>(c) <E T="03">Application for approval of construction or reconstruction.</E> An owner or operator who is subject to § 63.5(b)(3) shall submit to the Administrator an application for approval of the construction of a new major affected source, the reconstruction of a major affected source, or the reconstruction of a major source such that the source becomes a major affected source subject to the standards. The application shall be prepared in accordance with § 63.5(d).</P> <P>(d) <E T="03">Notification of CMS performance evaluation.</E> An owner or operator who is required by the Administrator to conduct a performance evaluation for a continuous monitoring system shall notify the Administrator of the date of the performance evaluation as specified in § 63.8(e)(2).</P> <P>(e) <E T="03">Precompliance report.</E> The Precompliance report shall be submitted at least 6 months prior to the compliance date of the standard. For <PRTPAGE P="101"/>new sources, the Precompliance report shall be submitted to the Administrator with the application for approval of construction or reconstruction. The Administrator shall have 90 days to approve or disapprove the plan. The plan shall be considered approved if the Administrator either approves the plan in writing, or fails to disapprove the plan in writing. The 90 day period shall begin when the Administrator receives the request. If the request is denied, the owner or operator must still be in compliance with the standard by the compliance date. To change any of the information submitted in the report, the owner or operator shall notify the Administrator 90 days before the planned change is to be implemented; the change shall be considered approved if the Administrator either approves the change in writing, or fails to disapprove the change in writing. The Precompliance report shall include:</P> <P>(1) Requests for approval to use alternative monitoring parameters or requests to set monitoring parameters according to § 63.1258(b)(4).</P> <P>(2) Descriptions of the daily or per batch demonstrations to verify that control devices subject to § 63.1258(b)(1)(i) are operating as designed.</P> <P>(3) A description of test conditions, and the corresponding monitoring parameter values for parameters that are set according to § 63.1258(b)(3)(ii)(C).</P> <P>(4) For owners and operators complying with the requirements of § 63.1252(e), the P2 demonstration summary required in § 63.1257(f).</P> <P>(5) Data and rationale used to support an engineering assessment to calculate uncontrolled emissions from process vents as required in § 63.1257(d)(2)(ii).</P> <P>(f) <E T="03">Notification of Compliance Status report.</E> The Notification of Compliance Status report required under § 63.9 shall be submitted no later than 150 days after the compliance date and shall include:</P> <P>(1) The results of any applicability determinations, emission calculations, or analyses used to identify and quantify HAP emissions from the affected source.</P> <P>(2) The results of emissions profiles, performance tests, engineering analyses, design evaluations, or calculations used to demonstrate compliance. For performance tests, results should include descriptions of sampling and analysis procedures and quality assurance procedures.</P> <P>(3) Descriptions of monitoring devices, monitoring frequencies, and the values of monitored parameters established during the initial compliance determinations, including data and calculations to support the levels established.</P> <P>(4) Listing of all operating scenarios.</P> <P>(5) Descriptions of worst-case operating and/or testing conditions for control devices.</P> <P>(6) Identification of emission points subject to overlapping requirements described in § 63.1250(h) and the authority under which the owner or operator will comply.</P> <P>(g) <E T="03">Periodic reports.</E> An owner or operator shall prepare Periodic reports in accordance with paragraphs (g)(1) and (2) of this section and submit them to the Administrator.</P> <P>(1) <E T="03">Submittal schedule.</E> Except as provided in (g)(1) (i), (ii) and (iii) of this section, an owner or operator shall submit Periodic reports semiannually, beginning 60 operating days after the end of the applicable reporting period. The first report shall be submitted no later than 240 days after the date the Notification of Compliance Status is due and shall cover the 6-month period beginning on the date the Notification of Compliance Status is due.</P> <P>(i) When the Administrator determines on a case-by-case basis that more frequent reporting is necessary to accurately assess the compliance status of the affected source; or</P> <P>(ii) When the monitoring data are used directly for compliance determination and the source experience excess emissions, in which case quarterly reports shall be submitted. Once an affected source reports excess emissions, the affected source shall follow a quarterly reporting format until a request to reduce reporting frequency is approved. If an owner or operator submits a request to reduce the frequency of reporting, the provisions in § 63.10(e)(3)(ii) and (iii) shall apply, except that the <PRTPAGE P="102"/>term “excess emissions and continuous monitoring system performance report and/or summary report” shall mean “Periodic report” for the purposes of this section.</P> <P>(iii) When a new operating scenario has been operated since the last report, in which case quarterly reports shall be submitted.</P> <P>(2) <E T="03">Content of Periodic report.</E> The owner or operator shall include the information in paragraphs (g)(2)(i) through (vii) of this section, as applicable.</P> <P>(i) Each Periodic report must include the information in § 63.10(e)(3)(vi)(A) through (I) and (K) through (M). For each continuous monitoring system, the Periodic report must also include the information in § 63.10(e)(3)(vi)(J).</P> <P>(ii) If the total duration of excess emissions, parameter exceedances, or excursions for the reporting period is 1 percent or greater of the total operating time for the reporting period, or the total continuous monitoring system downtime for the reporting period is 5 percent or greater of the total operating time for the reporting period, the Periodic report must include the information in paragraphs (g)(2)(ii)(A) through (D) of this section.</P> <P>(A) Monitoring data, including 15-minute monitoring values as well as daily average values of monitored parameters, for all operating days when the average values were outside the ranges established in the Notification of Compliance Status report or operating permit.</P> <P>(B) Duration of excursions, as defined in § 63.1258(b)(7).</P> <P>(C) Operating logs and operating scenarios for all operating scenarios for all operating days when the values are outside the levels established in the Notification of Compliance Status report or operating permit.</P> <P>(D) When a continuous monitoring system is used, the information required in § 63.10(c)(5) through (13).</P> <P>(iii) For each inspection conducted in accordance with § 63.1258(h)(2) or (3) during which a leak is detected, the records specified in § 63.1259(i)(7) must be included in the next Periodic report.</P> <P>(iv) For each vapor collection system or closed vent system with a bypass line subject to § 63.1252(b)(1), records required under § 63.1259(i)(6)(i) of all periods when the vent stream is diverted from the control device through a bypass line. For each vapor collection system or closed vent system with a bypass line subject to § 63.1252(b)(2), records required under § 63.1259(i)(6)(ii) of all periods in which the seal mechanism is broken, the bypass valve position has changed, or the key to unlock the bypass line valve was checked out.</P> <P>(v) The information in paragraphs (g)(2)(iv)(A) through (D) of this section shall be stated in the Periodic report, when applicable.</P> <P>(A) No excess emissions.</P> <P>(B) No exceedances of a parameter.</P> <P>(C) No excursions.</P> <P>(D) No continuous monitoring system has been inoperative, out of control, repaired, or adjusted.</P> <P>(vi) For each tank subject to control requirements, periods of planned routine maintenance during which the control device does not meet the specifications of § 63.1253(b) through (d).</P> <P>(vii) Each new operating scenario which has been operated since the time period covered by the last Periodic report. For the initial Periodic report, each operating scenario for each process operated since the compliance date shall be submitted.</P> <P>(h) <E T="03">Notification of process change.</E> </P> <P>(1) Except as specified in paragraph (h)(2) of this section, whenever a process change is made, or a change in any of the information submitted in the Notification of Compliance Status Report, the owner or operator shall submit a report quarterly. The report may be submitted as part of the next Periodic report required under paragraph (g) of this section. The report shall include:</P> <P>(i) A brief description of the process change.</P> <P>(ii) A description of any modifications to standard procedures or quality assurance procedures.</P> <P>(iii) Revisions to any of the information reported in the original Notification of Compliance Status Report under paragraph (f) of this section.</P> <P>(iv) Information required by the Notification of Compliance Status Report under paragraph (f) of this section for changes involving the addition of processes or equipment.<PRTPAGE P="103"/> </P> <P>(2) An owner or operator must submit a report 60 days before the scheduled implementation date of either of the following:</P> <P>(i) Any change in the activity covered by the Precompliance report.</P> <P>(ii) A change in the status of a control device from small to large.</P> <P>(i) <E T="03">Reports of startup, shutdown, and malfunction.</E> For the purposes of this subpart, the startup, shutdown, and malfunction reports shall be submitted on the same schedule as the periodic reports required under paragraph (g) of this section instead of the schedule specified in § 63.10(d)(5)(i). These reports shall include the information specified in § 63.1259(a)(3)(i) through (iii) and shall contain the name, title, and signature of the owner or operator or other responsible official who is certifying its accuracy. Reports are only required if a startup, shutdown, or malfunction occurred during the reporting period. Any time an owner or operator takes an action that is not consistent with the procedures specified in the affected source's startup, shutdown, and malfunction plan, the owner or operator shall submit an immediate startup, shutdown, and malfunction report as specified in § 63.10(d)(4)(ii).</P> <P>(j) <E T="03">Reports of LDAR programs.</E> The owner or operator of any affected source implementing the LDAR program specified in § 63.1255 of this subpart shall implement the reporting requirements in § 63.1255 of this subpart. Copies of all reports shall be retained as records for a period of 5 years, in accordance with the requirements of § 63.10(b)(1).</P> <P>(k) <E T="03">Reports of emissions averaging.</E> The owner or operator of any affected source that chooses to comply with the requirements of § 63.1252(d) shall submit the implementation plan described in § 63.1259(e) 6 months prior to the compliance date of the standard and the following information in the periodic reports:</P> <P>(1) The records specified in § 63.1259(e) for each process or storage tank included in the emissions average;</P> <P>(2) All information as specified in paragraph (g) of this section for each process or storage tank included in the emissions average;</P> <P>(3) Any changes of the processes or storage tanks included in the average.</P> <P>(4) The calculation of the overall percent reduction efficiency for the reporting period.</P> <P>(5) Changes to the Implementation Plan which affect the calculation methodology of uncontrolled or controlled emissions or the hazard or risk equivalency determination.</P> <P>(6) Every second semiannual or fourth quarterly report, as appropriate, shall include the results according to § 63.1259(e)(4) to demonstrate the emissions averaging provisions of §§ 63.1252(d), 63.1257(g) and (h), 63.1258(f), and 63.1259(f) are satisfied.</P> <P>(l) <E T="03">Notification of performance test and test plan.</E> The owner or operator of an affected source shall notify the Administrator of the planned date of a performance test at least 60 days before the test in accordance with § 63.7(b). The owner or operator also must submit the test plan required by § 63.7(c) and the emission profile required by 63.1257(b)(8)(ii) with the notification of the performance test.</P> <P>(m) <E T="03">Request for extension of compliance.</E> An owner or operator may submit to the Administrator a request for an extension of compliance in accordance with § 63.1250(f)(4).</P> </SECTION> <SECTION> <SECTNO>§ 63.1261</SECTNO> <SUBJECT>Delegation of authority.</SUBJECT> <P>(a) In delegating implementation and enforcement authority to a State under § 112(d) of the Clean Air Act, the authorities contained in paragraph (b) of this section shall be retained by the Administrator and not transferred to a State.</P> <P>(b) The authority conferred in § 63.177; the authority to approve applications for determination of equivalent means of emission limitation; and the authority to approve alternative test methods shall not be delegated to any State.<PRTPAGE P="104"/> </P> <GPOTABLE CDEF="s50,r150,xs48,r150" COLS="4" OPTS="L2,i1"> <TTITLE> <E T="04">Table</E> 1 <E T="04">To Subpart GGG.—General Provisions Applicability To Subpart GGG</E> </TTITLE> <BOXHD> <CHED H="1">General provisions reference</CHED> <CHED H="1">Summary of requirements</CHED> <CHED H="1">Applies to subpart GGG</CHED> <CHED H="1">Comments</CHED> </BOXHD> <ROW> <ENT I="01">63.1(a)(1)</ENT> <ENT>General applicability of the General Provisions </ENT> <ENT>Yes </ENT> <ENT>Additional terms defined in § 63.1251; when overlap between subparts A and GGG of this part, subpart GGG takes precedence.</ENT> </ROW> <ROW> <ENT I="01">63.1(a)(2-7) </ENT> <ENT/> <ENT O="xl">Yes </ENT> <ENT/> </ROW> <ROW> <ENT I="01">63.1(a)(8) </ENT> <ENT/> <ENT>No </ENT> <ENT>Discusses state programs.</ENT> </ROW> <ROW> <ENT I="01">63.1(a)(9-14) </ENT> <ENT/> <ENT O="xl">Yes </ENT> <ENT/> </ROW> <ROW> <ENT I="01">63.1(b)(1)</ENT> <ENT>Initial applicability determination </ENT> <ENT>Yes </ENT> <ENT>Subpart GGG clarifies the applicability in § 63.1250.</ENT> </ROW> <ROW> <ENT I="01">63.1(b)(2)</ENT> <ENT>Title V operating permit—see part 70 </ENT> <ENT>Yes </ENT> <ENT>All major affected sources are required to obtain a title V permit.</ENT> </ROW> <ROW> <ENT I="01">63.1(b)(3)</ENT> <ENT>Record of the applicability determination </ENT> <ENT>Yes </ENT> <ENT>All affected sources are subject to subpart GGG according to the applicability definition of subpart GGG.</ENT> </ROW> <ROW> <ENT I="01">63.1(c)(1)</ENT> <ENT>Applicability after standards are set </ENT> <ENT>Yes </ENT> <ENT>Subpart GGG clarifies the applicability of each paragraph of subpart A to sources subject to subpart GGG.</ENT> </ROW> <ROW> <ENT I="01">63.1(c)(2)</ENT> <ENT>Title V permit requirement </ENT> <ENT>No </ENT> <ENT>All major affected sources are required to obtain a title V permit. Area sources are not subject to subpart GGG.</ENT> </ROW> <ROW> <ENT I="01">63.1(c)(3)</ENT> <ENT O="xl">Reserved</ENT> <ENT/> <ENT/> </ROW> <ROW> <ENT I="01">63.1(c)(4)</ENT> <ENT>Requirements for existing source that obtains an extension of compliance </ENT> <ENT O="xl">Yes </ENT> <ENT/> </ROW> <ROW> <ENT I="01">63.1(c)(5) </ENT> <ENT>No </ENT> <ENT>Notification requirements for an area source that increases HAP emissions to major source levels </ENT> <ENT O="xl">Yes</ENT> </ROW> <ROW> <ENT I="01">63.1(d) </ENT> <ENT>[Reserved] </ENT> <ENT O="xl">NA</ENT> </ROW> <ROW> <ENT I="01">63.1(e) </ENT> <ENT>Applicability of permit program before a relevant standard has been set </ENT> <ENT O="xl">Yes</ENT> </ROW> <ROW> <ENT I="01">63.2 </ENT> <ENT>Definitions. </ENT> <ENT>Yes </ENT> <ENT>Additional terms defined in § 63.1251; when overlap between subparts A and GGG of this part occurs, subpart GGG takes precedence.</ENT> </ROW> <ROW> <ENT I="01">63.3 </ENT> <ENT>Units and abbreviations. </ENT> <ENT>Yes </ENT> <ENT>Other units used in subpart GGG are defined in that subpart.</ENT> </ROW> <ROW> <ENT I="01">63.4 </ENT> <ENT>Prohibited activities. </ENT> <ENT O="xl">Yes</ENT> </ROW> <ROW> <ENT I="01">63.5(a) </ENT> <ENT>Construction and reconstruction—applicability </ENT> <ENT>Yes </ENT> <ENT>Except replace the terms “source” and “stationary source” with “affected source”.</ENT> </ROW> <ROW> <ENT I="01">63.5(b)(1) </ENT> <ENT>Upon construction, relevant standards for new sources </ENT> <ENT O="xl">Yes</ENT> </ROW> <ROW> <ENT I="01">63.5(b)(2) </ENT> <ENT>[Reserved] </ENT> <ENT O="xl">NA</ENT> </ROW> <ROW> <ENT I="01">63.5(b)(3) </ENT> <ENT>New construction/reconstruction </ENT> <ENT O="xl">Yes</ENT> </ROW> <ROW> <ENT I="01">63.5(b)(4) </ENT> <ENT>Construction/reconstruction notification </ENT> <ENT O="xl">Yes</ENT> </ROW> <ROW> <ENT I="01">63.5(b)(5) </ENT> <ENT>Construction/reconstruction compliance </ENT> <ENT O="xl">Yes</ENT> </ROW> <ROW> <ENT I="01">63.5(b)(6) </ENT> <ENT>Equipment addition or process change </ENT> <ENT O="xl">Yes</ENT> </ROW> <ROW> <ENT I="01">63.5(c) </ENT> <ENT>[Reserved] </ENT> <ENT O="xl">NA</ENT> </ROW> <ROW> <ENT I="01">63.5(d) </ENT> <ENT>Application for approval of construction/reconstruction </ENT> <ENT>Yes </ENT> <ENT>Except for certain provisions identified in 63.1259(a)(5)</ENT> </ROW> <ROW> <ENT I="01">63.5(e) </ENT> <ENT/> <ENT>Construction/reconstruction approval. </ENT> <ENT O="xl">Yes</ENT> </ROW> <ROW> <ENT I="01">63.5(f) </ENT> <ENT>Construction/reconstruction approval based on prior State review. </ENT> <ENT>Yes </ENT> <ENT>Except replace “source” with “affected source”.</ENT> </ROW> <ROW> <PRTPAGE P="105"/> <ENT I="01">63.6(a)(1) </ENT> <ENT>Compliance with standards and maintenance requirements </ENT> <ENT O="xl">Yes</ENT> </ROW> <ROW> <ENT I="01">63.6(a)(2) </ENT> <ENT>Requirements for area source that increases emissions to become major </ENT> <ENT O="xl">Yes</ENT> </ROW> <ROW> <ENT I="01">63.6(b)(1-2) </ENT> <ENT>Compliance dates for new and reconstructed sources </ENT> <ENT>No </ENT> <ENT>Subpart GGG specifies compliance dates.</ENT> </ROW> <ROW> <ENT I="01">63.6(b)(3-6) </ENT> <ENT>Compliance dates for area sources that become major sources </ENT> <ENT O="xl">Yes</ENT> </ROW> <ROW> <ENT I="01">63.6 (b)(7) </ENT> <ENT>Compliance dates for new sources resulting from new unaffected area sources becoming subject to standards </ENT> <ENT>No </ENT> <ENT>Subpart GGG specifies NS applicability and compliance dates</ENT> </ROW> <ROW> <ENT I="01">63.6(c) </ENT> <ENT>Compliance dates for existing sources </ENT> <ENT>Yes </ENT> <ENT> Except replace “source” with “affected source”. Subpart GGG specifies compliance dates.</ENT> </ROW> <ROW> <ENT I="01">63.6(e) </ENT> <ENT>Operation and maintenance requirements </ENT> <ENT>Yes </ENT> <ENT>Startup, Shutdown, Malfunction Plan requirements specifically include malfunction process, control and monitoring equipment.</ENT> </ROW> <ROW> <ENT I="01">63.6(f)-(g) </ENT> <ENT>Compliance with nonopacity and alternative nonopacity emission standards </ENT> <ENT>Yes </ENT> <ENT>Except that subpart GGG specifies performance test conditions.</ENT> </ROW> <ROW> <ENT I="01">63.6(h) </ENT> <ENT>Opacity and visible emission standards </ENT> <ENT>No </ENT> <ENT>Subpart GGG does not contain any opacity or visible emission standards.</ENT> </ROW> <ROW> <ENT I="01">63.6(i) </ENT> <ENT>Extension of compliance with emission standards </ENT> <ENT>No </ENT> <ENT>§ 63.1250(f)(4) specifies provisions for compliance extensions.</ENT> </ROW> <ROW> <ENT I="01">63.6(j) </ENT> <ENT>Exemption from compliance with emission standards </ENT> <ENT O="xl">Yes</ENT> </ROW> <ROW> <ENT I="01">63.7(a)(1) </ENT> <ENT>Performance testing requirements. </ENT> <ENT>Yes </ENT> <ENT>Subpart GGG specifies required testing and compliance procedures.</ENT> </ROW> <ROW> <ENT I="01">63.7(a)(2)(I-ix) </ENT> <ENT/> <ENT O="xl">Yes</ENT> </ROW> <ROW> <ENT I="01">63.7(a)(3) </ENT> <ENT/> <ENT O="xl">Yes</ENT> </ROW> <ROW> <ENT I="01">63.7(b)(1) </ENT> <ENT>Notification of performance test </ENT> <ENT O="xl">Yes</ENT> </ROW> <ROW> <ENT I="01">63.7(b)(2) </ENT> <ENT>Notification of delay in conducting a scheduled performance test </ENT> <ENT O="xl">Yes</ENT> </ROW> <ROW> <ENT I="01">63.7(c) </ENT> <ENT>Quality assurance program </ENT> <ENT>Yes </ENT> <ENT>Except that the test plan must be submitted with the notification of the performance test.</ENT> </ROW> <ROW> <ENT I="01">63.7(d) </ENT> <ENT>Performance testing facilities. </ENT> <ENT>Yes </ENT> <ENT>Except replace “source” with “affected source”.</ENT> </ROW> <ROW> <ENT I="01">63.7(e) </ENT> <ENT>Conduct of performance tests. </ENT> <ENT>Yes </ENT> <ENT>Subpart GGG also contains test methods and procedures specific to pharmaceutical sources.</ENT> </ROW> <ROW> <ENT I="01">63.7(f) </ENT> <ENT>Use of alternative test method </ENT> <ENT O="xl">Yes</ENT> </ROW> <ROW> <ENT I="01">63.7(g) </ENT> <ENT>Data analysis, recordkeeping, and reporting </ENT> <ENT O="xl">Yes</ENT> </ROW> <ROW> <ENT I="01">63.7(h) </ENT> <ENT>Waiver of performance tests </ENT> <ENT O="xl">Yes</ENT> </ROW> <ROW> <ENT I="01">63.8(a) </ENT> <ENT>Monitoring requirements </ENT> <ENT>Yes </ENT> <ENT>See § 63.1258.</ENT> </ROW> <ROW> <ENT I="01">63.8(b)(1) </ENT> <ENT>Conduct of monitoring </ENT> <ENT O="xl">Yes</ENT> </ROW> <ROW> <ENT I="01">63.8(b)(2) </ENT> <ENT>CMS and combined effluents </ENT> <ENT>No </ENT> <ENT>§ 63.1258 of subpart GGG provides specific CMS requirements.</ENT> </ROW> <ROW> <ENT I="01">63.8(b)(3)-(c)(3) </ENT> <ENT>CMS requirements </ENT> <ENT O="xl">Yes</ENT> </ROW> <ROW> <ENT I="01">63.8(c)(4-5) </ENT> <ENT>CMS operation requirements </ENT> <ENT O="xl">Yes</ENT> </ROW> <ROW> <ENT I="01">63.8 (c)6-8) </ENT> <ENT>CMS calibration and malfunction provisions </ENT> <ENT O="xl">Yes</ENT> </ROW> <ROW> <ENT I="01">63.8(d) </ENT> <ENT>CMS quality control program </ENT> <ENT O="xl">Yes</ENT> </ROW> <ROW> <ENT I="01">63.8(e)(1) </ENT> <ENT>Performance evaluations of CMS </ENT> <ENT O="xl">Yes</ENT> </ROW> <ROW> <ENT I="01">63.8(e)(2)</ENT> <ENT>Notification of performance evaluation </ENT> <ENT O="xl">Yes </ENT> <ENT/> </ROW> <ROW> <ENT I="01">63.8(e)(3-4)</ENT> <ENT>CMS requirements/alternatives </ENT> <ENT O="xl">Yes </ENT> <ENT/> </ROW> <ROW> <ENT I="01">63.8(e)(5)(i)</ENT> <ENT>Reporting performance evaluation results </ENT> <ENT>Yes </ENT> <ENT>See §</ENT> </ROW> <ROW> <ENT I="01">63.1260 (a).</ENT> </ROW> <ROW> <ENT I="01">63.8(e)(5)(ii)</ENT> <ENT>Results of COMS performance evaluation </ENT> <ENT>No </ENT> <ENT>Subpart GGG does not contain any opacity or visible emission standards.</ENT> </ROW> <ROW> <ENT I="01">63.8(f)-(g)</ENT> <ENT>Alternative monitoring method/reduction of monitoring data </ENT> <ENT O="xl">Yes </ENT> <ENT/> </ROW> <ROW> <ENT I="01">63.9(a)-(d) </ENT> <ENT>Notification requirements—Applicability and general information </ENT> <ENT O="xl">Yes </ENT> <ENT/> </ROW> <ROW> <ENT I="01">63.9(e)</ENT> <ENT>Notification of performance test </ENT> <ENT O="xl">Yes </ENT> <ENT/> </ROW> <ROW> <ENT I="01">63.9(f) </ENT> <ENT>Notification of opacity and visible emissions observations </ENT> <ENT>No </ENT> <ENT>Subpart GGG does not contain any opacity or visible emission standards.</ENT> </ROW> <ROW> <ENT I="01">63.9(g)(1)</ENT> <ENT>Additional notification requirements for sources with CMS </ENT> <ENT O="xl">Yes </ENT> <ENT/> </ROW> <ROW> <PRTPAGE P="106"/> <ENT I="01">63.9(g)(2) </ENT> <ENT>Notification of compliance with opacity emission standard </ENT> <ENT>No </ENT> <ENT>Subpart GGG does not contain any opacity or visible emission standards.</ENT> </ROW> <ROW> <ENT I="01">63.9(g)(3) </ENT> <ENT>Notification that criterion to continue use of alternative to relative accuracy testing has been exceeded </ENT> <ENT O="xl">Yes </ENT> <ENT/> </ROW> <ROW> <ENT I="01">63.9(h) </ENT> <ENT>Notification of compliance status. </ENT> <ENT>Yes </ENT> <ENT>Due 150 days after compliance date.</ENT> </ROW> <ROW> <ENT I="01">63.9(i)</ENT> <ENT>Adjustment to time periods or postmark deadlines for submittal and review of required communications </ENT> <ENT O="xl">Yes </ENT> <ENT/> </ROW> <ROW> <ENT I="01">63.9(j)</ENT> <ENT>Change in information provided </ENT> <ENT O="xl">Yes </ENT> <ENT/> </ROW> <ROW> <ENT I="01">63.10(a)</ENT> <ENT>Recordkeeping requirements </ENT> <ENT>Yes </ENT> <ENT>See §</ENT> </ROW> <ROW> <ENT I="01">63.1259.</ENT> </ROW> <ROW> <ENT I="01">63.10(b)(1)</ENT> <ENT>Records retention </ENT> <ENT O="xl">Yes </ENT> <ENT/> </ROW> <ROW> <ENT I="01">63.10(b)(2) </ENT> <ENT>Information and documentation to support notifications </ENT> <ENT>No </ENT> <ENT>Subpart GGG specifies recordkeeping requirements.</ENT> </ROW> <ROW> <ENT I="01">63.10(b)(3) </ENT> <ENT>Records retention for sources not subject to relevant standard </ENT> <ENT>Yes </ENT> <ENT> Applicability requirements are given in § 63.1250.</ENT> </ROW> <ROW> <ENT I="01">63.10(c)-(d)(2) </ENT> <ENT>Other recordkeeping and reporting provisions </ENT> <ENT>Yes</ENT> </ROW> <ROW> <ENT I="01">63.10(d)(3) </ENT> <ENT>Reporting results of opacity or visible emissions observations </ENT> <ENT>No </ENT> <ENT>Subpart GGG does not include any opacity or visible emission standards.</ENT> </ROW> <ROW> <ENT I="01">63.10(d)(4-5) </ENT> <ENT>Other recordkeeping and reporting provisions </ENT> <ENT>Yes</ENT> </ROW> <ROW> <ENT I="01">63.10(e) </ENT> <ENT>Additional CMS reporting requirements </ENT> <ENT>Yes</ENT> </ROW> <ROW> <ENT I="01">63.10(f) </ENT> <ENT>Waiver of recordkeeping or reporting requirements. </ENT> <ENT>Yes</ENT> </ROW> <ROW> <ENT I="01">63.11 </ENT> <ENT>Control device requirements for flares </ENT> <ENT>Yes</ENT> </ROW> <ROW> <ENT I="01">63.12 </ENT> <ENT>State authority and delegations </ENT> <ENT>Yes </ENT> <ENT>See § 63.1261.</ENT> </ROW> <ROW> <ENT I="01">63.13 </ENT> <ENT>Addresses of State air pollution control agencies </ENT> <ENT>Yes</ENT> </ROW> <ROW> <ENT I="01">63.14 </ENT> <ENT>Incorporations by reference </ENT> <ENT>Yes</ENT> </ROW> <ROW> <ENT I="01">63.15 </ENT> <ENT>Availability of information and confidentiality </ENT> <ENT>Yes</ENT> </ROW> </GPOTABLE> <PRTPAGE P="107"/> <GPOTABLE CDEF="7/8,i1,xl100" COLS="1" OPTS="L1,p1"> <TTITLE> <E T="04">Table 2 To Subpart GGG.—Partially Soluble HAP</E> </TTITLE> <BOXHD> <CHED H="1"/> </BOXHD> <ROW> <ENT I="01">1,1,1-Trichloroethane (methyl chloroform)</ENT> </ROW> <ROW> <ENT I="01">1,1,2,2-Tetrachloroethane</ENT> </ROW> <ROW> <ENT I="01">1,1,2-Trichloroethane</ENT> </ROW> <ROW> <ENT I="01">1,1-Dichloroethylene (vinylidene chloride)</ENT> </ROW> <ROW> <ENT I="01">1,2-Dibromoethane</ENT> </ROW> <ROW> <ENT I="01">1,2-Dichloroethane (ethylene dichloride)</ENT> </ROW> <ROW> <ENT I="01">1,2-Dichloropropane</ENT> </ROW> <ROW> <ENT I="01">1,3-Dichloropropene</ENT> </ROW> <ROW> <ENT I="01">2,4,5-Trichlorophenol</ENT> </ROW> <ROW> <ENT I="01">2-Butanone (mek)</ENT> </ROW> <ROW> <ENT I="01">1,4-Dichlorobenzene</ENT> </ROW> <ROW> <ENT I="01">2-Nitropropane</ENT> </ROW> <ROW> <ENT I="01">4-Methyl-2-pentanone (mibk)</ENT> </ROW> <ROW> <ENT I="01">Acetaldehyde</ENT> </ROW> <ROW> <ENT I="01">Acrolein</ENT> </ROW> <ROW> <ENT I="01">Acrylonitrile</ENT> </ROW> <ROW> <ENT I="01">Allyl chloride</ENT> </ROW> <ROW> <ENT I="01">Benzene</ENT> </ROW> <ROW> <ENT I="01">Benzyl chloride</ENT> </ROW> <ROW> <ENT I="01">Biphenyl</ENT> </ROW> <ROW> <ENT I="01">Bromoform (tribromomethane)</ENT> </ROW> <ROW> <ENT I="01">Bromomethane</ENT> </ROW> <ROW> <ENT I="01">Butadiene</ENT> </ROW> <ROW> <ENT I="01">Carbon disulfide</ENT> </ROW> <ROW> <ENT I="01">Chlorobenzene</ENT> </ROW> <ROW> <ENT I="01">Chloroethane (ethyl chloride)</ENT> </ROW> <ROW> <ENT I="01">Chloroform</ENT> </ROW> <ROW> <ENT I="01">Chloromethane</ENT> </ROW> <ROW> <ENT I="01">Chloroprene</ENT> </ROW> <ROW> <ENT I="01">Cumene</ENT> </ROW> <ROW> <ENT I="01">Dichloroethyl ether</ENT> </ROW> <ROW> <ENT I="01">Dinitrophenol</ENT> </ROW> <ROW> <ENT I="01">Epichlorohydrin</ENT> </ROW> <ROW> <ENT I="01">Ethyl acrylate</ENT> </ROW> <ROW> <ENT I="01">Ethylbenzene</ENT> </ROW> <ROW> <ENT I="01">Ethylene oxide</ENT> </ROW> <ROW> <ENT I="01">Hexachlorobenzene</ENT> </ROW> <ROW> <ENT I="01">Hexachlorobutadiene</ENT> </ROW> <ROW> <ENT I="01">Hexachloroethane</ENT> </ROW> <ROW> <ENT I="01">Methyl methacrylate</ENT> </ROW> <ROW> <ENT I="01">Methyl-t-butyl ether</ENT> </ROW> <ROW> <ENT I="01">Methylene chloride</ENT> </ROW> <ROW> <ENT I="01">N,N-dimethylaniline</ENT> </ROW> <ROW> <ENT I="01">Propionaldehyde.</ENT> </ROW> <ROW> <ENT I="01">Propylene oxide</ENT> </ROW> <ROW> <ENT I="01">Styrene</ENT> </ROW> <ROW> <ENT I="01">Tetrachloroethene (perchloroethylene)</ENT> </ROW> <ROW> <ENT I="01">Tetrachloromethane (carbon tetrachloride</ENT> </ROW> <ROW> <ENT I="01">Toluene</ENT> </ROW> <ROW> <ENT I="01">Trichlorobenzene (1,2,4-)</ENT> </ROW> <ROW> <ENT I="01">Trichloroethylene</ENT> </ROW> <ROW> <ENT I="01">Triethylamine</ENT> </ROW> <ROW> <ENT I="01">Trimethylpentane</ENT> </ROW> <ROW> <ENT I="01">Vinyl acetate</ENT> </ROW> <ROW> <ENT I="01">Vinyl chloride</ENT> </ROW> <ROW> <ENT I="01">Xylene (m)</ENT> </ROW> <ROW> <ENT I="01">Xylene (o)</ENT> </ROW> <ROW> <ENT I="01">Xylene (p)</ENT> </ROW> <ROW> <ENT I="01">N-hexane</ENT> </ROW> </GPOTABLE> <GPOTABLE CDEF="xl200" COLS="1" OPTS="L1,i1"> <TTITLE> <E T="04">Table 3 To Subpart GGG.—Soluble HAP</E> </TTITLE> <BOXHD> <CHED H="1">Compound</CHED> </BOXHD> <ROW> <ENT I="01">1,1-Dimethylhydrazine.</ENT> </ROW> <ROW> <ENT I="01">1,4-Dioxane.</ENT> </ROW> <ROW> <ENT I="01">Acetonitrile.</ENT> </ROW> <ROW> <ENT I="01">Acetophenone.</ENT> </ROW> <ROW> <ENT I="01">Diethyl sulfate.</ENT> </ROW> <ROW> <ENT I="01">Dimethyl sulfate.</ENT> </ROW> <ROW> <ENT I="01">Dinitrotoluene.</ENT> </ROW> <ROW> <ENT I="01">Ethylene glycol dimethyl ether.</ENT> </ROW> <ROW> <ENT I="01">Ethylene glycol monobutyl ether acetate.</ENT> </ROW> <ROW> <ENT I="01">Ethylene glycol monomethyl ether acetate.</ENT> </ROW> <ROW> <ENT I="01">Isophorone.</ENT> </ROW> <ROW> <ENT I="01">Methanol (methyl alcohol).</ENT> </ROW> <ROW> <ENT I="01">Nitrobenzene.</ENT> </ROW> <ROW> <ENT I="01">Toluidene.</ENT> </ROW> </GPOTABLE> <PRTPAGE P="108"/> <GPOTABLE CDEF="s100,r100,r100,r100" COLS="4" OPTS="L2,i1"> <TTITLE> <E T="04">Table 4 to Subpart GGG.—Monitoring Requirements for Control Devices </E> <E T="51">a</E> </TTITLE> <BOXHD> <CHED H="1">Control device</CHED> <CHED H="1">Monitoring equipment required</CHED> <CHED H="1">Parameters to be monitored</CHED> <CHED H="1">Frequency</CHED> </BOXHD> <ROW> <ENT I="01">All control devices </ENT> <ENT>1. Flow indicator installed at all bypass lines to the atmosphere and equipped with continuous recorder <E T="03">or</E> </ENT> <ENT>1. Presence of flow diverted from the control device to the atmosphere <E T="03">or</E> </ENT> <ENT>Hourly records of whether the flow indicator was operating and whether a diversion was detected at any time during each hour.</ENT> </ROW> <ROW> <ENT I="22"/> <ENT>2. Valves sealed closed with car-seal or lock-and-key configuration </ENT> <ENT>2. Monthly inspections of sealed valves </ENT> <ENT>Monthly.</ENT> </ROW> <ROW> <ENT I="01">Scrubber </ENT> <ENT>Liquid flow rate or pressure drop mounting device. Also a pH monitor if the scrubber is used to control acid emissions </ENT> <ENT>1. Liquid flow rate into or out of the scrubber or the pressure drop across the scrubber </ENT> <ENT>1. Every 15 minutes.</ENT> </ROW> <ROW> <ENT I="22"/> <ENT O="xl"/> <ENT>2. pH of effluent scrubber liquid </ENT> <ENT>2. Once a day.</ENT> </ROW> <ROW> <ENT I="01">Thermal incinerator </ENT> <ENT>Temperature monitoring device installed in firebox or in ductwork immediately downstream of firebox <E T="51">b</E> </ENT> <ENT>Firebox temperature </ENT> <ENT>Every 15 minutes.</ENT> </ROW> <ROW> <ENT I="01">Catalytic incinerator </ENT> <ENT>Temperature monitoring device installed in gas stream immediately before and after catalyst bed </ENT> <ENT>Temperature difference across catalyst bed </ENT> <ENT>Every 15 minutes.</ENT> </ROW> <ROW> <ENT I="01">Flare </ENT> <ENT>Heat sensing device installed at the pilot light </ENT> <ENT>Presence of a flame at the pilot light </ENT> <ENT>Every 15 minutes.</ENT> </ROW> <ROW> <ENT I="01">Boiler or process heater <44 mega watts and vent stream is not mixed with the primary fuel </ENT> <ENT>Temperature monitoring device installed in firebox <E T="51">b</E> </ENT> <ENT>Combustion temperature </ENT> <ENT>Every 15 minutes.</ENT> </ROW> <ROW> <ENT I="01">Condenser </ENT> <ENT>Temperature monitoring device installed at condenser exit </ENT> <ENT>Condenser exit (product side) temperature </ENT> <ENT>Every 15 minutes.</ENT> </ROW> <ROW> <ENT I="01">Carbon adsorber (nonregenerative) </ENT> <ENT>None </ENT> <ENT>Operating time since last replacement </ENT> <ENT>N/A.</ENT> </ROW> <ROW> <ENT I="01">Carbon adsorber (regenerative) </ENT> <ENT>Stream flow monitoring device, <E T="03">and</E> </ENT> <ENT>1. Total regeneration stream mass or volumetric flow during carbon bed regeneration cycle(s) </ENT> <ENT>1. For each regeneration cycle, record the total regeneration stream mass or volumetric flow.</ENT> </ROW> <ROW> <ENT I="22"/> <ENT>Carbon bed temperature monitoring device </ENT> <ENT>2. Temperature of carbon bed after regeneration </ENT> <ENT>2. For each regeneration cycle, record the maximum carbon bed-temperature.</ENT> </ROW> <ROW> <ENT I="22"/> <ENT O="xl"/> <ENT>3. Temperature of carbon bed within 15 minutes of completing any cooling cycle(s) </ENT> <ENT>3. Within 15 minutes of completing any cooling cycle, record the carbon bed temperature.</ENT> </ROW> <ROW> <ENT I="22"/> <ENT O="xl"/> <ENT>4. Operating time since end of last regeneration </ENT> <ENT>4. Operating time to be based on worst-case conditions.</ENT> </ROW> <ROW> <ENT I="22"/> <ENT O="xl"/> <ENT>5. Check for bed poisoning </ENT> <ENT>5. Yearly.</ENT> </ROW> <TNOTE> <E T="51">a</E> As an alternative to the monitoring requirements specified in this table, the owner or operator may use a CEM meeting the requirements of Performance Specifications 8 or 9 of appendix B of part 60 to monitor TOC every 15 minutes.</TNOTE> <TNOTE> <E T="51">b</E> Monitor may be installed in the firebox or in the ductwork immediately downstream of the firebox before any substantial heat exchange is encountered.</TNOTE> </GPOTABLE> <PRTPAGE P="109"/> <GPOTABLE CDEF="s50,r200" COLS="2" OPTS="L2,i1"> <TTITLE> <E T="04">Table</E> 5 <E T="04">To Subpart GGG.—Control Requirements for Items of Equipment That Meet the Criteria of</E> § 63.1252(f)</TTITLE> <BOXHD> <CHED H="1">Item of equipment</CHED> <CHED H="1">Control requirement <E T="51">a</E> </CHED> </BOXHD> <ROW> <ENT I="01">Drain or drain hub </ENT> <ENT>(a) Tightly fitting solid cover (TFSC); or</ENT> </ROW> <ROW> <ENT I="22"/> <ENT>(b) TFSC with a vent to either a process, or to a fuel gas system, or to a control device meeting the requirements of § 63.1256(h)(2); or</ENT> </ROW> <ROW> <ENT I="22"/> <ENT>(c) Water seal with submerged discharge or barrier to protect discharge from wind.</ENT> </ROW> <ROW> <ENT I="01">Manhole <E T="52">b</E> </ENT> <ENT>(a) TFSC; or</ENT> </ROW> <ROW> <ENT I="22"/> <ENT>(b) TFSC with a vent to either a process, or to a fuel gas system, or to a control device meeting the requirements of § 63.1256(h)(2); or</ENT> </ROW> <ROW> <ENT I="22"/> <ENT>(c) If the item is vented to the atmosphere, use a TFSC with a properly operating water seal at the entrance or exit to the item to restrict ventilation in the collection system. The vent pipe shall be at least 90 cm in length and not exceeding 10.2 cm in nominal inside diameter.</ENT> </ROW> <ROW> <ENT I="01">Lift station </ENT> <ENT>(a) TFSC; or</ENT> </ROW> <ROW> <ENT I="22"/> <ENT>(b) TFSC with a vent to either a process, or to a fuel gas system, or to a control device meeting the requirements of § 63.1256(h)(2); or</ENT> </ROW> <ROW> <ENT I="22"/> <ENT>(c) If the lift station is vented to the atmosphere, use a TFSC with a properly operating water seal at the entrance or exit to the item to restrict ventilation in the collection system. The vent pipe shall be at least 90 cm in length and not exceeding 10.2 cm in nominal inside diameter. The lift station shall be level controlled to minimize changes in the liquid level.</ENT> </ROW> <ROW> <ENT I="01">Trench </ENT> <ENT>(a) TFSC; or</ENT> </ROW> <ROW> <ENT I="22"/> <ENT>(b) TFSC with a vent to either a process, or to a fuel gas system, or to a control device meeting the requirements of § 63.1256(h)(2); or</ENT> </ROW> <ROW> <ENT I="22"/> <ENT>(c) If the item is vented to the atmosphere, use a TFSC with a properly operating water seal at the entrance or exit to the item to restrict ventilation in the collection system. The vent pipe shall be at least 90 cm in length and not exceeding 10.2 cm in nominal inside diameter.</ENT> </ROW> <ROW> <ENT I="01">Pipe </ENT> <ENT>Each pipe shall have no visible gaps in joints, seals, or other emission interfaces</ENT> </ROW> <ROW> <ENT I="01">Oil/Water separator </ENT> <ENT>(a) Equip with a fixed roof and route vapors to a process or to a fuel gas system, or equip with a closed-vent system that routes vapors to a control device meeting the requirements of § 63.1256(h)(2); or</ENT> </ROW> <ROW> <ENT I="22"/> <ENT>(b) Equip with a floating roof that meets the equipment specifications of § 60.693 (a)(1)(i), (a)(1)(ii), (a)(2), (a)(3), and (a)(4).</ENT> </ROW> <ROW> <ENT I="01"> Tank </ENT> <ENT>Maintain a fixed roof.<E T="51">c</E> If the tank is sparged<E T="51">d</E> or used for heating or treating by means of an exothermic reaction, a fixed roof and a system shall be maintained that routes the organic hazardous air pollutants vapors to other process equipment or a fuel gas system, or a closed-vent system that routes vapors to a control device that meets the requirements of 40 CFR § 63.119 (e)(1) or (e)(2).</ENT> </ROW> <TNOTE> AAA<E T="51">a</E> Where a tightly fitting solid cover is required, it shall be maintained with no visible gaps or openings, except during periods of sampling, inspection, or maintenance.</TNOTE> <TNOTE> AAA<E T="51">b</E> Manhole includes sumps and other points of access to a conveyance system.</TNOTE> <TNOTE> AAA<E T="51">c</E> A fixed roof may have openings necessary for proper venting of the tank, such as pressure/vacuum vent, j-pipe vent.</TNOTE> <TNOTE> AAA <E T="51">d</E> The liquid in the tank is agitated by injecting compressed air or gas.</TNOTE> </GPOTABLE> <GPOTABLE CDEF="s100,12,xs80" COLS="3" OPTS="L2,i1"> <TTITLE> <E T="04">Table 6 to Subpart GGG.—Wastewater—Compliance Options for Wastewaster Tanks</E> </TTITLE> <BOXHD> <CHED H="1">Capacity, m<SU>3</SU> </CHED> <CHED H="1">Maximum true vapor pressure, kPa</CHED> <CHED H="1">Control requirements</CHED> </BOXHD> <ROW> <ENT I="01"><75</ENT> <ENT/> <ENT>§ 63.1256(b)(1).</ENT> </ROW> <ROW> <ENT I="01"> <E T="81">></E>75 and <151 </ENT> <ENT><13.1 </ENT> <ENT>§ 63.1256(b)(1).</ENT> </ROW> <ROW> <ENT I="22"/> <ENT> <E T="81">></E>13.1 </ENT> <ENT>§ 63.1256(b)(2).</ENT> </ROW> <ROW> <ENT I="01"> <E T="81">></E>151 </ENT> <ENT><5.2 </ENT> <ENT>§ 63.1256(b)(1).</ENT> </ROW> <ROW> <ENT I="22"/> <ENT> <E T="81">></E>5.2 </ENT> <ENT>§ 63.1256(b)(2).</ENT> </ROW> </GPOTABLE> <PRTPAGE P="110"/> <GPOTABLE CDEF="s100,r100,r100,xs160" COLS="4" OPTS="L2,i1"> <TTITLE> <E T="04">Table 7 to Subpart GGG.—Wastewater—Inspection and Monitoring Requirements for Waste Management Units</E> </TTITLE> <BOXHD> <CHED H="1">To comply with</CHED> <CHED H="1">Inspection or monitoring requirement</CHED> <CHED H="1">Frequency of inspection or monitoring</CHED> <CHED H="1">Method</CHED> </BOXHD> <ROW> <ENT I="22">TANKS:</ENT> </ROW> <ROW> <ENT I="03">63.1256(b)(3)(i) </ENT> <ENT>Inspect fixed roof and all openings for leaks </ENT> <ENT>Initially Semiannually </ENT> <ENT>Visual.</ENT> </ROW> <ROW> <ENT I="03">63.1256(b)(4) </ENT> <ENT>Inspect floating roof in accordance with §§ 63.120(a)(2) and (a)(3) </ENT> <ENT>See §§ 63.120(a)(2) and (a)(3) </ENT> <ENT>Visual.</ENT> </ROW> <ROW> <ENT I="03">63.1256(b)(5) </ENT> <ENT>Measure floating roof seal gaps in accordance with §§ 63.120(b)(2)(i) through (b)(4) </ENT> <ENT/> <ENT>See § 63.120(b)(2)(i) through (b)(4).</ENT> </ROW> <ROW> <ENT I="22"/> <ENT>—Primary seal gaps </ENT> <ENT O="xl">Initially Once every 5 years (annually if no secondary seal). </ENT> <ENT/> </ROW> <ROW> <ENT I="22"/> <ENT>—Secondary seal gaps </ENT> <ENT>Initially Semiannually </ENT> <ENT/> </ROW> <ROW> <ENT I="01">63.1256(b)(7)<LI>63.1256(b)(8) </LI> </ENT> <ENT>Inspect wastewater tank for control equipment failures and improper work practices </ENT> <ENT>Initially Semiannually </ENT> <ENT>Visual.</ENT> </ROW> <ROW> <ENT I="22">SURFACE IMPOUNDMENTS:</ENT> </ROW> <ROW> <ENT I="03">63.1256(c)(1)(i) </ENT> <ENT>Inspect cover and all openings for leaks </ENT> <ENT>Initially Semiannually </ENT> <ENT>Visual.</ENT> </ROW> <ROW> <ENT I="03">63.1256(c)(2) </ENT> <ENT>Inspect surface impoundment for control equipment failures and improper work practices </ENT> <ENT>Initially Semiannually </ENT> <ENT>Visual.</ENT> </ROW> <ROW> <ENT I="22">CONTAINERS:</ENT> </ROW> <ROW> <ENT I="03">63.1256(d)(1)(i)<LI>63.1256(d)(1)(ii) </LI> </ENT> <ENT>Inspect cover and all openings for leaks </ENT> <ENT>Initially Semiannually </ENT> <ENT>Visual.</ENT> </ROW> <ROW> <ENT I="03">63.1256(d)(3)(i) </ENT> <ENT>Inspect enclosure and all openings for leaks </ENT> <ENT>Initially Semiannually </ENT> <ENT>Visual.</ENT> </ROW> <ROW> <ENT I="03">63.1256(d)(4) </ENT> <ENT>Inspect container for control equipment failures and improper work practices </ENT> <ENT>Initially Semiannually </ENT> <ENT>Visual.</ENT> </ROW> <ROW> <ENT I="22">INDIVIDUAL DRAIN SYSTEMS <E T="51">a</E>:</ENT> </ROW> <ROW> <ENT I="03">63.1256(e)(1)(i) </ENT> <ENT>Inspect cover and all openings to ensure there are no gaps, cracks, or holes </ENT> <ENT>Initially Semiannually </ENT> <ENT>Visual.</ENT> </ROW> <ROW> <ENT I="03">63.1256(e)(2) </ENT> <ENT>Inspect individual drain system for control equipment failures and improper work practices </ENT> <ENT>Initially Semiannually </ENT> <ENT>Visual.</ENT> </ROW> <ROW> <ENT I="03">63.1256(e)(4)(i) </ENT> <ENT>Verify that sufficient water is present to properly maintain integrity of water seals </ENT> <ENT>Initially Semiannually </ENT> <ENT>Visual.</ENT> </ROW> <ROW> <ENT I="03">63.1256(e)(4)(ii)<LI>63.1256(e)(5)(i) </LI> </ENT> <ENT>Inspect all drains using tightly-fitted caps or plugs to ensure caps and plugs are in place and properly installed </ENT> <ENT>Initially Semiannually </ENT> <ENT>Visual.</ENT> </ROW> <ROW> <ENT I="03">63.1256(e)(5)(ii) </ENT> <ENT>Inspect all junction boxes to ensure covers are in place and have no visible gaps, cracks, or holes </ENT> <ENT>Initially Semiannually </ENT> <ENT>Visual or smoke test or other means as specified.</ENT> </ROW> <ROW> <ENT I="03">63.1256(e)(5)(iii) </ENT> <ENT>Inspect unburied portion of all sewer lines for cracks and gaps </ENT> <ENT>Initially Semiannually </ENT> <ENT>Visual.</ENT> </ROW> <ROW> <ENT I="22">OIL-WATER SEPARATORS:</ENT> </ROW> <ROW> <PRTPAGE P="111"/> <ENT I="03">63.1256(f)(2)(i) </ENT> <ENT>Inspect fixed roof and all openings for leaks </ENT> <ENT>Initially Semiannually </ENT> <ENT>Visual.</ENT> </ROW> <ROW> <ENT I="03">63.1256(f)(3) </ENT> <ENT>Measure floating roof seal gaps in accordance with 40 CFR 60.696(d)(1) </ENT> <ENT>Initially <E T="51">b</E> </ENT> <ENT>See 40 CFR 60.696(d)(1).</ENT> </ROW> <ROW> <ENT I="22"/> <ENT>—Primary seal gaps </ENT> <ENT>Once every 5 years. </ENT> <ENT/> </ROW> <ROW> <ENT I="03">63.1256(f)(3) </ENT> <ENT>—Secondary seal gaps </ENT> <ENT O="xl">Initially <E T="51">b</E> Annually.</ENT> </ROW> <ROW> <ENT I="03">63.1256(f)(4) </ENT> <ENT>Inspect oil-water separator for control equipment failures and improper work practices </ENT> <ENT>Initially Semiannually </ENT> <ENT>Visual.</ENT> </ROW> <TNOTE> <E T="51">a</E> As specified in § 63.1256(e), the owner or operator shall comply with either the requirements of § 63.1256(e)(1) and (2) or § 63.1256(e)(4) and (5).</TNOTE> <TNOTE> <E T="51">b</E> Within 60 days of installation as specified in § 63.1256(f)(3).</TNOTE> </GPOTABLE> <PRTPAGE P="112"/> <GPOTABLE CDEF="s100,12,7.5" COLS="3" OPTS="L2,i1"> <TTITLE> <E T="04">Table 8 To Subpart GGG.—Fraction Measured</E> (F<E T="52">m</E>) for HAP Compounds in Wastewater Streams</TTITLE> <BOXHD> <CHED H="1">Chemical name</CHED> <CHED H="1">CAS No. <E T="51">a</E> </CHED> <CHED H="1">F<E T="52">m</E> </CHED> </BOXHD> <ROW> <ENT I="01">Acetaldehyde </ENT> <ENT>75070 </ENT> <ENT>1.00</ENT> </ROW> <ROW> <ENT I="01">Acetonitrile </ENT> <ENT>75058 </ENT> <ENT>0.99</ENT> </ROW> <ROW> <ENT I="01">Acetophenone </ENT> <ENT>98862 </ENT> <ENT>0.31</ENT> </ROW> <ROW> <ENT I="01">Acrolein </ENT> <ENT>107028 </ENT> <ENT>1.00</ENT> </ROW> <ROW> <ENT I="01">Acrylonitrile </ENT> <ENT>107131 </ENT> <ENT>1.00</ENT> </ROW> <ROW> <ENT I="01">Allyl chloride </ENT> <ENT>107051 </ENT> <ENT>1.00</ENT> </ROW> <ROW> <ENT I="01">Benzene </ENT> <ENT>71432 </ENT> <ENT>1.00</ENT> </ROW> <ROW> <ENT I="01">Benzyl chloride </ENT> <ENT>100447 </ENT> <ENT>1.00</ENT> </ROW> <ROW> <ENT I="01">Biphenyl </ENT> <ENT>92524 </ENT> <ENT>0.86</ENT> </ROW> <ROW> <ENT I="01">Bromoform </ENT> <ENT>75252 </ENT> <ENT>1.00</ENT> </ROW> <ROW> <ENT I="01">Butadiene (1,3-) </ENT> <ENT>106990 </ENT> <ENT>1.00</ENT> </ROW> <ROW> <ENT I="01">Carbon disulfide </ENT> <ENT>75150 </ENT> <ENT>1.00</ENT> </ROW> <ROW> <ENT I="01">Carbon tetrachloride </ENT> <ENT>56235 </ENT> <ENT>1.00</ENT> </ROW> <ROW> <ENT I="01">Chlorobenzene </ENT> <ENT>108907 </ENT> <ENT>0.96</ENT> </ROW> <ROW> <ENT I="01">Chloroform </ENT> <ENT>67663 </ENT> <ENT>1.00</ENT> </ROW> <ROW> <ENT I="01">Chloroprene (2-Chloro-1,3-butadiene) </ENT> <ENT>126998 </ENT> <ENT>1.00</ENT> </ROW> <ROW> <ENT I="01">Cumene </ENT> <ENT>98828 </ENT> <ENT>1.00</ENT> </ROW> <ROW> <ENT I="01">Dichlorobenzene (p-1,4-) </ENT> <ENT>106467 </ENT> <ENT>1.00</ENT> </ROW> <ROW> <ENT I="01">Dichloroethane (1,2-) (Ethylene dichloride) </ENT> <ENT>107062 </ENT> <ENT>1.00</ENT> </ROW> <ROW> <ENT I="01">Dichloroethylether (Bis(2-Chloroethyl ether)) </ENT> <ENT>111444 </ENT> <ENT>0.76</ENT> </ROW> <ROW> <ENT I="01">Dichloropropene (1,3-) </ENT> <ENT>542756 </ENT> <ENT>1.00</ENT> </ROW> <ROW> <ENT I="01">Diethyl sulfate </ENT> <ENT>64675 </ENT> <ENT>0.0025</ENT> </ROW> <ROW> <ENT I="01">Dimethyl sulfate </ENT> <ENT>77781 </ENT> <ENT>0.086</ENT> </ROW> <ROW> <ENT I="01">Dimethylaniline (N,N-) </ENT> <ENT>121697 </ENT> <ENT>0.00080</ENT> </ROW> <ROW> <ENT I="01">Dimethylhydrazine (1,1-) </ENT> <ENT>57147 </ENT> <ENT>0.38</ENT> </ROW> <ROW> <ENT I="01">Dinitrophenol (2,4-) </ENT> <ENT>51285 </ENT> <ENT>0.0077</ENT> </ROW> <ROW> <ENT I="01">Dinitrotoluene (2,4-) </ENT> <ENT>121142 </ENT> <ENT>0.085</ENT> </ROW> <ROW> <ENT I="01">Dioxane (1,4-) (1,4-Diethyleneoxide) </ENT> <ENT>123911 </ENT> <ENT>0.87</ENT> </ROW> <ROW> <ENT I="01">Epichlorohydrin(1-Chloro-2,3-epoxypropane) </ENT> <ENT>106898 </ENT> <ENT>0.94</ENT> </ROW> <ROW> <ENT I="01">Ethyl acrylate </ENT> <ENT>140885 </ENT> <ENT>1.00</ENT> </ROW> <ROW> <ENT I="01">Ethylbenzene </ENT> <ENT>100414 </ENT> <ENT>1.00</ENT> </ROW> <ROW> <ENT I="01">Ethyl chloride (Chloroethane) </ENT> <ENT>75003 </ENT> <ENT>1.00</ENT> </ROW> <ROW> <ENT I="01">Ethylene dibromide (Dibromomethane) </ENT> <ENT>106934 </ENT> <ENT>1.00</ENT> </ROW> <ROW> <ENT I="01">Ethylene glycol dimethyl ether </ENT> <ENT>110714 </ENT> <ENT>0.86</ENT> </ROW> <ROW> <ENT I="01">Ethylene glycol monobutyl ether acetate </ENT> <ENT>112072 </ENT> <ENT>0.043</ENT> </ROW> <ROW> <ENT I="01">Ethylene glycol monomethyl ether acetate </ENT> <ENT>110496 </ENT> <ENT>0.093</ENT> </ROW> <ROW> <ENT I="01">Ethylene oxide </ENT> <ENT>75218 </ENT> <ENT>1.00</ENT> </ROW> <ROW> <ENT I="01">Ethylidene dichloride (1,1-Dichloroethane) </ENT> <ENT>75343 </ENT> <ENT>1.00</ENT> </ROW> <ROW> <ENT I="01">Hexachlorobenzene </ENT> <ENT>118741 </ENT> <ENT>0.97</ENT> </ROW> <ROW> <ENT I="01">Hexachlorobutadiene </ENT> <ENT>87683 </ENT> <ENT>0.88</ENT> </ROW> <ROW> <ENT I="01">Hexachloroethane </ENT> <ENT>67721 </ENT> <ENT>0.50</ENT> </ROW> <ROW> <ENT I="01">Hexane </ENT> <ENT>110543 </ENT> <ENT>1.00</ENT> </ROW> <ROW> <ENT I="01">Isophorone </ENT> <ENT>78591 </ENT> <ENT>0.47</ENT> </ROW> <ROW> <ENT I="01">Methanol </ENT> <ENT>67561 </ENT> <ENT>0.85</ENT> </ROW> <ROW> <ENT I="01">Methyl bromide (Bromomethane) </ENT> <ENT>74839 </ENT> <ENT>1.00</ENT> </ROW> <ROW> <ENT I="01">Methyl chloride (Chloromethane) </ENT> <ENT>74873 </ENT> <ENT>1.00</ENT> </ROW> <ROW> <ENT I="01">Methyl ethyl ketone (2-Butanone) </ENT> <ENT>78933 </ENT> <ENT>0.99</ENT> </ROW> <ROW> <ENT I="01">Methyl isobutyl ketone (Hexone) </ENT> <ENT>108101 </ENT> <ENT>0.98</ENT> </ROW> <ROW> <ENT I="01">Methyl methacrylate </ENT> <ENT>80626 </ENT> <ENT>1.00</ENT> </ROW> <ROW> <ENT I="01">Methyl tert-butyl ether </ENT> <ENT>1634044 </ENT> <ENT>1.00</ENT> </ROW> <ROW> <ENT I="01">Methylene chloride (Dichloromethane) </ENT> <ENT>75092 </ENT> <ENT>1.00</ENT> </ROW> <ROW> <ENT I="01">Naphthalene </ENT> <ENT>91203 </ENT> <ENT>0.99</ENT> </ROW> <ROW> <ENT I="01">Nitrobenzene </ENT> <ENT>98953 </ENT> <ENT>0.39</ENT> </ROW> <ROW> <ENT I="01">Nitropropane (2-) </ENT> <ENT>79469 </ENT> <ENT>0.99</ENT> </ROW> <ROW> <ENT I="01">Phosgene </ENT> <ENT>75445 </ENT> <ENT>1.00</ENT> </ROW> <ROW> <ENT I="01">Propionaldehyde </ENT> <ENT>123386 </ENT> <ENT>1.00</ENT> </ROW> <ROW> <ENT I="01">Propylene dichloride (1,2-Dichloropropane) </ENT> <ENT>78875 </ENT> <ENT>1.00</ENT> </ROW> <ROW> <ENT I="01">Propylene oxide </ENT> <ENT>75569 </ENT> <ENT>1.00</ENT> </ROW> <ROW> <ENT I="01">Styrene </ENT> <ENT>100425 </ENT> <ENT>1.00</ENT> </ROW> <ROW> <ENT I="01">Tetrachloroethane (1,1,2,2-) </ENT> <ENT>79345 </ENT> <ENT>1.00</ENT> </ROW> <ROW> <ENT I="01">Tetrachloroethylene (Perchloroethylene) </ENT> <ENT>127184 </ENT> <ENT>1.00</ENT> </ROW> <ROW> <ENT I="01">Toluene </ENT> <ENT>108883 </ENT> <ENT>1.00</ENT> </ROW> <ROW> <ENT I="01">Toluidine (o-) </ENT> <ENT>95534 </ENT> <ENT>0.15</ENT> </ROW> <ROW> <ENT I="01">Trichlorobenzene (1,2,4-) </ENT> <ENT>120821 </ENT> <ENT>1.00</ENT> </ROW> <ROW> <ENT I="01">Trichloroethane (1,1,1-) (Methyl chloroform) </ENT> <ENT>71556 </ENT> <ENT>1.00</ENT> </ROW> <ROW> <ENT I="01">Trichloroethane (1,1,2-) (Vinyl Trichloride) </ENT> <ENT>79005 </ENT> <ENT>0.98</ENT> </ROW> <ROW> <ENT I="01">Trichloroethylene </ENT> <ENT>79016 </ENT> <ENT>1.00</ENT> </ROW> <ROW> <ENT I="01">Trichlorophenol (2,4,5-) </ENT> <ENT>95954 </ENT> <ENT>1.00</ENT> </ROW> <ROW> <ENT I="01">Triethylamine </ENT> <ENT>121448 </ENT> <ENT>1.00</ENT> </ROW> <ROW> <ENT I="01">Trimethylpentane (2,2,4-) </ENT> <ENT>540841 </ENT> <ENT>1.00</ENT> </ROW> <ROW> <ENT I="01">Vinyl acetate </ENT> <ENT>108054 </ENT> <ENT>1.00</ENT> </ROW> <ROW> <PRTPAGE P="113"/> <ENT I="01">Vinyl chloride (Chloroethylene) </ENT> <ENT>75014 </ENT> <ENT>1.00</ENT> </ROW> <ROW> <ENT I="01">Vinylidene chloride (1,1-Dichloroethylene) </ENT> <ENT>75354 </ENT> <ENT>1.00</ENT> </ROW> <ROW> <ENT I="01">Xylene (m-) </ENT> <ENT>108383 </ENT> <ENT>1.00</ENT> </ROW> <ROW> <ENT I="01">Xylene (o-) </ENT> <ENT>95476 </ENT> <ENT>1.00</ENT> </ROW> <ROW> <ENT I="01">Xylene (p-) </ENT> <ENT>106423 </ENT> <ENT>1.00</ENT> </ROW> <TNOTE> <E T="51">a</E> CAS numbers refer to the Chemical Abstracts Service registry number assigned to specific compounds, isomers, or mixtures of compounds.</TNOTE> </GPOTABLE> <GPOTABLE CDEF="s200,12" COLS="2" OPTS="L2,i1"> <TTITLE> <E T="04">Table 9 to Subpart GGG.—Default Biorates for List 1 Compounds</E> </TTITLE> <BOXHD> <CHED H="1">Compound name</CHED> <CHED H="1">Biorate (K1), L/g MLVSS-hr</CHED> </BOXHD> <ROW> <ENT I="01">Acetonitrile </ENT> <ENT>0.100</ENT> </ROW> <ROW> <ENT I="01">Acetophenone </ENT> <ENT>0.538</ENT> </ROW> <ROW> <ENT I="01">Diethyl sulfate </ENT> <ENT>0.105</ENT> </ROW> <ROW> <ENT I="01">Dimethyl hydrazine(1,1) </ENT> <ENT>0.227</ENT> </ROW> <ROW> <ENT I="01">Dimethyl sulfate </ENT> <ENT>0.178</ENT> </ROW> <ROW> <ENT I="01">Dinitrotoluene(2,4) </ENT> <ENT>0.784</ENT> </ROW> <ROW> <ENT I="01">Dioxane(1,4) </ENT> <ENT>0.393</ENT> </ROW> <ROW> <ENT I="01">Ethylene glycol dimethyl ether </ENT> <ENT>0.364</ENT> </ROW> <ROW> <ENT I="01">Ethylene glycol monomethyl ether acetate </ENT> <ENT>0.159</ENT> </ROW> <ROW> <ENT I="01">Ethylene glycol monobutyl ether acetate </ENT> <ENT>0.496</ENT> </ROW> <ROW> <ENT I="01">Isophorone </ENT> <ENT>0.598</ENT> </ROW> <ROW> <ENT I="01">Methanol </ENT> <ENT>(<E T="51">a</E>)</ENT> </ROW> <ROW> <ENT I="01">Nitrobenzene </ENT> <ENT>2.300</ENT> </ROW> <ROW> <ENT I="01">Toluidine (-0) </ENT> <ENT>0.859</ENT> </ROW> <TNOTE> <E T="51">a</E> For direct dischargers, the default biorate for methanol is 3.5 L/g MLVSS-hr; for indirect dischargers, the default biorate for methanol is 0.2 L/g MLVSS-hr.</TNOTE> </GPOTABLE> </SECTION> </SUBPART> <SUBPART> <HD SOURCE="HED">Subpart HHH—National Emission Standards for Hazardous Air Pollutants From Natural Gas Transmission and Storage Facilities</HD> <SOURCE> <HD SOURCE="HED">Source:</HD> <P>64 FR 32648, June 17, 1999, unless otherwise noted.</P> </SOURCE> <SECTION> <SECTNO>§ 63.1270</SECTNO> <SUBJECT>Applicability and designation of affected source.</SUBJECT> <P>(a) This subpart applies to owners and operators of natural gas transmission and storage facilities that transport or store natural gas prior to entering the pipeline to a local distribution company or to a final end user (if there is no local distribution company), and that are major sources of hazardous air pollutants (HAP) emissions as determined using the maximum natural gas throughput calculated in either paragraph (a)(1) or (a)(2) of this section and paragraphs (a)(3) and (a)(4) of this section. A compressor station that transports natural gas prior to the point of custody transfer, or to a natural gas processing plant (if present) is considered a part of the oil and natural gas production source category. A facility that is determined to be an area source, based on emission estimates using the maximum natural gas throughput calculated as specified in paragraph (a)(1) or (a)(2) of this section, but subsequently increases emissions or potential to emit above the major source levels (without first obtaining and complying with other limitations that keep its potential to emit HAP below major source levels, becomes a major source and must comply thereafter with all applicable provisions of this subpart starting on the applicable compliance date specified in paragraph (d) of this section. Nothing in this paragraph is intended to preclude a source from limiting its potential to emit through other appropriate mechanisms that may be available through the permitting authority.</P> <P>(1) Facilities that store natural gas or facilities that transport and store natural gas shall determine major source status using the maximum annual facility natural gas throughput calculated according to paragraphs <PRTPAGE P="114"/>(a)(1)(i) through (a)(1)(iv) of this section.</P> <P>(i) The owner or operator shall determine the number of hours to complete the storage cycle for the facility. The storage cycle is the number of hours for the injection cycle, calculated according to the equation in paragraph (a)(1)(i)(A) of this section, plus the number of hours for the withdrawal cycle, calculated according to the equation in paragraph (a)(1)(i)(B) of this section.</P> <P>(A) The hours for the facility injection cycle are determined according to the following equation:</P> <GPH DEEP="27" SPAN="1"> <GID>ER17JN99.005</GID> </GPH> <FP SOURCE="FP-2">Where:</FP> <EXTRACT> <FP SOURCE="FP-2">IC = Facility injection cycle in hours/cycle.</FP> <FP SOURCE="FP-2">WGC = Working gas capacity in cubic meters. The working gas capacity is defined as the maximum storage capacity minus the FERC cushion (as defined in § 63.1271).</FP> <FP SOURCE="FP-2">IR<E T="52">max</E> = Maximum facility injection rate in cubic meters per hour.</FP> </EXTRACT> <P>(B) The hours for the facility withdrawal cycle are determined according to the following equation:</P> <GPH DEEP="27" SPAN="1"> <GID>ER17JN99.006</GID> </GPH> <FP SOURCE="FP-2">Where:</FP> <EXTRACT> <FP SOURCE="FP-2">WC = Facility withdrawal cycle, hours/cycle.</FP> <FP SOURCE="FP-2">WGC = Working gas capacity, cubic meters. The working gas capacity is defined as the maximum storage capacity minus the FERC cushion (as defined in § 63.1271) and shall be the same value as used in paragraph (a)(1)(i)(A) of this section.</FP> <FP SOURCE="FP-2">WR<E T="52">max</E> = Maximum facility withdrawal rate in cubic meters per hour.</FP> </EXTRACT> <P>(ii) The owner or operator shall calculate the number of storage cycles for the facility per year according to the following equation:</P> <GPH DEEP="24" SPAN="1"> <GID>ER17JN99.007</GID> </GPH> <FP SOURCE="FP-2">Where:</FP> <EXTRACT> <FP SOURCE="FP-2">Cycle = Number of storage cycles for the facility per year.</FP> <FP SOURCE="FP-2">IC = Number of hours for a facility injection cycle, hours/cycle, as calculated in paragraph (a)(1)(i)(A) of this section.</FP> <FP SOURCE="FP-2">WC = Number of hours for a facility withdrawal cycle, hours/cycle, as calculated in paragraph (a)(1)(i)(B) of this section.</FP> </EXTRACT> <P>(iii) The owner or operator shall calculate the facilitywide maximum annual glycol dehydration unit hours of operation based on the following equation: </P> <FP SOURCE="FP-2">Operation = Cycles × WC</FP> <FP SOURCE="FP-2">Where:</FP> <EXTRACT> <FP SOURCE="FP-2">Operation = Facilitywide maximum annual glycol dehydration unit hours of operation (hr/yr).</FP> <FP SOURCE="FP-2">Cycles = Number of storage cycles for the facility per year, as calculated in paragraph (a)(1)(ii) of this section.</FP> <FP SOURCE="FP-2">WC = Number of hours for a facility withdrawal cycle, hours/cycle, as calculated in paragraph (a)(1)(i)(B) of this section.</FP> </EXTRACT> <P>(iv) The owner or operator shall calculate the maximum facilitywide natural gas throughput based on the following equation: </P> <FP SOURCE="FP-2">Throughput = Operation × WR<E T="52">max</E> </FP> <FP SOURCE="FP-2">Where:</FP> <EXTRACT> <FP SOURCE="FP-2">Throughput = Maximum facilitywide natural gas throughput in cubic meters per year.</FP> <FP SOURCE="FP-2">Operation = Maximum facilitywide annual glycol dehydration unit hours of operation in hours per year, as calculated in paragraph (a)(1)(iii) of this section.</FP> <FP SOURCE="FP-2">WR<E T="52">max</E> = Maximum facility withdrawal rate in cubic meters per hour.</FP> </EXTRACT> <P>(2) Facilities that only transport natural gas shall calculate the maximum natural gas throughput as the highest annual natural gas throughput over the 5 years prior to June 17, 1999, multiplied by a factor of 1.2.</P> <P>(3) The owner or operator shall maintain records of the annual facility natural gas throughput each year and upon request, submit such records to the Administrator. If the facility annual natural gas throughput increases above the maximum natural gas throughput calculated in paragraph (a)(1) or (a)(2) of this section, the maximum natural gas throughput must be recalculated using the higher throughput multiplied by a factor of 1.2.</P> <P>(4) The owner or operator shall determine the maximum values for other parameters used to calculate potential emissions as the maximum over the same period for which maximum throughput is determined as specified in paragraph (a)(1) or (a)(2) of this section. These parameters shall be based <PRTPAGE P="115"/>on an annual average or the highest single measured value.</P> <P>(b) The affected source is each glycol dehydration unit.</P> <P>(c) The owner or operator of a facility that does not contain an affected source, as specified in paragraph (b) of this section, is not subject to the requirements of this subpart.</P> <P>(d) The owner or operator of each affected source shall achieve compliance with the provisions of this subpart by the following dates:</P> <P>(1) The owner or operator of an affected source, the construction or reconstruction of which commenced before February 6, 1998, shall achieve compliance with this provisions of the subpart no later than June 17, 2002 except as provided for in § 63.6(i). The owner or operator of an area source, the construction or reconstruction of which commenced before February 6, 1998, that increases its emissions of (or its potential to emit) HAP such that the source becomes a major source that is subject to this subpart shall comply with this subpart 3 years after becoming a major source.</P> <P>(2) The owner or operator of an affected source, the construction or reconstruction of which commences on or after February 6, 1998, shall achieve compliance with the provisions of this subpart immediately upon initial startup or June 17, 1999, whichever date is later. Area sources, the construction or reconstruction of which commences on or after February 6, 1998, that become major sources shall comply with the provisions of this standard immediately upon becoming a major source.</P> <P>(e) An owner or operator of an affected source that is a major source or is located at a major source and is subject to the provisions of this subpart is also subject to 40 CFR part 70 or part 71 permitting requirements.</P> <P>(f) <E T="03">Exemptions</E>. A facility with a facilitywide actual annual average natural gas throughput less than 28.3 thousand standard cubic meters per day, where glycol dehydration units are the only HAP emission source, is not subject to the requirements of this subpart. Records shall be maintained as required in § 63.10(b)(3).</P> </SECTION> <SECTION> <SECTNO>§ 63.1271</SECTNO> <SUBJECT>Definitions.</SUBJECT> <P>All terms used in this subpart shall have the meaning given to them in the Clean Air Act, subpart A of this part (General Provisions), and in this section. If the same term is defined in subpart A and in this section, it shall have the meaning given in this section for purposes of this subpart.</P> <P> <E T="03">Boiler</E> means an enclosed device using controlled flame combustion and having the primary purpose of recovering and exporting thermal energy in the form of steam or hot water. Boiler also means any industrial furnace as defined in 40 CFR 260.10.</P> <P> <E T="03">Closed-vent system</E> means a system that is not open to the atmosphere and is composed of piping, ductwork, connections, and if necessary, flow inducing devices that transport gas or vapor from an emission point to one or more control devices. If gas or vapor from regulated equipment is routed to a process (e.g., to a fuel gas system), the conveyance system shall not be considered a closed-vent system and is not subject to closed-vent system standards.</P> <P> <E T="03">Combustion device</E> means an individual unit of equipment, such as a flare, incinerator, process heater, or boiler, used for the combustion of organic HAP emissions.</P> <P> <E T="03">Compressor station</E> means any permanent combination of compressors that move natural gas at increased pressure from fields, in transmission pipelines, or into storage.</P> <P> <E T="03">Continuous recorder</E> means a data recording device that either records an instantaneous data value at least once every hour or records hourly or more frequent block average values.</P> <P> <E T="03">Control device</E> means any equipment used for recovering or oxidizing HAP or volatile organic compounds (VOC) vapors. Such equipment includes, but is not limited to, absorbers, carbon adsorbers, condensers, incinerators, flares, boilers, and process heaters. For the purposes of this subpart, if gas or vapor from regulated equipment is used, reused (i.e., injected into the flame zone of a combustion device), returned back to the process, or sold, <PRTPAGE P="116"/>then the recovery system used, including piping, connections, and flow inducing devices, is not considered to be control devices or closed-vent systems.</P> <P> <E T="03">Custody transfer</E> means the transfer of hydrocarbon liquids or natural gas:</P> <P>(1) After processing and/or treatment in the producing operations; or</P> <P>(2) From storage vessels or automatic transfer facilities, or other equipment, including product loading racks, to pipelines or any other forms of transportation.</P> <P> <E T="03">Facility</E> means any grouping of equipment where natural gas is processed, compressed, or stored prior to entering a pipeline to a local distribution company or (if there is no local distribution company) to a final end user. Examples of a facility for this source category are: an underground natural gas storage operation; or a natural gas compressor station that receives natural gas via pipeline, from an underground natural gas storage operation, or from a natural gas processing plant. The emission points associated with these phases include, but are not limited to, process vents. Processes that may have vents include, but are not limited to, dehydration and compressor station engines.</P> <P>Facility, for the purpose of a major source determination, means natural gas transmission and storage equipment that is located inside the boundaries of an individual surface site (as defined in this section) and is connected by ancillary equipment, such as gas flow lines or power lines. Equipment that is part of a facility will typically be located within close proximity to other equipment located at the same facility. Natural gas transmission and storage equipment or groupings of equipment located on different gas leases, mineral fee tracts, lease tracts, subsurface unit areas, surface fee tracts, or surface lease tracts shall not be considered part of the same facility.</P> <P> <E T="03">Federal Energy Regulatory Commission Cushion</E> or <E T="03">FERC Cushion</E> means the minimum natural gas capacity of a storage field as determined by the Federal Energy Regulatory Commission.</P> <P> <E T="03">Flame zone</E> means the portion of the combustion chamber in a combustion device occupied by the flame envelope.</P> <P> <E T="03">Flash tank</E>. See the definition for gas-condensate-glycol (GCG) separator.</P> <P> <E T="03">Flow indicator</E> means a device which indicates whether gas flow is present in a line or whether the valve position would allow gas flow to be present in a line.</P> <P> <E T="03">Gas-condensate-glycol (GCG) separator</E> means a two-or three-phase separator through which the “rich” glycol stream of a glycol dehydration unit is passed to remove entrained gas and hydrocarbon liquid. The GCG separator is commonly referred to as a flash separator or flash tank.</P> <P> <E T="03">Glycol dehydration unit</E> means a device in which a liquid glycol (including, but not limited to, ethylene glycol, diethylene glycol, or triethylene glycol) absorbent directly contacts a natural gas stream and absorbs water in a contact tower or absorption column (absorber). The glycol contacts and absorbs water vapor and other gas stream constituents from the natural gas and becomes “rich” glycol. This glycol is then regenerated in the glycol dehydration unit reboiler. The “lean” glycol is then recycled.</P> <P> <E T="03">Glycol dehydration unit baseline operations</E> means operations representative of the glycol dehydration unit operations as of June 17, 1999. For the purposes of this subpart, for determining the percentage of overall HAP emission reduction attributable to process modifications, glycol dehydration unit baseline operations shall be parameter values (including, but not limited to, glycol circulation rate or glycol-HAP absorbency) that represent actual long-term conditions (i.e., at least 1 year). Glycol dehydration units in operation for less than 1 year shall document that the parameter values represent expected long-term operating conditions had process modifications not been made.</P> <P> <E T="03">Glycol dehydration unit process vent</E> means either the glycol dehydration unit reboiler vent and the vent from the GCG separator (flash tank), if present.</P> <P> <E T="03">Glycol dehydration unit reboiler vent</E> means the vent through which exhaust from the reboiler of a glycol dehydration unit passes from the reboiler to the atmosphere or to a control device.<PRTPAGE P="117"/> </P> <P> <E T="03">Hazardous air pollutants</E> or <E T="03">HAP</E> means the chemical compounds listed in section 112(b) of the Clean Air Act (Act). All chemical compounds listed in section 112(b) of the Act need to be considered when making a major source determination. Only the HAP compounds listed in Table 1 of this subpart need to be considered when determining compliance.</P> <P> <E T="03">Incinerator</E> means an enclosed combustion device that is used for destroying organic compounds. Auxiliary fuel may be used to heat waste gas to combustion temperatures. Any energy recovery section is not physically formed into one manufactured or assembled unit with the combustion section; rather, the energy recovery section is a separate section following the combustion section and the two are joined by ducts or connections carrying flue gas. The above energy recovery section limitation does not apply to an energy recovery section used solely to preheat the incoming vent stream or combustion air.</P> <P> <E T="03">Initial startup</E> means the first time a new or reconstructed source begins production. For the purposes of this subpart, initial startup does not include subsequent startups (as defined in this section) of equipment, for example, following malfunctions or shutdowns.</P> <P> <E T="03">Major source</E>, as used in this subpart, shall have the same meaning as in § 63.2, except that:</P> <P>(1) Emissions from any pipeline compressor station or pump station shall not be aggregated with emissions from other similar units, whether or not such units are in a contiguous area or under common control; and</P> <P>(2) Emissions from processes, operations, and equipment that are not part of the same facility, as defined in this section, shall not be aggregated.</P> <P> <E T="03">Natural gas</E> means a naturally occurring mixture of hydrocarbon and nonhydrocarbon gases found in geologic formations beneath the earth's surface. The principal hydrocarbon constituent is methane.</P> <P> <E T="03">Natural gas transmission</E> means the pipelines used for the long distance transport of natural gas (excluding processing). Specific equipment used in natural gas transmission includes the land, mains, valves, meters, boosters, regulators, storage vessels, dehydrators, compressors, and their driving units and appurtenances, and equipment used for transporting gas from a production plant, delivery point of purchased gas, gathering system, storage area, or other wholesale source of gas to one or more distribution area(s).</P> <P> <E T="03">No detectable emissions</E> means no escape of HAP from a device or system to the atmosphere as determined by:</P> <P>(1) Instrument monitoring results in accordance with the requirements of § 63.1282(b); and</P> <P>(2) The absence of visible openings or defects in the device or system, such as rips, tears, or gaps.</P> <P> <E T="03">Operating parameter value</E> means a minimum or maximum value established for a control device or process parameter which, if achieved by itself or in combination with one or more other operating parameter values, indicates that an owner or operator has complied with an applicable operating parameter limitation, over the appropriate averaging period as specified in § 63.1282 (e) and (f).</P> <P> <E T="03">Operating permit</E> means a permit required by 40 CFR part 70 or part 71.</P> <P> <E T="03">Organic monitoring device</E> means an instrument used to indicate the concentration level of organic compounds exiting a control device based on a detection principle such as infra-red, photoionization, or thermal conductivity.</P> <P> <E T="03">Primary fuel</E> means the fuel that provides the principal heat input (i.e., more than 50 percent) to the device. To be considered primary, the fuel must be able to sustain operation without the addition of other fuels.</P> <P> <E T="03">Process heater</E> means an enclosed device using a controlled flame, the primary purpose of which is to transfer heat to a process fluid or process material that is not a fluid, or to a heat transfer material for use in a process (rather than for steam generation) .</P> <P> <E T="03">Safety device</E> means a device that meets both of the following conditions: the device is not used for planned or routine venting of liquids, gases, or fumes from the unit or equipment on which the device is installed; and the <PRTPAGE P="118"/>device remains in a closed, sealed position at all times except when an unplanned event requires that the device open for the purpose of preventing physical damage or permanent deformation of the unit or equipment on which the device is installed in accordance with good engineering and safety practices for handling flammable, combustible, explosive, or other hazardous materials. Examples of unplanned events which may require a safety device to open include failure of an essential equipment component or a sudden power outage.</P> <P> <E T="03">Shutdown</E> means for purposes including, but not limited to, periodic maintenance, replacement of equipment, or repair, the cessation of operation of a glycol dehydration unit, or other affected source under this subpart, or equipment required or used solely to comply with this subpart.</P> <P> <E T="03">Startup</E> means the setting into operation of a glycol dehydration unit, or other affected equipment under this subpart, or equipment required or used to comply with this subpart. Startup includes initial startup and operation solely for the purpose of testing equipment.</P> <P> <E T="03">Storage vessel</E> means a tank or other vessel that is designed to contain an accumulation of crude oil, condensate, intermediate hydrocarbon liquids, produced water, or other liquid, and is constructed primarily of non-earthen materials (e.g., wood, concrete, steel, plastic) that provide structural support.</P> <P> <E T="03">Surface site</E> means any combination of one or more graded pad sites, gravel pad sites, foundations, platforms, or the immediate physical location upon which equipment is physically affixed.</P> <P> <E T="03">Temperature monitoring device</E> means an instrument used to monitor temperature and having a minimum accuracy of <E T="61">±</E>2 percent of the temperature being monitored expressed in °C, or <E T="61">±</E>2.5 °C, whichever is greater. The temperature monitoring device may measure temperature in degrees Fahrenheit or degrees Celsius, or both.</P> <P> <E T="03">Total organic compounds</E> or <E T="03">TOC,</E> as used in this subpart, means those compounds which can be measured according to the procedures of Method 18, 40 CFR part 60, appendix A.</P> <P> <E T="03">Underground storage</E> means the subsurface facilities utilized for storing natural gas that has been transferred from its original location for the primary purpose of load balancing, which is the process of equalizing the receipt and delivery of natural gas. Processes and operations that may be located at an underground storage facility include, but are not limited to, compression and dehydration.</P> </SECTION> <SECTION> <SECTNO>§ 63.1272</SECTNO> <SUBJECT>Startups, shutdowns, and malfunctions.</SUBJECT> <P>(a) The provisions set forth in this subpart shall apply at all times except during startups or shutdowns, during malfunctions, and during periods of non-operation of the affected sources (or specific portion thereof) resulting in cessation of the emissions to which this subpart applies. However, during the startup, shutdown, malfunction, or period of non-operation of one portion of an affected source, all emission points which can comply with the specific provisions to which they are subject must do so during the startup, shutdown, malfunction, or period of non-operation.</P> <P>(b) The owner or operator shall not shut down items of equipment that are required or utilized for compliance with the provisions of this subpart during times when emissions are being routed to such items of equipment, if the shutdown would contravene requirements of this subpart applicable to such items of equipment. This paragraph does not apply if the item of equipment is malfunctioning, or if the owner or operator must shut down the equipment to avoid damage due to a contemporaneous startup, shutdown, or malfunction of the affected source or a portion thereof.</P> <P>(c) During startups, shutdowns, and malfunctions when the requirements of this subpart do not apply pursuant to paragraphs (a) and (b) of this section, the owner or operator shall implement, to the extent reasonably available, measures to prevent or minimize excess emissions to the maximum extent practical. For purposes of this paragraph, the term “excess emissions” means emissions in excess of those that would have occurred if there were no startup, shutdown, or malfunction, and <PRTPAGE P="119"/>the owner or operator complied with the relevant provisions of this subpart. The measures to be taken shall be identified in the applicable startup, shutdown, and malfunction plan, and may include, but are not limited to, air pollution control technologies, recovery technologies, work practices, pollution prevention, monitoring, and/or changes in the manner of operation of the source. Back-up control devices are not required, but may be used if available.</P> <P>(d) The owner or operator shall prepare a startup, shutdown, or malfunction plan as required in § 63.6(e)(3) except that the plan is not required to be incorporated by reference into the source's title V permit as specified in § 63.6(e)(3)(i). Instead, the owner or operator shall keep the plan on record as required by § 63.6(e)(3)(v). The failure of the plan to adequately minimize emissions during the startup, shutdown, or malfunction does not shield an owner or operator from enforcement actions.</P> </SECTION> <SECTION> <SECTNO>§ 63.1273</SECTNO> <RESERVED>[Reserved]</RESERVED> </SECTION> <SECTION> <SECTNO>§ 63.1274</SECTNO> <SUBJECT>General standards.</SUBJECT> <P>(a) Table 2 of this subpart specifies the provisions of subpart A (General Provisions) that apply and those that do not apply to owners and operators of affected sources subject to this subpart.</P> <P>(b) All reports required under this subpart shall be sent to the Administrator at the appropriate address listed in § 63.13. Reports may be submitted on electronic media.</P> <P>(c) Except as specified in paragraph (d) of this section, the owner or operator of an affected source (i.e., glycol dehydration unit) located at an existing or new major source of HAP emissions shall comply with the requirements in this subpart as follows:</P> <P>(1) The control requirements for glycol dehydration unit process vents specified in § 63.1275;</P> <P>(2) The monitoring requirements specified in § 63.1283, and</P> <P>(3) The recordkeeping and reporting requirements specified in §§ 63.1284 and 63.1285.</P> <P>(d) <E T="03">Exemptions.</E> The owner or operator is exempt from the requirements of paragraph (c) of this section if the criteria listed in paragraph (d)(1) or (d)(2) of this section are met. Records of the determination of these criteria must be maintained as required in § 63.1284(d) of this subpart.</P> <P>(1) The actual annual average flow of gas to the glycol dehydration unit is less than 283 thousand standard cubic meters per day, as determined by the procedures specified in § 63.1282(a)(1) of this subpart; or</P> <P>(2) The actual average emissions of benzene from the glycol dehydration unit process vents to the atmosphere are less than 0.90 megagram per year as determined by the procedures specified in § 63.1282(a)(2) of this subpart.</P> <P>(e) Each owner or operator of a major HAP source subject to this subpart is required to apply for a part 70 or part 71 operating permit from the appropriate permitting authority. If the Administrator has approved a State operating permit program under part 70, the permit shall be obtained from the State authority. If a State operating permit program has not been approved, the owner or operator shall apply to the EPA Regional Office pursuant to part 71.</P> <P>(f) [Reserved]</P> <P>(g) In all cases where the provisions of this subpart require an owner or operator to repair leaks by a specified time after the leak is detected, it is a violation of this standard to fail to take action to repair the leak(s) within the specified time. If action is taken to repair the leak(s) within the specified time, failure of that action to successfully repair the leak(s) is not a violation of this standard. However, if the repairs are unsuccessful, a leak is detected and the owner or operator shall take further action as required by the applicable provisions of this subpart.</P> </SECTION> <SECTION> <SECTNO>§ 63.1275</SECTNO> <SUBJECT>Glycol dehydration unit process vent standards.</SUBJECT> <P>(a) This section applies to each glycol dehydration unit, subject to this subpart, with an actual annual average natural gas flowrate equal to or greater than 283 thousand standard cubic meters per day and with actual average benzene glycol dehydration unit process vent emissions equal to or greater than 0.90 megagrams per year.</P> <P>(b) Except as provided in paragraph (c) of this section, an owner or operator <PRTPAGE P="120"/>of a glycol dehydration unit process vent shall comply with the requirements specified in paragraphs (b)(1) and (b)(2) of this section.</P> <P>(1) For each glycol dehydration unit process vent, the owner or operator shall control air emissions by either paragraph (b)(1)(i) or (b)(1)(ii) of this section.</P> <P>(i) The owner or operator shall connect the process vent to a control device or a combination of control devices through a closed-vent system. The closed-vent system shall be designed and operated in accordance with the requirements of § 63.1281(c). The control device(s) shall be designed and operated in accordance with the requirements of § 63.1281(d).</P> <P>(ii) The owner or operator shall connect the process vent to a control device or a combination of control devices through a closed-vent system and the outlet benzene emissions from the control device(s) shall be less than 0.90 megagrams per year. The closed-vent system shall be designed and operated in accordance with the requirements of § 63.1281(c). The control device(s) shall be designed and operated in accordance with the requirements of § 63.1281(d), except that the performance requirements specified in § 63.1281(d)(1)(i) and (ii) do not apply.</P> <P>(2) One or more safety devices that vent directly to the atmosphere may be used on the air emission control equipment installed to comply with paragraph (b)(1) of this section.</P> <P>(c) As an alternative to the requirements of paragraph (b) of this section, the owner or operator may comply with one of the following:</P> <P>(1) The owner or operator shall control air emissions by connecting the process vent to a process natural gas line.</P> <P>(2) The owner or operator shall demonstrate, to the Administrator's satisfaction, that the total HAP emissions to the atmosphere from the glycol dehydration unit process vent are reduced by 95.0 percent through process modifications or a combination of process modifications and one or more control devices, in accordance with the requirements specified in § 63.1281(e).</P> <P>(3) Control of HAP emissions from a GCG separator (flash tank) vent is not required if the owner or operator demonstrates, to the Administrator's satisfaction, that total emissions to the atmosphere from the glycol dehydration unit process vent are reduced by one of the levels specified in paragraphs (c)(3)(i) through (c)(3)(ii), through the installation and operation of controls as specified in paragraph (b) (1) of this section.</P> <P>(i) HAP emissions are reduced by 95.0 percent or more.</P> <P>(ii) Benzene emissions are reduced to a level less than 0.90 megagrams per year.</P> </SECTION> <SECTION> <SECTNO>§§ 63.1276-63.1280</SECTNO> <RESERVED>[Reserved]</RESERVED> </SECTION> <SECTION> <SECTNO>§ 63.1281</SECTNO> <SUBJECT>Control equipment requirements.</SUBJECT> <P>(a) This section applies to each closed-vent system and control device installed and operated by the owner or operator to control air emissions as required by the provisions of this subpart. Compliance with paragraphs (c) and (d) of this section will be determined by review of the records required by § 63.1284, the reports required by § 63.1285, by review of performance test results, and by inspections.</P> <P>(b) [Reserved]</P> <P>(c) <E T="03">Closed-vent system requirements.</E> (1) The closed-vent system shall route all gases, vapors, and fumes emitted from the material in a HAP emissions unit to a control device that meets the requirements specified in paragraph (d) of this section.</P> <P>(2) The closed-vent system shall be designed and operated with no detectable emissions.</P> <P>(3) If the closed-vent system contains one or more bypass devices that could be used to divert all or a portion of the gases, vapors, or fumes from entering the control device, the owner or operator shall meet the requirements specified in paragraphs (c)(3)(i) and (c)(3)(ii) of this section.</P> <P>(i) For each bypass device, except as provided for in paragraph (c)(3)(ii) of this section, the owner or operator shall either:</P> <P>(A) Properly install, calibrate, maintain, and operate a flow indicator at the inlet to the bypass device that could divert the stream away from the control device to the atmosphere that <PRTPAGE P="121"/>takes a reading at least once every 15 minutes, and that sounds an alarm when the bypass device is open such that the stream is being, or could be, diverted away from the control device to the atmosphere; or</P> <P>(B) Secure the bypass device valve installed at the inlet to the bypass device in the non-diverting position using a car-seal or a lock-and-key type configuration. The owner or operator shall visually inspect the seal or closure mechanism at least once every month to verify that the valve is maintained in the non-diverting position and the vent stream is not diverted through the bypass device.</P> <P>(ii) Low leg drains, high point bleeds, analyzer vents, open-ended valves or lines, and safety devices are not subject to the requirements of paragraph (c)(3)(i) of this section.</P> <P>(d) <E T="03">Control device requirements.</E> (1) The control device used to reduce HAP emissions in accordance with the standards of this subpart shall be one of the control devices specified in paragraphs (d)(1)(i) through (iii) of this section.</P> <P>(i) An enclosed combustion device (e.g., thermal vapor incinerator, catalytic vapor incinerator, boiler, or process heater) that is designed and operated in accordance with one of the following performance requirements:</P> <P>(A) Reduces the mass content of either TOC or total HAP in the gases vented to the device by 95.0 percent by weight or greater, as determined in accordance with the requirements of § 63.1282(d);</P> <P>(B) Reduces the concentration of either TOC or total HAP in the exhaust gases at the outlet to the device to a level equal to or less than 20 parts per million by volume on a dry basis corrected to 3 percent oxygen as determined in accordance with the requirements of § 63.1282(d); or</P> <P>(C) Operates at a minimum residence time of 0.5 second at a minimum temperature of 760 °C.</P> <P>(D) If a boiler or process heater is used as the control device, then the vent stream shall be introduced into the flame zone of the boiler or process heater.</P> <P>(ii) A vapor recovery device (e.g., carbon adsorption system or condenser) or other control device that is designed and operated to reduce the mass content of either TOC or total HAP in the gases vented to the device by 95.0 percent by weight or greater as determined in accordance with the requirements of § 63.1282(d).</P> <P>(iii) A flare that is designed and operated in accordance with the requirements of § 63.11(b).</P> <P>(2) [Reserved]</P> <P>(3) The owner or operator shall demonstrate that a control device achieves the performance requirements of paragraph (d)(1) of this section by following the procedures specified in § 63.1282(d).</P> <P>(4) The owner or operator shall operate each control device in accordance with the requirements specified in paragraphs (d)(4)(i) and (ii) of this section.</P> <P>(i) Each control device used to comply with this subpart shall be operating at all times when gases, vapors, and fumes are vented from the emissions unit or units through the closed-vent system to the control device, as required under § 63.1275, except when maintenance or repair of a unit cannot be completed without a shutdown of the control device. An owner or operator may vent more than one unit to a control device used to comply with this subpart.</P> <P>(ii) For each control device monitored in accordance with the requirements of § 63.1283(d), the owner or operator shall demonstrate compliance according to the requirements of § 63.1282(e), or (f) as applicable.</P> <P>(5) For each carbon adsorption system used as a control device to meet the requirements of paragraph (d)(1) of this section, the owner or operator shall manage the carbon as follows:</P> <P>(i) Following the initial startup of the control device, all carbon in the control device shall be replaced with fresh carbon on a regular, predetermined time interval that is no longer than the carbon service life established for the carbon adsorption system.</P> <P>(ii) The spent carbon removed from the carbon adsorption system shall be either regenerated, reactivated, or burned in one of the units specified in paragraphs (d)(5)(ii)(A) through (d)(5)(ii)(G) of this section.<PRTPAGE P="122"/> </P> <P>(A) Regenerated or reactivated in a thermal treatment unit for which the owner or operator has been issued a final permit under 40 CFR part 270 that implements the requirements of 40 CFR part 264, subpart X.</P> <P>(B) Regenerated or reactivated in a thermal treatment unit equipped with and operating organic air emission controls in accordance with this section.</P> <P>(C) Regenerated or reactivated in a thermal treatment unit equipped with and operating organic air emission controls in accordance with a national emissions standard for HAP under another subpart in 40 CFR part 61 or this part.</P> <P>(D) Burned in a hazardous waste incinerator for which the owner or operator has been issued a final permit under 40 CFR part 270 that implements the requirements of 40 CFR part 264, subpart O.</P> <P>(E) Burned in a hazardous waste incinerator which the owner or operator has designed and operates in accordance with the requirements of 40 CFR part 265, subpart O.</P> <P>(F) Burned in a boiler or industrial furnace for which the owner or operator has been issued a final permit under 40 CFR part 270 that implements the requirements of 40 CFR part 266, subpart H.</P> <P>(G) Burned in a boiler or industrial furnace which the owner or operator has designed and operates in accordance with the interim status requirements of 40 CFR part 266, subpart H.</P> <P>(e) <E T="03">Process modification requirements.</E> Each owner or operator that chooses to comply with § 63.1275(c)(2) shall meet the requirements specified in paragraphs (e)(1) through (e)(3) of this section.</P> <P>(1) The owner or operator shall determine glycol dehydration unit baseline operations (as defined in § 63.1271). Records of glycol dehydration unit baseline operations shall be retained as required under § 63.1284(b)(9).</P> <P>(2) The owner or operator shall document, to the Administrator's satisfaction, the conditions for which glycol dehydration unit baseline operations shall be modified to achieve the 95.0 percent overall HAP emission reduction, either through process modifications or through a combination of process modifications and one or more control devices. If a combination of process modifications and one or more control devices are used, the owner or operator shall also establish the percent HAP reduction to be achieved by the control device to achieve an overall HAP emission reduction of 95.0 percent for the glycol dehydration unit process vent. Only modifications in glycol dehydration unit operations directly related to process changes, including, but not limited to, changes in glycol circulation rate or glycol-HAP absorbency, shall be allowed. Changes in the inlet gas characteristics or natural gas throughput rate shall not be considered in determining the overall HAP emission reduction.</P> <P>(3) The owner or operator that achieves a 95.0 percent HAP emission reduction using process modifications alone shall comply with paragraph (e)(3)(i) of this section. The owner or operator that achieves a 95.0 percent HAP emission reduction using a combination of process modifications and one or more control devices shall comply with paragraphs (e)(3)(i) and (e)(3)(ii) of this section.</P> <P>(i) The owner or operator shall maintain records, as required in § 63.1284(b)(10), that the facility continues to operate in accordance with the conditions specified under paragraph (e)(2) of this section.</P> <P>(ii) The owner or operator shall comply with the control device requirements specified in paragraph (d) of this section, except that the emission reduction achieved shall be the emission reduction specified in paragraph (e)(2) of this section.</P> </SECTION> <SECTION> <SECTNO>§ 63.1282</SECTNO> <SUBJECT>Test methods, compliance procedures, and compliance demonstrations.</SUBJECT> <P>(a) <E T="03">Determination of glycol dehydration unit flowrate or benzene emissions.</E> The procedures of this paragraph shall be used by an owner or operator to determine glycol dehydration unit natural gas flowrate or benzene emissions to meet the criteria for the exemption from control requirements under § 63.1274(d).</P> <P>(1) The determination of actual flowrate of natural gas to a glycol dehydration unit shall be made using the <PRTPAGE P="123"/>procedures of either paragraph (a)(1)(i) or (a)(1)(ii) of this section.</P> <P>(i) The owner or operator shall install and operate a monitoring instrument that directly measures natural gas flowrate to the glycol dehydration unit with an accuracy of plus or minus 2 percent or better. The owner or operator shall convert the annual natural gas flowrate to a daily average by dividing the annual flowrate by the number of days per year the glycol dehydration unit processed natural gas.</P> <P>(ii) The owner or operator shall document, to the Administrator's satisfaction, that the actual annual average natural gas flowrate to the glycol dehydration unit is less than 85 thousand standard cubic meters per day.</P> <P>(2) The determination of actual average benzene emissions from a glycol dehydration unit shall be made using the procedures of either paragraph (a)(2)(i) or (a)(2)(ii) of this section. Emissions shall be determined either uncontrolled or with federally enforceable controls in place.</P> <P>(i) The owner or operator shall determine actual average benzene emissions using the model GRI-GLYCalc<E T="51">TM</E>, Version 3.0 or higher, and the procedures presented in the associated GRI-GLYCalc<E T="51">TM</E> Technical Reference Manual. Inputs to the model shall be representative of actual operating conditions of the glycol dehydration unit and may be determined using the procedures documented in the Gas Research Institute (GRI) report entitled “Atmospheric Rich/Lean Method for Determining Glycol Dehydrator Emissions” (GRI-95/0368.1); or</P> <P>(ii) The owner or operator shall determine an average mass rate of benzene emissions in kilograms per hour through direct measurement by performing three runs of Method 18 in 40 CFR part 60, appendix A (or an equivalent method), and averaging the results of the three runs. Annual emissions in kilograms per year shall be determined by multiplying the mass rate by the number of hours the unit is operated per year. This result shall be converted to megagrams per year.</P> <P>(b) <E T="03">No detectable emissions test procedure.</E> (1) The procedure shall be conducted in accordance with Method 21, 40 CFR part 60, appendix A.</P> <P>(2) The detection instrument shall meet the performance criteria of Method 21, 40 CFR part 60, appendix A, except the instrument response factor criteria in section 3.1.2(a) of Method 21 shall be for the average composition of the fluid, and not for each individual organic compound in the stream.</P> <P>(3) The detection instrument shall be calibrated before use on each day of its use by the procedures specified in Method 21, 40 CFR part 60, appendix A.</P> <P>(4) Calibration gases shall be as follows:</P> <P>(i) Zero air (less than 10 parts per million by volume hydrocarbon in air); and</P> <P>(ii) A mixture of methane in air at a methane concentration of less than 10,000 parts per million by volume.</P> <P>(5) An owner or operator may choose to adjust or not adjust the detection instrument readings to account for the background organic concentration level. If an owner or operator chooses to adjust the instrument readings for the background level, the background level value must be determined according to the procedures in Method 21 of 40 CFR part 60, appendix A.</P> <P>(6)(i) Except as provided in paragraph (b)(6)(i) of this section, the detection instrument shall meet the performance criteria of Method 21 of 40 CFR part 60, appendix A, except the instrument response factor criteria in section 3.1.2(a) of Method 21 shall be for the average composition of the process fluid not each individual volatile organic compound in the stream. For process streams that contain nitrogen, air, or other inerts which are not organic hazardous air pollutants or volatile organic compounds, the average stream response factor shall be calculated on an inert-free basis.</P> <P>(ii) If no instrument is available at the facility that will meet the performance criteria specified in paragraph (b)(6)(i) of this section, the instrument readings may be adjusted by multiplying by the average response factor of the process fluid, calculated on an inert-free basis as described in paragraph (b)(6)(i) of this section.</P> <P>(7) An owner or operator must determine if a potential leak interface operates with no detectable emissions using the applicable procedure specified in <PRTPAGE P="124"/>paragraph (b)(7)(i) or (b)(7)(ii) of this section.</P> <P>(i) If an owner or operator chooses not to adjust the detection instrument readings for the background organic concentration level, then the maximum organic concentration value measured by the detection instrument is compared directly to the applicable value for the potential leak interface as specified in paragraph (b)(8) of this section.</P> <P>(ii) If an owner or operator chooses to adjust the detection instrument readings for the background organic concentration level, the value of the arithmetic difference between the maximum organic concentration value measured by the instrument and the background organic concentration value as determined in paragraph (b)(5) of this section is compared with the applicable value for the potential leak interface as specified in paragraph (b)(8) of this section.</P> <P>(8) A potential leak interface is determined to operate with no detectable organic emissions if the organic concentration value determined in paragraph (b)(7) is less than 500 parts per million by volume.</P> <P>(c) [Reserved]</P> <P>(d) <E T="03">Control device performance test procedures.</E> This paragraph applies to the performance testing of control devices. The owners or operators shall demonstrate that a control device achieves the performance requirements of § 63.1281(d)(1) or (e)(3)(ii) using either a performance test as specified in paragraph (d)(3) of this section or a design analysis as specified in paragraph (d)(4) of this section. The owner or operator may elect to use the alternative procedures in paragraph (d)(5) of this section for performance testing of a condenser used to control emissions from a glycol dehydration unit process vent.</P> <P>(1) The following control devices are exempt from the requirements to conduct performance tests and design analyses under this section:</P> <P>(i) A flare that is designed and operated in accordance with § 63.11(b);</P> <P>(ii) A boiler or process heater with a design heat input capacity of 44 megawatts or greater;</P> <P>(iii) A boiler or process heater into which the vent stream is introduced with the primary fuel or is used as the primary fuel;</P> <P>(iv) A boiler or process heater burning hazardous waste for which the owner or operator has either been issued a final permit under 40 CFR part 270 and complies with the requirements of 40 CFR part 266, subpart H, or has certified compliance with the interim status requirements of 40 CFR part 266, subpart H;</P> <P>(v) A hazardous waste incinerator for which the owner or operator has been issued a final permit under 40 CFR part 270 and complies with the requirements of 40 CFR part 264, subpart O, or has certified compliance with the interim status requirements of 40 CFR part 265, subpart O.</P> <P>(vi) A control device for which a performance test was conducted for determining compliance with a regulation promulgated by the EPA, and the test was conducted using the same methods specified in this section, and either no process changes have been made since the test, or the owner or operator can demonstrate that the results of the performance test, with or without adjustments, reliably demonstrate compliance despite process changes.</P> <P>(2) An owner or operator shall design and operate each flare in accordance with the requirements specified in § 63.11(b) and in paragraphs (d)(2)(i) and (d)(2)(ii) of this section.</P> <P>(i) The compliance determination shall be conducted using Method 22 of 40 CFR part 60, appendix A, to determine visible emissions.</P> <P>(ii) An owner or operator is not required to conduct a performance test to determine percent emission reduction or outlet organic HAP or TOC concentration when a flare is used.</P> <P>(3) For a performance test conducted to demonstrate that a control device meets the requirements of § 63.1281(d)(1) or (e)(3)(ii), the owner or operator shall use the test methods and procedures specified in paragraphs (d)(3)(i) through (d)(3)(iv) of this section. The performance test shall be conducted according to the schedule specified in § 63.7(a)(2), and the results of the performance test shall be submitted in the Notification of Compliance Status Report as required in § 63.1285(d)(1)(ii).<PRTPAGE P="125"/> </P> <P>(i) Method 1 or 1A, 40 CFR part 60, appendix A, as appropriate, shall be used for selection of the sampling sites specified in paragraphs (d)(3)(i)(A) and (B) of this section. Any references to particulate mentioned in Methods 1 and 1A do not apply to this section.</P> <P>(A) To determine compliance with the control device percent reduction requirements specified in § 63.1281(d)(1)(i)(A),(d)(1)(ii), or (e)(3)(ii), sampling sites shall be located at the inlet of the first control device and at the outlet of the final control device.</P> <P>(B) To determine compliance with the enclosed combustion device total HAP concentration limit specified in § 63.1281(d)(1)(i)(B), the sampling site shall be located at the outlet of the device.</P> <P>(ii) The gas volumetric flowrate shall be determined using Method 2, 2A, 2C, or 2D, 40 CFR part 60, appendix A, as appropriate.</P> <P>(iii) To determine compliance with the control device percent reduction performance requirement in § 63.1281(d)(1)(i)(A), 63.1281(d)(1)(ii), or 63.1281(e)(3)(ii), the owner or operator shall use either Method 18, 40 CFR part 60, appendix A, or Method 25A, 40 CFR part 60, appendix A; alternatively, any other method or data that have been validated according to the applicable procedures in Method 301 of appendix A of this part may be used. The following procedures shall be used to calculate the percentage of reduction:</P> <P>(A) The minimum sampling time for each run shall be 1 hour in which either an integrated sample or a minimum of four grab samples shall be taken. If grab sampling is used, then the samples shall be taken at approximately equal intervals in time, such as 15-minute intervals during the run.</P> <P>(B) The mass rate of either TOC (minus methane and ethane) or total HAP (E<E T="52">i</E>, E<E T="52">o</E>) shall be computed.</P> <P>(<E T="03">1</E>) The following equations shall be used:</P> <GPH DEEP="35" SPAN="1"> <GID>ER17JN99.008</GID> </GPH> <GPH DEEP="35" SPAN="1"> <GID>ER17JN99.009</GID> </GPH> <FP SOURCE="FP-2">Where:</FP> <EXTRACT> <FP SOURCE="FP-2">C<E T="52">ij</E>, C<E T="52">oj</E> = Concentration of sample component j of the gas stream at the inlet and outlet of the control device, respectively, dry basis, parts per million by volume.</FP> <FP SOURCE="FP-2">E<E T="52">i</E>, E<E T="52">o</E> = Mass rate of TOC (minus methane and ethane) or total HAP at the inlet and outlet of the control device, respectively, dry basis, kilogram per hour.</FP> <FP SOURCE="FP-2">M<E T="52">ij</E>, M<E T="52">oj</E> = Molecular weight of sample component j of the gas stream at the inlet and outlet of the control device, respectively, gram/gram-mole.</FP> <FP SOURCE="FP-2">Q<E T="52">i</E>, Q<E T="52">o</E> = Flowrate of gas stream at the inlet and outlet of the control device, respectively, dry standard cubic meter per minute.</FP> <FP SOURCE="FP-2">K<E T="52">2</E> = Constant, 2.494x10 <E T="51">−6</E> (parts per million) <E T="51">−1</E> (gram-mole per standard cubic meter) (kilogram/gram) (minute/hour), where standard temperature is 20°C.</FP> </EXTRACT> <P>(<E T="03">2</E>) When the TOC mass rate is calculated, all organic compounds (minus methane and ethane) measured by Method 18, of 40 CFR part 60, appendix A; or Method 25A, 40 CFR part 60, appendix A, shall be summed using the equations in paragraph (d)(3)(iii)(B)(<E T="03">1</E>) of this section.</P> <P>(<E T="03">3</E>) When the total HAP mass rate is calculated, only HAP chemicals listed in Table 1 of this subpart shall be summed using the equations in paragraph (d)(3)(iii)(B)(<E T="03">1</E>) of this section.</P> <P>(C) The percentage of reduction in TOC (minus methane and ethane) or total HAP shall be calculated as follows:</P> <GPH DEEP="27" SPAN="1"> <GID>ER17JN99.010</GID> </GPH> <FP SOURCE="FP-2">Where:</FP> <EXTRACT> <FP SOURCE="FP-2">R<E T="52">cd</E> = Control efficiency of control device, percent.</FP> <FP SOURCE="FP-2">E<E T="52">i</E> = Mass rate of TOC (minus methane and ethane) or total HAP at the inlet to the control device as calculated under paragraph (d)(3)(iii)(B) of this section, kilograms TOC per hour or kilograms HAP per hour.</FP> <FP SOURCE="FP-2">E<E T="52">o</E> = Mass rate of TOC (minus methane and ethane) or total HAP at the outlet of the control device, as calculated under paragraph (d)(3)(iii)(B) of this section, kilograms TOC per hour or kilograms HAP per hour.</FP> </EXTRACT> <PRTPAGE P="126"/> <P>(D) If the vent stream entering a boiler or process heater with a design capacity less than 44 megawatts is introduced with the combustion air or as a secondary fuel, the weight-percentage of reduction of total HAP or TOC (minus methane and ethane) across the device shall be determined by comparing the TOC (minus methane and ethane) or total HAP in all combusted vent streams and primary and secondary fuels with the TOC (minus methane and ethane) or total HAP exiting the device, respectively.</P> <P>(iv) To determine compliance with the enclosed combustion device total HAP concentration limit specified in § 63.1281(d)(1)(i)(B), the owner or operator shall use either Method 18, 40 CFR part 60, appendix A; or Method 25A, 40 CFR part 60, appendix A, to measure either TOC (minus methane and ethane) or total HAP. Alternatively, any other method or data that have been validated according to Method 301 of appendix A of this part, may be used. The following procedures shall be used to calculate parts per million by volume concentration, corrected to 3 percent oxygen:</P> <P>(A) The minimum sampling time for each run shall be 1 hour in which either an integrated sample or a minimum of four grab samples shall be taken. If grab sampling is used, then the samples shall be taken at approximately equal intervals in time, such as 15-minute intervals during the run.</P> <P>(B) The TOC concentration or total HAP concentration shall be calculated according to paragraph (d)(3)(iv)(B)(<E T="03">1</E>) or (d)(3)(iv)(B)(<E T="03">2</E>) of this section.</P> <P>(<E T="03">1</E>) The TOC concentration (C<E T="52">TOC</E>) is the sum of the concentrations of the individual components and shall be computed for each run using the following equation:</P> <GPH DEEP="50" SPAN="1"> <GID>ER17JN99.011</GID> </GPH> <FP SOURCE="FP-2">Where:</FP> <EXTRACT> <FP SOURCE="FP-2">C<E T="52">TOC</E> = Concentration of total organic compounds minus methane and ethane, dry basis, parts per million by volume.</FP> <FP SOURCE="FP-2">C<E T="52">ji</E> = Concentration of sample components j of sample i, dry basis, parts per million by volume.</FP> <FP SOURCE="FP-2">n = Number of components in the sample.</FP> <FP SOURCE="FP-2">x = Number of samples in the sample run.</FP> </EXTRACT> <P>(<E T="03">2</E>) The total HAP concentration (C<E T="52">HAP</E>) shall be computed according to the equation in paragraph (d)(3)(iv)(B)(<E T="03">1</E>) of this section, except that only HAP chemicals listed in Table 1 of this subpart shall be summed.</P> <P>(C) The TOC concentration or total HAP concentration shall be corrected to 3 percent oxygen as follows:</P> <P>(<E T="03">1</E>) The emission rate correction factor for excess air, integrated sampling and analysis procedures of Method 3B, 40 CFR part 60, appendix A, shall be used to determine the oxygen concentration (%O<E T="52">2d</E>). The samples shall be taken during the same time that the samples are taken for determining TOC concentration or total HAP concentration.</P> <P>(<E T="03">2</E>) The concentration corrected to 3 percent oxygen (C<E T="52">c</E>) shall be computed using the following equation:</P> <GPH DEEP="31" SPAN="1"> <GID>ER17JN99.012</GID> </GPH> <FP SOURCE="FP-2">Where:</FP> <EXTRACT> <FP SOURCE="FP-2">C<E T="52">c</E> = TOC concentration of total HAP concentration corrected to 3 percent oxygen, dry basis, parts per million by volume.</FP> <FP SOURCE="FP-2">C<E T="52">m</E> = TOC concentration or total HAP concentration, dry basis, parts per million by volume.</FP> <FP SOURCE="FP-2">%O<E T="52">2d</E> = Concentration of oxygen, dry basis, percent by volume.</FP> </EXTRACT> <P>(4) For a design analysis conducted to meet the requirements of § 63.1281(d)(1) or (e)(3)(ii), the owner or operator shall meet the requirements specified in paragraphs (d)(4)(i) and (d)(4)(ii) of this section. Documentation of the design analysis shall be submitted as a part of the Notification of Compliance Status Report as required in § 63.1285(d)(1)(i).</P> <P>(i) The design analysis shall include analysis of the vent stream characteristics and control device operating parameters for the applicable control device as specified in paragraphs (d)(4)(i) (A) through (F) of this section.</P> <P>(A) For a thermal vapor incinerator, the design analysis shall include the vent stream composition, constituent <PRTPAGE P="127"/>concentrations, and flowrate and shall establish the design minimum and average temperatures in the combustion zone and the combustion zone residence time.</P> <P>(B) For a catalytic vapor incinerator, the design analysis shall include the vent stream composition, constituent concentrations, and flowrate and shall establish the design minimum and average temperatures across the catalyst bed inlet and outlet, and the design service life of the catalyst.</P> <P>(C) For a boiler or process heater, the design analysis shall include the vent stream composition, constituent concentrations, and flowrate; shall establish the design minimum and average flame zone temperatures and combustion zone residence time; and shall describe the method and location where the vent stream is introduced into the flame zone.</P> <P>(D) For a condenser, the design analysis shall include the vent stream composition, constituent concentrations, flowrate, relative humidity, and temperature, and shall establish the design outlet organic compound concentration level, design average temperature of the condenser exhaust vent stream, and the design average temperatures of the coolant fluid at the condenser inlet and outlet. As an alternative to the design analysis, an owner or operator may elect to use the procedures specified in paragraph (d)(5) of this section.</P> <P>(E) For a regenerable carbon adsorption, the design analysis shall include the vent stream composition, constituent concentrations, flowrate, relative humidity, and temperature, and shall establish the design exhaust vent stream organic compound concentration level, adsorption cycle time, number and capacity of carbon beds, type and working capacity of activated carbon used for the carbon beds, design total regeneration stream flow over the period of each complete carbon bed regeneration cycle, design carbon bed temperature after regeneration, design carbon bed regeneration time, and design service life of the carbon.</P> <P>(F) For a nonregenerable carbon adsorption system, such as a carbon canister, the design analysis shall include the vent stream composition, constituent concentrations, flowrate, relative humidity, and temperature, and shall establish the design exhaust vent stream organic compound concentration level, capacity of the carbon bed, type and working capacity of activated carbon used for the carbon bed, and design carbon replacement interval based on the total carbon working capacity of the control device and source operating schedule. In addition, these systems will incorporate dual carbon canisters in case of emission breakthrough occurring in one canister.</P> <P>(ii) If the owner or operator and the Administrator do not agree on a demonstration of control device performance using a design analysis, then the disagreement shall be resolved using the results of a performance test performed by the owner or operator in accordance with the requirements of paragraph (d)(3) of this section. The Administrator may choose to have an authorized representative observe the performance test.</P> <P>(5) As an alternative to the procedures in paragraphs (d)(3) and (d)(4)(i)(D) of this section, an owner or operator may elect to use the procedures documented in the GRI report entitled, “Atmospheric Rich/Lean Method for Determining Glycol Dehydrator Emissions,” (GRI-95/0368.1) as inputs for the model GRI-GLYCalc<E T="51">TM</E>, Version 3.0 or higher, to determine condenser performance.</P> <P>(e) <E T="03">Compliance demonstration for control devices performance requirements.</E> This paragraph applies to the demonstration of compliance with the control device performance requirements specified in § 63.1281(d)(1) and (e)(3)(ii). Compliance shall be demonstrated using the requirements in paragraphs (e)(1) through (e)(3) of this section. As an alternative, an owner or operator that installs a condenser as the control device to achieve the requirements specified in § 63.1281(d)(2)(ii) or § 63.1275(c)(2), may demonstrate compliance according to paragraph (f) of this section. An owner or operator may switch between compliance with paragraph (e) of this section and compliance with paragraph (f) of this section only after at least 1 year of operation in compliance with the selected approach. Notification of such a change <PRTPAGE P="128"/>in the compliance method shall be reported in the next Periodic Report, as required in § 63.1285(e), following the change.</P> <P>(1) The owner or operator shall establish a site specific maximum or minimum monitoring parameter value (as appropriate) according to the requirements of § 63.1283(d)(5)(i).</P> <P>(2) The owner or operator shall calculate the daily average of the applicable monitored parameter in accordance with § 63.1283(d)(4).</P> <P>(3) Compliance is achieved when the daily average of the monitoring parameter value calculated under paragraph (e)(2) of this section is either equal to or greater than the minimum or equal to or less than the maximum monitoring value established under paragraph (e)(1) of this section.</P> <P>(f) <E T="03">Compliance demonstration with percent reduction performance requirements—condensers.</E> This paragraph applies to the demonstration of compliance with the performance requirements specified in § 63.1281(d)(1)(ii) for condensers. Compliance shall be demonstrated using the procedures in paragraphs (f)(1) through (f)(3) of this section.</P> <P>(1) The owner or operator shall establish a site-specific condenser performance curve according to the procedures specified in § 63.1283(d)(5)(ii).</P> <P>(2) Compliance with the percent reduction requirement in § 63.1281(d)(1)(ii) or § 63.1275(c)(2) shall be demonstrated by the procedures in paragraphs (f)(2)(i) through (f)(2)(iii) of this section.</P> <P>(i) The owner or operator must calculate the daily average condenser outlet temperature in accordance with § 63.1283(d)(4).</P> <P>(ii) The owner or operator shall determine the condenser efficiency for the current operating day using the daily average condenser outlet temperature calculated in paragraph (f)(2)(i) of this section and the condenser performance curve established in paragraph (f)(1) of this section.</P> <P>(iii) Except as provided in paragraphs (f)(2)(iii) (A), (B), and (D) of this section, at the end of each operating day the owner or operator shall calculate the 30-day average HAP emission reduction from the condenser efficiencies determined in paragraph (f)(2)(ii) of this section for the preceding 30 operating days. If the owner or operator uses a combination of process modifications and a condenser in accordance with the requirements of § 63.1275(c)(2), the 30-day average HAP emission reduction shall be calculated using the emission reduction achieved through process modifications and the condenser efficiency determined in paragraph (f)(2)(ii) of this section, both for the preceding 30 operating days.</P> <P>(A) After the compliance date specified in § 63.1270(f), an owner or operator of a facility that stores natural gas that has less than 30 days of data for determining the average HAP emission reduction, shall calculate the cumulative average at the end of the withdrawal season, each season, until 30 days of condenser operating data are accumulated. For a facility that does not store natural gas, the owner or operator that has less than 30 days of data for determining average HAP emission reduction, shall calculate the cumulative average at the end of the calendar year, each year, until 30 days of condenser operating data are accumulated.</P> <P>(B) After the compliance date specified in § 63.1270(f), an owner or operator that has less than 30 days of data for determining the average HAP emission reduction, compliance is achieved if the average HAP emission reduction calculated in paragraph (f)(2)(iii)(A) of this section, is equal to or greater than 95.0 percent.</P> <P>(C) For the purposes of this subpart, a withdrawal season begins the first time gas is withdrawn from the storage field after July 1 of the calendar year and ends on June 30 of the next calendar year.</P> <P>(D) Glycol dehydration units that are operated continuously have the option of complying with the requirements specified in 40 CFR 63.772(g).</P> <P>(3) Compliance is achieved with the emission limitation specified in § 63.1281(d)(1)(ii) or § 63.1275(c)(2) if the average HAP emission reduction calculated in paragraph (f)(2)(iii) of this section is equal to or greater than 95.0 percent.</P> </SECTION> <SECTION> <PRTPAGE P="129"/> <SECTNO>§ 63.1283</SECTNO> <SUBJECT>Inspection and monitoring requirements.</SUBJECT> <P>(a) This section applies to an owner or operator using air emission controls in accordance with the requirements of § 63.1275.</P> <P>(b) [Reserved]</P> <P>(c) <E T="03">Closed-vent system inspection and monitoring requirements.</E> (1) For each closed-vent system required to comply with this section, the owner or operator shall comply with the requirements of paragraphs (c)(2) through (7) of this section.</P> <P>(2) Except as provided in paragraphs (c) (5) and (6) of this section, each closed-vent system shall be inspected according to the procedures and schedule specified in paragraphs (c)(2) (i) and (ii) of this section.</P> <P>(i) For each closed-vent system joints, seams, or other connections that are permanently or semi-permanently sealed (e.g., a welded joint between two sections of hard piping or a bolted or gasketed ducting flange), the owner or operator shall:</P> <P>(A) Conduct an initial inspection according to the procedures specified in § 63.1282(b) to demonstrate that the closed-vent system operates with no detectable emissions.</P> <P>(B) Conduct annual visual inspections for defects that could result in air emissions. Defects include, but are not limited to, visible cracks, holes, or gaps in piping; loose connections; or broken or missing caps or other closure devices. The owner or operator shall monitor a component or connection using the procedures specified in § 63.1282(b) to demonstrate that it operates with no detectable emissions following any time the component or connection is repaired or replaced or the connection is unsealed.</P> <P>(ii) For closed-vent system components other than those specified in paragraph (c)(2)(i) of this section, the owner or operator shall:</P> <P>(A) Conduct an initial inspection according to the procedures specified in § 63.1282(b) to demonstrate that the closed-vent system operates with no detectable emissions.</P> <P>(B) Conduct annual inspections according to the procedures specified in § 63.1282(b) to demonstrate that the components or connections operate with no detectable emissions.</P> <P>(C) Conduct annual visual inspections for defects that could result in air emissions. Defects include, but are not limited to, visible cracks, holes, or gaps in ductwork; loose connections; or broken or missing caps or other closure devices.</P> <P>(3) In the event that a leak or defect is detected, the owner or operator shall repair the leak or defect as soon as practicable, except as provided in paragraph (c)(4) of this section.</P> <P>(i) A first attempt at repair shall be made no later than 5 calendar days after the leak is detected.</P> <P>(ii) Repair shall be completed no later than 15 calendar days after the leak is detected.</P> <P>(4) Delay of repair of a closed-vent system for which leaks or defects have been detected is allowed if the repair is technically infeasible without a shutdown, as defined in § 63.1271, or if the owner or operator determines that emissions resulting from immediate repair would be greater than the fugitive emissions likely to result from delay of repair. Repair of such equipment shall be completed by the end of the next shutdown.</P> <P>(5) Any parts of the closed-vent system or cover that are designated, as described in paragraphs (c)(5) (i) and (ii) of this section, as unsafe to inspect are exempt from the inspection requirements of paragraphs (c)(2) (i) and (ii) of this section if:</P> <P>(i) The owner or operator determines that the equipment is unsafe to inspect because inspecting personnel would be exposed to an imminent or potential danger as a consequence of complying with paragraph (c)(2) (i) or (ii) of this section; and</P> <P>(ii) The owner or operator has a written plan that requires inspection of the equipment as frequently as practicable during safe-to-inspect times.</P> <P>(6) Any parts of the closed-vent system or cover that are designated, as described in paragraphs (c)(6) (i) and (ii) of this section, as difficult to inspect are exempt from the inspection requirements of paragraphs (c)(2) (i) and (ii) of this section if:<PRTPAGE P="130"/> </P> <P>(i) The owner or operator determines that the equipment cannot be inspected without elevating the inspecting personnel more than 2 meters above a support surface; and</P> <P>(ii) The owner or operator has a written plan that requires inspection of the equipment at least once every 5 years.</P> <P>(7) Records shall be maintained as specified in § 63.1284(b)(5) through (8).</P> <P>(d) <E T="03">Control device monitoring requirements.</E> (1) For each control device except as provided for in paragraph (d)(2) of this section, the owner or operator shall install and operate a continuous parameter monitoring system in accordance with the requirements of paragraphs (d)(3) through (9) of this section that will allow a determination to be made whether the control device is achieving the applicable performance requirements of § 63.1281(d) or (e)(3). The continuous parameter monitoring system must meet the following specifications and requirements:</P> <P>(i) Each continuous parameter monitoring system shall measure data values at least once every hour and record either:</P> <P>(A) Each measured data value; or</P> <P>(B) Each block average value for each 1-hour period or shorter periods calculated from all measured data values during each period. If values are measured more frequently than once per minute, a single value for each minute may be used to calculate the hourly (or shorter period) block average instead of all measured values.</P> <P>(ii) The monitoring system must be installed, calibrated, operated, and maintained in accordance with the manufacturer's specifications or other written procedures that provide reasonable assurance that the monitoring equipment is operating properly.</P> <P>(2) An owner or operator is exempted from the monitoring requirements specified in paragraphs (d)(3) through (9) of this section for the following types of control devices:</P> <P>(i) A boiler or process heater in which all vent streams are introduced with the primary fuel or are used as the primary fuel;</P> <P>(ii) A boiler or process heater with a design heat input capacity equal to or greater than 44 megawatts.</P> <P>(3) The owner or operator shall install, calibrate, operate, and maintain a device equipped with a continuous recorder to measure the values of operating parameters appropriate for the control device as specified in either paragraph (d)(3)(i), (d)(3)(ii), or (d)(3)(iii) of this section.</P> <P>(i) A continuous monitoring system that measures the following operating parameters as applicable:</P> <P>(A) For a thermal vapor incinerator, a temperature monitoring device equipped with a continuous recorder. The monitoring device shall have a minimum accuracy of <E T="61">±</E>2 percent of the temperature being monitored in °C, or <E T="61">±</E>2.5 °C, whichever value is greater. The temperature sensor shall be installed at a location in the combustion chamber downstream of the combustion zone.</P> <P>(B) For a catalytic vapor incinerator, a temperature monitoring device equipped with a continuous recorder. The device shall be capable of monitoring temperatures at two locations and have a minimum accuracy of <E T="61">±</E>2 percent of the temperatures being monitored in °C, or <E T="61">±</E>2.5 °C, whichever value is greater. One temperature sensor shall be installed in the vent stream at the nearest feasible point to the catalyst bed inlet and a second temperature sensor shall be installed in the vent stream at the nearest feasible point to the catalyst bed outlet.</P> <P>(C) For a flare, a heat sensing monitoring device equipped with a continuous recorder that indicates the continuous ignition of the pilot flame.</P> <P>(D) For a boiler or process heater with a design heat input capacity of less than 44 megawatts, a temperature monitoring device equipped with a continuous recorder. The temperature monitoring device shall have a minimum accuracy of <E T="61">±</E>2 percent of the temperature being monitored in °C, or <E T="61">±</E>2.5 °C, whichever value is greater. The temperature sensor shall be installed at a location in the combustion chamber downstream of the combustion zone.</P> <P>(E) For a condenser, a temperature monitoring device equipped with a continuous recorder. The temperature monitoring device shall have a minimum accuracy of <E T="61">±</E>2 percent of the <PRTPAGE P="131"/>temperature being monitored in °C, or <E T="61">±</E>2.5 °C, whichever value is greater. The temperature sensor shall be installed at a location in the exhaust vent stream from the condenser.</P> <P>(F) For a regenerative-type carbon adsorption system:</P> <P>(<E T="03">1</E>) A continuous parameter monitoring system to measure and record the average total regeneration stream mass flow or volumetric flow during each carbon bed regeneration cycle. The integrating regenerating stream flow monitoring device must have an accuracy of <E T="61">±</E>10 percent; and</P> <P>(<E T="03">2</E>) A continuous parameter monitoring system to measure and record the average carbon bed temperature for the duration of the carbon bed steaming cycle and to measure the actual carbon bed temperature after regeneration and within 15 minutes of completing the cooling cycle. The temperature monitoring device shall have a minimum accuracy of <E T="61">±</E>2 percent of the temperature being monitored in °C, or <E T="61">±</E>2.5 °C, whichever value is greater.</P> <P>(G) For a nonregenerative-type carbon adsorption system, the owner or operator shall monitor the design carbon replacement interval established using a performance test performed in accordance with § 63.1282(d)(3) or a design analysis in accordance with § 63.1282(d)(4)(i)(F) and shall be based on the total carbon working capacity of the control device and source operating schedule.</P> <P>(ii) A continuous monitoring system that measures the concentration level of organic compounds in the exhaust vent stream from the control device using an organic monitoring device equipped with a continuous recorder. The monitor must meet the requirements of Performance Specification 8 or 9 of appendix B of 40 CFR part 60 and must be installed, calibrated, and maintained according to the manufacturer's specifications.</P> <P>(iii) A continuous monitoring system that measures alternative operating parameters other than those specified in paragraph (d)(3)(i) or (d)(3)(ii) of this section upon approval of the Administrator as specified in § 63.8(f)(1) through (5).</P> <P>(4) Using the data recorded by the monitoring system, the owner or operator must calculate the daily average value for each monitored operating parameter for each operating day. If HAP emissions unit operation is continuous, the operating day is a 24-hour period. If the HAP emissions unit operation is not continuous, the operating day is the total number of hours of control device operation per 24-hour period. Valid data points must be available for 75 percent of the operating hours in an operating day to compute the daily average.</P> <P>(5) For each operating parameter monitored in accordance with the requirements of paragraph (d)(3) of this section, the owner or operator shall comply with paragraph (d)(5)(i) of this section for all control devices, and when condensers are installed, the owner or operator shall also comply with paragraph (d)(5)(ii) of this section for condensers.</P> <P>(i) The owner or operator shall establish a minimum operating parameter value or a maximum operating parameter value, as appropriate for the control device, to define the conditions at which the control device must be operated to continuously achieve the applicable performance requirements of § 63.1281(d)(1) or (e)(3)(ii). Each minimum or maximum operating parameter value shall be established as follows:</P> <P>(A) If the owner or operator conducts performance tests in accordance with the requirements of § 63.1282(d)(3) to demonstrate that the control device achieves the applicable performance requirements specified in § 63.1281(d)(1) or (e)(3)(ii), then the minimum operating parameter value or the maximum operating parameter value shall be established based on values measured during the performance test and supplemented, as necessary, by control device design analysis or control device manufacturer's recommendations or a combination of both.</P> <P>(B) If the owner or operator uses a control device design analysis in accordance with the requirements of § 63.1282(d)(4) to demonstrate that the control device achieves the applicable performance requirements specified in § 63.1281(d)(1) or (e)(3)(ii), then the minimum operating parameter value or the maximum operating parameter value <PRTPAGE P="132"/>shall be established based on the control device design analysis and may be supplemented by the control device manufacturer's recommendations.</P> <P>(ii) The owner or operator shall establish a condenser performance curve showing the relationship between condenser outlet temperature and condenser control efficiency. The curve shall be established as follows:</P> <P>(A) If the owner or operator conducts a performance test in accordance with the requirements of § 63.1282(d)(3) to demonstrate that the condenser achieves the applicable performance requirements in § 63.1281(d)(1) or (e)(3)(ii), then the condenser performance curve shall be based on values measured during the performance test and supplemented as necessary by control device design analysis, or control device manufacturer's recommendations, or a combination or both.</P> <P>(B) If the owner or operator uses a control device design analysis in accordance with the requirements of § 63.1282(d)(4)(i)(D) to demonstrate that the condenser achieves the applicable performance requirements specified in § 63.1281(d)(1) or (e)(3)(ii), then the condenser performance curve shall be based on the condenser design analysis and may be supplemented by the control device manufacturer's recommendations.</P> <P>(C) As an alternative to paragraphs (d)(5)(ii)(A) and (B) of this section, the owner or operator may elect to use the procedures documented in the GRI report entitled, “Atmospheric Rich/Lean Method for Determining Glycol Dehydrator Emissions” (GRI-95/0368.1) as inputs for the model GRI-GLYCalc<E T="51">TM</E>, Version 3.0 or higher, to generate a condenser performance curve.</P> <P>(6) An excursion for a given control device is determined to have occurred when the monitoring data or lack of monitoring data result in any one of the criteria specified in paragraphs (d)(6)(i) through (d)(6)(iv) of this section being met. When multiple operating parameters are monitored for the same control device and during the same operating day, and more than one of these operating parameters meets an excursion criterion specified in paragraphs (d)(6)(i) through (d)(6)(iv) of this section, then a single excursion is determined to have occurred for the control device for that operating day.</P> <P>(i) An excursion occurs when the daily average value of a monitored operating parameter is less than the minimum operating parameter limit (or, if applicable, greater than the maximum operating parameter limit) established for the operating parameter in accordance with the requirements of paragraph (d)(5)(i) of this section.</P> <P>(ii) An excursion occurs when average condenser efficiency calculated according to the requirements specified in § 63.1282(f)(2)(iii) is less than 95.0 percent, as specified in § 63.1282(f)(3).</P> <P>(iii) An excursion occurs when the monitoring data are not available for at least 75 percent of the operating hours.</P> <P>(iv) If the closed-vent system contains one or more bypass devices that could be used to divert all or a portion of the gases, vapors, or fumes from entering the control device, an excursion occurs when:</P> <P>(A) For each bypass line subject to § 63.1281(c)(3)(i)(A) the flow indicator indicates that flow has been detected and that the stream has been diverted away from the control device to the atmosphere.</P> <P>(B) For each bypass line subject to § 63.1281(c)(3)(i)(B), if the seal or closure mechanism has been broken, the bypass line valve position has changed, the key for the lock-and-key type lock has been checked out, or the car-seal has broken.</P> <P>(7) For each excursion, except as provided for in paragraph (d)(8) of this section, the owner or operator shall be deemed to have failed to have applied control in a manner that achieves the required operating parameter limits. Failure to achieve the required operating parameter limits is a violation of this standard.</P> <P>(8) An excursion is not a violation of the operating parameter limit as specified in paragraphs (d)(8)(i) and (d)(8)(ii) of this section.</P> <P>(i) An excursion does not count toward the number of excused excursions allowed under paragraph (d)(8)(ii) of this section when the excursion occurs during any one of the following periods:<PRTPAGE P="133"/> </P> <P>(A) During a period of startup, shutdown, or malfunction when the affected facility is operated during such period in accordance with the facility's startup, shutdown, and malfunction plan; or</P> <P>(B) During periods of non-operation of the unit or the process that is vented to the control device (resulting in cessation of HAP emissions to which the monitoring applies).</P> <P>(ii) For each control device, or combinations of control devices, installed on the same HAP emissions unit, one excused excursion is allowed per semiannual period for any reason. The initial semiannual period is the 6-month reporting period addressed by the first Periodic Report submitted by the owner or operator in accordance with § 63.1285(e) of this subpart.</P> <P>(9) Nothing in paragraphs (d)(1) through (d)(8) of this section shall be construed to allow or excuse a monitoring parameter excursion caused by any activity that violates other applicable provisions of this subpart.</P> </SECTION> <SECTION> <SECTNO>§ 63.1284</SECTNO> <SUBJECT>Recordkeeping requirements.</SUBJECT> <P>(a) The recordkeeping provisions of subpart A of this part, that apply and those that do not apply to owners and operators of facilities subject to this subpart are listed in Table 2 of this subpart.</P> <P>(b) Except as specified in paragraphs (c) and (d) of this section, each owner or operator of a facility subject to this subpart shall maintain the records specified in paragraphs (b)(1) through (b)(10) of this section:</P> <P>(1) The owner or operator of an affected source subject to the provisions of this subpart shall maintain files of all information (including all reports and notifications) required by this subpart. The files shall be retained for at least 5 years following the date of each occurrence, measurement, maintenance, corrective action, report or period.</P> <P>(i) All applicable records shall be maintained in such a manner that they can be readily accessed.</P> <P>(ii) The most recent 12 months of records shall be retained on site or shall be accessible from a central location by computer or other means that provides access within 2 hours after a request.</P> <P>(iii) The remaining 4 years of records may be retained offsite.</P> <P>(iv) Records may be maintained in hard copy or computer-readable form including, but not limited to, on paper, microfilm, computer, floppy disk, magnetic tape, or microfiche.</P> <P>(2) Records specified in § 63.10(b)(2);</P> <P>(3) Records specified in § 63.10(c) for each monitoring system operated by the owner or operator in accordance with the requirements of § 63.1283(d). Notwithstanding the previous sentence, monitoring data recorded during periods identified in paragraphs (b)(2)(i) through (b)(2)(iv) of this section shall not be included in any average or percent leak rate computed under this subpart. Records shall be kept of the times and durations of all such periods and any other periods during process or control device operation when monitors are not operating.</P> <P>(i) Monitoring system breakdowns, repairs, calibration checks, and zero (low-level) and high-level adjustments;</P> <P>(ii) Startup, shutdown, and malfunction events. During startup, shutdown and malfunction events, the owner or operator shall maintain records indicating whether or not the startup, shutdown, or malfunction plan, required under § 63.1272(d), was followed.</P> <P>(iii) Periods of non-operation resulting in cessation of the emissions to which the monitoring applies; and</P> <P>(iv) Excursions due to invalid data as defined in § 63.1283(d)(6)(iii).</P> <P>(4) Each owner or operator using a control device to comply with § 63.1274 shall keep the following records up-to-date and readily accessible:</P> <P>(i) Continuous records of the equipment operating parameters specified to be monitored under § 63.1283(d) or specified by the Administrator in accordance with § 63.1283(d)(3)(iii). For flares, the hourly records and records of pilot flame outages specified in § 63.1283(d)(3)(i)(C) shall be maintained in place of continuous records.</P> <P>(ii) Records of the daily average value of each continuously monitored parameter for each operating day determined according to the procedures specified in § 63.1283(d)(4) of this subpart. For flares, records of the times and duration of all periods during <PRTPAGE P="134"/>which all pilot flames are absent shall be kept rather than daily averages.</P> <P>(iii) Hourly records of whether the flow indicator specified under § 63.1281(c)(3)(i)(A) was operating and whether flow was detected at any time during the hour, as well as records of the times and durations of all periods when the vent stream is diverted from the control device or the monitor is not operating.</P> <P>(iv) Where a seal or closure mechanism is used to comply with § 63.1281(c)(3)(i)(B), hourly records of flow are not required. In such cases, the owner or operator shall record that the monthly visual inspection of the seals or closure mechanism has been done, and shall record the duration of all periods when the seal mechanism is broken, the bypass line valve position has changed, or the key for a lock-and-key type lock has been checked out, and records of any car-seal that has broken.</P> <P>(5) Records identifying all parts of the closed-vent system that are designated as unsafe to inspect in accordance with § 63.1283(c)(5), an explanation of why the equipment is unsafe to inspect, and the plan for inspecting the equipment.</P> <P>(6) Records identifying all parts of the closed-vent system that are designated as difficult to inspect in accordance with § 63.1283(c)(6), an explanation of why the equipment is difficult to inspect, and the plan for inspecting the equipment.</P> <P>(7) For each inspection conducted in accordance with § 63.1283(c), during which a leak or defect is detected, a record of the information specified in paragraphs (b)(7)(i) through (b)(7)(viii) of this section.</P> <P>(i) The instrument identification numbers, operator name or initials, and identification of the equipment.</P> <P>(ii) The date the leak or defect was detected and the date of the first attempt to repair the leak or defect.</P> <P>(iii) Maximum instrument reading measured by the method specified in § 63.1283(c)(3) after the leak or defect is successfully repaired or determined to be nonrepairable.</P> <P>(iv) “Repair delayed” and the reason for the delay if a leak or defect is not repaired within 15 calendar days after discovery of the leak or defect.</P> <P>(v) The name, initials, or other form of identification of the owner or operator (or designee) whose decision it was that repair could not be effected without a shutdown.</P> <P>(vi) The expected date of successful repair of the leak or defect if a leak or defect is not repaired within 15 calendar days.</P> <P>(vii) Dates of shutdowns that occur while the equipment is unrepaired.</P> <P>(viii) The date of successful repair of the leak or defect.</P> <P>(8) For each inspection conducted in accordance with § 63.1283(c) during which no leaks or defects are detected, a record that the inspection was performed, the date of the inspection, and a statement that no leaks or defects were detected.</P> <P>(9) Records of glycol dehydration unit baseline operations calculated as required under § 63.1281(e)(1).</P> <P>(10) Records required in § 63.1281(e)(3)(i) documenting that the facility continues to operate under the conditions specified in § 63.1281(e)(2).</P> <P>(c) An owner or operator that elects to comply with the benzene emission limit specified in § 63.1275(b)(1)(ii) shall document, to the Administrator's satisfaction, the following items:</P> <P>(1) The method used for achieving compliance and the basis for using this compliance method; and</P> <P>(2) The method used for demonstrating compliance with 0.90 megagrams per year of benzene.</P> <P>(3) Any information necessary to demonstrate compliance as required in the methods specified in paragraphs (c)(1) and (c)(2) of this section.</P> <P>(d) An owner or operator that is exempt from control requirements under § 63.1274(d) shall maintain the records specified in paragraph (d)(1) or (d)(2) of this section, as appropriate, for each glycol dehydration unit that is not controlled according to the requirements of § 63.1274(c).</P> <P>(1) The actual annual average natural gas throughput (in terms of natural gas flowrate to the glycol dehydration unit per day), as determined in accordance with § 63.1282(a)(1); or</P> <P>(2) The actual average benzene emissions (in terms of benzene emissions <PRTPAGE P="135"/>per year), as determined in accordance with § 63.1282(a)(2).</P> <P>(e) Record the following when using a flare to comply with § 63.1281(d):</P> <P>(1) Flare design (i.e., steam-assisted, air-assisted, or non-assisted);</P> <P>(2) All visible emission readings, heat content determinations, flowrate measurements, and exit velocity determinations made during the compliance determination required by § 63.1282(d)(2); and</P> <P>(3) All periods during the compliance determination when the pilot flame is absent.</P> </SECTION> <SECTION> <SECTNO>§ 63.1285</SECTNO> <SUBJECT>Reporting requirements.</SUBJECT> <P>(a) The reporting provisions of subpart A, of this part that apply and those that do not apply to owners and operators of facilities subject to this subpart are listed in Table 2 of this subpart.</P> <P>(b) Each owner or operator of a facility subject to this subpart shall submit the information listed in paragraphs (b)(1) through (b)(6) of this section, except as provided in paragraph (b)(7) of this section.</P> <P>(1) The initial notifications required for existing affected sources under § 63.9(b)(2) shall be submitted by 1 year after an affected source becomes subject to the provisions of this subpart or by June 17, 2000, whichever is later. Affected sources that are major sources on or before June 17, 2000 and plan to be area sources by June 17, 2002 shall include in this notification a brief, nonbinding description of a schedule for the action(s) that are planned to achieve area source status.</P> <P>(2) The date of the performance evaluation as specified in § 63.8(e)(2), required only if the owner or operator is requested by the Administrator to conduct a performance evaluation for a continuous monitoring system. A separate notification of the performance evaluation is not required if it is included in the initial notification submitted in accordance with paragraph (b)(1) of this section.</P> <P>(3) The planned date of a performance test at least 60 days before the test in accordance with § 63.7(b). Unless requested by the Administrator, a site-specific test plan is not required by this subpart. If requested by the Administrator, the owner or operator must also submit the site-specific test plan required by § 63.7(c) with the notification of the performance test. A separate notification of the performance test is not required if it is included in the initial notification submitted in accordance with paragraph (b)(1) of this section.</P> <P>(4) A Notification of Compliance Status Report as described in paragraph (d) of this section;</P> <P>(5) Periodic Reports as described in paragraph (e) of this section; and</P> <P>(6) Startup, shutdown, and malfunction reports, as specified in § 63.10(d)(5), shall be submitted as required. Separate startup, shutdown, or malfunction reports as described in § 63.10(d)(5)(i) are not required if the information is included in the Periodic Report specified in paragraph (e) of this section.</P> <P>(7) Each owner or operator of a glycol dehydration unit subject to this subpart that is exempt from the control requirements for glycol dehydration unit process vents in § 63.1275, is exempt from all reporting requirements for major sources in this subpart for that unit.</P> <P>(c) [Reserved]</P> <P>(d) Each owner or operator of a source subject to this subpart shall submit a Notification of Compliance Status Report as required under § 63.9(h) within 180 days after the compliance date specified in § 63.1270(d). In addition to the information required under § 63.9(h), the Notification of Compliance Status Report shall include the information specified in paragraphs (d)(1) through (d)(10) of this section. This information may be submitted in an operating permit application, in an amendment to an operating permit application, in a separate submittal, or in any combination of the three. If all of the information required under this paragraph have been submitted at any time prior to 180 days after the applicable compliance dates specified in § 63.1270(d), a separate Notification of Compliance Status Report is not required. If an owner or operator submits the information specified in paragraphs (d)(1) through (d)(9) of this section at different times, and/or different submittals, later submittals may refer to <PRTPAGE P="136"/>earlier submittals instead of duplicating and resubmitting the previously submitted information.</P> <P>(1) If a closed-vent system and a control device other than a flare are used to comply with § 63.1274, the owner or operator shall submit:</P> <P>(i) The design analysis documentation specified in § 63.1282(d)(4) of this subpart if the owner or operator elects to prepare a design analysis; or</P> <P>(ii) If the owner or operator elects to conduct a performance test, the performance test results including the information specified in paragraphs (d)(1)(ii)(A) and (B) of this section. Results of a performance test conducted prior to the compliance date of this subpart can be used provided that the test was conducted using the methods specified in § 63.1282(d)(3), and that the test conditions are representative of current operating conditions.</P> <P>(A) The percent reduction of HAP or TOC, or the outlet concentration of HAP or TOC (parts per million by volume on a dry basis), determined as specified in § 63.1282(d)(3) of this subpart; and</P> <P>(B) The value of the monitored parameters specified in § 63.1283(d) of this subpart, or a site-specific parameter approved by the permitting agency, averaged over the full period of the performance test.</P> <P>(2) If a closed-vent system and a flare are used to comply with § 63.1274, the owner or operator shall submit performance test results including the information in paragraphs (d)(2)(i) and (ii) of this section.</P> <P>(i) All visible emission readings, heat content determinations, flowrate measurements, and exit velocity determinations made during the compliance determination required by § 63.1282(d)(2) of this subpart, and</P> <P>(ii) A statement of whether a flame was present at the pilot light over the full period of the compliance determination.</P> <P>(3) The owner or operator shall submit one complete test report for each test method used for a particular source.</P> <P>(i) For additional tests performed using the same test method, the results specified in paragraph (d)(1)(ii) of this section shall be submitted, but a complete test report is not required.</P> <P>(ii) A complete test report shall include a sampling site description, description of sampling and analysis procedures and any modifications to standard procedures, quality assurance procedures, record of operating conditions during the test, record of preparation of standards, record of calibrations, raw data sheets for field sampling, raw data sheets for field and laboratory analyses, documentation of calculations, and any other information required by the test method.</P> <P>(4) For each control device other than a flare used to meet the requirements of § 63.1274, the owner or operator shall submit the information specified in paragraphs (d)(4)(i) through (iii) of this section for each operating parameter required to be monitored in accordance with the requirements of § 63.1283(d).</P> <P>(i) The minimum operating parameter value or maximum operating parameter value, as appropriate for the control device, established by the owner or operator to define the conditions at which the control device must be operated to continuously achieve the applicable performance requirements of § 63.1281(d)(1) or (e)(3)(ii).</P> <P>(ii) An explanation of the rationale for why the owner or operator selected each of the operating parameter values established in § 63.1283(d)(5) of this subpart. This explanation shall include any data and calculations used to develop the value, and a description of why the chosen value indicates that the control device is operating in accordance with the applicable requirements of § 63.1281(d)(1) or (e)(3)(ii).</P> <P>(iii) A definition of the source's operating day for purposes of determining daily average values of monitored parameters. The definition shall specify the times at which an operating day begins and ends.</P> <P>(5) Results of any continuous monitoring system performance evaluations shall be included in the Notification of Compliance Status Report.</P> <P>(6) After a title V permit has been issued to the owner or operator of an affected source, the owner or operator <PRTPAGE P="137"/>of such source shall comply with all requirements for compliance status reports contained in the source's title V permit, including reports required under this subpart. After a title V permit has been issued to the owner or operator of an affected source, and each time a notification of compliance status is required under this subpart, the owner or operator of such source shall submit the notification of compliance status to the appropriate permitting authority following completion of the relevant compliance demonstration activity specified in this subpart.</P> <P>(7) The owner or operator that elects to comply with the requirements of § 63.1275(b)(1)(ii) shall submit the records required under § 63.1284(c).</P> <P>(8) The owner or operator shall submit an analysis demonstrating whether an affected source is a major source using the maximum throughput calculated according to § 63.1270(a).</P> <P>(9) The owner or operator shall submit a statement as to whether the source has complied with the requirements of this subpart.</P> <P>(10) The owner or operator shall submit the analysis prepared under § 63.1281(e)(2) to demonstrate that the conditions by which the facility will be operated to achieve an overall HAP emission reduction of 95.0 percent through process modifications or a combination of process modifications and one or more control devices.</P> <P>(e) <E T="03">Periodic Reports.</E> An owner or operator shall prepare Periodic Reports in accordance with paragraphs (e)(1) and (2) of this section and submit them to the Administrator.</P> <P>(1) An owner or operator shall submit Periodic Reports semiannually, beginning 60 operating days after the end of the applicable reporting period. The first report shall be submitted no later than 240 days after the date the Notification of Compliance Status Report is due and shall cover the 6-month period beginning on the date the Notification of Compliance Status Report is due.</P> <P>(2) The owner or operator shall include the information specified in paragraphs (e)(2)(i) through (viii) of this section, as applicable.</P> <P>(i) The information required under § 63.10(e)(3). For the purposes of this subpart and the information required under § 63.10(e)(3), excursions (as defined in § 63.1283(d)(6)) shall be considered excess emissions.</P> <P>(ii) A description of all excursions as defined in § 63.1283(d)(6) of this subpart that have occurred during the 6-month reporting period.</P> <P>(A) For each excursion caused when the daily average value of a monitored operating parameter is less than the minimum operating parameter limit (or, if applicable, greater than the maximum operating parameter limit), as specified in § 63.1283(d)(6)(i), the report must include the daily average values of the monitored parameter, the applicable operating parameter limit, and the date and duration of the period that the excursion occurred.</P> <P>(B) For each excursion caused when the 30-day average condenser control efficiency is less than 95.0 percent, as specified in § 63.1283(d)(6)(ii), the report must include the 30-day average values of the condenser control efficiency, and the date and duration of the period that the excursion occurred.</P> <P>(C) For each excursion caused by lack of monitoring data, as specified in § 63.1283(d)(6)(iii), the report must include the date and duration of period when the monitoring data were not collected and the reason why the data were not collected.</P> <P>(iii) For each inspection conducted in accordance with § 63.1283(c) during which a leak or defect is detected, the records specified in § 63.1284(b)(7) must be included in the next Periodic Report.</P> <P>(iv) For each closed-vent system with a bypass line subject to § 63.1281(c)(3)(i)(A), records required under § 63.1284(b)(4)(iii) of all periods when the vent stream is diverted from the control device through a bypass line. For each closed-vent system with a bypass line subject to § 63.1281(c)(3)(i)(B), records required under § 63.1284(b)(4)(iv) of all periods in which the seal or closure mechanism is broken, the bypass valve position has changed, or the key to unlock the bypass line valve was checked out.</P> <P>(v) If an owner or operator elects to comply with § 63.1275(b)(1)(ii), the records required under § 63.1284(c)(3).</P> <P>(vi) The information in paragraphs (e)(2)(vi)(A) and (B) of this section shall <PRTPAGE P="138"/>be stated in the Periodic Report, when applicable.</P> <P>(A) No excursions.</P> <P>(B) No continuous monitoring system has been inoperative, out of control, repaired, or adjusted.</P> <P>(vii) Any change in compliance methods as specified in § 63.1275(b).</P> <P>(viii) If the owner or operator elects to comply with § 63.1275(c)(2), the records required under § 63.1284(b)(10).</P> <P>(f) <E T="03">Notification of process change.</E> Whenever a process change is made, or a change in any of the information submitted in the Notification of Compliance Status Report, the owner or operator shall submit a report within 180 days after the process change is made or as a part of the next Periodic Report as required under paragraph (e) of this section, whichever is sooner. The report shall include:</P> <P>(1) A brief description of the process change;</P> <P>(2) A description of any modification to standard procedures or quality assurance procedures;</P> <P>(3) Revisions to any of the information reported in the original Notification of Compliance Status Report under paragraph (d) of this section; and</P> <P>(4) Information required by the Notification of Compliance Status Report under paragraph (d) of this section for changes involving the addition of processes or equipment.</P> </SECTION> <SECTION> <SECTNO>§ 63.1286</SECTNO> <SUBJECT>Delegation of authority.</SUBJECT> <P>(a) In delegating implementation and enforcement authority to a State under section 112(l) of the Act, the authorities contained in paragraph (b) of this section shall be retained by the Administrator and not transferred to a State.</P> <P>(b) Authorities will not be delegated to States for §§ 63.1282 and 63.1287 of this subpart.</P> </SECTION> <SECTION> <SECTNO>§ 63.1287</SECTNO> <SUBJECT>Alternative means of emission limitation.</SUBJECT> <P>(a) If, in the judgment of the Administrator, an alternative means of emission limitation will achieve a reduction in HAP emissions at least equivalent to the reduction in HAP emissions from that source achieved under the applicable requirements in §§ 63.1274 through 63.1281, the Administrator will publish a notice in the <E T="04">Federal Register</E> permitting the use of the alternative means for purposes of compliance with that requirement. The notice may condition the permission on requirements related to the operation and maintenance of the alternative means.</P> <P>(b) Any notice under paragraph (a) of this section shall be published only after public notice and an opportunity for a hearing.</P> <P>(c) Any person seeking permission to use an alternative means of compliance under this section shall collect, verify, and submit to the Administrator information showing that this means achieves equivalent emission reductions.</P> </SECTION> <SECTION> <SECTNO>§§ 63.1288-63.1289</SECTNO> <RESERVED>[Reserved]</RESERVED> <EAR>Pt. 63, Subpt. HHH,</EAR> </SECTION> <APPENDIX> <HD SOURCE="HED">Appendix to Subpart HHH—Tables</HD> <GPOTABLE CDEF="s25,r100" COLS="2" OPTS="L2,i1"> <TTITLE> <E T="04">Table 1.—List of Hazardous Air Pollutants (HAP) for Subpart HHH</E> </TTITLE> <BOXHD> <CHED H="1">CAS Number <E T="51">a</E> </CHED> <CHED H="1">Chemical name</CHED> </BOXHD> <ROW> <ENT I="01">75070 </ENT> <ENT>Acetaldehyde</ENT> </ROW> <ROW> <ENT I="01">71432 </ENT> <ENT>Benzene (includes benzene in gasoline)</ENT> </ROW> <ROW> <ENT I="01">75150 </ENT> <ENT>Carbon disulfide</ENT> </ROW> <ROW> <ENT I="01">463581 </ENT> <ENT>Carbonyl sulfide</ENT> </ROW> <ROW> <ENT I="01">100414 </ENT> <ENT>Ethyl benzene</ENT> </ROW> <ROW> <ENT I="01">107211 </ENT> <ENT>Ethylene glycol</ENT> </ROW> <ROW> <ENT I="01">75050 </ENT> <ENT>Acetaldehyde</ENT> </ROW> <ROW> <ENT I="01">50000 </ENT> <ENT>Formaldehyde</ENT> </ROW> <ROW> <ENT I="01">110543 </ENT> <ENT>n-Hexane</ENT> </ROW> <ROW> <ENT I="01">91203 </ENT> <ENT>Naphthalene</ENT> </ROW> <ROW> <ENT I="01">108883 </ENT> <ENT>Toluene</ENT> </ROW> <ROW> <ENT I="01">540841 </ENT> <ENT>2,2,4-Trimethylpentane</ENT> </ROW> <ROW> <ENT I="01">1330207 </ENT> <ENT>Xylenes (isomers and mixture)</ENT> </ROW> <ROW> <ENT I="01">95476 </ENT> <ENT>o-Xylene</ENT> </ROW> <ROW> <ENT I="01">108383 </ENT> <ENT>m-Xylene</ENT> </ROW> <ROW> <ENT I="01">106423 </ENT> <ENT>p-Xylene</ENT> </ROW> <TNOTE> <E T="51">a</E> CAS numbers refer to the Chemical Abstracts Services registry number assigned to specific compounds, isomers, or mixtures of compounds.</TNOTE> </GPOTABLE> <PRTPAGE P="139"/> <GPOTABLE CDEF="s100,xs60,r200" COLS="3" OPTS="L2,i1"> <TTITLE> <E T="04">Table 2 to Subpart HHH.—Applicability of 40 CFR Part 63 General Provisions to Subpart HHH</E> </TTITLE> <BOXHD> <CHED H="1">General provisions reference</CHED> <CHED H="1">Applicable to<LI>subpart HHH</LI> </CHED> <CHED H="1">Explanation</CHED> </BOXHD> <ROW> <ENT I="01">§ 63.1(a)(1)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.1(a)(2)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.1(a)(3)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.1(a)(4)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.1(a)(5)</ENT> <ENT>No</ENT> <ENT>Section reserved. </ENT> </ROW> <ROW> <ENT I="01">§ 63.1(a)(6) through (a)(8)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.1(a)(9)</ENT> <ENT>No</ENT> <ENT>Section reserved. </ENT> </ROW> <ROW> <ENT I="01">§ 63.1(a)(10)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.1(a)(11)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.1(a)(12) through (a)(14)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.1(b)(1)</ENT> <ENT>No</ENT> <ENT>Subpart HHH specifies applicability. </ENT> </ROW> <ROW> <ENT I="01">§ 63.1(b)(2)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.1(b)(3)</ENT> <ENT>No </ENT> </ROW> <ROW> <ENT I="01">§ 63.1(c)(1)</ENT> <ENT>No</ENT> <ENT>Subpart HHH specifies applicability. </ENT> </ROW> <ROW> <ENT I="01">§ 63.1(c)(2)</ENT> <ENT O="xl">No </ENT> </ROW> <ROW> <ENT I="01">§ 63.1(c)(3)</ENT> <ENT>No </ENT> <ENT>Section reserved. </ENT> </ROW> <ROW> <ENT I="01">§ 63.1(c)(4)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.1(c)(5)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.1(d)</ENT> <ENT>No</ENT> <ENT>Section reserved. </ENT> </ROW> <ROW> <ENT I="01">§ 63.1(e)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.2</ENT> <ENT>Yes</ENT> <ENT>Except definition of major source is unique for this source category and there are additional definitions in subpart HHH. </ENT> </ROW> <ROW> <ENT I="01">§ 63.3(a) through (c)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.4(a)(1) through (a)(3)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.4(a)(4)</ENT> <ENT>No</ENT> <ENT>Section reserved. </ENT> </ROW> <ROW> <ENT I="01">§ 63.4(a)(5)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.4(b)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.4(c)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.5(a)(1)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.5(a)(2)</ENT> <ENT>No</ENT> <ENT>Preconstruction review required only for major sources that commence construction after promulgation of the standard. </ENT> </ROW> <ROW> <ENT I="01">§ 63.5(b)(1)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.5(b)(2)</ENT> <ENT>No</ENT> <ENT>Section reserved. </ENT> </ROW> <ROW> <ENT I="01">§ 63.5(b)(3)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.5(b)(4)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.5(b)(5)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.5(b)(6)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.5(c)</ENT> <ENT>No</ENT> <ENT>Section reserved. </ENT> </ROW> <ROW> <ENT I="01">§ 63.5(d)(1)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.5(d)(2)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.5(d)(3)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.5(d)(4)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.5(e)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.5(f)(1)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.5(f)(2)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.6(a)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.6(b)(1)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.6(b)(2)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.6(b)(3)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.6(b)(4)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.6(b)(5)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.6(b)(6)</ENT> <ENT>No</ENT> <ENT>Section reserved. </ENT> </ROW> <ROW> <PRTPAGE P="140"/> <ENT I="01">§ 63.6(b)(7)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.6(c)(1)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.6(c)(2)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.6(c)(3) and (c)(4)</ENT> <ENT>No</ENT> <ENT>Section reserved. </ENT> </ROW> <ROW> <ENT I="01">§ 63.6(c)(5)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.6(d)</ENT> <ENT>No</ENT> <ENT>Section reserved. </ENT> </ROW> <ROW> <ENT I="01">§ 63.6(e)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.6(e)</ENT> <ENT O="xl">Yes</ENT> <ENT>Except as otherwise specified. </ENT> </ROW> <ROW> <ENT I="01">§ 63.6(e)(1)(i)</ENT> <ENT>No</ENT> <ENT>Addressed in § 63.1272. </ENT> </ROW> <ROW> <ENT I="01">§ 63.6(e)(1)(ii)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.6(e)(1)(iii)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.6(e)(2)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.6(e)(3)(i)</ENT> <ENT>Yes</ENT> <ENT>Except as otherwise specified. </ENT> </ROW> <ROW> <ENT I="01">§ 63.6(e)(3)(i)(A)</ENT> <ENT>No</ENT> <ENT>Addressed by § 63.1272(c). </ENT> </ROW> <ROW> <ENT I="01">§ 63.6(e)(3)(i)(B)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.6(e)(3)(i)(C)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.6(e)(3)(ii) through (3)(vi)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.6(e)(3)(vii) </ENT> </ROW> <ROW> <ENT I="01">§ 63.6(e)(3)(vii) (A)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.6(e)(3)(vii) (B)</ENT> <ENT>Yes</ENT> <ENT>Except that the plan must provide for operation in compliance with § 63.1272(c). </ENT> </ROW> <ROW> <ENT I="01">§ 63.6(e)(3)(vii) (C)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.6(e)3)(viii)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.7(e)(1)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.7(e)(2)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.7(e)(3)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.7(e)(4)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.7(f)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.7(g)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.7(h)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.8(a)(1)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.8(a)(2)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.8(a)(3)</ENT> <ENT>No</ENT> <ENT>Section reserved. </ENT> </ROW> <ROW> <ENT I="01">§ 63.8(a)(4)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.8(b)(1)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.8(b)(2)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.8(b)(3)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.8(c)(1)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.8(c)(2)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.8(c)(3)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.8(c)(4)</ENT> <ENT>No </ENT> </ROW> <ROW> <ENT I="01">§ 63.8(c)(5) through (c)(8)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.8(d)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.8(e)</ENT> <ENT>Yes</ENT> <ENT>Subpart HHH does not specifically require continuous emissions monitor performance evaluations, however, the Administrator can request that one be conducted. </ENT> </ROW> <ROW> <ENT I="01">§ 63.8(f)(1) through (f)(5)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.8(f)(6)</ENT> <ENT>No</ENT> <ENT>Subpart HHH does not require continuous emissions monitoring. </ENT> </ROW> <ROW> <ENT I="01">§ 63.8(g)</ENT> <ENT>No</ENT> <ENT>Subpart HHH specifies continuous monitoring system data reduction requirements. </ENT> </ROW> <ROW> <ENT I="01">§ 63.9(a)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.9(b)(1)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.9(b)(2)</ENT> <ENT>Yes</ENT> <ENT>Sources are given 1 year (rather than 120 days) to submit this notification. </ENT> </ROW> <ROW> <ENT I="01">§ 63.9(b)(3)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.9(b)(4)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <PRTPAGE P="141"/> <ENT I="01">§ 63.9(b)(5)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.9(c) </ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.9(d) </ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.9(e)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.9(f)</ENT> <ENT>No </ENT> </ROW> <ROW> <ENT I="01">§ 63.9(g)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.9(h)(1) through (h)(3)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.9(h)(4)</ENT> <ENT>No</ENT> <ENT>Section reserved. </ENT> </ROW> <ROW> <ENT I="01">§ 63.9(h)(5) and (h)(6)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.9(i) </ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.9(j)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.10(a) </ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.10(b)(1)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.10(b)(2)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.10(b)(3)</ENT> <ENT O="xl">No </ENT> </ROW> <ROW> <ENT I="01">§ 63.10(c)(1)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.10(c)(2) through (c)(4)</ENT> <ENT>No</ENT> <ENT>Sections reserved. </ENT> </ROW> <ROW> <ENT I="01">§ 63.10(c)(5) through (c)(8)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.10(c)(9)</ENT> <ENT>No</ENT> <ENT>Section reserved. </ENT> </ROW> <ROW> <ENT I="01">§ 63.10(c)(10) through (c)(15)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.10(d)(1)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.10(d)(2)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.10(d)(3)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.10(d)(4)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.10(d)(5)</ENT> <ENT>Yes</ENT> <ENT>Subpart HHH requires major sources to submit a startup, shutdown and malfunction report semi-annually. </ENT> </ROW> <ROW> <ENT I="01">§ 63.10(e)(1)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.10(e)(2)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.10(e)(3)(i)</ENT> <ENT>Yes</ENT> <ENT>Subpart HHH requires major sources to submit Periodic Reports semi-annually. </ENT> </ROW> <ROW> <ENT I="01">§ 63.10(e)(3)(i)(A)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.10(e)(3)(i)(B)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.10(e)(3)(i)(C)</ENT> <ENT>No</ENT> <ENT>Subpart HHH does not require quarterly reporting for excess emissions. </ENT> </ROW> <ROW> <ENT I="01">§ 63.10(e)(3)(ii) through (e)(3)(viii) </ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.10(f)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.11(a) and (b)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.12(a) through (c)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.13(a) through (c)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.14(a) and (b)</ENT> <ENT O="xl">Yes </ENT> </ROW> <ROW> <ENT I="01">§ 63.15(a) and (b)</ENT> <ENT O="xl">Yes </ENT> </ROW> </GPOTABLE> </APPENDIX> </SUBPART> <SUBPART> <PRTPAGE P="142"/> <HD SOURCE="HED">Subpart III—National Emission Standards for Hazardous Air Pollutants for Flexible Polyurethane Foam Production</HD> <SOURCE> <HD SOURCE="HED">Source:</HD> <P>63 FR 53996, Oct. 7, 1998, unless otherwise noted.</P> </SOURCE> <SECTION> <SECTNO>§ 63.1290</SECTNO> <SUBJECT>Applicability.</SUBJECT> <P>(a) The provisions of this subpart apply to each new and existing flexible polyurethane foam or rebond foam process that meets the criteria listed in paragraphs (a)(1) through (3) of this section.</P> <P>(1) Produces flexible polyurethane or rebond foam;</P> <P>(2) Emits a HAP, except as provided in paragraph (c)(2) of this section; and</P> <P>(3) Is located at a plant site that is a major source, as defined in § 63.2 of subpart A.</P> <P>(b) For the purpose of this subpart, an affected source includes all processes meeting the criteria in paragraphs (a)(1) through (a)(3) of this section that are located at a contiguous plant site, with the exception of those processes listed in paragraph (c) of this section.</P> <P>(c) A process meeting one of the following criteria listed in paragraphs (c)(1) through (3) of this section shall not be subject to the provisions of this subpart:</P> <P>(1) A process exclusively dedicated to the fabrication of flexible polyurethane foam;</P> <P>(2) A research and development process; or</P> <P>(3) A slabstock flexible polyurethane foam process at a plant site where the total amount of HAP, excluding diisocyanate reactants, used for slabstock foam production and foam fabrication is less than or equal to five tons per year, provided that slabstock foam production and foam fabrication processes are the only processes at the plant site that emit HAP. The amount of non-diisocyanate HAP used, HAP<E T="52">used,</E> shall be calculated using Equation 1. Owners or operators of slabstock foam processes exempt from the regulation in accordance with this paragraph shall maintain records to verify that total non-diisocyanate HAP use at the plant site is less than 5 tons per year (4.5 megagrams per year).</P> <GPH DEEP="33" SPAN="2"> <GID>ER07OC98.012</GID> </GPH> <FP SOURCE="FP-2">Where,</FP> <FP SOURCE="FP-2">HAP<E T="52">used</E> = amount of HAP, excluding diisocyanate reactants, used at the plant site for slabstock foam production and foam fabrication, tons per year</FP> <FP SOURCE="FP-2">VOL<E T="52">ABA,i</E> = volume of HAP ABA i used at the facility, gallons per year</FP> <FP SOURCE="FP-2">D<E T="52">ABA,i</E> = density of HAP ABA i, pounds per gallon</FP> <FP SOURCE="FP-2">m = number of HAP ABAs used</FP> <FP SOURCE="FP-2">VOL<E T="52">clean,j</E> = volume of HAP used as an equipment cleaner, gallons per year</FP> <FP SOURCE="FP-2">D<E T="52">clean,j</E> = density of HAP equipment cleaner j, pounds per gallon</FP> <FP SOURCE="FP-2">WT<E T="52">HAPclean,k</E> = HAP content of equipment cleaner j, weight percent</FP> <FP SOURCE="FP-2">n = number of HAP equipment cleaners used</FP> <FP SOURCE="FP-2">VOL<E T="52">adh,k</E> = volume of adhesive k, gallons per year</FP> <FP SOURCE="FP-2">D<E T="52">adh,k</E> = density of adhesive k, pounds per gallon</FP> <FP SOURCE="FP-2">WT<E T="52">HAPadh,k</E> = HAP content of adhesive k, weight percent</FP> <FP SOURCE="FP-2">o = number of adhesives used</FP> </SECTION> <SECTION> <SECTNO>§ 63.1291</SECTNO> <SUBJECT>Compliance schedule.</SUBJECT> <P>(a) Existing affected sources shall be in compliance with all provisions of this subpart no later than October 8, 2001.</P> <P>(b) New or reconstructed affected sources shall be in compliance with all provisions of this subpart upon initial startup.</P> </SECTION> <SECTION> <PRTPAGE P="143"/> <SECTNO>§ 63.1292</SECTNO> <SUBJECT>Definitions.</SUBJECT> <P>All terms used in this subpart shall have the meaning given them in the Act, in subpart A of this part, and in this section. If a term is defined in subpart A and in this section, it shall have the meaning given in this section for purposes of this subpart.</P> <P> <E T="03">Auxiliary blowing agent, or ABA,</E> means a low-boiling point liquid added to assist foaming by generating gas beyond that resulting from the isocyanate-water reaction.</P> <P> <E T="03">Breakthrough</E> means that point in the adsorption step when the mass transfer zone (i.e., the section of the carbon bed where the HAP is removed from the carrier gas stream) first reaches the carbon bed outlet as the mass transfer zone moves down the bed in the direction of flow. The breakthrough point is characterized by the beginning of a sharp increase in the outlet HAP or organic compound concentration.</P> <P> <E T="03">Calibrate</E> means to verify the accuracy of a measurement device against a known standard. For the purpose of this subpart, there are two levels of calibration. The initial calibration includes the verification of the accuracy of the device over the entire operating range of the device. Subsequent calibrations can be conducted for a point or several points in a limited range of operation that represents the most common operation of the device.</P> <P> <E T="03">Canned motor pump</E> means a pump with interconnected cavity housings, motor rotors, and pump casing. In a canned motor pump, the motor bearings run in the process liquid and all seals are eliminated.</P> <P> <E T="03">Carbon adsorption system</E> means a system consisting of a tank or container that contains a specific quantity of activated carbon. For the purposes of this subaprt, a carbon adsorption system is used as a control device for storage vessels. Typically, the spent carbon bed does not undergo regeneration, but is replaced.</P> <P> <E T="03">Connector</E> means flanged, screwed, or other joined fittings used to connect two pipe lines or a pipe line and a piece of equipment. A common connector is a flange. Joined fittings welded completely around the circumference of the interface are not considered to be connectors for the purposes of this subpart.</P> <P> <E T="03">Cured foam</E> means flexible polyurethane foam with fully developed physical properties. A period of 12 to 24 hours from pour is typically required to completely cure foam, although mechanical or other devices are sometimes used to accelerate the curing process.</P> <P> <E T="03">Curing area</E> means the area in a slabstock foam production facility where foam buns are allowed to fully develop physical properties.</P> <P> <E T="03">Diaphragm pump</E> means a pump where the driving member is a flexible diaphragm made of metal, rubber, or plastic. In a diaphragm pump, there is no packing or seals that are exposed to the process liquid.</P> <P> <E T="03">Diisocyanate</E> means a compound containing two isocyanate groups per molecule. The most common diisocyanate compounds used in the flexible polyurethane foam industry are toluene diisocyanate (TDI) and methylene diphenyl diisocyanate (MDI).</P> <P> <E T="03">Flexible polyurethane foam</E> means a flexible cellular polymer containing urea and carbamate linkages in the chain backbone produced by reacting a diisocyanate, polyol, and water. Flexible polyurethane foams are open-celled, permit the passage of air through the foam, and possess the strength and flexibility to allow repeated distortion or compression under stress with essentially complete recovery upon removal of the stress.</P> <P> <E T="03">Flexible polyurethane foam process</E> means the equipment used to produce a flexible polyurethane foam product. For the purpose of this subpart, the flexible polyurethane foam process includes raw material storage; production equipment and associated piping, ductwork, etc.; and curing and storage areas.</P> <P> <E T="03">Foam fabrication process</E> means an operation for cutting or bonding flexible polyurethane foam pieces together or to other substrates.</P> <P> <E T="03">Grade of foam</E> means foam with a distinct combination of indentation force deflection (IFD) and density values.</P> <P> <E T="03">HAP ABA</E> means methylene chloride, or any other HAP compound used as an auxiliary blowing agent.<PRTPAGE P="144"/> </P> <P> <E T="03">HAP-based</E> means to contain 5 percent (by weight) or more of HAP. This applies to equipment cleaners (and mixhead flushes) and mold release agents. The concentration of HAP may be determined using EPA test method 18, material safety data sheets, or engineering calculations.</P> <P> <E T="03">High-pressure mixhead</E> means a mixhead where mixing is achieved by impingement of the high pressure streams within the mixhead.</P> <P> <E T="03">Indentation Force Deflection (IFD)</E> means a measure of the load bearing capacity of flexible polyurethane foam. IFD is generally measured as the force (in pounds) required to compress a 50 square inch circular indentor foot into a four inch thick sample, typically 15 inches square or larger, to 25 percent of the sample's initial height.</P> <P> <E T="03">In diisocyanate service</E> means a piece of equipment that contains or contacts a diisocyanate.</P> <P> <E T="03">In HAP ABA service</E> means a piece of equipment that contains or contacts a HAP ABA.</P> <P> <E T="03">Initial startup</E> means the first time a new or reconstructed affected source begins production of flexible polyurethane foam.</P> <P> <E T="03">Isocyanate</E> means a reactive chemical grouping composed of a nitrogen atom bonded to a carbon atom bonded to an oxygen atom; or a chemical compound, usually organic, containing one or more isocyanate groups.</P> <P> <E T="03">Magnetic drive pump</E> means a pump where an externally-mounted magnet coupled to the pump motor drives the impeller in the pump casing. In a magnetic drive pump, no seals contact the process fluid.</P> <P> <E T="03">Metering pump</E> means a pump used to deliver reactants, ABA, or additives to the mixhead.</P> <P> <E T="03">Mixhead</E> means a device that mixes two or more component streams before dispensing foam producing mixture to the desired container.</P> <P> <E T="03">Molded flexible polyurethane foam</E> means a flexible polyurethane foam that is produced by shooting the foam mixture into a mold of the desired shape and size.</P> <P> <E T="03">Mold release agent</E> means any material which, when applied to the mold surface, serves to prevent sticking of the foam part to the mold.</P> <P> <E T="03">Plant site</E> means all contiguous or adjoining property that is under common control, including properties that are separated only by a road or other public right-of-way. Common control includes properties that are owned, leased, or otherwise operated by the same entity, parent entity, subsidiary, or any combination thereof.</P> <P> <E T="03">Polyol,</E> for the purpose of this subpart, means a polyether or polyester polymer with more than one reactive hydroxyl group attached to the molecule.</P> <P> <E T="03">Rebond foam</E> means the foam resulting from a process of adhering small particles of foam (usually scrap or recycled foam) together to make a usable cushioning product. Various adhesives and bonding processes are used. A typical application for rebond foam is for carpet underlay.</P> <P> <E T="03">Rebond foam process</E> means the equipment used to produce a rebond foam product. For the purpose of this subpart, the rebond foam process includes raw material storage; production equipment and associated piping, ductwork, etc.; and curing and storage areas.</P> <P> <E T="03">Reconstructed source</E> means an affected source undergoing reconstruction, as defined in subpart A. For the purposes of this subpart, process modifications made to reduce HAP ABA emissions to meet the existing source requirements of this subpart shall not be counted in determining whether or not a change or replacement meets the definition of reconstruction.</P> <P> <E T="03">Recovery device</E> means an individual unit of equipment capable of and used for the purpose of recovering chemicals for use, reuse, or sale. Recovery devices include, but are not limited to, carbon adsorbers, absorbers, and condensers.</P> <P> <E T="03">Research and development process</E> means a laboratory or pilot plant operation whose primary purpose is to conduct research and development into new processes and products, where the operations are under the close supervision of technically trained personnel, and which is not engaged in the manufacture of products for commercial sale except in a de minimis manner.</P> <P> <E T="03">Run of foam</E> means a continuous production of foam, which may consist of several grades of foam.<PRTPAGE P="145"/> </P> <P> <E T="03">Sealless pump</E> means a canned-motor pump, diaphragm pump, or magnetic drive pump, as defined in this section.</P> <P> <E T="03">Slabstock flexible polyurethane foam</E> means flexible polyurethane foam that is produced in large continuous buns that are then cut into the desired size and shape.</P> <P> <E T="03">Slabstock flexible polyurethane foam production line</E> includes all portions of the flexible polyurethane foam process from the mixhead to the point in the process where the foam is completely cured.</P> <P> <E T="03">Storage vessel</E> means a tank or other vessel that is used to store diisocyanate or HAP ABA for use in the production of flexible polyurethane foam. Storage vessels do not include vessels with capacities smaller than 38 cubic meters (or 10,000 gallons).</P> <P> <E T="03">Transfer pump</E> means all pumps used to transport diisocyanate or HAP ABA that are not metering pumps.</P> <P> <E T="03">Transfer vehicle</E> means a railcar, tank truck, or other vehicle used to transport HAP ABA to the flexible polyurethane foam facility.</P> </SECTION> <SECTION> <SECTNO>§ 63.1293</SECTNO> <SUBJECT>Standards for slabstock flexible polyurethane foam production.</SUBJECT> <P>Each owner or operator of a new or existing slabstock affected source shall comply with § 63.1294 and either paragraph (a) or (b) of this section:</P> <P>(a) The emission point specific limitations in §§ 63.1295 through 63.1298; or</P> <P>(b) For sources that use no more than one HAP as an ABA and an equipment cleaner, the source-wide emission limitation in § 63.1299.</P> </SECTION> <SECTION> <SECTNO>§ 63.1294</SECTNO> <SUBJECT>Standards for slabstock flexible polyurethane foam production—diisocyanate emissions.</SUBJECT> <P>Each new and existing slabstock affected source shall comply with the provisions of this section.</P> <P>(a) <E T="03">Diisocyanate storage vessels.</E> Diisocyanate storage vessels shall be equipped with either a system meeting the requirements in paragraph (a)(1) of this section, or a carbon adsorption system meeting the requirements of paragraph (a)(2) of this section.</P> <P>(1) The storage vessel shall be equipped with a vapor return line from the storage vessel to the tank truck or rail car that is connected during unloading.</P> <P>(i) During each unloading event, the vapor return line shall be inspected for leaks by visual, audible, or any other detection method.</P> <P>(ii) When a leak is detected, it shall be repaired as soon as practicable, but not later than the subsequent unloading event.</P> <P>(2) The storage vessel shall be equipped with a carbon adsorption system, meeting the monitoring requirements of § 63.1303(a), that routes displaced vapors through activated carbon before being discharged to the atmosphere. The owner or operator shall replace the existing carbon with fresh carbon upon indication of breakthrough before the next unloading event.</P> <P>(b) <E T="03">Transfer pumps in diisocyanate service.</E> Each transfer pump in diisocyanate service shall meet the requirements of paragraph (b)(1) or (b)(2) of this section.</P> <P>(1) The pump shall be a sealless pump; or</P> <P>(2) The pump shall be a submerged pump system meeting the requirements in paragraphs (b)(2)(i) through (iii) of this section.</P> <P>(i) The pump shall be completely immersed in bis(2-ethylhexyl)phthalate (DEHP, CAS <E T="61">#</E>118-81-7), 2(methyloctyl)phthalate (DINP, CAS <E T="61">#</E>68515-48-0), or another neutral oil.</P> <P>(ii) The pump shall be visually monitored weekly to detect leaks,</P> <P>(iii) When a leak is detected, it shall be repaired in accordance with the procedures in paragraphs (b)(2)(iii)(A) and (B) of this section, except as provided in paragraph (d) of this section.</P> <P>(A) The leak shall be repaired as soon as practicable, but not later than 15 calendar days after it is detected.</P> <P>(B) A first attempt at repair shall be made no later than 5 calendar days after the leak is detected. First attempts at repair include, but are not limited to, the following practices where practicable:</P> <P>(<E T="03">1</E>) Tightening of packing gland nuts.</P> <P>(<E T="03">2</E>) Ensuring that the seal flush is operating at design pressure and temperature.</P> <P>(c) <E T="03">Other components in diisocyanate service.</E> If evidence of a leak is found by <PRTPAGE P="146"/>visual, audible, or any other detection method, it shall be repaired as soon as practicable, but not later than 15 calendar days after it is detected, except as provided in paragraph (d) of this section. The first attempt at repair shall be made no later than 5 calendar days after each leak is detected.</P> <P>(d) <E T="03">Delay of repair.</E> (1) Delay of repair of equipment for which leaks have been detected is allowed for equipment that is isolated from the process and that does not remain in diisocyanate service.</P> <P>(2) Delay of repair for valves and connectors is also allowed if:</P> <P>(i) The owner or operator determines that diisocyanate emissions of purged material resulting from immediate repair are greater than the fugitive emissions likely to result from delay of repair, and</P> <P>(ii) The purged material is collected and destroyed or recovered in a control device when repair procedures are effected.</P> <P>(3) Delay of repair for pumps is also allowed if repair requires replacing the existing seal design with a sealless pump, and repair is completed as soon as practicable, but not later than 6 months after the leak was detected.</P> </SECTION> <SECTION> <SECTNO>§ 63.1295</SECTNO> <SUBJECT>Standards for slabstock flexible polyurethane foam production—HAP ABA storage vessels.</SUBJECT> <P>Each owner or operator of a new or existing slabstock affected source complying with the emission point specific limitation option provided in § 63.1293(a) shall control HAP ABA storage vessels in accordance with the provisions of this section.</P> <P>(a) Each HAP ABA storage vessel shall be equipped with either a vapor balance system meeting the requirements in paragraph (b) of this section, or a carbon adsorption system meeting the requirements of paragraph (c) of this section.</P> <P>(b) The storage vessel shall be equipped with a vapor balance system. The owner or operator shall ensure that the vapor return line from the storage vessel to the tank truck or rail car is connected during unloading.</P> <P>(1) During each unloading event, the vapor return line shall be inspected for leaks by visual, audible, olfactory, or any other detection method.</P> <P>(2) When a leak is detected, it shall be repaired as soon as practicable, but not later than the subsequent unloading event.</P> <P>(c) The storage vessel shall be equipped with a carbon adsorption system, meeting the monitoring requirements of § 63.1303(a), that routes displaced vapors through activated carbon before discharging to the atmosphere. The owner or operator shall replace the existing carbon with fresh carbon upon indication of breakthrough before the next unloading event.</P> </SECTION> <SECTION> <SECTNO>§ 63.1296</SECTNO> <SUBJECT>Standards for slabstock flexible polyurethane foam production—HAP ABA equipment leaks.</SUBJECT> <P>Each owner or operator of a new or existing slabstock affected source complying with the emission point specific limitation option provided in § 63.1293(a) shall control HAP ABA emissions from leaks from transfer pumps, valves, connectors, pressure-relief valves, and open-ended lines in accordance with the provisions in this section.</P> <P>(a) <E T="03">Pumps.</E> Each pump in HAP ABA service shall be controlled in accordance with either paragraph (a)(1) or (a)(2) of this section.</P> <P>(1) The pump shall be a sealless pump, or</P> <P>(2) Each pump shall be monitored for leaks in accordance with paragraphs (a)(2)(i) and (ii) of this section. Leaks shall be repaired in accordance with paragraph (a)(2)(iii) of this section.</P> <P>(i) Each pump shall be monitored quarterly to detect leaks by the method specified in § 63.1304(a). If an instrument reading of 10,000 parts per million (ppm) or greater is measured, a leak is detected.</P> <P>(ii) Each pump shall be checked by visual inspection each calendar week for indications of liquids dripping from the pump seal. If there are indications of liquids dripping from the pump seal, a leak is detected.</P> <P>(iii) When a leak is detected, it shall be repaired in accordance with the procedures in paragraphs (a)(2)(iii)(A) and (B) of this section, except as provided in paragraph (f) of this section.<PRTPAGE P="147"/> </P> <P>(A) The leak shall be repaired as soon as practicable, but not later than 15 calendar days after it is detected.</P> <P>(B) A first attempt at repair shall be made no later than 5 calendar days after the leak is detected. First attempts at repair include, but are not limited to, the following practices, where practicable:</P> <P>(<E T="03">1</E>) Tightening of packing gland nuts.</P> <P>(<E T="03">2</E>) Ensuring that the seal flush is operating at design pressure and temperature.</P> <P>(b) <E T="03">Valves.</E> Each valve in HAP ABA service shall be monitored for leaks in accordance with paragraph (b)(1) of this section, except as provided in paragraphs (b)(3) and (4) of this section. Leaks shall be repaired in accordance with paragraph (b)(2) of this section.</P> <P>(1) Each valve shall be monitored quarterly to detect leaks by the method specified in § 63.1304(a). If an instrument reading of 10,000 parts per million or greater is measured, a leak is detected.</P> <P>(2) When a leak is detected, the owner or operator shall repair the leak in accordance with the procedures in paragraphs (b)(2)(i) and (ii) of this section, except as provided in paragraph (f) of this section.</P> <P>(i) The leak shall be repaired as soon as practicable, but not later than 15 calendar days after it is detected.</P> <P>(ii) A first attempt at repair shall be made no later than 5 calendar days after the leak is detected. First attempts at repair include, but are not limited to, the following practices where practicable:</P> <P>(A) Tightening of bonnet bolts;</P> <P>(B) Replacement of bonnet bolts;</P> <P>(C) Tightening of packing gland nuts; and</P> <P>(D) Injection of lubricant into lubricated packing.</P> <P>(3) Any valve that is designated as an unsafe-to-monitor valve is exempt from the requirements of paragraphs (b)(1) and (2) of this section if:</P> <P>(i) The owner or operator of the valve determines that the valve is unsafe to monitor because monitoring personnel would be exposed to an immediate danger as a consequence of complying with paragraphs (b)(1) and (2) of this section; and</P> <P>(ii) The owner or operator of the valve has a written plan that requires monitoring of the valve as frequently as practicable during safe-to-monitor times. The plan shall also include requirements for repairing leaks as soon as possible after detection.</P> <P>(iii) The owner or operator shall monitor the unsafe-to-monitor valve in accordance with the written plan, and</P> <P>(iv) The owner or operator shall repair leaks in accordance with the written plan.</P> <P>(4) Any valve that is designated as a difficult-to-monitor valve is exempt from the requirements of paragraphs (b)(1) and (2) of this section if:</P> <P>(i) The owner or operator of the valve determines that the valve cannot be monitored without elevating the monitoring personnel more than 2 meters above a support surface or it is not accessible at any time in a safe manner;</P> <P>(ii) The process within which the valve is located is an existing source, or the process within which the valve is located is a new source that has less than 3 percent of the total number of valves designated as difficult to monitor; and</P> <P>(iii) The owner or operator of the valve develops a written plan that requires monitoring of the valve at least once per calendar year. The plan shall also include requirements for repairing leaks as soon as possible after detection.</P> <P>(iv) The owner or operator shall monitor the difficult-to-monitor valve in accordance with the written plan, and</P> <P>(v) The owner or operator shall repair leaks in accordance with the written plan.</P> <P>(c) <E T="03">Connectors.</E> Each connector in HAP ABA service shall be monitored for leaks in accordance with paragraph (c)(1) of this section, except as provided in paragraph (c)(3) of this section. Leaks shall be repaired in accordance with (c)(2) of this section, except as provided in paragraph (c)(4) of this section.</P> <P>(1) Connectors shall be monitored at the times specified in paragraphs (c)(1)(i) through (iii) of this section to detect leaks by the method specified in § 63.1304(a). If an instrument reading of 10,000 ppm or greater is measured, a leak is detected.<PRTPAGE P="148"/> </P> <P>(i) Each connector shall be monitored annually, and</P> <P>(ii) Each connector that has been opened or has otherwise had the seal broken shall be monitored for leaks within the first 3 months after being returned to HAP ABA service.</P> <P>(iii) If a leak is detected, the connector shall be monitored for leaks in accordance with paragraph (c)(1) of this section within the first 3 months after its repair.</P> <P>(2) When a leak is detected, it shall be repaired in accordance with the procedures in paragraphs (c)(2)(i) and (ii) of this section, except as provided in paragraph (c)(4) and paragraph (f) of this section.</P> <P>(i) The leak shall be repaired as soon as practicable, but no later than 15 calendar days after the leak is detected.</P> <P>(ii) A first attempt at repair shall be made no later than 5 calendar days after the leak is detected.</P> <P>(3) Any connector that is designated as an unsafe-to-monitor connector is exempt from the requirements of paragraph (c)(1) of this section if:</P> <P>(i) The owner or operator determines that the connector is unsafe to monitor because personnel would be exposed to an immediate danger as a result of complying with paragraph (c)(1) of this section; and</P> <P>(ii) The owner or operator has a written plan that requires monitoring of the connector as frequently as practicable during safe-to-monitor periods.</P> <P>(4) Any connector that is designated as an unsafe-to-repair connector is exempt from the requirements of paragraph (c)(2) of this section if:</P> <P>(i) The owner or operator determines that repair personnel would be exposed to an immediate danger as a consequence of complying with paragraph (c)(2) of this section; and</P> <P>(ii) The connector will be repaired as soon as practicable, but not later than 6 months after the leak was detected.</P> <P>(d) <E T="03">Pressure-relief devices.</E> Each pressure-relief device in HAP ABA service shall be monitored for leaks in accordance with paragraph (d)(1) of this section. Leaks shall be repaired in accordance with paragraph (d)(2) of this section.</P> <P>(1) Each pressure-relief device in HAP ABA service shall be monitored within 5 calendar days by the method specified in § 63.1304(a) if evidence of a potential leak is found by visual, audible, olfactory, or any other detection method. If an instrument reading of 10,000 ppm or greater is measured, a leak is detected.</P> <P>(2) When a leak is detected, the leak shall be repaired as soon as practicable, but not later than 15 calendar days after it is detected, except as provided in paragraph (f) of this section. The owner or operator shall make a first attempt at repair no later than 5 calendar days after the leak is detected.</P> <P>(e) <E T="03">Open-ended valves or lines.</E> (1)(i) Each open-ended valve or line in HAP ABA service shall be equipped with a cap, blind flange, plug, or a second valve, except as provided in paragraph (e)(4) of this section.</P> <P>(ii) The cap, blind flange, plug, or second valve shall seal the open end at all times except during operations requiring process fluid flow through the open-ended valve or line, or during maintenance or repair.</P> <P>(2) Each open-ended valve or line equipped with a second valve shall be operated in a manner such that the valve on the process fluid end is closed before the second valve is closed.</P> <P>(3) When a double block and bleed system is being used, the bleed valve or line may remain open during operations that require venting the line between the block valves but shall comply with paragraph (e)(1) of this section at all other times.</P> <P>(4) Open-ended valves or lines in an emergency shutdown system which are designed to open automatically in the event of a process upset are exempt from the requirements of paragraphs (e)(1), (2), and (3) of this section.</P> <P>(f) <E T="03">Delay of repair.</E> (1) Delay of repair of equipment for which leaks have been detected is allowed for equipment that is isolated from the process and that does not remain in HAP ABA service.</P> <P>(2) Delay of repair for valves and connectors is also allowed if:</P> <P>(i) The owner or operator determines that emissions of purged material resulting from immediate repair are greater than the fugitive emissions likely to result from delay of repair, and<PRTPAGE P="149"/> </P> <P>(ii) The purged material is collected and destroyed or recovered in a control device when repair procedures are effected.</P> <P>(3) Delay of repair for pumps is also allowed if repair requires replacing the existing seal design with a sealless pump, and repair is completed as soon as practicable, but not later than 6 months after the leak was detected.</P> </SECTION> <SECTION> <SECTNO>§ 63.1297</SECTNO> <SUBJECT>Standards for slabstock flexible polyurethane foam production—HAP ABA emissions from the production line.</SUBJECT> <P>(a) Each owner or operator of a new or existing slabstock affected source complying with the emission point specific limitation option provided in § 63.1293(a)(1) shall control HAP ABA emissions from the slabstock polyurethane foam production line in accordance with the provisions in this section. Compliance shall be determined on a rolling annual basis as described in paragraph (a)(1) of this section. As an alternative, the owner or operator can determine compliance on a monthly basis, as described in paragraph (a)(2) of this section.</P> <P>(1) <E T="03">Rolling annual compliance.</E> In determining compliance on a rolling annual basis, actual HAP ABA emissions shall be compared to allowable HAP ABA emissions for each consecutive 12-month period. The allowable HAP ABA emission level shall be calculated based on the production for the 12-month period, resulting in a potentially different allowable level for each 12-month period. Compliance shall be determined each month for the previous 12-month period. The compliance requirements are provided in paragraph (b) of this section.</P> <P>(2) <E T="03">Monthly compliance alternative.</E> As an alternative to determining compliance on a rolling annual basis, an owner or operator can determine compliance by comparing actual HAP ABA emissions to allowable HAP ABA emissions for each month. The allowable HAP ABA emission level shall be calculated based on the production for the month, resulting in a potentially different allowable level each month. The requirements for this monthly compliance alternative are provided in paragraph (c) of this section.</P> <P>(3) Each owner or operator electing to change between the compliance methods described under paragraphs (a)(1) and (a)(2) of this section shall notify the Administrator no later than 180 calendar days prior to the change.</P> <P>(b) <E T="03">Rolling annual compliance.</E> At each slabstock foam production source complying with the rolling annual compliance provisions described in paragraph (a)(1) of this section, actual HAP ABA emissions shall not exceed the allowable HAP ABA emission level for a consecutive 12-month period. The actual HAP ABA emission level for a consecutive 12-month period shall be determined using the procedures in paragraph (b)(1) of this section, and the allowable HAP ABA emission level for the corresponding 12-month period shall be calculated in accordance with paragraph (b)(2) of this section.</P> <P>(1) The actual HAP ABA emissions for a 12-month period shall be calculated as the sum of actual monthly HAP ABA emissions for each of the individual 12 months in the period. Actual monthly HAP ABA emissions shall be equal to the amount of HAP ABA added to the slabstock foam production line at the mixhead, determined in accordance with § 63.1303(b), unless a recovery device is used. Slabstock foam production sources using recovery devices to reduce HAP ABA emissions shall determine actual monthly HAP ABA emissions using the procedures in paragraph (e) of this section.</P> <P>(2) The allowable HAP ABA emissions for a consecutive 12-month period shall be calculated as the sum of allowable monthly HAP ABA emissions for each of the individual 12 months in the period. Allowable HAP ABA emissions for each individual month shall be calculated using Equation 2.</P> <GPH DEEP="33" SPAN="2"> <GID>ER07OC98.004</GID> </GPH> <PRTPAGE P="150"/> <FP SOURCE="FP-2">Where:</FP> <FP SOURCE="FP-2">emiss<E T="52">allow,month</E> = Allowable HAP ABA emissions from the slabstock foam production source for the month, pounds.</FP> <FP SOURCE="FP-2">m = Number of slabstock foam production lines.</FP> <FP SOURCE="FP-2">polyol<E T="52">i</E> = Amount of polyol used in the month in the production of foam grade i on foam production line j, determined in accordance with paragraph (b)(3) of this section, pounds.</FP> <FP SOURCE="FP-2">n = Number of foam grades produced in the month on foam production line j.</FP> <FP SOURCE="FP-2">limit<E T="52">i</E> = HAP ABA formulation limit for foam grade i, parts HAP ABA per 100 parts polyol. The HAP ABA formulation limits are determined in accordance with paragraph (d) of this section.</FP> <P>(3) The amount of polyol used for specific foam grades shall be based on the amount of polyol added to the slabstock foam production line at the mixhead, determined in accordance with the provisions of § 63.1303(b).</P> <P>(c) <E T="03">Monthly compliance alternative.</E> At each slabstock foam production source complying with the monthly compliance alternative described in paragraph (a)(2) of this section, actual HAP ABA emissions shall not exceed the corresponding allowable HAP ABA emission level for the same month. The actual monthly HAP ABA emission level shall be determined using the procedures in paragraph (c)(1) of this section, and the allowable monthly HAP ABA emission level shall be calculated in accordance with paragraph (c)(2) of this section.</P> <P>(1) The actual monthly HAP ABA emissions shall be equal to the amount of HAP ABA added to the slabstock foam production line at the mixhead, determined in accordance with § 63.1303(b), unless a recovery device is used. Slabstock foam production sources using recovery devices to reduce HAP ABA emissions shall determine actual monthly HAP ABA emissions using the procedures in paragraph (e) of this section.</P> <P>(2) The allowable HAP ABA emissions for the month shall be determined in accordance with Equation 2 of this section.</P> <P>(d) <E T="03">HAP ABA formulation limitations.</E> For each grade, the HAP ABA formulation limitation shall be determined in accordance with paragraphs (d)(1) through (d)(3) of this section. For any grade, the owner or operator may designate zero as the HAP ABA formulation limitation and not determine the HAP ABA formulation limitation in accordance with paragraphs (d)(1) through (d)(3) of this section.</P> <P>(1) For existing sources, the HAP ABA formulation limitation for each grade of slabstock foam produced shall be determined using Equation 3 of this section. Zero shall be the formulation limitation for any grade of foam where the result of the formulation limitation equation (Equation 3) is negative (i.e., less than zero).</P> <GPH DEEP="35" SPAN="2"> <GID>ER07OC98.005</GID> </GPH> <FP SOURCE="FP-2">Where:</FP> <FP SOURCE="FP-2">ABA<E T="52">limit</E>= HAP ABA formulation limitation, parts HAP ABA allowed per hundred parts polyol (pph).</FP> <FP SOURCE="FP-1">IFD = Indentation force deflection, pounds.</FP> <FP SOURCE="FP-2">DEN = Density, pounds per cubic foot.</FP> <P>(2) For new sources, the HAP ABA formulation limitation for each grade of slabstock foam produced shall be determined as described in paragraphs (d)(2)(i) through (d)(2)(iv) of this section and in Table 1 of this subpart.</P> <P>(i) For each foam grade with a density of 0.95 pounds per cubic foot or less, the HAP ABA formulation limitation shall be determined using Equation 3. Zero shall be the formulation limitation for any grade of foam where the result of the formulation limitation equation (Equation 3 of this section) is negative (i.e., less than zero).<PRTPAGE P="151"/> </P> <P>(ii) For each foam grade with a density of 1.4 pounds per cubic foot or less, and an IFD of 15 pounds or less, the HAP ABA formulation limitation shall be determined using Equation 3.</P> <P>(iii) For each foam grade with a density greater than 0.95 pounds per cubic foot and an IFD greater than 15 pounds, the HAP ABA formulation limitation shall be zero.</P> <P>(iv) For each foam grade with a density greater than 1.40 pounds per cubic foot, the HAP ABA formulation limitation shall be zero.</P> <P>(3) With the exception of those grades for which the owner or operator has designated zero as the HAP ABA formulation limitation, the IFD and density for each foam grade shall be determined in accordance with § 63.1304(b) and recorded in accordance with § 63.1307(c)(1)(i)(B) or § 63.1307(c)(2)(i)(B) within 10 working days of the production of the foam.</P> <P>(e) <E T="03">Compliance using recovery devices.</E> If a recovery device is used to comply with paragraphs (b) or (c) of this section, the owner or operator shall determine the allowable HAP ABA emissions for each month using Equation 2 in paragraph (b)(2) of this section, and the actual monthly HAP ABA emissions in accordance with paragraph (e)(1) of this section. The owner or operator shall also comply with the provisions of paragraph (e)(2) of this section.</P> <P>(1) The actual monthly HAP ABA emissions shall be determined using Equation 4:</P> <GPH DEEP="13" SPAN="2"> <GID>ER07OC98.006</GID> </GPH> <FP SOURCE="FP-2">Where:</FP> <FP SOURCE="FP-2">E<E T="52">actual</E> = Actual HAP ABA emissions after control, pounds/month.</FP> <FP SOURCE="FP-2">E<E T="52">unc</E> = Uncontrolled HAP ABA emissions, pounds/month, determined in accordance with paragraph (b)(1) of this section.</FP> <FP SOURCE="FP-2">HAPABA<E T="52">recovered</E> = HAP ABA recovered, pounds/month, determined in accordance with paragraph (e)(2) of this section.</FP> <P>(2) The amount of HAP ABA recovered shall be determined in accordance with § 63.1303(c).</P> </SECTION> <SECTION> <SECTNO>§ 63.1298</SECTNO> <SUBJECT>Standards for slabstock flexible polyurethane foam production—HAP emissions from equipment cleaning.</SUBJECT> <P>Each owner or operator of a new or existing slabstock affected source complying with the emission point specific limitation option provided in § 63.1293(a)(1) shall not use a HAP or a HAP-based material as an equipment cleaner.</P> </SECTION> <SECTION> <SECTNO>§ 63.1299</SECTNO> <SUBJECT>Standards for slabstock flexible polyurethane foam production—source-wide emission limitation.</SUBJECT> <P>Each owner or operator of a new or existing slabstock affected source complying with the source-wide emission limitation option provided in § 63.1293(b) shall control HAP ABA storage and equipment leak emissions, HAP ABA emissions from the production line, and equipment cleaning HAP emissions in accordance with the provisions in this section. Compliance shall be determined on a rolling annual basis in accordance with paragraph (a) of this section. As an alternative, the owner or operator can determine compliance monthly, as described in paragraph (b) of this section.</P> <P>(a) <E T="03">Rolling annual compliance.</E> Under the rolling annual compliance provisions, actual source-wide HAP ABA storage and equipment leak emissions, HAP ABA emissions from the production line, and equipment cleaning HAP emissions are compared to allowable source-wide emissions for each consecutive 12-month period. The allowable source-wide HAP emission level is calculated based on the production for the 12-month period, resulting in a potentially different allowable level for each 12-month period. While compliance is on an annual basis, compliance shall be determined monthly for the preceding 12-month period. The actual source-wide HAP emission level for a consecutive 12-month period shall be determined using the procedures in <PRTPAGE P="152"/>paragraphs (c)(1) through (4) of this section, unless a recovery device is used. Slabstock foam production sources using recovery devices shall determine actual source-wide HAP emissions in accordance with paragraph (e) of this section. The allowable HAP emission level for a consecutive 12-month period shall be determined using the procedures in paragraph (d) of this section.</P> <P>(b) <E T="03">Monthly compliance alternative.</E> As an alternative to determining compliance on a rolling annual basis, an owner or operator can determine compliance by comparing actual HAP emissions to allowable HAP emissions for each month. The allowable source-wide emission level is calculated based on the production for the month, resulting in a potentially different allowable level each month. The actual monthly emission level shall be determined using the procedures in paragraphs (c)(1) through (3) of this section, unless a recovery device is used. Slabstock foam production sources using recovery devices shall determine actual source-wide HAP emissions in accordance with paragraph (e) of this section. The allowable monthly HAP ABA emission level shall be determined in accordance with Equation 6.</P> <P>(c) <E T="03">Procedures for determining actual source-wide HAP emissions.</E> The actual source-wide HAP ABA storage and equipment leak emissions, HAP ABA emissions from the production line, and equipment cleaning HAP emissions shall be determined using the procedures in this section. Actual source-wide HAP emissions for each individual month shall be determined using the procedures specified in paragraphs (c)(1) through (3) of this section.</P> <P>(1) Actual source-wide HAP emissions for a month shall be determined using Equation 5 and the information determined in accordance with paragraphs (c)(2) and (3) of this section.</P> <GPH DEEP="29" SPAN="2"> <GID>ER07OC98.007</GID> </GPH> <FP SOURCE="FP-2">Where:</FP> <FP SOURCE="FP-2">PWE<E T="52">actual</E> = Actual source-wide HAP ABA and equipment cleaning HAP emissions for a month, pounds/month.</FP> <FP SOURCE="FP-2">n = Number of HAP ABA storage vessels.</FP> <FP SOURCE="FP-2">ST<E T="52">i, begin</E> = Amount of HAP ABA in storage vessel i at the beginning of the month, pounds, determined in accordance with the procedures listed in paragraph (c)(2) of this section.</FP> <FP SOURCE="FP-2">ST<E T="52">i, end</E> = Amount of HAP ABA in storage vessel i at the end of the month, pounds, determined in accordance with the procedures listed in paragraph (c)(2) of this section.</FP> <FP SOURCE="FP-2">ADD<E T="52">i</E> = Amount of HAP ABA added to storage vessel i during the month, pounds, determined in accordance with the procedures listed in paragraph (c)(3) of this section.</FP> <P>(2) The amount of HAP ABA in a storage vessel shall be determined by monitoring the HAP ABA level in the storage vessel in accordance with § 63.1303(d).</P> <P>(3) The amount of HAP ABA added to a storage vessel for a given month shall be the sum of the amounts of all individual HAP ABA deliveries that occur during the month. The amount of each individual HAP ABA delivery shall be determined in accordance with § 63.1303(e).</P> <P>(4) Actual source-wide HAP emissions for each consecutive 12-month period shall be calculated as the sum of actual monthly source-wide HAP emissions for each of the individual 12 months in the period, calculated in accordance with paragraphs (c) (1) through (3) of this section.</P> <P>(d) Allowable source-wide HAP emissions for a consecutive 12-month period shall be calculated as the sum of allowable monthly source-wide HAP emissions for each of the individual 12 months in the period. Allowable <PRTPAGE P="153"/>source-wide HAP emissions for each individual month shall be calculated using Equation 6.</P> <GPH DEEP="33" SPAN="2"> <GID>ER07OC98.008</GID> </GPH> <FP SOURCE="FP-2">Where:</FP> <FP SOURCE="FP-2">emiss<E T="52">allow, month</E> = Allowable HAP ABA storage and equipment leak emissions, HAP ABA emissions from the production line, and equipment cleaning HAP emissions from the slabstock foam production source for the month, pounds.</FP> <FP SOURCE="FP-2">m = Number of slabstock foam production lines.</FP> <FP SOURCE="FP-2">polyol<E T="52">i</E> = Amount of polyol used in the month in the production of foam grade i on foam production line j, determined in accordance with § 63.1303(b), pounds.</FP> <FP SOURCE="FP-2">n = Number of foam grades produced in the month on foam production line j.</FP> <FP SOURCE="FP-2">limit<E T="52">i</E> = HAP ABA formulation limit for foam grade i, parts HAP ABA per 100 parts polyol. The HAP ABA formulation limits are determined in accordance with § 63.1297(d).</FP> <P>(e) <E T="03">Compliance using recovery devices.</E> If a recovery device is used to comply with paragraphs (a) or (b) of this section, the owner or operator shall determine the allowable source-wide HAP emissions for each month using Equation 6 in paragraph (d) of this section, and the actual monthly source-wide HAP emissions in accordance with paragraph (e)(1) of this section. The owner or operator shall also comply with the provisions of paragraph (e)(2) of this section.</P> <P>(1) Actual monthly source-wide HAP emissions shall be determined using Equation 7.</P> <GPH DEEP="13" SPAN="2"> <GID>ER07OC98.009</GID> </GPH> <FP SOURCE="FP-2">Where:</FP> <FP SOURCE="FP-2">E<E T="52">actual</E> = Actual source-wide HAP emissions after control, pounds/month.</FP> <FP SOURCE="FP-2">E<E T="52">unc</E> = Uncontrolled source-wide HAP emissions, pounds/month, determined in accordance with paragraph (c) (1) through (3) of this section.</FP> <FP SOURCE="FP-2">HAPABA<E T="52">recovered</E> = HAP ABA recovered, pounds/month, determined in accordance with paragraph (e)(2) of this section.</FP> <P>(2) The amount of HAP ABA recovered shall be determined in accordance with § 63.1303(c).</P> </SECTION> <SECTION> <SECTNO>§ 63.1300</SECTNO> <SUBJECT>Standards for molded flexible polyurethane foam production.</SUBJECT> <P>Each owner or operator of a new or existing molded affected source shall comply with the provisions in paragraphs (a) and (b) of this section.</P> <P>(a) A HAP or HAP-based material shall not be used as an equipment cleaner to flush the mixhead, nor shall it be used elsewhere as an equipment cleaner in a molded flexible polyurethane foam process, with the following exception. Diisocyanates may be used to flush the mixhead and associated piping during periods of startup or maintenance, provided that the diisocyanate compounds are contained in a closed-loop system and are re-used in production.</P> <P>(b) A HAP-based mold release agent shall not be used in a molded flexible polyurethane foam source process.</P> </SECTION> <SECTION> <SECTNO>§ 63.1301</SECTNO> <SUBJECT>Standards for rebond foam production.</SUBJECT> <P>Each owner or operator of a new or existing rebond foam affected source <PRTPAGE P="154"/>shall comply with the provisions in paragraphs (a) and (b) of this section.</P> <P>(a) A HAP or HAP-based material shall not be used as an equipment cleaner at a rebond foam source.</P> <P>(b) A HAP-based mold release agent shall not be used in a rebond foam source.</P> </SECTION> <SECTION> <SECTNO>§ 63.1302</SECTNO> <SUBJECT>Applicability of subpart A requirements.</SUBJECT> <P>The owner or operator of an affected source shall comply with the applicable requirements of subpart A of this part, as specified in Table 2 of this subpart.</P> </SECTION> <SECTION> <SECTNO>§ 63.1303</SECTNO> <SUBJECT>Monitoring requirements.</SUBJECT> <P>Owners and operators of affected sources shall comply with each applicable monitoring provision in this section.</P> <P>(a) <E T="03">Monitoring requirements for storage vessel carbon adsorption systems.</E> Each owner or operator using a carbon adsorption system to meet the requirements of § 63.1294(a) or § 63.1295 shall monitor the concentration level of the HAP or the organic compounds in the exhaust vent stream (or outlet stream exhaust) from the carbon adsorption system at the frequency specified in (a)(1) or (2) of this section in accordance with either (a)(3) or (4) of this section.</P> <P>(1) The concentration level of HAP or organic compounds shall be monitored during each unloading event, or once per month during an unloading event if multiple unloading events occur in a month.</P> <P>(2) As an alternative to monthly monitoring, the owner or operator can set the monitoring frequency at an interval no greater than 20 percent of the carbon replacement interval, which is established using a design analysis described below in paragraphs (a)(1)(i) through (iii) of this section.</P> <P>(i) The design analysis shall consider the vent stream composition, constituent concentration, flow rate, relative humidity, and temperature.</P> <P>(ii) The design analysis shall establish the outlet organic concentration level, the capacity of the carbon bed, and the working capacity of activated carbon used for the carbon bed, and</P> <P>(iii) The design analysis shall establish the carbon replacement interval based on the total carbon working capacity of the carbon adsorption system and the schedule for filling the storage vessel.</P> <P>(3) Measurements of HAP concentration shall be made using 40 CFR part 60, appendix A, Method 18. The measurement shall be conducted over at least one 5-minute interval during which the storage vessel is being filled.</P> <P>(4) Measurements of organic compounds shall be made using 40 CFR part 60, Appendix A, Method 25A. The measurement shall be conducted over at least one 5-minute interval during which the storage vessel is being filled.</P> <P>(b) <E T="03">Monitoring for HAP ABA and polyol added to the foam production line at the mixhead.</E> (1) The owner or operator of each slabstock affected source shall comply with the provisions in paragraph (b)(1)(i) of this section, and, if applicable, the provisions of paragraph (b)(1)(ii) of this section. Alternatively, the owner or operator may comply with paragraph (b)(5) of this section.</P> <P>(i) Owners or operators of all slabstock affected sources shall continuously monitor the amount of polyol added at the mixhead when foam is being poured, in accordance with paragraphs (b)(2) through (4) of this section.</P> <P>(ii) Owners or operators of slabstock foam affected sources using the emission point specific limitation option provided in § 63.1293(a)(1) shall continuously monitor the amount of HAP ABA added at the mixhead when foam is being poured, in accordance with paragraphs (b)(2)(ii), (b)(3), and (b)(4) of this section.</P> <P>(2) The owner or operator shall monitor either:</P> <P>(i) Pump revolutions; or</P> <P>(ii) Flow rate.</P> <P>(3) The device used to monitor the parameter from paragraph (b)(2) shall have an accuracy to within +/−2.0 percent of the HAP ABA being measured, and shall be calibrated initially, and periodically, in accordance with paragraph (b)(3)(i) or (ii) of this section.</P> <P>(i) For polyol pumps, the device shall be calibrated at least once each 6 months.<PRTPAGE P="155"/> </P> <P>(ii) For HAP ABA pumps, the device shall be calibrated at least once each month.</P> <P>(4) Measurements must be recorded at the beginning and end of the production of each grade of foam within a run of foam.</P> <P>(5) As an alternative to the monitoring described in paragraphs (b)(2) through (4) of this section, the owner or operator may develop an alternative monitoring program. Alternative monitoring programs must be submitted to the Administrator for approval in the Precompliance Report as specified in § 63.1306(c)(4) for existing sources or in the Application for approval of construction or reconstruction for new sources. If an owner or operator wishes to develop an alternative monitoring program after the compliance date, the program shall be submitted to the Administrator for approval before the owner or operator wishes to begin using the alternative program. If the Administrator does not notify the owner or operator of objections to the program, or any part of the program, within 45 days after its receipt, the program shall be deemed approved. Until the program is approved, the owner or operator of an affected source remains subject to the requirements of this subpart. The components of an alternative monitoring program shall include, at a minimum, the items listed in paragraphs (b)(5)(i) through (iv) of this section.</P> <P>(i) A description of the parameter to be continuously monitored when foam is being poured to measure the amount of HAP ABA or polyol added at the mixhead.</P> <P>(ii) A description of how the monitoring results will be recorded, and how the results will be converted into amount of HAP ABA or polyol delivered to the mixhead.</P> <P>(iii) Data demonstrating that the monitoring device is accurate to within +/−2.0 percent.</P> <P>(iv) Procedures to ensure that the accuracy of the parameter monitoring results is maintained. These procedures shall, at a minimum, consist of periodic calibration of all monitoring devices.</P> <P>(c) <E T="03">Recovered HAP ABA monitoring.</E> The owner or operator of each slabstock affected source using a recovery device to reduce HAP ABA emissions shall develop and comply with a recovered HAP ABA monitoring and recordkeeping program. The components of these plans shall include, at a minimum, the items listed in paragraphs (c)(1) through (5) of this section. These plans must be submitted for approval in accordance with paragraph (c)(6) of this section.</P> <P>(1) A device, installed, calibrated, maintained, and operated according to the manufacturer's specifications, that indicates the cumulative amount of HAP ABA recovered by the solvent recovery device over each 1-month period. The device shall be certified by the manufacturer to be accurate to within +/−2.0 percent.</P> <P>(2) The location where the monitoring will occur shall ensure that the measurements are taken after HAP ABA has been fully recovered (i.e., after separation from water introduced into the HAP ABA during regeneration).</P> <P>(3) A description of the parameter to be monitored, and the times the parameter will be monitored.</P> <P>(4) Data demonstrating that the monitoring device is accurate to within +/−2.0 percent.</P> <P>(5) Procedures to ensure that the accuracy of the parameter monitoring results is maintained. These procedures shall, at a minimum, consist of periodic calibration of all monitoring devices.</P> <P>(6) Recovered HAP ABA monitoring and recordkeeping programs must be submitted to the Administrator for approval in the Precompliance Report as specified in § 63.1306(c)(6) for existing sources or in the Application for approval of construction or reconstruction for new sources. If an owner or operator wishes to develop a recovered HAP ABA monitoring program after the compliance date, the program shall be submitted to the Administrator for approval before the owner or operator wishes to begin using the program. If the Administrator does not notify the owner or operator of objections to the program within 45 days after its receipt, the program shall be deemed approved. Until the program is approved, the owner or operator of an affected <PRTPAGE P="156"/>source remains subject to the requirements of this subpart.</P> <P>(d) <E T="03">Monitoring of HAP ABA in a storage vessel.</E> The amount of HAP ABA in a storage vessel shall be determined weekly by monitoring the HAP ABA level in the storage vessel using a level measurement device that meets the criteria described in paragraphs (d)(1) and either (d)(2) or (d)(3) of this section.</P> <P>(1) The level measurement device must be calibrated initially and at least once per year thereafter.</P> <P>(2) With the exception of visually-read level measurement devices (i.e., gauge glass), the device must have either a digital or printed output.</P> <P>(3) If the level measurement device is a visually-read device, the device must be equipped with permanent graduated markings to indicate HAP ABA level in the storage tank.</P> <P>(e) <E T="03">Monitoring of HAP ABA added to a storage vessel.</E> The amount of HAP ABA added to a storage vessel during a delivery shall be determined in accordance with either paragraphs (e)(1), (2), (3), or (4) of this section.</P> <P>(1) The volume of HAP ABA added to the storage vessel shall be determined by recording the volume in the storage vessel prior to the delivery and the volume after the delivery, provided that the storage tank level measurement device used to determine the levels meets the criteria in (d) of this section.</P> <P>(2) The volume of HAP ABA added to the storage vessel shall be determined by monitoring the flow rate using a device with an accuracy of <E T="61">±</E> 2.0 percent, and calibrated initially and at least once each six months thereafter.</P> <P>(3) The weight of HAP ABA added to the storage vessel shall be calculated as the difference of the full weight of the transfer vehicle prior to unloading into the storage vessel and the empty weight of the transfer vehicle after unloading into the storage vessel. The weight shall be determined using a scale meeting the requirements of either paragraph (e)(2)(i) or (ii) of this section.</P> <P>(i) A scale approved by the State or local agencies using the procedures contained in Handbook 44, Specifications, Tolerances, and Other Technical Requirements for Weighing and Measuring Devices 1998 (incorporation by reference—see § 63.14).</P> <P>(ii) A scale determined to be in compliance with the requirements of the National Institute of Standards and Technology Handbook 44 at least once per year by a registered scale technician.</P> <P>(4) As an alternative to the monitoring options described in paragraphs (e)(1) through (e)(3) of this section, the owner or operator may develop an alternative monitoring program. Alternative monitoring programs must be submitted to the Administrator for approval in the Precompliance Report as specified in § 63.1306(c)(4) for existing sources or in the Application for approval of construction or reconstruction for new sources. If an owner or operator wishes to develop an alternative monitoring program after the compliance date, the program shall be submitted to the Administrator for approval before the owner or operator wishes to begin using the alternative program. If the Administrator does not notify the owner or operator of objections to the program within 45 days after its receipt, the program shall be deemed approved. Until the program is approved, the owner or operator of an affected source remains subject to the requirements of this subpart. The components of an alternative monitoring program shall include, at a minimum, the items listed in paragraphs (e)(3)(i) through (iv) of this section.</P> <P>(i) A description of the parameter to be monitored to determine the amount of HAP ABA added to the storage vessel during a delivery,</P> <P>(ii) A description of how the results will be recorded, and how the results will be converted into the amount of HAP ABA added to the storage vessel during a delivery,</P> <P>(iii) Data demonstrating that the monitoring device is accurate to within <E T="61">±</E> 2.0 percent, and</P> <P>(iv) Procedures to ensure that the accuracy of the monitoring measurements is maintained. These procedures shall, at a minimum, consist of periodic calibration of all monitoring devices.</P> </SECTION> <SECTION> <PRTPAGE P="157"/> <SECTNO>§ 63.1304</SECTNO> <SUBJECT>Testing requirements.</SUBJECT> <P>Owners and operators of affected sources shall use the test methods listed in this section, as applicable, to demonstrate compliance with this subpart.</P> <P>(a) <E T="03">Test method and procedures to determine equipment leaks.</E> Monitoring, as required under § 63.1296, shall comply with the following requirements:</P> <P>(1) Monitoring shall comply with Method 21 of 40 CFR part 60, appendix A.</P> <P>(2) The detection instrument shall meet the performance criteria of Method 21 of 40 CFR part 60, appendix A, except that the instrument response factor criteria in section 3.1.2(a) of Method 21 shall be for the average composition of the source fluid, rather than for each individual VOC in the stream. For source streams that contain nitrogen, air, or other inerts which are not HAP or VOC, the average stream response factor shall be calculated on an inert-free basis. The response factor may be determined at any concentration for which monitoring for leaks will be conducted.</P> <P>(3) The instrument shall be calibrated before use on each day of its use by the procedures specified in Method 21 of 40 CFR part 60, appendix A.</P> <P>(4) Calibration gases shall be:</P> <P>(i) Zero air (less than 10 ppm of hydrocarbon in air); and</P> <P>(ii) A mixture of methane and air at a concentration of approximately, 1,000 ppm for all transfer pumps; and 500 ppm for all other equipment, except as provided in paragraph (a)(4)(iii) of this section.</P> <P>(iii) The instrument may be calibrated at a higher methane concentration (up to 2,000 ppm) than the leak definition concentration for a specific piece of equipment for monitoring that piece of equipment. If the monitoring instrument's design allows for multiple calibration gas concentrations, then the lower concentration calibration gas shall be no higher than 2,000 ppm methane and the higher concentration calibration gas shall be no higher than 10,000 ppm methane.</P> <P>(5) Monitoring shall be performed when the equipment is in HAP ABA service, in use with an acceptable surrogate volatile organic compound which is not a HAP ABA, or is in use with any other detectable gas or vapor.</P> <P>(6) If no instrument is available onsite that will meet the performance criteria specified in section 3.1.2(a) of Method 21 of 40 CFR Part 60, appendix A, the readings from an available instrument may be adjusted by multiplying by the average response factor for the stream.</P> <P>(b) <E T="03">Test method to determine foam properties.</E> The IFD and density of each grade of foam produced during each run of foam shall be determined using ASTM D3574-91, Standard Test Methods for Flexible Cellular Materials—Slab, Bonded, and Molded (incorporation by reference—see § 63.14), using a sample of foam cut from the center of the foam bun. The maximum sample size for which the IFD and density is determined shall not be larger than 24 inches by 24 inches by 4 inches. For grades of foam where the owner or operator has designated the HAP ABA formulation limitation as zero, the owner or operator is not required to determine the IFD and density in accordance with this paragraph.</P> </SECTION> <SECTION> <SECTNO>§ 63.1305</SECTNO> <SUBJECT>Alternative means of emission limitation.</SUBJECT> <P>An owner or operator of an affected source may request approval to use an alternative means of emission limitation, following the procedures in this section.</P> <P>(a) The owner or operator can request approval to use an alternative means of emission limitation in the precompliance report for existing sources, the application for construction or reconstruction for new sources, or at any time.</P> <P>(b) This request shall include a complete description of the alternative means of emission limitation.</P> <P>(c) Each owner or operator applying for permission to use an alternative means of emission limitation under § 63.6(g) shall be responsible for collecting and verifying data to demonstrate the emission reduction achieved by the alternative means of emission limitation.</P> <P>(d) Use of the alternative means of emission limitation shall not begin <PRTPAGE P="158"/>until approval is granted by the Administrator in accordance with § 63.6(g).</P> </SECTION> <SECTION> <SECTNO>§ 63.1306</SECTNO> <SUBJECT>Reporting requirements.</SUBJECT> <P>Owners and operators of affected sources shall comply with each applicable reporting provision in this section.</P> <P>(a) <E T="03">Initial notification.</E> Each affected source shall submit an initial notification in accordance with § 63.9(b).</P> <P>(b) <E T="03">Application for approval of construction or reconstruction.</E> Each owner or operator shall submit an application for approval of construction or reconstruction in accordance with the provisions of § 63.5(d).</P> <P>(c) <E T="03">Precompliance report.</E> Each slabstock affected source shall submit a precompliance report no later than 12 months before the compliance date. This report shall contain the information listed in paragraphs (c)(1) through (c)(8) of this section, as applicable.</P> <P>(1) Whether the source will comply with the emission point specific limitations described in § 63.1293(a), or with the source-wide emission limitation described in § 63.1293(b).</P> <P>(2) For a source complying with the emission point specific limitations, whether the source will comply on a rolling annual basis in accordance with § 63.1297(b), or will comply with the monthly alternative for compliance contained in § 63.1297(c).</P> <P>(3) For a source complying with the source-wide emission limitation, whether the source will comply on a rolling annual basis in accordance with § 63.1299(a), or will comply with the monthly alternative for compliance contained in § 63.1299(b).</P> <P>(4) A description of how HAP ABA and/or polyol added at the mixhead will be monitored. If the owner or operator is developing an alternative monitoring program, the alternative monitoring program containing the information in § 63.1303(b)(5)(i) through (iv) shall be submitted.</P> <P>(5) Notification of the intent to use a recovery device to comply with the provisions of § 63.1297 or § 63.1299.</P> <P>(6) For slabstock affected sources complying with § 63.1297 or § 63.1299 using a recovery device, the continuous recovered HAP ABA monitoring and recordkeeping program, developed in accordance with § 63.1303(c).</P> <P>(7) For sources complying with the source-wide emission limitation, a description of how the amount of HAP ABA in a storage vessel shall be determined.</P> <P>(8) For sources complying with the source-wide emission limitation, a description of how the amount of HAP ABA added to a storage vessel during a delivery will be monitored. If the owner or operator is developing an alternative monitoring program, the alternative monitoring program containing the information in § 63.1303(e)(4)(i) through (iv) shall be submitted.</P> <P>(9) If the Administrator does not notify the owner or operator of objections to an alternative monitoring program submitted in accordance with (c)(4) or (c)(6) of this section, or a recovered HAP ABA monitoring and recordkeeping program submitted in accordance with (c)(7) of this section, the program shall be deemed approved 45 days after its receipt by the Administrator.</P> <P>(d) <E T="03">Notification of compliance status.</E> Each affected source shall submit a notification of compliance status report no later than 180 days after the compliance date. For slabstock affected sources, this report shall contain the information listed in paragraphs (d)(1) through (3) of this section, as applicable. This report shall contain the information listed in paragraph (d)(4) of this section for molded foam processes and in paragraph (d)(5) for rebond foam processes.</P> <P>(1) A list of diisocyanate storage vessels, along with a record of the type of control utilized for each storage vessel.</P> <P>(2) For transfer pumps in diisocyanate service, a record of the type of control utilized for each transfer pump.</P> <P>(3) If the source is complying with the emission point specific limitations of §§ 63.1294 through 63.1298, the information listed in paragraphs (b)(3)(i) through (iii) of this section.</P> <P>(i) A list of HAP ABA storage vessels, along with a record of the type of control utilized for each storage vessel.</P> <P>(ii) A list of pumps, valves, connectors, pressure-relief devices, and open-<PRTPAGE P="159"/>ended valves or lines in HAP ABA service.</P> <P>(iii) A list of any modifications to equipment in HAP ABA service made to comply with the provisions of § 63.1296.</P> <P>(4) A statement that the molded foam affected source is in compliance with § 63.1300, or a statement that molded foam processes at an affected source are in compliance with § 63.1300.</P> <P>(5) A statement that the rebond foam affected source is in compliance with § 63.1301, or that rebond processes at an affected source are in compliance with § 63.1301.</P> <P>(e) <E T="03">Semiannual reports.</E> Each slabstock affected source shall submit a report containing the information specified in paragraphs (e)(1) through (5) of this section semiannually no later than 60 days after the end of each 180 day period. The first report shall be submitted no later than 240 days after the date that the Notification of Compliance Status is due and shall cover the 6-month period beginning on the date that the Notification of Compliance Status Report is due.</P> <P>(1) For slabstock affected sources complying with the rolling annual compliance provisions of either § 63.1297 or § 63.1299, the allowable and actual HAP ABA emissions (or allowable and actual source-wide HAP emissions) for each of the 12-month periods ending on each of the six months in the reporting period. This information is not required to be included in the initial semi-annual compliance report.</P> <P>(2) For sources complying with the monthly compliance alternative of either § 63.1297 or § 63.1299, the allowable and actual HAP ABA emissions (or allowable and actual source-wide HAP emissions) for each of the six months in the reporting period.</P> <P>(3) For sources complying with the storage vessel provisions of § 63.1294(a) or § 63.1295 using a carbon adsorption system, unloading events that occurred after breakthrough was detected and before the carbon was replaced.</P> <P>(4) Any equipment leaks that were not repaired in accordance with § 63.1294(b)(2)(iii), § 63.1294(c), § 63.1296(a)(2)(iii), (b)(2), (b)(3)(iv), (b)(4)(v), (c)(2), (c)(4)(ii), and (d)(2).</P> <P>(5) Any leaks in vapor return lines that were not repaired in accordance with § 63.1294(a)(1)(ii) or § 63.1295(b)(2).</P> <P>(f) <E T="03">Other reports.</E> (1) Change in selected emission limitation. An owner or operator electing to change their slabstock flexible polyurethane foam emission limitation (from emission point specific limitations to a source-wide emission limitation, or vice versa), selected in accordance with § 63.1293, shall notify the Administrator no later than 180 days prior to the change.</P> <P>(2) <E T="03">Change in selected compliance method.</E> An owner or operator changing the period of compliance for either § 63.1297 or § 63.1299 (between rolling annual and monthly) shall notify the Administrator no later than 180 days prior to the change.</P> <P>(g) <E T="03">Annual compliance certifications.</E> Each affected source subject to the provisions in §§ 63.1293 through 63.1301 shall submit a compliance certification annually.</P> <P>(1) The compliance certification shall be based on information consistent with that contained in § 63.1308 of this section, as applicable.</P> <P>(2) A compliance certification required pursuant to a State or local operating permit program may be used to satisfy the requirements of this section, provided that the compliance certification is based on information consistent with that contained in § 63.1308 of this section, and provided that the Administrator has approved the State or local operating permit program under part 70 of this chapter.</P> <P>(3) Each compliance certification submitted pursuant to this section shall be signed by a responsible official of the company that owns or operates the affected source.</P> </SECTION> <SECTION> <SECTNO>§ 63.1307</SECTNO> <SUBJECT>Recordkeeping requirements.</SUBJECT> <P>The applicable records designated in paragraphs (a) through (c) of this section shall be maintained by owners and operators of all affected sources.</P> <P>(a) <E T="03">Storage vessel records.</E> (1) A list of diisocyanate storage vessels, along with a record of the type of control utilized for each storage vessel.</P> <P>(2) For each slabstock affected source complying with the emission point specific limitations of §§ 63.1294 through <PRTPAGE P="160"/>63.1298, a list of HAP ABA storage vessels, along with a record of the type of control utilized for each storage vessel.</P> <P>(3) For storage vessels complying through the use of a carbon adsorption system, paragraph (a)(3)(i) or (ii), and paragraph (a)(3)(iii) of this section.</P> <P>(i) Records of dates and times when the carbon adsorption system is monitored for carbon breakthrough and the monitoring device reading, when the device is monitored in accordance with § 63.1303(a); or</P> <P>(ii) For affected sources monitoring at an interval no greater than 20 percent of the carbon replacement interval, in accordance with § 63.1303(a)(2), the records listed in paragraphs (a)(3)(ii)(A) and (B) of this section.</P> <P>(A) Records of the design analysis, including all the information listed in § 63.1303(a)(2)(i) through (iii), and</P> <P>(B) Records of dates and times when the carbon adsorption system is monitored for carbon breakthrough and the monitoring device reading.</P> <P>(iii) Date when the existing carbon in the carbon adsorption system is replaced with fresh carbon.</P> <P>(4) For storage vessels complying through the use of a vapor return line, paragraphs (a)(4)(i) through (iii) of this section.</P> <P>(i) Dates and times when each unloading event occurs and each inspection of the vapor return line for leaks occurs.</P> <P>(ii) Records of dates and times when a leak is detected in the vapor return line.</P> <P>(iii) Records of dates and times when a leak is repaired.</P> <P>(b) <E T="03">Equipment leak records.</E> (1) A list of components as specified below in paragraphs (b)(1)(i) and (ii).</P> <P>(i) For all affected sources, a list of components in diisocyanate service,</P> <P>(ii) For affected sources complying with the emission point specific limitations of §§ 63.1294 through 63.1298, a list of components in HAP ABA service.</P> <P>(2) For transfer pumps in diisocyanate service, a record of the type of control utilized for each transfer pump and the date of installation.</P> <P>(3) When a leak is detected as specified in § 63.1294(b)(2)(ii), § 63.1294(c), § 63.1296(a)(2), (b)(1), (c)(1), and (d)(1), the requirements listed in paragraphs (b)(3)(i) and (ii) of this section apply:</P> <P>(i) Leaking equipment shall be identified in accordance with the requirements in paragraphs (b)(3)(i)(A) through (C) of this section.</P> <P>(A) A readily visible identification, marked with the equipment identification number, shall be attached to the leaking equipment.</P> <P>(B) The identification on a valve may be removed after it has been monitored for 2-successive quarters as specified in § 63.1296(b)(1) and no leak has been detected during those 2 quarters.</P> <P>(C) The identification on equipment, other than a valve, may be removed after it has been repaired.</P> <P>(ii) The information in paragraphs (b)(2)(ii)(A) through (H) shall be recorded for leaking components.</P> <P>(A) The instrument and operator identification numbers and the equipment identification number.</P> <P>(B) The date the leak was detected and the dates of each attempt to repair the leak.</P> <P>(C) Repair methods applied in each attempt to repair the leak.</P> <P>(D) The words “above leak definition” if the maximum instrument reading measured by the methods specified in § 63.1304(a) after each repair attempt is equal or greater than the leak definitions for the specified equipment.</P> <P>(E) The words “repair delayed” and the reason for the delay if a leak is not repaired within 15 calendar days after discovery of the leak.</P> <P>(F) The expected date of the successful repair of the leak if a leak is not repaired within 15 calendar days.</P> <P>(G) The date of successful repair of the leak.</P> <P>(H) The date the identification is removed.</P> <P>(c) <E T="03">HAP ABA records</E>—(1) <E T="03">Emission point specific limitations—rolling annual compliance and monthly compliance alternative records.</E> Each slabstock affected source complying with the emission point specific limitations of §1A63.1294 through 63.1298, and the rolling annual compliance provisions of § 63.1297(a)(1), shall maintain the records listed in paragraphs (c)(1)(i), (ii), (iii), and (iv) of this section. Each flexible polyurethane foam slabstock source complying with the emission point specific <PRTPAGE P="161"/>limitations of §§ 63.1294 through 63.1298, and the monthly compliance alternative of § 63.1297(a)(2), shall maintain the records listed in paragraphs (c)(1)(i), (ii), and (iv) of this section.</P> <P>(i) Daily records of the information listed below in paragraphs (c)(1)(i)(A) through (C) of this section.</P> <P>(A) A log of foam runs each day. For each run, the log shall include a list of the grades produced during the run.</P> <P>(B) Results of the density and IFD testing for each grade of foam produced during each run of foam, conducted in accordance with the procedures in § 63.1304(b). The results of this testing shall be recorded within 10 working days of the production of the foam. For grades of foam where the owner or operator has designated the HAP ABA formulation limitation as zero, the owner or operator is not required to keep records of the IFD and density.</P> <P>(C) The amount of polyol added to the slabstock foam production line at the mixhead for each run of foam, determined in accordance with § 63.1303(b).</P> <P>(ii) Monthly records of the information listed in paragraphs (c)(1)(ii)(A) through (E) of this section.</P> <P>(A) A listing of all foam grades produced during the month,</P> <P>(B) For each foam grade produced, the HAP ABA formulation limitation, calculated in accordance with § 63.1297(d).</P> <P>(C) With the exception of those grades for which the owner or operator has designated zero as the HAP ABA formulation limitation, the total amount of polyol used in the month for each foam grade produced.</P> <P>(D) The total allowable HAP ABA emissions for the month, determined in accordance with § 63.1297(b)(2).</P> <P>(E) The total amount of HAP ABA added to the slabstock foam production line at the mixhead during the month, determined in accordance with § 63.1303(b).</P> <P>(iii) Each source complying with the rolling annual compliance provisions of § 63.1297(b) shall maintain the records listed in paragraphs (c)(1)(iii)(A) and (B) of this section.</P> <P>(A) The sum of the total allowable HAP ABA emissions for the month and the previous 11 months.</P> <P>(B) The sum of the total actual HAP ABA emissions for the month and the previous 11 months.</P> <P>(iv) Records of all calibrations for each device used to measure polyol and HAP ABA added at the mixhead, conducted in accordance with § 63.1303(b)(3).</P> <P>(2) <E T="03">Source-wide limitations—rolling annual compliance and monthly compliance alternative records.</E> Each slabstock affected source complying with the source-wide limitations of § 63.1299, and the rolling annual compliance provisions in § 63.1299(a), shall maintain the records listed in paragraphs (c)(2)(i) through (c)(2)(vii) of this section. Each flexible polyurethane foam slabstock source complying with the source-wide limitations of § 63.1299, and the monthly compliance alternative of § 63.1299(b), shall maintain the records listed in paragraphs (c)(2)(i) through (c)(2)(iii) and paragraphs (c)(2)(v) through (c)(2)(vii) of this section.</P> <P>(i) Daily records of the information listed in paragraphs (c)(2)(i)(A) through (C) of this section.</P> <P>(A) A log of foam runs each day. For each run, the log shall include a list of the grades produced during the run.</P> <P>(B) Results of the density and IFD testing for each grade of foam produced during each run of foam, conducted in accordance with the procedures in § 63.1304(b). The results of this testing shall be recorded within 10 working days of the production of the foam. For grades of foam where the the owner or operator has designated the HAP ABA formulation limitation as zero, the owner or operator is not required to keep records of the IFD and density.</P> <P>(C) With the exception of those grades for which the owner or operator has designated zero as the HAP ABA formulation limitation, the amount of polyol added to the slabstock foam production line at the mixhead for each grade produced during each run of foam, determined in accordance with § 63.1303(b).</P> <P>(ii) For sources complying with the source-wide emission limitation, weekly records of the storage tank level, determined in accordance with § 63.1303(d).<PRTPAGE P="162"/> </P> <P>(iii) Monthly records of the information listed below in paragraphs (c)(2)(iii)(A) through (E) of this section.</P> <P>(A) A listing of all foam grades produced during the month,</P> <P>(B) For each foam grade produced, the residual HAP formulation limitation, calculated in accordance with § 63.1297(d).</P> <P>(C) With the exception of those grades for which the owner or operator has designated zero as the HAP ABA formulation limitation, the total amount of polyol used in the month for each foam grade produced.</P> <P>(D) The total allowable HAP ABA and equipment cleaning emissions for the month, determined in accordance with § 63.1297(b)(2).</P> <P>(E) The total actual source-wide HAP ABA emissions for the month, determined in accordance with § 63.1299(c)(1), along with the information listed in paragraphs (c)(2)(iii)(E)(<E T="03">1</E>) and (<E T="03">2</E>) of this section.</P> <P>(<E T="03">1</E>) The amounts of HAP ABA in the storage vessel at the beginning and end of the month, determined in accordance with § 63.1299(c)(2); and</P> <P>(<E T="03">2</E>) The amount of each delivery of HAP ABA to the storage vessel, determined in accordance with § 63.1299(c)(3).</P> <P>(iv) Each source complying with the rolling annual compliance provisions of § 63.1299(a) shall maintain the records listed in paragraphs (c)(2)(iv)(A) and (B) of this section.</P> <P>(A) The sum of the total allowable HAP ABA and equipment cleaning HAP emissions for the month and the previous 11 months.</P> <P>(B) The sum of the total actual HAP ABA and equipment cleaning HAP emissions for the month and the previous 11 months.</P> <P>(v) Records of all calibrations for each device used to measure polyol added at the mixhead, conducted in accordance with § 63.1303(b)(3).</P> <P>(vi) Records of all calibrations for each device used to measure the amount of HAP ABA in the storage vessel, conducted in accordance with § 63.1303(d)(1).</P> <P>(vii) Records to verify that all scales used to measure the amount of HAP ABA added to the storage vessel meet the requirements of § 63.1303(e)(3). For scales meeting the criteria of § 63.1303(e)(3)(i), this documentation shall be in the form of written confirmation of the State or local approval. For scales complying with § 63.1303(e)(3)(ii), this documentation shall be in the form of a report provided by the registered scale technician.</P> <P>(d) The owner or operator of each affected source complying with § 63.1297 or § 63.1299 through the use of a recovery device shall maintain the following records:</P> <P>(1) A copy of the recovered HAP ABA monitoring and recordkeeping program, developed pursuant to § 63.1303(c);</P> <P>(2) Certification of the accuracy of the monitoring device,</P> <P>(3) Records of periodic calibration of the monitoring devices,</P> <P>(4) Records of parameter monitoring results, and</P> <P>(5) The amount of HAP ABA recovered each time it is measured.</P> <P>(e) The owner or operator of an affected source subject to § 63.1298 of this subpart shall maintain a product data sheet for each equipment cleaner used which includes the HAP content, in kg of HAP/kg solids (lb HAP/lb solids).</P> <P>(f) The owner or operator of an affected source following the compliance methods in § 63.1308(b)(1) and (c)(1) shall maintain records of each use of a vapor return line during unloading, of any leaks detected during unloading, and of repairs of leaks detected during unloading.</P> <P>(g) The owner or operator of an affected source subject to § 63.1300 or § 63.1301 of this subpart shall maintain a product data sheet for each compound other than diisocyanates used to flush the mixhead and associated piping during periods of startup or maintenance, which includes the HAP content, in kg of HAP/kg solids (lb HAP/lb solids), of each solvent other than diisocyanates used to flush the mixhead and associated piping during periods of startup or maintenance.</P> <P>(h) The owner or operator of an affected source subject to § 63.1300 or § 63.1301 of this subpart shall maintain a product data sheet for each mold release agent used that includes the HAP content, in kg of HAP/kg solids (lb <PRTPAGE P="163"/>HAP/lb solids), of each mold release agent.</P> </SECTION> <SECTION> <SECTNO>§ 63.1308</SECTNO> <SUBJECT>Compliance demonstrations.</SUBJECT> <P>(a) For each affected source, compliance with the requirements listed in paragraphs (a)(1) through (a)(2) of this section shall mean compliance with the requirements contained in §§ 63.1293 through 63.1301, absent any credible evidence to the contrary.</P> <P>(1) The requirements described in Tables 3, 4, and 5 of this subpart; and</P> <P>(2) The requirement to submit a compliance certification annually as required under § 63.1306(g).</P> <P>(b) <E T="03">All slabstock affected sources.</E> For slabstock affected sources, failure to meet the requirements contained in § 63.1294 shall be considered a violation of this subpart. Violation of each item listed in the paragraphs (b)(1) through (b)(6) of this section, as applicable, shall be considered a separate violation.</P> <P>(1) For each affected source complying with § 63.1294(a) in accordance with § 63.1294(a)(1), each unloading event that occurs when the diisocyanate storage vessel is not equipped with a vapor return line from the storage vessel to the tank truck or rail car, each unloading event that occurs when the vapor line is not connected, each unloading event that the vapor line is not inspected for leaks as described in § 63.1294(a)(1)(i), each unloading event that occurs after a leak has been detected and not repaired, and each calendar day after a leak is detected, but not repaired as soon as practicable;</P> <P>(2) For each affected source complying with § 63.1294(a) in accordance with § 63.1294(a)(2), each unloading event that the diisocyanate storage vessel is not equipped with a carbon adsorption system, each unloading event (or each month if more than one unloading event occurs in a month) that the carbon adsorption system is not monitored for breakthrough in accordance with § 63.1303(a)(3) or (4), and each unloading event that occurs when the carbon is not replaced after an indication of breakthrough;</P> <P>(3) For each affected source complying with § 63.1294(a) in accordance with § 63.1294(a)(2) through the alternative monitoring procedures in § 63.1303(a)(2), each unloading event that the diisocyanate storage vessel is not equipped with a carbon adsorption system, each time that the carbon adsorption system is not monitored for breakthrough in accordance with § 63.1303(a)(3) or (4) at the interval established in the design analysis, and each unloading event that occurs when the carbon is not replaced after an indication of breakthrough;</P> <P>(4) For each affected source complying with § 63.1294(b) in accordance with § 63.1294(b)(1), each calendar day that a transfer pump in diisocyanate service is not a sealless pump;</P> <P>(5) For each affected source complying with § 63.1294(b) in accordance with § 63.1294(b)(2), each calendar day that a transfer pump in diisocyanate service is not submerged as described in § 63.1294(b)(2)(i), each week that the pump is not visually monitored for leaks, each calendar day after 5 calendar days after detection of a leak that a first attempt at repair has not been made in accordance with § 63.1294(b)(2)(iii)(B), and the earlier of each calendar day after 15 calendar days after detection of a leak that a leak is not repaired, or a leak is not repaired as soon as practicable, each subsequent calender day (with the exception of situations meeting the criteria of § 63.1294(d));</P> <P>(6) For each affected source complying with § 63.1294(c), each calendar day after 5 calendar days after detection of a leak that a first attempt at repair has not been made, and the earlier of each calendar day after 15 calendar days after detection of a leak that a leak is not repaired, or if a leak is not repaired as soon as practicable, each subsequent calender day (with the exception of situations meeting the criteria of § 63.1296(f)).</P> <P>(c) <E T="03">Slabstock affected sources complying with the emission point specific limitations.</E> For slabstock affected sources complying with the emission point specific limitations as provided in § 63.1293(a), failure to meet the requirements contained in §§ 63.1295 through 63.1298 shall be considered a violation of this subpart. Violation of each item listed in the paragraphs (c)(1) through (c)(17) of this section, as applicable, <PRTPAGE P="164"/>shall be considered a separate violation.</P> <P>(1) For each affected source complying with § 63.1295(a) in accordance with § 63.1295(b), each unloading event that occurs when the HAP ABA storage vessel is not equipped with a vapor return line from the storage vessel to the tank truck or rail car, each unloading event that occurs when the vapor line is not connected, each unloading event that the vapor line is not inspected for leaks as described in § 63.1295(b)(1), each unloading event that occurs after a leak has been detected and not repaired, and each calendar day after a leak is detected but not repaired as soon as practicable;</P> <P>(2) For each affected source complying with § 63.1295(a) in accordance with § 63.1295(c), each unloading event that the HAP ABA storage vessel is not equipped with a carbon adsorption system, each unloading event (or each month if more than one unloading event occurs in a month) that the carbon adsorption system is not monitored for breakthrough in accordance with § 63.1303(a)(3) or (4), and each unloading event that occurs when the carbon is not replaced after an indication of breakthrough ;</P> <P>(3) For each affected source complying with § 63.1295(a) in accordance with § 63.1295(c) through the alternative monitoring procedures in § 63.1303(a)(2), each unloading event that the HAP ABA storage vessel is not equipped with a carbon adsorption system, each time that the carbon adsorption system is not monitored for breakthrough in accordance with § 63.1303(a)(3) or (4) at the interval established in the design analysis, and each unloading event that occurs when the carbon is not replaced after an indication of breakthrough;</P> <P>(4) For each affected source complying with § 63.1296(a) in accordance with § 63.1296(a)(1), each calendar day that a transfer pump in HAP ABA service is not a sealless pump;</P> <P>(5) For each affected source complying with § 63.1296(a) in accordance with § 63.1296(a)(2), each week that a visual inspection of a pump in HAP ABA service is not performed, each quarter that a pump in HAP ABA service is not monitored to detect leaks in accordance with § 63.1304(a), each calendar day after 5 calendar days after detection of a leak that a first attempt at repair has not been made in accordance with § 63.1296(b)(2)(iii)(B), and the earlier of each calendar day after 15 calendar days after detection of a leak that a leak is not repaired, or if a leak is not repaired as soon as practicable, each subsequent calender day (with the exception of situations meeting the criteria of § 63.1296(f));</P> <P>(6) For each affected source complying with § 63.1296(b) in accordance with § 63.1296(b)(1) and (2), each quarter that a valve in HAP ABA service is not monitored to detect leaks in accordance with § 63.1304(a), each calendar day after 5 calendar days after detection of a leak that a first attempt at repair has not been made in accordance with § 63.1296(b)(2)(ii), and each calendar day after 15 calendar days after detection of a leak that a leak is not repaired, or if a leak is not repaired as soon as practicable, whichever is earlier (with the exception of situations meeting the criteria of § 63.1296(f));</P> <P>(7) For each affected source complying with § 63.1296(b)(3) for each valve designated as unsafe to monitor as described in § 63.1296(b)(3)(i), failure to develop the written plan required by § 63.1296(b)(3)(ii), each period specified in the written plan that an unsafe-to-monitor valve in HAP ABA service is not monitored, and each calendar day in which a leak is not repaired in accordance with the written plan;</P> <P>(8) For each affected source complying with § 63.1296(b)(4) for one or more valves designated as difficult-to-monitor in accordance with § 63.1296(b)(4)(i) and (ii), failure to develop the written plan required by § 63.1296(b)(4)(iii), each calendar year that a difficult-to-monitor valve in HAP ABA service is not monitored, and each calendar day in which a leak is not repaired in accordance with the written plan;</P> <P>(9) For each affected source complying with § 63.1296(c) in accordance with § 63.1296(c)(1) and (2), each year that a connector in HAP ABA service is not monitored to detect leaks in accordance with § 63.1304(a); each calendar day after 3 months after a connector has been opened, has otherwise <PRTPAGE P="165"/>had the seal broken, or a leak is repaired, that each connector in HAP ABA service is not monitored to detect leaks in accordance with § 63.1304(a); each calendar day after 5 calendar days after detection of a leak that a first attempt at repair has not been made, and the earlier of each calendar day after 15 calendar days after detection of a leak that a leak is not repaired, or if a leak is not repaired as soon as practicable, each subsequent calendar day (with the exception of situations meeting the criteria of § 63.1296(f));</P> <P>(10) For each affected source complying with § 63.1296(c)(3) for one or more connectors designated as unsafe-to-monitor in accordance with § 63.1296(c)(3)(i), failure to develop the written plan required by § 63.1296(c)(3)(ii), each period specified in the written plan that an unsafe-to-monitor valve in HAP ABA service is not monitored, each calendar day after 5 calendar days after detection of a leak of an unsafe-to-monitor connector that a first attempt at repair has not been made, and the earlier of each calendar day after 15 calendar days after detection of a leak that a leak is not repaired, or if a leak is not repaired as soon as practicable, each subsequent calender day (with the exception of situations meeting the criteria of § 63.1296(f));</P> <P>(11) For each affected source complying with § 63.1296(c)(4) for one or more connectors designated as unsafe to repair, each year that one or more unsafe-to-repair connectors in HAP ABA service is not monitored to detect leaks in accordance with § 63.1304(a); each calendar day after 3 months after one or more unsafe-to-repair connectors has been opened, has otherwise had the seal broken, or a leak is repaired, that each unsafe-to-repair connector in HAP ABA service is not monitored to detect leaks in accordance with § 63.1304(a); and the earlier of each calendar day after six-months after detection of a leak that a leak is not repaired, or if a leak is not repaired as soon as practicable, each subsequent calendar day;</P> <P>(12) For each affected source complying with § 63.1296(d) in accordance with § 63.1296(d)(1) and (2), each calendar day after the 5 days that the pressure-relief device has not been monitored in accordance with § 63.1304(a) after a potential leak was discovered as described in § 63.1296(d)(1), each calendar day after 5 calendar days after detection of a leak that a first attempt at repair has not been made, and the earlier of each calendar day after 15 calendar days after detection of a leak that a leak is not repaired, or if a leak is detected and not repaired as soon as practicable, each subsequent calendar day (with the exception of situations meeting the criteria of § 63.1296(f));</P> <P>(13) For each affected source complying with § 63.1296(e) in accordance with § 63.1296(e)(1) through (5), each calendar day that an open-ended valve or line has no cap, blind flange, plug or second valve as described in § 63.1296(e)(2), and each calendar day that a valve on the process fluid end of an open-ended valve or line equipped with a second valve is not closed before the second valve is closed;</P> <P>(14) For each affected source complying with § 63.1297(a) in accordance with the rolling annual compliance option in § 63.1297(a)(1) and (b), each calendar day in the 12-month period for which the actual HAP ABA emissions exceeded the allowable HAP ABA emissions level, each calendar day in which foam is being poured where the amount of polyol added at the mixhead is not monitored (as required) in accordance with § 63.1303(b)(1)(i), each calendar day in which foam is being poured where the amount of HAP ABA added at the mixhead is not monitored (as required) in accordance with § 63.1303(b)(1)(ii), each calendar day in a 6-month period in which the polyol pumps are not calibrated in accordance with § 63.1303(b)(3)(i), each calendar day in a month in which the HAP ABA pumps are not calibrated in accordance with § 63.1303(b)(3)(ii), and each calendar day after 10 working days after production where the IFD and density of a foam grade are not determined (where required) in accordance with § 63.1304(b);</P> <P>(15) For each affected source complying with § 63.1297(a) in accordance with the monthly compliance option in § 63.1297(a)(2) and (c), each calendar day of each month for which the actual HAP ABA emissions exceeded the allowable HAP ABA emissions level for <PRTPAGE P="166"/>that month, each calendar day in which foam is being poured where the amount of polyol added at the mixhead is not monitored (as required) in accordance with § 63.1303(b)(1)(i), each calendar day in which foam is being poured where the amount of HAP ABA added at the mixhead is not monitored (as required) in accordance with § 63.1303(b)(1)(ii), each 6-month period in which the polyol pumps are not calibrated in accordance with § 63.1303(b)(3)(i), each month in which the HAP ABA pumps are not calibrated in accordance with § 63.1303(b)(3)(ii), and each calendar day after 10 working days after production where the IFD and density of a foam grade are not determined (where required) in accordance with § 63.1304(b);</P> <P>(16) For each affected source complying with § 63.1297(a) by using a recovery device as allowed under § 63.1297(e), the items listed in (c)(16)(i) or (ii) of this section, as applicable.</P> <P>(i) If complying with rolling annual compliance option in § 63.1297(a)(1) and (b), each item listed in (c)(14) of this section, failure to develop a recovered HAP ABA monitoring and recordkeeping program in accordance with § 63.1303(c), and each instance when an element of the program is not followed.</P> <P>(ii) If complying with the monthly compliance option in § 63.1297(a)(2) and (c), each item listed in (c)(15) of this section, failure to develop a recovered HAP ABA monitoring and recordkeeping program in accordance with § 63.1303(c), and each instance when an element of the program is not followed.</P> <P>(17) For each affected source complying with § 63.1298, each calendar day that a HAP or any HAP-based material is used as an equipment cleaner.</P> <P>(d) <E T="03">Slabstock affected sources complying with the source-wide emission limitation.</E> For slabstock affected sources complying with the source-wide emission limitation as provided in § 63.1293(b), failure to meet the requirements contained in § 63.1299 shall be considered a violation of this subpart. Violation of each item listed in the paragraphs (d)(1) through (d)(3) of this section, as applicable, shall be considered a separate violation.</P> <P>(1) For each affected source complying with § 63.1299 in accordance with the rolling annual compliance option in § 63.1299(a), each calendar day in the 12-month period for which the actual HAP ABA emissions exceeded the allowable HAP ABA emissions level, each calendar day in which foam is being poured where the amount of polyol added at the mixhead is not monitored (as required) in accordance with § 63.1303(b)(1)(i), each calendar day in a week in which the amount of HAP ABA in a storage vessel is not determined in accordance with § 63.1303(d), each delivery of HAP ABA in which the amount of HAP ABA added to the storage vessel is not determined in accordance with § 63.1303(e), each calendar day in a 6-month period in which the polyol pumps are not calibrated in accordance with § 63.1303(b)(3)(i), and each calendar day after 10 working days after production where the IFD and density of a foam grade are not determined (where required) in accordance with § 63.1304(b);</P> <P>(2) For each affected source complying with § 63.1299 in accordance with the monthly compliance option in § 63.1299(b), each calendar day of each month for which the actual HAP ABA emissions exceeded the allowable HAP ABA emissions level for that month, each calendar day in which foam is being poured where the amount of polyol added at the mixhead is not monitored (as required) in accordance with § 63.1303(b)(1)(i), each calendar day in a week in which the amount of HAP ABA in a storage vessel is not determined in accordance with § 63.1303(d), each delivery of HAP ABA in which the amount of HAP ABA added to the storage vessel is not determined in accordance with § 63.1303(e), and each calendar day in a 6-month period in which the polyol pumps are not calibrated in accordance with § 63.1303(b)(3)(i), and each calendar day after 10 working days after production where the IFD and density of a foam grade are not determined (where required) in accordance with § 63.1304(b).</P> <P>(3) For each affected source complying with § 63.1299 by using a recovery device as allowed under § 63.1299(e), the items listed in (d)(3)(i) or (ii) of this section, as applicable.</P> <P>(i) If complying with rolling annual compliance option in § 63.1299(a), each <PRTPAGE P="167"/>item listed in (d)(1) of this section, failure to develop a recovered HAP ABA monitoring and recordkeeping program in accordance with § 63.1303(c), and each instance when an element of the program is not followed.</P> <P>(ii) If complying with the monthly compliance option in § 63.1299(b), each item listed in (d)(2) of this section, failure to develop a recovered HAP ABA monitoring and recordkeeping program in accordance with § 63.1303(c), and each instance when an element of the program is not followed.</P> <P>(e) <E T="03">Molded and rebond foam affected sources.</E> For molded and rebond foam affected sources, failure to meet the requirements contained in § 63.1300 and § 63.1301, respectively, shall be considered a violation of this subpart. Violation of each item listed in the following paragraphs shall be considered a separate violation.</P> <P>(1) For each molded foam affected source subject to the provisions in § 63.1300(a), each calendar day that a HAP-based material is used as an equipment cleaner (except for diisocyanates used to flush the mixhead and associated piping during periods of startup or maintenance, provided that the diisocyanate compounds are contained in a closed-loop system and are re-used in production);</P> <P>(2) For each molded foam affected source subject to the provisions of § 63.1300(b), each calendar day that a HAP-base material is used as a mold release agent;</P> <P>(3) For each rebond foam affected source subject to the provisions of § 63.1301(a), each calendar day that a HAP-based material is used as an equipment cleaner; and</P> <P>(4) For each rebond foam affected source complying with § 63.1301(b), each calendar day that a HAP-based mold release agent is used.</P> </SECTION> <SECTION> <SECTNO>§ 63.1309</SECTNO> <SUBJECT>Delegation of authority.</SUBJECT> <P>(a) In delegating implementation and enforcement authority to a State under § 112(d) of the Clean Air Act, the authorities contained in paragraph (b) of this section shall be retained by the Administrator and not transferred to a State.</P> <P>(b) The authority conferred in § 63.1303(b)(5) and § 63.1305(d) shall not be delegated to any State.</P> </SECTION> <APPENDIX> <EAR>Pt. 63, Subpt. III, App.</EAR> <HD SOURCE="HED">Appendix to Subpart III—Tables</HD> <P>For the convenience of the readers of subpart III, the tables below summarize the requirements in §§ 63.1290 to 63.1307. These tables are intended to assist the reader in determining the requirements applicable to affected sources and do not alter an affected source's obligation to comply with the requirements in §§ 63.1290 to 63.1307.</P> <P>TABLE 1 TO SUBPART III—HAP ABA FORMULATION LIMITATIONS MATRIX FOR NEW SOURCES [see § 63.1297(d)(2)]</P> <GPH DEEP="288" SPAN="2"> <PRTPAGE P="168"/> <GID>ER07OC98.010</GID> </GPH> <GPOTABLE CDEF="xs120,11C,r100" COLS="3" OPTS="L2,i1"> <TTITLE> <E T="04">Table</E> 2 <E T="04">to Subpart III—Applicability of General Provisions (</E>40 <E T="04">CFR Part</E> 63, <E T="04">Subpart A) to Subpart III.</E> </TTITLE> <BOXHD> <CHED H="1">Subpart A reference</CHED> <CHED H="1">Applies to<LI>subpart III</LI> </CHED> <CHED H="1">Comment</CHED> </BOXHD> <ROW> <ENT I="01">§ 63.1</ENT> <ENT>YES</ENT> <ENT>Except that § 63.1(c)(2) is not applicable to the extent area sources are not subject to subpart III.</ENT> </ROW> <ROW> <ENT I="01">§ 63.2</ENT> <ENT>YES</ENT> <ENT>Definitions are modified and supplemented by § 63.1292.</ENT> </ROW> <ROW> <ENT I="01">§ 63.3</ENT> <ENT>YES</ENT> </ROW> <ROW> <ENT I="01">§ 63.4</ENT> <ENT>YES</ENT> </ROW> <ROW> <ENT I="01">§ 63.5</ENT> <ENT>YES</ENT> </ROW> <ROW> <ENT I="01">§ 63.6 (a)-(d)</ENT> <ENT>YES</ENT> </ROW> <ROW> <ENT I="01">§ 63.6(e) (1)-(2)</ENT> <ENT>YES</ENT> </ROW> <ROW> <ENT I="01">§ 63.6(e)(3)</ENT> <ENT>NO</ENT> <ENT>Owners and operators of subpart III affected sources are not required to develop and implement a startup, shutdown, and malfunction plan.</ENT> </ROW> <ROW> <ENT I="01">§ 63.6 (f)-(g)</ENT> <ENT>YES</ENT> </ROW> <ROW> <ENT I="01">§ 63.6(h)</ENT> <ENT>NO</ENT> <ENT>Subpart III does not require opacity and visible emission standards.</ENT> </ROW> <ROW> <ENT I="01">§ 63.6 (i)-(j)</ENT> <ENT>YES</ENT> </ROW> <ROW> <ENT I="01">§ 63.7</ENT> <ENT>NO</ENT> <ENT>Performance tests not required by subpart III.</ENT> </ROW> <ROW> <ENT I="01">§ 63.8</ENT> <ENT>NO</ENT> <ENT>Continuous monitoring, as defined in subpart A, is not required by subpart III.</ENT> </ROW> <ROW> <ENT I="01">§ 63.9 (a)-(d)</ENT> <ENT>YES</ENT> </ROW> <ROW> <ENT I="01">§ 63.9 (e)-(g)</ENT> <ENT>NO</ENT> </ROW> <ROW> <ENT I="01">§ 63.9(h)</ENT> <ENT>NO</ENT> <ENT>Subpart III specifies Notification of Compliance Status requirements.</ENT> </ROW> <ROW> <ENT I="01">§ 63.9 (i)-(j)</ENT> <ENT>YES</ENT> </ROW> <ROW> <ENT I="01">§ 63.10 (a)-(b)</ENT> <ENT>YES</ENT> <ENT>Except that the records specified in § 63.10(b)(2)(vi) through (xi) and (xiii) are not required.</ENT> </ROW> <ROW> <ENT I="01">§ 63.10(c)</ENT> <ENT>NO</ENT> </ROW> <ROW> <PRTPAGE P="169"/> <ENT I="01">§ 63.10(d)(1)</ENT> <ENT>YES</ENT> </ROW> <ROW> <ENT I="01">§ 63.10 (d) (2)-(3)</ENT> <ENT>NO</ENT> </ROW> <ROW> <ENT I="01">§ 63.10 (d) (4)-(5) </ENT> <ENT>YES</ENT> </ROW> <ROW> <ENT I="01">§ 63.10(e)</ENT> <ENT>NO</ENT> </ROW> <ROW> <ENT I="01">§ 63.10(f)</ENT> <ENT>YES</ENT> </ROW> <ROW> <ENT I="01">§ 63.11</ENT> <ENT>YES</ENT> </ROW> <ROW> <ENT I="01">§ 63.12</ENT> <ENT>YES</ENT> </ROW> <ROW> <ENT I="01">§ 63.13</ENT> <ENT>YES</ENT> </ROW> <ROW> <ENT I="01">§ 63.14</ENT> <ENT>YES</ENT> </ROW> <ROW> <ENT I="01">§ 63.15</ENT> <ENT>YES</ENT> </ROW> </GPOTABLE> <PRTPAGE P="170"/> <GPOTABLE CDEF="s50,r50,r50,r50,r75,r50" COLS="6" OPTS="L2,i1"> <TTITLE>Table 3 <E T="04">to Subpart III.—Compliance Requirements for Slabstock Foam Production Affected Sources Complying with the Emission Point Specific Limitations</E> </TTITLE> <BOXHD> <CHED H="1">Emission point</CHED> <CHED H="1">Emission point compliance option</CHED> <CHED H="1">Emission, work practice, and equipment standards</CHED> <CHED H="1">Monitoring</CHED> <CHED H="1">Recordkeeping</CHED> <CHED H="1">Reporting</CHED> </BOXHD> <ROW> <ENT I="11">Diisocyanate storage vessels § 63.1294(a)</ENT> <ENT>Vapor balance</ENT> <ENT>§ 63.1294(a)(1) and (1)(ii)</ENT> <ENT>§ 63.1294(a)(1)(i)</ENT> <ENT>§ 63.1307(a)(1) and (4)</ENT> <ENT>§ 63.1306(e)(5).</ENT> </ROW> <ROW> <ENT I="22"/> <ENT>Carbon adsorber</ENT> <ENT>§ 63.1294(a)(2)</ENT> <ENT>§ 63.1303(a)(1), (3), and (4)</ENT> <ENT>§ 63.1307(a)(1), (3)(i), and (3)(iii)</ENT> <ENT>§ 63.1306(e)(3).</ENT> </ROW> <ROW> <ENT I="22"/> <ENT>Carbon adsorber—alternative monitoring</ENT> <ENT>§ 63.1294(a)(2)</ENT> <ENT>§ 63.1303(a)(2), (3) and (4)</ENT> <ENT>§ 63.1307(a)(1), (3)(ii), and (3)(iii)</ENT> <ENT>§ 63.1306(e)(3).</ENT> </ROW> <ROW> <ENT I="11">Diisocyanate transfer pumps § 63.1294(b)</ENT> <ENT>Sealless pump</ENT> <ENT>§ 63.1294(b)(1)</ENT> <ENT/> <ENT>§ 63.1307 (b)(1)(i) and (2)</ENT> <ENT/> </ROW> <ROW> <ENT I="22"/> <ENT>Submerged pump</ENT> <ENT>§ 63.1294(b)(2)(i) and (iii)</ENT> <ENT>§ 63.1294 (b)(2)(ii)</ENT> <ENT>§ 63.1307 (b)(1)(i), (2), and (3)</ENT> <ENT>§ 63.1306(e)(4).</ENT> </ROW> <ROW> <ENT I="01">Other components in diisocyanate service § 63.1294(c)</ENT> <ENT>N/A</ENT> <ENT>§ 63.1294(c)</ENT> <ENT>§ 63.1294(c)</ENT> <ENT>§ 63.1307 (b)(1)(i) and (3)</ENT> <ENT>§ 63.1306(e)(4).</ENT> </ROW> <ROW> <ENT I="11">HAP ABA storage vessels § 63.1295</ENT> <ENT>Vapor balance</ENT> <ENT>§ 63.1295(b) and (b)(2)</ENT> <ENT>§ 63.1295 (b)(1)</ENT> <ENT>§ 63.1307(a)(2) and (4)</ENT> <ENT>§ 63.1306(e)(5).</ENT> </ROW> <ROW> <ENT I="22"/> <ENT>Carbon adsorber</ENT> <ENT>§ 63.1295(c)</ENT> <ENT>§ 63.1303(a)(1), (3), and (4)</ENT> <ENT>§ 63.1307(a)(2), (3)(i), (3)(iii)</ENT> <ENT>§ 63.1306(e)(3).</ENT> </ROW> <ROW> <ENT I="22"/> <ENT>Carbon adsorber—alternative monitoring</ENT> <ENT>§ 63.1295(c)</ENT> <ENT>§ 63.1303(a)(2), (3) and (4)</ENT> <ENT>§ 63.1307(a)(2), (3)(ii), and (3)(iii)</ENT> <ENT>§ 63.1306(e)(3).</ENT> </ROW> <ROW> <ENT I="11">HAP ABA pumps § 63.1296(a):</ENT> <ENT>Sealless pump</ENT> <ENT>§ 63.1296(a)(1)</ENT> <ENT/> <ENT>§ 63.1307 (b)(1)(ii)</ENT> <ENT/> </ROW> <ROW> <ENT I="22"/> <ENT>Quarterly monitoring</ENT> <ENT>§ 63.1296(a)(2) and (2)(iii)</ENT> <ENT>§ 63.1296(a)(2)(i), (2)(ii) and § 63.1304(a)</ENT> <ENT>§ 63.1307 (b)(1)(ii) and (3)</ENT> <ENT>§ 63.1304(e)(4).</ENT> </ROW> <ROW> <ENT I="11">HAP ABA valves § 63.1296(b):</ENT> <ENT>Quarterly monitoring</ENT> <ENT>§ 63.1296(b), and (b)(2)</ENT> <ENT>§ 63.1296 (b)(1) and § 63.1304(a)</ENT> <ENT>§ 63.1307 (b)(1)(ii) and (3)</ENT> <ENT>§ 63.1304(e)(4).</ENT> </ROW> <ROW> <ENT I="22"/> <ENT>Unsafe-to-monitor</ENT> <ENT>§ 63.1296(b)(3) (i), (ii), and (iv)</ENT> <ENT>§ 63.1296 (b)(3)(iii)</ENT> <ENT>§ 63.1307 (b)(1)(ii), and (4)</ENT> <ENT>§ 63.1304(e)(4).</ENT> </ROW> <ROW> <ENT I="22"/> <ENT>Difficult-to-monitor</ENT> <ENT>§ 63.1296(b)(4) (i), (ii), (iii), and (v)</ENT> <ENT>§ 63.1296(b)(4)(iv) and § 63.1304(a)</ENT> <ENT>§ 63.1307 (b)(1)(ii) and (4)</ENT> <ENT>§ 63.1306(e)(4).</ENT> </ROW> <ROW> <ENT I="01">HAP ABA Connectors § 63.1296(c):</ENT> <ENT>Annual monitoring</ENT> <ENT>§ 63.1296(c) and (c)(2)</ENT> <ENT>§ 63.1296(c)(1) and § 63.1304(a)</ENT> <ENT>§ 63.1307 (b)(1)(ii) and (3)</ENT> <ENT>§ 63.1306(e)(4).</ENT> </ROW> <ROW> <ENT I="22"/> <ENT>Unsafe-to-monitor</ENT> <ENT>§ 63.1296(c)(2), (3) (i), and (ii)</ENT> <ENT>§ 63.1296(c)(3) (iii) and § 63.1304(a)</ENT> <ENT>§ 63.1307 (b)(1)(ii) and (4)</ENT> <ENT>§ 63.1306(e)(4).</ENT> </ROW> <ROW> <ENT I="22"/> <ENT>Unsafe-to-repair</ENT> <ENT>§ 63.1296(c)(4)</ENT> <ENT>§ 63.1296(c)(1)</ENT> <ENT>§ 63.1307 (b)(1)(ii)</ENT> <ENT>§ 63.1306(e)(4).</ENT> </ROW> <ROW> <ENT I="11">Pressure-relief devices § 63.1296(d)</ENT> <ENT>N/A</ENT> <ENT>§ 63.1296(d) and (d)(2)</ENT> <ENT>§ 63.1296 (d)(1) and § 63.1304(a)</ENT> <ENT>§ 63.1307 (b)(1)(ii) and (3)</ENT> <ENT>§ 63.1306(e)(4).</ENT> </ROW> <ROW> <ENT I="01">Open-ended valves or lines § 63.1296(e)</ENT> <ENT>N/A</ENT> <ENT>§ 63.1296(e)</ENT> <ENT/> <ENT>§ 63.1307 (b)(1)(ii)</ENT> <ENT/> </ROW> <ROW> <ENT I="01">Production line § 63.1297</ENT> <ENT>Rolling annual compliance</ENT> <ENT>§ 63.1297(a)(1) and (b)</ENT> <ENT>§ 63.1303 (b)</ENT> <ENT>§ 63.1307(c)(1)</ENT> <ENT>§ 63.1306(e)(1).</ENT> </ROW> <ROW> <ENT I="22"/> <ENT>Monthly compliance</ENT> <ENT>§ 63.1297(a)(2) and (c)</ENT> <ENT>§ 63.1303 (b)</ENT> <ENT>§ 63.1307(c)(1)</ENT> <ENT>§ 63.1306(e)(2).</ENT> </ROW> <ROW> <PRTPAGE P="171"/> <ENT I="22"/> <ENT>Compliance Using a Recovery device</ENT> <ENT>§ 63.1297(a)(1), (b), and (e) for rolling annual compliance or § 63.1297(a)(2), (c), and (e) for monthly compliance</ENT> <ENT>§ 63.1303 (b) and (c)</ENT> <ENT>§ 63.1307(c)(1) and (d)</ENT> <ENT>§ 63.1306(e)(1) or (2).</ENT> </ROW> <ROW> <ENT I="01">Equipment Cleaning § 63.1298</ENT> <ENT>N/A</ENT> <ENT>§ 63.1298</ENT> <ENT/> <ENT>§ 63.1307(e)</ENT> <ENT/> </ROW> </GPOTABLE> <GPOTABLE CDEF="s50,r50,r50,r50,r75,r50" COLS="6" OPTS="L2,i1"> <TTITLE> <E T="04">Table</E> 4 <E T="04">to Subpart III.—Compliance Requirements for Slabstock Foam Production Affected Sources Complying With the Source-Wide Emission Limitation</E> </TTITLE> <BOXHD> <CHED H="1">Emission point</CHED> <CHED H="1">Emission point compliance option</CHED> <CHED H="1">Emission, work practice, and equipment standards</CHED> <CHED H="1">Monitoring</CHED> <CHED H="1">Recordkeeping</CHED> <CHED H="1">Reporting</CHED> </BOXHD> <ROW> <ENT I="01">Diisocyanate storage vessels § 63.1294(a)</ENT> <ENT>Vapor balance</ENT> <ENT>§ 63.1294(a)(1) and (1)(ii)</ENT> <ENT>§ 63.1294(a)(1)(i)</ENT> <ENT>§ 63.1307(a)(1) and (4)</ENT> <ENT>§ 63.1306(e)(5).</ENT> </ROW> <ROW> <ENT I="22"/> <ENT>Carbon adsorber</ENT> <ENT>§ 63.1294(a)(2)</ENT> <ENT>§ 63.1303(a)(1), (3), and (4)</ENT> <ENT>§ 63.1307(a)(1), (3)(i), and (3)(iii)</ENT> <ENT>§ 63.1306(e)(3).</ENT> </ROW> <ROW> <ENT I="22"/> <ENT>Carbon adsorber—alternative monitoring</ENT> <ENT>§ 63.1294(a)(2) </ENT> <ENT>§ 63.1303(a)(2), (3) and (4)</ENT> <ENT>§ 63.1307(a)(1), (3)(ii), and (3)(iii)</ENT> <ENT>§ 63.1306(e)(3).</ENT> </ROW> <ROW> <ENT I="01">Diisocyanate transfer pumps § 63.1294(b)</ENT> <ENT>Sealless pump</ENT> <ENT>§ 63.1294(b)(1)</ENT> <ENT/> <ENT>§ 63.1307 (b)(1)(i) and (2)</ENT> <ENT/> </ROW> <ROW> <ENT I="22"/> <ENT>Submerged pump</ENT> <ENT>§ 63.1294(b)(2)(i) and (iii)</ENT> <ENT>§ 63.1294 (b)(2)(ii)</ENT> <ENT>§ 63.1307 (b)(1)(i), (2), and (3)</ENT> <ENT>§ 63.1306(e)(4).</ENT> </ROW> <ROW> <ENT I="01">Other components in diisocyanate service § 63.1294(c)</ENT> <ENT>N/A</ENT> <ENT>§ 63.1294(c)</ENT> <ENT>§ 63.1294(c)</ENT> <ENT>§ 63.1307 (b)(1)(i) and (3)</ENT> <ENT>§ 63.1306(e)(4).</ENT> </ROW> <ROW> <ENT I="01">HAP ABA storage vessels, equipment leaks, production line, and equipment cleaning</ENT> <ENT>Rolling annual compliance </ENT> <ENT>§ 63.1299(a), (c)(1) through (4), and (d) </ENT> <ENT>§ 63.1303 (b) except (b)(1)(ii), (d), and (e)</ENT> <ENT>§ 63.1307(c)(2)</ENT> <ENT>§ 63.1306(e)(1).</ENT> </ROW> <ROW> <ENT I="22"/> <ENT>Monthly compliance</ENT> <ENT>§ 63.1299(b), (c)(1) through (4), and (d) </ENT> <ENT>§ 63.1303 (b) except (b)(1)(ii), (d), and (e)</ENT> <ENT>§ 63.1307(c)(2)</ENT> <ENT>§ 63.1306(e)(2).</ENT> </ROW> <ROW> <ENT I="22"/> <ENT>Compliance Using a Recovery device</ENT> <ENT>§ 63.1299(a), (d), and (e) for rolling annual compliance or § 63.1299(b), (d), and (e) for monthly compliance</ENT> <ENT>§ 63.1303 (b) except (b)(1)(ii) and (c)</ENT> <ENT>§ 63.1307(c)(2) and (d)</ENT> <ENT>§ 63.1306(e)(1) or (2).</ENT> </ROW> </GPOTABLE> <GPOTABLE CDEF="s50,r50,r50,r50,r75,r50" COLS="6" OPTS="L2,i1"> <TTITLE> <E T="04">Table</E> 5 <E T="04">to Subpart III.—Compliance Requirements for Molded and Rebond Foam Production Affected Sources</E> </TTITLE> <BOXHD> <CHED H="1">Emission point</CHED> <CHED H="1">Emission point compliance option</CHED> <CHED H="1">Emission, work practice, and equipment standards</CHED> <CHED H="1">Monitoring</CHED> <CHED H="1">Recordkeeping</CHED> <CHED H="1">Reporting</CHED> </BOXHD> <ROW> <ENT I="21">Molded Foam</ENT> </ROW> <ROW> <ENT I="01">Equipment cleaning </ENT> <ENT>N/A </ENT> <ENT>§ 63.1300(a) </ENT> <ENT/> <ENT>§ 63.1307(g)</ENT> <ENT/> </ROW> <ROW> <ENT I="01">Mold release agent </ENT> <ENT>N/A </ENT> <ENT>§ 63.1300(b) </ENT> <ENT/> <ENT>§ 63.1307 (h) </ENT> <ENT/> </ROW> <ROW> <PRTPAGE P="172"/> <ENT I="21">Rebond Foam</ENT> </ROW> <ROW> <ENT I="01">Equipment cleaning </ENT> <ENT>N/A </ENT> <ENT>§ 63.1301(a) </ENT> <ENT/> <ENT>§ 63.1307 (g) </ENT> <ENT/> </ROW> <ROW> <ENT I="01">Mold release agent </ENT> <ENT>N/A </ENT> <ENT>§ 63.1301(b) </ENT> <ENT/> <ENT>§ 63.1307 (h) </ENT> <ENT/> </ROW> </GPOTABLE> </APPENDIX> </SUBPART> <SUBPART> <PRTPAGE P="173"/> <HD SOURCE="HED">Subpart JJJ—National Emission Standards for Hazardous Air Pollutant Emissions: Group IV Polymers and Resins</HD> <SOURCE> <HD SOURCE="HED">Source:</HD> <P>61 FR 48229, Sept. 12, 1996, unless otherwise noted.</P> </SOURCE> <SECTION> <SECTNO>§ 63.1310</SECTNO> <SUBJECT>Applicability and designation of affected sources.</SUBJECT> <P>(a) <E T="03">Definition of affected source.</E> The provisions of this subpart apply to each affected source. An affected source is either an existing affected source or a new affected source. Existing affected source is defined in paragraph (a)(6) of this section, and new affected source is defined in paragraph (a)(7) of this section. The affected source also includes the emission points and equipment specified in paragraphs (a)(1) through (a)(5) of this section that are associated with each group of TPPU.</P> <P>(1) Each wastewater stream.</P> <P>(2) Each wastewater operation.</P> <P>(3) Each heat exchange system.</P> <P>(4) Each process contact cooling tower used in the manufacture of PET that is associated with a new affected source.</P> <P>(5) Each process contact cooling tower used in the manufacture of PET using a continuous terephthalic acid high viscosity multiple end finisher process that is associated with an existing affected source.</P> <P>(6) Except as specified in paragraphs (b) through (d) of this section, an existing affected source is defined as each group of one or more thermoplastic product process units (TPPUs) that is not part of a new affected source as defined in paragraph (a)(7) of this section, that is manufacturing the same primary product, where each TPPU uses as a reactant, or uses as a process solvent, or produces as a by-product or co-product any organic hazardous air pollutant (organic HAP), and that is located at a plant site that is a major source.</P> <P>(7) Except as specified in paragraphs (b) through (d) of this section, a new affected source is defined as a source meeting the criteria of paragraph (a)(7)(i), (a)(7)(ii), or (a)(7)(iii) of this section:</P> <P>(i) At a plant site previously without HAP emissions points, each group of one or more TPPUs manufacturing the same primary product that is part of a major source on which construction commenced after March 29, 1995;</P> <P>(ii) A TPPU meeting the criteria in paragraph (i)(1)(i) of this section; or</P> <P>(iii) A reconstructed affected source meeting the criteria in paragraph (i)(2)(i) of this section.</P> <P>(b) <E T="03">TPPUs exempted from the affected source.</E> For a TPPU to be excluded from the designation of affected source due to the fact that it does not use as a reactant, or use as a process solvent, or produce as a by-product or co-product any organic HAP, the owner or operator shall comply with the requirements of paragraph (b)(1) of this section and shall comply with the requirements of paragraph (b)(2) of this section if requested to do so by the Administrator.</P> <P>(1) Retain information, data, and analysis used to document the basis for the determination that the TPPU does not use as a reactant or use as a process solvent, or manufacture as a by-product or a co-product any organic HAP. Types of information that could document this determination include, but are not limited to, records of chemicals purchased for the process, analyses of process stream composition, or engineering calculations.</P> <P>(2) When requested by the Administrator, demonstrate that the TPPU does not use as a reactant, or use as a process solvent, or manufacture as a by-product or co-product any organic HAP.</P> <P>(c) <E T="03">Emission points exempted from the affected source.</E> The affected source does not include the emission points listed in paragraphs (c)(1) through (c)(6) of this section:</P> <P>(1) Stormwater from segregated sewers;</P> <P>(2) Water from fire-fighting and deluge systems in segregated sewers;</P> <P>(3) Spills;</P> <P>(4) Water from safety showers;</P> <P>(5) Vessels and equipment storing and/or handling material that contain no organic HAP and/or organic HAP as impurities only; and</P> <P>(6) Equipment that is intended to operate in organic HAP service for less than 300 hours during the calendar year.<PRTPAGE P="174"/> </P> <P>(d) <E T="03">Processes exempted from the affected source.</E> The processes specified in paragraphs (d)(1) through (d)(5) of this section are exempted from the affected source:</P> <P>(1) Research and development facilities;</P> <P>(2) Polymerization processes occurring in a mold;</P> <P>(3) Processes which manufacture binder systems containing a thermoplastic product for paints, coatings, or adhesives;</P> <P>(4) Finishing processes including equipment such as compounding units, spinning units, drawing units, extruding units, and other finishing steps; and</P> <P>(5) Solid state polymerization processes.</P> <P>(e) <E T="03">Applicability determination of nonthermoplastic equipment included in a TPPU producing a thermoplastic product.</E> If a polymer that is not subject to this subpart is produced within the equipment (i.e., collocated) making up a TPPU and at least 50 percent of said polymer is used in the production of a thermoplastic product manufactured by said TPPU, the unit operations involved in the production of said polymer are considered part of the TPPU and are subject to this rule except as specified in this paragraph (e). If said unit operations are subject to another MACT standard regulating the same emission points, said unit operations are not subject to this subpart.</P> <P>(f) <E T="03">Primary product determination and applicability.</E> The primary product of a process unit shall be determined according to the procedures specified in paragraphs (f)(1) through (f)(2) of this section. Paragraphs (f)(3) through (f)(4) of this section describe whether or not a process unit is subject to this subpart. Paragraphs (f)(5) through (f)(7) of this section discuss compliance for those TPPUs operated as flexible operation units, as specified in paragraph (f)(2) of this section.</P> <P>(1) If a process unit only manufactures one product, then that product shall represent the primary product of the process unit.</P> <P>(2) If a process unit is designed and operated as a flexible operation unit, the primary product shall be determined as specified in paragraphs (f)(2)(i) or (f)(2)(ii) of this section based on the anticipated operations for the 5 years following September 12, 1996 for existing affected sources and for the first 5 years after initial start-up for new affected sources.</P> <P>(i) If the flexible operation unit will manufacture one product for the greatest operating time over the five year period, then that product shall represent the primary product of the flexible operation unit.</P> <P>(ii) If the flexible operation unit will manufacture multiple products equally based on operating time, then the product with the greatest production on a mass basis over the five year period shall represent the primary product of the flexible operation unit.</P> <P>(3) If the primary product of a process unit is a thermoplastic product, then said process unit is considered a TPPU. If said TPPU meets all the criteria of paragraph (a) of this section, it is either an affected source or is part of an affected source comprised of other TPPU subject to this rule at the same plant site with the same primary product. The status of a process unit as a TPPU and as an affected source or part of an affected source shall not change regardless of what products are produced in the future by said TPPU, with the exception noted in paragraph (f)(3)(i) of this section.</P> <P>(i) If a process unit terminates the production of all thermoplastic products and does not anticipate the production of any thermoplastic product in the future, the process unit is no longer a TPPU and is not subject to this rule after notification is made as specified in paragraph (f)(3)(ii) of this section.</P> <P>(ii) The owner or operator of a process unit that wishes to remove the TPPU designation from the process unit, as specified in paragraph (f)(3)(i) of this section, shall notify the Administrator. This notification shall be accompanied by rationale for why it is anticipated that no thermoplastic products will be produced in the process unit in the future.</P> <P>(iii) If a process unit meeting the criteria of paragraph (f)(3)(i) of this section begins the production of a thermoplastic product in the future, the owner or operator shall use the procedures in <PRTPAGE P="175"/>paragraph (f)(4)(i) of this section to determine if the process unit is re-designated as a TPPU.</P> <P>(4) If the primary product of a process unit is not a thermoplastic product, then said process unit is not an affected source nor is it part of any affected source subject to this rule. Said process unit is not subject to this rule at any time, regardless of what product is being produced. The status of a process unit as not being a TPPU, and therefore not an affected source nor part of an affected source subject to this subpart, shall not change regardless of what products are produced in the future by said TPPU, with the exception noted in paragraph (f)(4)(i) of this section.</P> <P>(i) If, at any time beginning September 12, 2001, the owner or operator determines that a thermoplastic product is the primary product for the process unit based on actual production data for any preceding consecutive five-year period, then the process unit shall be designated as a TPPU. If said TPPU meets all the criteria of paragraph (a) of this section and is not subject to another subpart of 40 CFR part 63, it is either an affected source or part of an affected source and shall be subject to this rule.</P> <P>(ii) If a process unit meets the criteria of paragraph (f)(4)(i) of this section, the owner or operator shall notify the Administrator within 6 months of making this determination. The TPPU, as the entire affected source or part of an affected source, shall be in compliance with the provisions of this rule within 3 years from the date of such notification.</P> <P>(iii) If a process unit is re-designated as a TPPU but does not meet all the criteria of paragraph (a) of this section, the owner or operator shall notify the Administrator within 6 months of making this determination. Said notification shall include documentation justifying the TPPU's status as not being an affected source or not being part of an affected source.</P> <P>(5) Once the primary product of a process unit has been determined to be a thermoplastic product and it has been determined that all the criteria of paragraph (a) of this section are met for said TPPU, the owner or operator of the affected source shall comply with the standards for the primary product. Owners or operators of flexible operation units shall comply with the standards for the primary product as specified in either paragraph (f)(5)(i) or (f)(5)(ii) of this section, except as specified in paragraph (f)(5)(iii) of this section.</P> <P>(i) Each owner or operator shall determine the group status of each emission point that is part of said flexible operation unit based on emission point characteristics when the primary product is being manufactured. Based on this finding, the owner or operator shall comply with the applicable standards for the primary product for each emission point, as appropriate, at all times, regardless of what product is being produced.</P> <P>(ii) Alternatively, each owner or operator shall determine the group status of each emission point that is part of said flexible operation unit based on the emission point characteristics when each product produced by the flexible operation unit is manufactured, regardless of whether said product is a thermoplastic product or not. Based on these findings, the owner or operator shall comply with the applicable standards for the primary product for each emission point, as appropriate, regardless of what product is being produced.</P> <NOTE> <HD SOURCE="HED">Note:</HD> <P>Under this scenario it is possible that the group status, and therefore the requirement to achieve emission reductions, for an emission point may change depending on the product being produced.</P> </NOTE> <P>(iii) Whenever a flexible operation unit manufactures a product that meets the criteria of paragraph (b) of this section (i.e., does not use or produce any organic HAP), all activities associated with the manufacture of said product shall be exempt from the requirements of this rule, to include the operation and monitoring of control or recovery devices.</P> <P>(6) The determination of the primary product for a process unit, to include the determination of applicability of this subpart to process units that are designed and operated as flexible operation units, shall be reported in the Notification of Compliance Status required by § 63.1335(e)(5) when the primary product is determined to be a <PRTPAGE P="176"/>thermoplastic product. The Notification of Compliance Status shall include the information specified in either paragraph (f)(6)(i) or (f)(6)(ii) of this section. If the primary product is determined to be something other than a thermoplastic product, the owner or operator shall retain information, data, and analysis used to document the basis for the determination that the primary product is not a thermoplastic product.</P> <P>(i) If the TPPU manufactures only one thermoplastic product, identification of said thermoplastic product.</P> <P>(ii) If the TPPU is designed and operated as a flexible operation unit, the information specified in paragraphs (f)(6)(ii)(A) through (f)(6)(ii)(C) of this section, as appropriate.</P> <P>(A) Identification of the primary product.</P> <P>(B) Information concerning operating time and/or production mass for each product that was used to make the determination of the primary product under paragraph (f)(2)(i) or (f)(2)(ii) of this section.</P> <P>(C) Identification of which compliance option, either paragraph (f)(5)(i) or (f)(5)(ii) of this section, has been selected by the owner or operator.</P> <P>(7) To demonstrate compliance with the rule during those periods when a flexible operation unit that is subject to this subpart is producing a product other than a thermoplastic product or is producing a thermoplastic product that is not the primary product, the owner or operator shall comply with either paragraphs (f)(7)(i) through (f)(7)(ii) or paragraph (f)(7)(iii) of this section.</P> <P>(i) Establish parameter monitoring levels, as specified in § 63.1334, for those emission points designated as Group 1, as appropriate.</P> <P>(ii) Submit the parameter monitoring levels developed under paragraph (f)(7)(i) of this section and the basis for them in the Notification of Compliance Status report as specified in § 63.1335(e)(5).</P> <P>(iii) Demonstrate that the parameter monitoring levels established for the primary product are also appropriate for those periods when products other than the primary product are being produced. Material demonstrating this finding shall be submitted in the Notification of Compliance Status report as specified in § 63.1335(e)(5).</P> <P>(g) <E T="03">Storage vessel ownership determination</E>. The owner or operator shall follow the procedures specified in paragraphs (g)(1) through (g)(8) of this section to determine to which process unit a storage vessel shall belong.</P> <P>(1) If a storage vessel is already subject to another subpart of 40 CFR part 63 on September 12, 1996, said storage vessel shall belong to the process unit subject to the other subpart.</P> <P>(2) If a storage vessel is dedicated to a single process unit, the storage vessel shall belong to that process unit.</P> <P>(3) If a storage vessel is shared among process units, then the storage vessel shall belong to that process unit located on the same plant site as the storage vessel that has the greatest input into or output from the storage vessel (i.e., said process unit has the predominant use of the storage vessel).</P> <P>(4) If predominant use cannot be determined for a storage vessel that is shared among process units and if one of those process units is a TPPU subject to this subpart, the storage vessel shall belong to said TPPU.</P> <P>(5) If predominant use cannot be determined for a storage vessel that is shared among process units and if more than one of the process units are TPPUs that have different primary products and that are subject to this subpart, then the owner or operator shall assign the storage vessel to any one of the said TPPUs.</P> <P>(6) If the predominant use of a storage vessel varies from year to year, then predominant use shall be determined based on the utilization that occurred during the year preceding September 12, 1996 or based on the expected utilization for the 5 years following September 12, 1996 for existing affected sources, whichever is more representative of the expected operations for said storage vessel, and based on the first 5 years after initial start-up for new affected sources. The determination of predominant use shall be reported in the Notification of Compliance Status required by § 63.1335(e)(5). If the predominant use <PRTPAGE P="177"/>changes, the redetermination of predominant use shall be reported in the next Periodic Report.</P> <P>(7) If the storage vessel begins receiving material from (or sending material to) another process unit; or ceasing to receive material from (or send material to) a process unit; or if the applicability of this subpart to a storage vessel has been determined according to the provisions of paragraphs (g)(1) through (g)(6) of this section and there is a significant change in the use of the storage vessel that could reasonably change the predominant use, the owner or operator shall reevaluate the applicability of this subpart to the storage vessel.</P> <P>(8) Where a storage vessel is located at a major source that includes one or more process units which place material into, or receive materials from the storage vessel, but the storage vessel is located in a tank farm, the applicability of this subpart shall be determined according to the provisions in paragraphs (g)(8)(i) through (g)(8)(iv) of this section.</P> <P>(i) The storage vessel may only be assigned to a process unit that utilizes the storage vessel and does not have an intervening storage vessel for that product (or raw materials, as appropriate). With respect to any process unit, an intervening storage vessel means a storage vessel connected by hard-piping to the process unit and to the storage vessel in the tank farm so that product or raw material entering or leaving the process unit flows into (or from) the intervening storage vessel and does not flow directly into (or from) the storage vessel in the tank farm.</P> <P>(ii) If there is no process unit at the major source that meets the criteria of paragraph (g)(8)(i) of this section with respect to a storage vessel, this subpart does not apply to the storage vessel.</P> <P>(iii) If there is only one process unit at the major source that meets the criteria of paragraph (g)(8)(i) of this section with respect to a storage vessel, the storage vessel shall be assigned to that process unit.</P> <P>(iv) If there are two or more process units at the major source that meet the criteria of paragraph (g)(8)(i) of this section with respect to a storage vessel, the storage vessel shall be assigned to one of those process units according to the provisions of paragraph (g)(7) of this section. The predominant use shall be determined among only those thermoplastic product process units that meet the criteria of paragraph (g)(8)(i) of this section.</P> <P>(h) <E T="03">Recovery operation equipment ownership determination</E>. The owner or operator shall follow the procedures specified in paragraphs (h)(1) through (h)(7) of this section to determine to which process unit recovery operation equipment shall belong.</P> <P>(1) If recovery operation equipment is already subject to another subpart of 40 CFR part 63 on September 12, 1996, said recovery operation equipment shall belong to the process unit subject to the other subpart.</P> <P>(2) If recovery operation equipment is used exclusively by a single process unit, the recovery operation shall belong to that process unit.</P> <P>(3) If recovery operation equipment is shared among process units, then the recovery operation equipment shall belong to that process unit located on the same plant site as the recovery operation equipment that has the greatest input into or output from the recovery operation equipment (i.e., said process unit has the predominant use of the recovery operation equipment).</P> <P>(4) If predominant use cannot be determined for recovery operation equipment that is shared among process units and if one of those process units is a TPPU subject to this subpart, the recovery operation equipment shall belong to said TPPU.</P> <P>(5) If predominant use cannot be determined for recovery operation equipment that is shared among process units and if more than one of the process units are TPPUs that have different primary products and that are subject to this subpart, then the owner or operator shall assign the recovery operation equipment to any one of said TPPUs.</P> <P>(6) If the predominant use of recovery operation equipment varies from year to year, then predominant use shall be determined based on the utilization that occurred during the year preceding September 12, 1996 or based on the expected utilization for the 5 years <PRTPAGE P="178"/>following September 12, 1996 for existing affected sources, whichever is the more representative of the expected operations for said recovery operations equipment, and based on the first 5 years after initial start-up for new affected sources. This determination shall be reported in the Notification of Compliance Status required by § 63.1335(e)(5). If the predominant use changes, the redetermination of predominant use shall be reported in the next Periodic Report.</P> <P>(7) If there is an unexpected change in the utilization of recovery operation equipment that could reasonably change the predominant use, the owner or operator shall redetermine to which process unit the recovery operation belongs by reperforming the procedures specified in paragraphs (h)(2) through (h)(6) of this section.</P> <P>(i) <E T="03">Changes or additions to plant sites.</E> The provisions of paragraphs (i)(1) through (i)(4) of this section apply to owners or operators that change or add to their plant site or affected source. Paragraph (i)(5) of this section provides examples of what are and are not considered process changes for purposes of paragraph (i) of this section.</P> <P>(1) <E T="03">Adding a TPPU to a plant site.</E> The provisions of paragraphs (i)(1)(i) through (i)(1)(ii) of this section apply to owners or operators that add TPPUs to a plant site.</P> <P>(i) If a TPPU is added to a plant site, said addition shall be a new affected source and shall be subject to the requirements for a new affected source in this subpart upon initial start-up or by September 12, 1996, whichever is later, if said addition meets the criteria specified in paragraphs (i)(1)(i)(A) through (i)(1)(i)(B) and either (i)(1)(i)(C) or (i)(1)(i)(D) of this section:</P> <P>(A) Said addition meets the definition of construction in § 63.2;</P> <P>(B) Such construction commenced after March 29, 1995; and</P> <P>(C) Said addition has the potential to emit 10 tons per year or more of any HAP or 25 tons per year or more of any combination of HAP, and the primary product of said addition is currently produced at the plant site as the primary product of an affected source; or</P> <P>(D) The primary product of said addition is not currently produced at the plant site as the primary product of an affected source and the plant site meets, or after the addition is completed will meet, the definition of major source.</P> <P>(ii) If a TPPU is added to a plant site, said addition shall be subject to the requirements for an existing affected source in this subpart upon initial start-up or by 3 years after September 12, 1996, whichever is later, if said addition does not meet the criteria specified in paragraph (i)(1)(i) of this section and the plant site meets, or after the addition is completed will meet, the definition of major source.</P> <P>(2) <E T="03">Adding emission points or making process changes to existing affected sources.</E> The provisions of paragraphs (i)(2)(i) through (i)(2)(ii) of this section apply to owners or operators that add emission points or make process changes to an existing affected source.</P> <P>(i) If any process change is made or emission point is added to an existing affected source, or if a process change creating one or more additional Group 1 emission point(s) is made to an existing affected source, said affected source shall be a new affected source and shall be subject to the requirements for a new affected source in this subpart upon initial start-up or by September 12, 1996, whichever is later, if said process change or addition meets the criteria specified in paragraphs (i)(2)(i)(A) through (i)(2)(i)(B) of this section:</P> <P>(A) Said process change or addition meets the definition of reconstruction in § 63.2; and</P> <P>(B) Such reconstruction commenced after March 29, 1995.</P> <P>(ii) If any process change is made or emission point is added to an existing affected source, or if a process change creating one or more additional Group 1 emission point(s) is made to an existing affected source and said process change or addition does not meet the criteria specified in paragraphs (i)(2)(i)(A) through (i)(2)(i)(B) of this section, the resulting emission point(s) shall be subject to the requirements for an existing affected source in this subpart. Said emission point(s) shall be in compliance upon initial start-up or by <PRTPAGE P="179"/>3 years after September 12, 1996, whichever is later, unless the owner or operator demonstrates to the Administrator that achieving compliance will take longer than making said process change or addition. If this demonstration is made to the Administrator's satisfaction, the owner or operator shall follow the procedures in paragraphs (i)(2)(iii)(A) through (i)(2)(iii)(C) of this section to establish a compliance date.</P> <P>(iii) To establish a compliance date for an emission point or points specified in paragraph (i)(2)(ii) of this section, the procedures specified in paragraphs (i)(2)(iii)(A) through (i)(2)(iii)(C) of this section shall be followed.</P> <P>(A) The owner or operator shall submit to the Administrator for approval a compliance schedule, along with a justification for the schedule.</P> <P>(B) The compliance schedule shall be submitted within 180 days after the process change or addition is made or the information regarding said change or addition is known to the owner or operator, unless the compliance schedule has been previously submitted to the permitting authority. The compliance schedule may be submitted in the next Periodic Report if the process change or addition is made after the date the Notification of Compliance Status report is due.</P> <P>(C) The Administrator shall approve the compliance schedule or request changes within 120 calendar days of receipt of the compliance schedule and justification.</P> <P>(3) <E T="03">Existing source requirements for Group 2 emission points that become Group 1 emission points.</E> If a process change or addition that does not meet the criteria in paragraph (i)(1) or (i)(2) of this section is made to an existing plant site or existing affected source, and the change causes a Group 2 emission point to become a Group 1 emission point, for said emission point, the owner or operator shall comply with the requirements of this subpart for existing Group 1 emission points. Compliance shall be achieved as expeditiously as practicable, but in no event later than 3 years after said emission point becomes a Group 1 emission point.</P> <P>(4) <E T="03">Existing source requirements for some emission points that become subject to the requirements of subpart H of this part.</E> If a compressor becomes subject to § 63.164, the owner or operator shall be in compliance upon initial start-up or by 3 years after September 12, 1996, whichever is later, unless the owner or operator demonstrates to the Administrator that achieving compliance will take longer than making the change. If this demonstration is made to the Administrator's satisfaction, the owner or operator shall follow the procedures in paragraphs (i)(2)(iii)(A) through (i)(2)(iii)(C) of this section to establish a compliance date.</P> <P>(5) <E T="03">Determining what are and are not process changes.</E> For purposes of paragraph (i) of this section, examples of process changes include, but are not limited to, changes in production capacity, feedstock type, or catalyst type, or whenever there is a replacement, removal, or the addition of recovery equipment. For purposes of paragraph (i) of this section, process changes do not include: process upsets, unintentional temporary process changes, and changes that are within the equipment configuration and operating conditions documented in the Notification of Compliance Status report required by § 63.1335(e)(5).</P> <P>(j) <E T="03">Applicability of this subpart except during periods of start-up, shutdown, and malfunction.</E> Each provision set forth in this subpart or referred to in this subpart shall apply at all times except during periods of start-up, shutdown, and malfunction if the start-up, shutdown, or malfunction precludes the ability of a particular emission point of an affected source to comply with one or more specific provisions to which it is subject. Start-up, shutdown, and malfunction is defined in § 63.1312 for all emission points except equipment leaks subject to subpart H of this part, which shall follow the provisions for periods of start-up, malfunction, and process unit shutdown, as defined in § 63.161. Only then shall an emission point not be required to comply with all applicable provisions of this subpart.</P> </SECTION> <SECTION> <PRTPAGE P="180"/> <SECTNO>§ 63.1311</SECTNO> <SUBJECT>Compliance schedule and relationship to existing applicable rules.</SUBJECT> <P>(a) Affected sources are required to achieve compliance on or before the dates specified in paragraphs (b) through (d) of this section. Paragraph (e) of this section provides information on requesting compliance extensions. Paragraphs (f) through (l) of this section discuss the relationship of this subpart to subpart A of this part and to other applicable rules. Where an override of another authority of the Act is indicated in this subpart, only compliance with the provisions of this subpart is required. Paragraph (m) of this section specifies the meaning of time periods.</P> <P>(b) New affected sources that commence construction or reconstruction after March 29, 1995 shall be in compliance with this subpart upon initial start-up or February 27, 1998, whichever is later, as provided in § 63.6(b), except that new affected sources whose primary product, as determined using the procedures specified in § 63.1310(f), is poly(ethylene terephthalate) (PET) shall be in compliance with § 63.1331 upon initial start-up or February 27, 2001, whichever is later. </P> <NOTE> <HD SOURCE="HED">[Note:</HD> <P>The compliance date for new affected sources with an initial start-up date on or after March 9, 1999 is stayed indefinitely. The EPA will publish a document in the <E T="04">Federal Register</E> establishing a new compliance date for new affected sources with an initial start-up date on or after March 9, 1999.]</P> </NOTE> <P>(c) Existing affected sources shall be in compliance with this subpart (except for § 63.1331 for which compliance is covered by paragraph (d) of this section) no later than September 12, 1999, as provided in § 63.6(c), unless an extension has been granted as specified in paragraph (e) of this section, except that the compliance date for the provisions contained in § 63.1329 is extended from September 12, 1999 to February 27, 2001, for existing affected sources whose primary product, as determined using the procedures specified in 63.1310(f), is PET using a continuous terephthalic acid high viscosity multiple end finisher process. </P> <NOTE> <HD SOURCE="HED">[Note:</HD> <P>The compliance date of September 12, 1999 for existing affected sources, except for emission points addressed under § 63.1331, which are covered by paragraph (d) of this section, is stayed indefinitely. The EPA will publish a document in the <E T="04">Federal Register</E> establishing a new compliance date for existing affected sources.]</P> </NOTE> <P>(d) Except as provided for in paragraphs (d)(1) through (d)(6) of this section, existing affected sources shall be in compliance with § 63.1331 no later than February 27, 1998 unless a request for a compliance extension is granted pursuant to section 112(i)(3)(B) of the Act, as discussed in § 63.182(a)(6).</P> <P>(1) Compliance with the compressor provisions of § 63.164 shall occur no later than February 27, 1998 for any compressor meeting one or more of the criteria in paragraphs (d)(1)(i) through (d)(1)(iii) of this section if the work can be accomplished without a process unit shutdown, as defined in § 63.161:</P> <P>(i) The seal system will be replaced;</P> <P>(ii) A barrier fluid system will be installed;</P> <P>(iii) A new barrier fluid will be utilized which requires changes to the existing barrier fluid system; or</P> <P>(iv) The compressor will be modified to permit connecting the compressor to a fuel gas system or a closed vent system or modified so that emissions from the compressor can be routed to a process.</P> <P>(2) Compliance with the compressor provisions of § 63.164 shall occur no later than March 12, 1998, for any compressor meeting all the criteria in paragraphs (d)(2)(i) through (d)(2)(ii) of this section.</P> <P>(i) The compressor meets one or more of the criteria specified in paragraphs (d)(1)(i)(A) through (d)(1)(i)(B) of this section:</P> <P>(A) The work can be accomplished without a process unit shutdown as defined in § 63.161; or</P> <P>(B) The additional time is actually necessary due to the unavailability of parts beyond the control of the owner or operator.</P> <P>(ii) The owner or operator submits the request for a compliance extension to the U.S. Environmental Protection Agency (EPA) Regional Office at the addresses listed in § 63.13 no later than June 16, 1997. The request for a compliance extension shall contain the information specified in § 63.6(i)(6)(i) (A), (B), and (D). Unless the EPA Regional <PRTPAGE P="181"/>Office objects to the request for a compliance extension within 30 calendar days after receipt of the request, the request shall be deemed approved.</P> <P>(3) If compliance with the compressor provisions of § 63.164 cannot reasonably be achieved without a process unit shutdown, as defined in § 63.161, the owner or operator shall achieve compliance no later than September 14, 1998. The owner or operator who elects to use this provision shall submit a request for a compliance extension in accordance with the requirements of paragraph (d)(2)(ii) of this section.</P> <P>(4) Compliance with the compressor provisions of § 63.164 shall occur not later than September 12, 1999 for any compressor meeting one or more of the criteria in paragraphs (d)(4)(i) through (d)(4)(iii) of this section. The owner or operator who elects to use these provisions shall submit a request for an extension of compliance in accordance with the requirements of paragraph (d)(2)(iv) of this section.</P> <P>(i) Compliance cannot be achieved without replacing the compressor;</P> <P>(ii) Compliance cannot be achieved without recasting the distance piece; or</P> <P>(iii) Design modifications are required to connect to a closed-vent or recovery system.</P> <P>(5) Compliance with the provisions of § 63.170 shall occur no later than September 13, 1999.</P> <P>(6) Notwithstanding paragraphs (d)(1) through (d)(4) of this section, existing affected sources whose primary product, as determined using the procedures specified in § 63.1310(f), is PET shall be in compliance with § 63.1331 no later than February 27, 2001.</P> <P>(e) Pursuant to section 112(i)(3)(B) of the Act, an owner or operator may request an extension allowing the existing source up to 1 additional year to comply with section 112(d) standards. For purposes of this subpart, a request for an extension shall be submitted to the operating permit authority as part of the operating permit application or to the Administrator as a separate submittal or as part of the Precompliance Report. Requests for extensions shall be submitted no later than the date the Precompliance Report is required to be submitted in § 63.1335(e)(3)(i). The dates specified in § 63.6(i) for submittal of requests for extensions shall not apply to this subpart.</P> <P>(1) A request for an extension of compliance shall include the data described in § 63.6(i)(6)(i) (A),(B), and (D).</P> <P>(2) The requirements in § 63.6(i)(8) through § 63.6(i)(14) shall govern the review and approval of requests for extensions of compliance with this subpart.</P> <P>(f) Table 1 of this subpart specifies the provisions of subpart A of this part that apply and those that do not apply to owners and operators of affected sources subject to this subpart.</P> <P>(g)(1) After the compliance dates specified in this section, an affected source subject to this subpart that is also subject to the provisions of subpart I of this part, is required to comply only with the provisions of this subpart. After the compliance dates specified in this section, said affected source shall no longer be subject to subpart I of this part.</P> <P>(2) Said affected sources that elected to comply with subpart I of this part through a quality improvement program, as specified in § 63.175 or § 63.176 or both, may elect to continue these programs without interruption as a means of complying with this subpart. In other words, becoming subject to this subpart does not restart or reset the “compliance clock” as it relates to reduced burden earned through a quality improvement program.</P> <P>(h) After the compliance dates specified in this section, a storage vessel that belongs to an affected source subject to this subpart that is also subject to the provisions of 40 CFR part 60, subpart Kb, is required to comply only with the provisions of this subpart. After the compliance dates specified in this section, said storage vessel shall no longer be subject to 40 CFR part 60, subpart Kb.</P> <P>(i)(1) Except as provided in paragraph (i)(2) of this section, after the compliance dates specified in this section, affected sources producing PET using a continuous terephthalic acid process, producing PET using a continuous dimethyl terephthalate process, or producing polystyrene resin using a continuous process subject to this subpart that are also subject to the provisions <PRTPAGE P="182"/>of 40 CFR part 60, subpart DDD, are required to comply only with the provisions of this subpart. After the compliance dates specified in this section, said sources shall no longer be subject to 40 CFR part 60, subpart DDD.</P> <P>(2) Existing affected sources producing PET using a continuous terephthalic acid high viscosity multiple end finisher process shall continue to be subject to 40 CFR 60.562-1(c)(2)(ii)(C). Once said affected source becomes subject to and achieves compliance with § 63.1329(c) of this subpart, said affected source is no longer subject to the provisions of 40 CFR part 60, subpart DDD.</P> <P>(j) Affected sources subject to this subpart that are also subject to the provisions of subpart Q of this part shall comply with both subparts.</P> <P>(k) After the compliance dates specified in this section, an affected source subject to this subpart that is also subject to the provisions of 40 CFR part 60, subpart VV, is required to comply only with the provisions of this subpart. After the compliance dates specified in this section, said source shall no longer be subject to 40 CFR part 60, subpart VV.</P> <P>(l) After the compliance dates specified in this section, a distillation operation that belongs to an affected source subject to this subpart that is also subject to the provisions of 40 CFR part 60, subpart NNN, is required to comply only with the provisions of this subpart. After the compliance dates specified in this section, said distillation operation shall no longer be subject to 40 CFR part 60, subpart NNN.</P> <P>(m) All terms in this subpart that define a period of time for completion of required tasks (e.g., weekly, monthly, quarterly, annual), unless specified otherwise in the section or subsection that imposes the requirement, refer to the standard calendar periods.</P> <P>(1) Notwithstanding time periods specified in this subpart for completion of required tasks, such time periods may be changed by mutual agreement between the owner or operator and the Administrator, as specified in subpart A of this part (e.g., a period could begin on the compliance date or another date, rather than on the first day of the standard calendar period). For each time period that is changed by agreement, the revised period shall remain in effect until it is changed. A new request is not necessary for each recurring period.</P> <P>(2) Where the period specified for compliance is a standard calendar period, if the initial compliance date occurs after the beginning of the period, compliance shall be required according to the schedule specified in paragraphs (m)(i) or (m)(ii) of this section, as appropriate.</P> <P>(i) Compliance shall be required before the end of the standard calendar period within which the compliance deadline occurs, if there remain at least 3 days for tasks that must be performed weekly, at least 2 weeks for tasks that must be performed monthly, at least 1 month for tasks that must be performed each quarter, or at least 3 months for tasks that must be performed annually; or</P> <P>(ii) In all other cases, compliance shall be required before the end of the first full standard calendar period after the period within which the initial compliance deadline occurs.</P> <P>(3) In all instances where a provision of this subpart requires completion of a task during each multiple successive period, an owner or operator may perform the required task at any time during the specified period, provided that the task is conducted at a reasonable interval after completion of the task during the previous period.</P> <CITA>[61 FR 48229, Sept. 12, 1996, as amended at 62 FR 1838, Jan. 14, 1997; 62 FR 30995, June 6, 1997; 63 FR 9945, Feb. 27, 1998; 63 FR 15315, Mar. 31, 1998; 64 FR 11547, Mar. 9, 1999; 64 FR 30409, June 8, 1999; 64 FR 35028, June 30, 1999]</CITA> <EFFDNOT> <HD SOURCE="HED">Effective Date Notes:</HD> <P>1. At 64 FR 30409, June 8, 1999, § 63.1311 was amended by revising paragraphs (b) and (d)(6), effective Aug. 9, 1999. For the convenience of the user, the supersed text is set forth as follows:</P> <SUPERSED> <SECTION> <SECTNO>§ 63.1311</SECTNO> <SUBJECT>Compliance schedule and relationship to existing applicable rules.</SUBJECT> <STARS/> <P>(b) New affected sources that commence construction or reconstruction after March 29, 1995, shall be in compliance with this subpart upon initial start-up or February 27, 1998, whichever is later, as provided in § 63.6(b), except that new affected sources whose primary product, as determined using the procedures specified in § 63.1310(f), is <PRTPAGE P="183"/>poly(ethylene terephthalate) (PET) shall be in compliance with § 63.1331 upon initial start-up or by September 12, 1999, whichever is later.<STARS/> </P> <P>(d) * * *</P> <P>(6) Notwithstanding paragraphs (d)(1) through (d)(4) of this section, existing affected sources whose primary product, as determined using the procedures specified in § 63.1310(f), is PET shall be in compliance with § 63.1331 no later than September 12, 1999.<STARS/> </P> <P>2. At 64 FR 35028, June 30, 1999, § 63.1311 was amended by revising paragraphs (b) and (c), effective Aug. 30, 1999. For the convenience of the user, paragraph (b) in effect from Aug. 9, 1999 until Aug. 30, 1999 and paragraph (c) is set forth as follows:</P> <SUPERSED> <SECTION> <SECTNO>§ 63.1311</SECTNO> <SUBJECT>Compliance schedule and relationship to existing applicable rules.</SUBJECT> <STARS/> <P>(b) New affected sources that commence construction or reconstruction after March 29, 1995 shall be in compliance with this subpart upon initial start-up or September 12, 1996, whichever is later, as provided in § 63.6(b), except that new affected sources whose primary product, as determined using the procedures specified in § 63.1310(f), is PET shall be in compliance with § 63.1331 upon initial start-up or February 27, 2001, whichever is later.</P> <P>(c) Existing affected sources shall be in compliance with this subpart (except for § 63.1331 for which compliance is covered by paragraph (d) of this section) no later than September 12, 1999, as provided in § 63.6(c), unless an extension has been granted as specified in paragraph (e) of this section, except that the compliance date for the provisions contained in 40 CFR 63.1329 is temporarily extended from September 12, 1999, to February 27, 2001, for existing affected sources whose primary product, as determined using the procedures specified in § 63.1310(f), is PET using a continuous terephthalic acid high viscosity multiple end finisher process.<STARS/> </P> </SECTION> <SECTION> <SECTNO>§ 63.1312</SECTNO> <SUBJECT>Definitions.</SUBJECT> <P>(a) The following terms used in this subpart shall have the meaning given them in § 63.2, § 63.101, § 63.111, and § 63.161 as specified after each term:</P> <FP SOURCE="FP-2">Act (§ 63.2)</FP> <FP SOURCE="FP-2">Administrator (§ 63.2)</FP> <FP SOURCE="FP-2">Automated monitoring and recording system (§ 63.111)</FP> <FP SOURCE="FP-2">Average concentration (§ 63.111)</FP> <FP SOURCE="FP-2">Boiler (§ 63.111)</FP> <FP SOURCE="FP-2">Bottoms receiver (§ 63.161)</FP> <FP SOURCE="FP-2">By compound (§ 63.111)</FP> <FP SOURCE="FP-2">By-product (§ 63.101)</FP> <FP SOURCE="FP-2">Car-seal (§ 63.111)</FP> <FP SOURCE="FP-2">Chemical manufacturing process unit (§ 63.101)</FP> <FP SOURCE="FP-2">Closed-vent system (§ 63.111)</FP> <FP SOURCE="FP-2">Co-product (§ 63.101)</FP> <FP SOURCE="FP-2">Combustion device (§ 63.111)</FP> <FP SOURCE="FP-2">Commenced (§ 63.2)</FP> <FP SOURCE="FP-2">Compliance date (§ 63.2)</FP> <FP SOURCE="FP-2">Compliance schedule (§ 63.2)</FP> <FP SOURCE="FP-2">Connector (§ 63.161)</FP> <FP SOURCE="FP-2">Construction (§ 63.2)</FP> <FP SOURCE="FP-2">Continuous monitoring system (§ 63.2)</FP> <FP SOURCE="FP-2">Continuous record (§ 63.111)</FP> <FP SOURCE="FP-2">Continuous recorder (§ 63.111)</FP> <FP SOURCE="FP-2">Cover (§ 63.111)</FP> <FP SOURCE="FP-2">Distillation unit (§ 63.111)</FP> <FP SOURCE="FP-2">Emission standard (§ 63.2)</FP> <FP SOURCE="FP-2">Emissions averaging (§ 63.2)</FP> <FP SOURCE="FP-2">EPA (§ 63.2)</FP> <FP SOURCE="FP-2">Equipment (§ 63.161)</FP> <FP SOURCE="FP-2">Equipment leak (§ 63.101)</FP> <FP SOURCE="FP-2">Existing source (§ 63.2)</FP> <FP SOURCE="FP-2">External floating roof (§ 63.111)</FP> <FP SOURCE="FP-2">Fill (§ 63.111)</FP> <FP SOURCE="FP-2">Fixed roof (§ 63.111)</FP> <FP SOURCE="FP-2">Flame zone (§ 63.111)</FP> <FP SOURCE="FP-2">Flexible operation unit (§ 63.101)</FP> <FP SOURCE="FP-2">Floating roof (§ 63.111)</FP> <FP SOURCE="FP-2">Flow indicator (§ 63.111)</FP> <FP SOURCE="FP-2">Group 1 wastewater streams (§ 63.111)</FP> <FP SOURCE="FP-2">Group 2 wastewater streams (§ 63.111)</FP> <FP SOURCE="FP-2">Halogens and hydrogen halides (§ 63.111)</FP> <FP SOURCE="FP-2">Hazardous air pollutant (§ 63.2)</FP> <FP SOURCE="FP-2">Impurity (§ 63.101)</FP> <FP SOURCE="FP-2">In organic hazardous air pollutant service (§ 63.161)</FP> <FP SOURCE="FP-2">Incinerator (§ 63.111)</FP> <FP SOURCE="FP-2">Instrumentation system (§ 63.161)</FP> <FP SOURCE="FP-2">Internal floating roof (§ 63.111)</FP> <FP SOURCE="FP-2">Lesser quantity (§ 63.2)</FP> <FP SOURCE="FP-2">Major source (§ 63.2)</FP> <FP SOURCE="FP-2">Malfunction (§ 63.2)</FP> <FP SOURCE="FP-2">Mass flow rate (§ 63.111)</FP> <FP SOURCE="FP-2">Maximum true vapor pressure (§ 63.111)</FP> <FP SOURCE="FP-2">New source (§ 63.2)</FP> <FP SOURCE="FP-2">Open-ended valve or line (§ 63.161)</FP> <FP SOURCE="FP-2">Operating permit (§ 63.101)</FP> <FP SOURCE="FP-2">Organic HAP service (§ 63.161)</FP> <FP SOURCE="FP-2">Organic monitoring device (§ 63.111)</FP> <FP SOURCE="FP-2">Owner or operator (§ 63.2)</FP> <FP SOURCE="FP-2">Performance evaluation (§ 63.2)</FP> <FP SOURCE="FP-2">Performance test (§ 63.2)<PRTPAGE P="184"/> </FP> <FP SOURCE="FP-2">Permitting authority (§ 63.2)</FP> <FP SOURCE="FP-2">Plant site (§ 63.101)</FP> <FP SOURCE="FP-2">Point of generation (§ 63.111)</FP> <FP SOURCE="FP-2">Potential to emit (§ 63.2)</FP> <FP SOURCE="FP-2">Primary fuel (§ 63.111)</FP> <FP SOURCE="FP-2">Process heater (§ 63.111)</FP> <FP SOURCE="FP-2">Process unit shutdown (§ 63.161)</FP> <FP SOURCE="FP-2">Process wastewater (§ 63.101)</FP> <FP SOURCE="FP-2">Process wastewater stream (§ 63.111)</FP> <FP SOURCE="FP-2">Product separator (§ 63.111)</FP> <FP SOURCE="FP-2">Reactor (§ 63.111)</FP> <FP SOURCE="FP-2">Reconstruction (§ 63.2)</FP> <FP SOURCE="FP-2">Recovery device (§ 63.111)</FP> <FP SOURCE="FP-2">Reference control technology for process vents (§ 63.111)</FP> <FP SOURCE="FP-2">Reference control technology for storage vessels (§ 63.111)</FP> <FP SOURCE="FP-2">Reference control technology for wastewater (§ 63.111)</FP> <FP SOURCE="FP-2">Relief valve (§ 63.111)</FP> <FP SOURCE="FP-2">Research and development facility (§ 63.101)</FP> <FP SOURCE="FP-2">Residual (§ 63.111)</FP> <FP SOURCE="FP-2">Run (§ 63.2)</FP> <FP SOURCE="FP-2">Secondary fuel (§ 63.111)</FP> <FP SOURCE="FP-2">Sensor (§ 63.161)</FP> <FP SOURCE="FP-2">Shutdown (§ 63.2)</FP> <FP SOURCE="FP-2">Specific gravity monitoring device (§ 63.111)</FP> <FP SOURCE="FP-2">Start-up (§ 63.2)</FP> <FP SOURCE="FP-2">Start-up, shutdown, and malfunction plan (§ 63.101)</FP> <FP SOURCE="FP-2">State (§ 63.2)</FP> <FP SOURCE="FP-2">Surge control vessel (§ 63.161)</FP> <FP SOURCE="FP-2">Temperature monitoring device (§ 63.111)</FP> <FP SOURCE="FP-2">Test method (§ 63.2)</FP> <FP SOURCE="FP-2">Total resource effectiveness index value (§ 63.111)</FP> <FP SOURCE="FP-2">Treatment process (§ 63.111)</FP> <FP SOURCE="FP-2">Unit operation (§ 63.101)</FP> <FP SOURCE="FP-2">Visible emission (§ 63.2)</FP> <FP SOURCE="FP-2">Waste management unit (§ 63.111)</FP> <FP SOURCE="FP-2">Wastewater (§ 63.101)</FP> <FP SOURCE="FP-2">Wastewater stream (§ 63.111)</FP> <P>(b) All other terms used in this subpart shall have the meaning given them in this section. If a term is defined in §§ 63.2, 63.101, 63.111, or 63.161 and in this section, it shall have the meaning given in this section for purposes of this subpart.</P> <P> <E T="03">Acrylonitrile butadiene styrene latex resin (ABS latex)</E> means ABS produced through an emulsion process, however the product is not coagulated or dried as typically occurs in an emulsion process.</P> <P> <E T="03">Acrylonitrile butadiene styrene resin (ABS)</E> means styrenic terpolymers consisting primarily of acrylonitrile, 1,3-butadiene, and styrene monomer units. ABS is usually composed of a styrene-acrylonitrile copolymer continuous phase with dispersed butadiene derived rubber.</P> <P> <E T="03">Acrylonitrile styrene acrylate resin (ASA)</E> means a resin formed using acrylic ester-based elastomers to impact-modify styrene acrylonitrile resin matrices.</P> <P> <E T="03">Aggregate batch vent stream</E> means a gaseous emission stream containing only the exhausts from two or more batch process vents that are ducted together before being routed to a control device that is in continuous operation.</P> <P> <E T="03">Affected source</E> is defined in § 63.1310(a).</P> <P> <E T="03">Alpha methyl styrene acrylonitrile resin (AMSAN)</E> means copolymers consisting primarily of alpha methyl styrene and acrylonitrile.</P> <P> <E T="03">Average flow rate,</E> as used in conjunction with wastewater provisions, is determined by the specifications in § 63.144(c); or, as used in conjunction with batch process vent provisions, is determined by the specifications in § 63.1323(e).</P> <P> <E T="03">Batch cycle</E> means the operational step or steps, from start to finish, that occur as part of a batch unit operation. Batch cycle limitation means an enforceable restriction on the number of batch cycles that can be performed in a year for an individual batch process vent.</P> <P> <E T="03">Batch emission episode</E> means a discrete emission venting episode associated with a single batch unit operation. Multiple batch emission episodes may occur from a single batch unit operation.</P> <P> <E T="03">Batch process</E> means a discontinuous process involving the bulk movement of material through sequential manufacturing steps. Mass, temperature, concentration, and other properties of the process vary with time. Addition of raw material and withdrawal of product do not typically occur simultaneously in a batch process. For the purposes of this subpart, a process producing polymers is characterized as continuous or batch based on the operation of the polymerization reactors.<PRTPAGE P="185"/> </P> <P> <E T="03">Batch process vent</E> means a point of emission from a batch unit operation having a gaseous emission stream with annual organic HAP emissions greater than 225 kilograms per year. Batch process vents exclude relief valve discharges and leaks from equipment regulated under § 63.1331.</P> <P> <E T="03">Batch unit operation</E> means a unit operation operated in a batch process mode.</P> <P> <E T="03">Combustion device burner</E> means a device designed to mix and ignite fuel and air to provide a flame to heat and oxidize waste organic vapors in a combustion device.</P> <P> <E T="03">Compounding unit</E> means a unit operation which blends, melts, and resolidifies solid polymers for the purpose of incorporating additives, colorants, or stabilizers into the final thermoplastic product. A unit operation whose primary purpose is to remove residual monomers from polymers is not a compounding unit.</P> <P> <E T="03">Continuous process</E> means a process where the inputs and outputs flow continuously through sequential manufacturing steps throughout the duration of the process. Continuous processes typically approach steady-state conditions. Continuous processes typically involve the simultaneous addition of raw material and withdrawal of product. For the purposes of this subpart, a process producing polymers is characterized as continuous or batch based on the operation of the polymerization reactors.</P> <P> <E T="03">Continuous process vent</E> means a point of emission from a continuous unit operation within an affected source having a gaseous emission stream containing greater than 0.005 weight percent total organic HAP. Continuous process vents exclude relief valve discharges and leaks from equipment regulated under § 63.1331.</P> <P> <E T="03">Continuous unit operation</E> means a unit operation operated in a continuous process mode.</P> <P> <E T="03">Control device</E> is defined in § 63.111, except that the term “process vents” shall be replaced with the term “continuous process vents subject to § 63.1315” for the purpose of this subpart.</P> <P> <E T="03">Drawing unit</E> means a unit operation which converts polymer into a different shape by melting or mixing the polymer and then pulling it through an orifice to create a continuously extruded product.</P> <P> <E T="03">Emission point</E> means an individual continuous process vent, batch process vent, storage vessel, wastewater stream, equipment leak, heat exchange system, or process contact cooling tower.</P> <P> <E T="03">Emulsion process</E> means a process carried out with the reactants in an emulsified form (e.g., polymerization reaction).</P> <P> <E T="03">Expandable polystyrene resin (EPS)</E> means a polystyrene bead to which a blowing agent has been added using either an in-situ suspension process or a post-impregnation suspension process.</P> <P> <E T="03">Extruding unit</E> means a unit operation which converts polymer into a different shape by melting or mixing the polymer and then forcing it through an orifice to create a continuously extruded product.</P> <P> <E T="03">Group 1 batch process vent</E> means a batch process vent releasing annual organic HAP emissions greater than the level specified in § 63.1323(d) and with a cutoff flow rate, calculated in accordance with § 63.1323(f), greater than or equal to the annual average flow rate.</P> <P> <E T="03">Group 2 batch process vent</E> means a batch process vent that does not fall within the definition of a Group 1 batch process vent.</P> <P> <E T="03">Group 1 continuous process vent</E> means a continuous process vent releasing a gaseous emission stream that has a total resource effectiveness index value, calculated according to § 63.115, less than or equal to 1.0 unless the continuous process vent is associated with existing thermoplastic product process units that produce methyl methacrylate butadiene styrene resin, then said vent falls within the Group 1 definition if the released emission stream has a total resource effectiveness index value less than or equal to 3.7.</P> <P> <E T="03">Group 2 continuous process vent</E> means a continuous process vent that does not fall within the definition of a Group 1 continuous process vent.</P> <P> <E T="03">Group 1 storage vessel</E> means a storage vessel at an existing affected source that meets the applicability criteria specified in Table 2 or Table 3 of this <PRTPAGE P="186"/>subpart, or a storage vessel at a new affected source that meets the applicability criteria specified in Table 4 or Table 5 of this subpart.</P> <P> <E T="03">Group 2 storage vessel</E> means a storage vessel that does not fall within the definition of a Group 1 storage vessel.</P> <P> <E T="03">Halogenated aggregate batch vent stream</E> means an aggregate batch vent stream determined to have a total mass emission rate of halogen atoms contained in organic compounds of 3,750 kilograms per year or greater determined by the procedures specified in § 63.1323(h).</P> <P> <E T="03">Halogenated batch process vent</E> means a batch process vent determined to have a mass emission rate of halogen atoms contained in organic compounds of 3,750 kilograms per year or greater determined by the procedures specified in § 63.1323(h).</P> <P> <E T="03">Halogenated continuous process vent</E> means a continuous process vent determined to have a mass emission rate of halogen atoms contained in organic compounds of 0.45 kilograms per hour or greater determined by the procedures specified in § 63.115(d)(2)(v).</P> <P> <E T="03">Heat exchange system</E> means any cooling tower system or once-through cooling water system (e.g., river or pond water) designed and operated to not allow contact between the cooling medium and process fluid or gases (i.e., a noncontact system). A heat exchange system can include more than one heat exchanger and can include recirculating or once-through cooling systems.</P> <P> <E T="03">Maintenance wastewater</E> means wastewater generated by the draining of process fluid from components in the TPPU into an individual drain system prior to or during maintenance activities. Maintenance wastewater can be generated during planned and unplanned shutdowns and during periods not associated with a shutdown. Examples of activities that can generate maintenance wastewater include descaling of heat exchanger tubing bundles, cleaning distillation column traps, draining of low legs and high point bleeds, draining of pumps into an individual drain system, reactor and equipment washdown, and draining of portions of the TPPU for repair.</P> <P> <E T="03">Mass process</E> means a process carried out through the use of thermal energy (e.g., polymerization reaction). Mass processes do not utilize emulsifying or suspending agents, but can utilize catalysts or other additives.</P> <P> <E T="03">Material recovery section</E> means the equipment that recovers unreacted or by-product materials from any process section for return to the TPPU, off-site purification or treatment, or sale. Equipment used to store recovered materials are not included. Equipment designed to separate unreacted or by-product material from the polymer product are to be included in this process section, provided that at the time of initial compliance some of the material is recovered for reuse in the process, off-site purification or treatment, or sale. Otherwise, such equipment are to be assigned to one of the other process sections, as appropriate. If equipment are used to recover unreacted or by-product material and return it directly to the same piece of process equipment from which it was emitted, then said recovery equipment are considered part of the process section that contains the process equipment. On the other hand, if equipment are used to recover unreacted or by-product material and return it to a different piece of process equipment in the same process section, said recovery equipment are considered part of a material recovery section. Equipment that treats recovered materials are to be included in this process section, but equipment that also treats raw materials are not to be included in this process section. The latter equipment are to be included in the raw materials preparation section. Equipment used for the on-site recovery of ethylene glycol from PET plants, however, are not included in the material recovery section; they are to be included in the polymerization reaction section. Equipment used for the on-site recovery of ethylene glycol <E T="03">and</E> other materials (e.g., methanol) from PET plants are not included in the material recovery section; these equipment are to be included in the polymerization reaction section.</P> <P> <E T="03">Methyl methacrylate acrylonitrile butadiene styrene resin (MABS)</E> means styrenic polymers containing methyl <PRTPAGE P="187"/>methacrylate, acrylonitrile, butadiene, and styrene. MABS is prepared by dissolving or dispersing polybutadiene rubber in a mixture of methyl methacrylate-acrylonitrile-styrene and butadiene monomer. The graft polymerization is carried out by a bulk or a suspension process.</P> <P> <E T="03">Methyl methacrylate butadiene styrene resin (MBS)</E> means styrenic polymers containing methyl methacrylate, butadiene, and styrene. Production of MBS is achieved using an emulsion process in which methyl methacrylate and styrene are grafted onto a styrene-butadiene rubber.</P> <P> <E T="03">Nitrile resin</E> means a resin produced through the polymerization of acrylonitrile, methyl acrylate, and butadiene latex using an emulsion process.</P> <P> <E T="03">Organic hazardous air pollutant(s) (organic HAP)</E> means one or more of the chemicals listed in Table 6 of this subpart or any other chemical which is:</P> <P>(1) Knowingly introduced into the manufacturing process other than as an impurity, or has been or will be reported under any Federal or State program, such as Title V or the Emergency Planning and Community Right-To-Know Act section 311, 312, or 313; and</P> <P>(2) Listed in Table 2 of subpart F of this part.</P> <P> <E T="03">PET using a dimethyl terephthalate process</E> means the manufacturing of PET based on the esterification of dimethyl terephthalate with ethylene glycol to form the intermediate monomer bis-(2-hydroxyethyl)-terephthalate that is subsequently polymerized to form PET.</P> <P> <E T="03">PET using a terephthalic acid process</E> means the manufacturing of PET based on the esterification reaction of terephthalic acid with ethylene glycol to form the intermediate monomer bis-(2-hydroxyethyl)-terephthalate that is subsequently polymerized to form PET.</P> <P> <E T="03">Poly(ethylene terephthalate) resin (PET)</E> means a polymer or copolymer comprised of at least 50 percent bis-(2-hydroxyethyl)-terephthalate by weight.</P> <P> <E T="03">Polymerization reaction section</E> means the equipment designed to cause monomer(s) to react to form polymers, including equipment designed primarily to cause the formation of short polymer chains (e.g., oligomers or low polymers), but not including equipment designed to prepare raw materials for polymerization (e.g., esterification vessels). For the purposes of these standards, the polymerization reaction section begins with the equipment used to transfer the materials from the raw materials preparation section and ends with the last vessel in which polymerization occurs. Equipment used for the on-site recovery of ethylene glycol from PET plants, however, are included in this process section, rather than in the material recovery process section.</P> <P> <E T="03">Polystyrene resin</E> means a thermoplastic polymer or copolymer comprised of at least 80 percent styrene or para-methylstyrene by weight.</P> <P> <E T="03">Primary product</E> is defined in and determined by the procedures specified in § 63.1310(f).</P> <P> <E T="03">Process contact cooling tower system</E> means a cooling tower system that is designed and operated to allow contact between the cooling medium and process fluid or gases.</P> <P> <E T="03">Process section</E> means the equipment designed to accomplish a general but well-defined task in polymers production. Process sections include, but are not limited to, raw materials preparation, polymerization reaction, and material recovery. A process section may be dedicated to a single TPPU or common to more than one TPPU.</P> <P> <E T="03">Process unit</E> means a collection of equipment assembled and connected by pipes or ducts to process raw materials and to manufacture a product.</P> <P> <E T="03">Process vent</E> means a point of emission from a unit operation having a gaseous emission stream. Typical process vents include condenser vents, dryer vents, vacuum pumps, steam ejectors, and atmospheric vents from reactors and other process vessels, but do not include pressure relief valves.</P> <P> <E T="03">Product</E> means a compound or material which is manufactured by a process unit. By-products, isolated intermediates, impurities, wastes, and trace contaminants are not considered products.</P> <P> <E T="03">Raw materials preparation section</E> means the equipment at a polymer manufacturing plant designed to prepare raw materials, such as monomers and solvents, for polymerization. For <PRTPAGE P="188"/>the purposes of these standards, this process section begins with the equipment used to transfer raw materials from storage and/or the equipment used to transfer recovered material from the material recovery process sections, and ends with the last piece of equipment that prepares the material for polymerization. The raw materials preparation section may include equipment that is used to purify, dry, or otherwise treat raw materials or raw and recovered materials together; to activate catalysts; and to promote esterification including the formation of some short polymer chains (oligomers). The raw materials preparation section does not include equipment that is designed primarily to accomplish the formation of oligomers, the treatment of recovered materials alone, or the storage of raw materials.</P> <P> <E T="03">Recovery operations equipment</E> means the equipment used to separate the components of process streams. Recovery operations equipment includes distillation unit, condensers, etc. Equipment used for wastewater treatment shall not be considered recovery operations equipment.</P> <P> <E T="03">Solid state polymerization unit</E> means a unit operation which, through the application of heat, furthers the polymerization (i.e., increases the intrinsic viscosity) of polymer chips.</P> <P> <E T="03">Steady-state conditions</E> means that all variables (temperatures, pressures, volumes, flow rates, etc.) in a process do not vary significantly with time; minor fluctuations about constant mean values can occur.</P> <P> <E T="03">Storage vessel</E> means a tank or other vessel that is used to store liquids that contain one or more organic HAP and that has been assigned, according to the procedures in § 63.1310(g), to a TPPU that is subject to this subpart. Storage vessels do not include:</P> <P>(1) Vessels permanently attached to motor vehicles such as trucks, railcars, barges, or ships;</P> <P>(2) Pressure vessels designed to operate in excess of 204.9 kilopascals and without breathing or working losses to the atmosphere;</P> <P>(3) Vessels with capacities smaller than 38 cubic meters;</P> <P>(4) Vessels and equipment storing and/or handling material that contains no organic HAP and/or organic HAP as impurities only; and</P> <P>(5) Wastewater storage tanks.</P> <P> <E T="03">Supplemental combustion air</E> means the air that is added to a vent stream after the vent stream leaves the unit operation. Air that is part of the vent stream as a result of the nature of the unit operation is not considered supplemental combustion air. Air required to operate combustion device burner(s) is not considered supplemental combustion air.</P> <P> <E T="03">Styrene acrylonitrile resin (SAN)</E> means copolymers consisting primarily of styrene and acrylonitrile monomer units.</P> <P> <E T="03">Suspension process</E> means a process carried out with the reactants in a state of suspension, typically achieved through the use of water and/or suspending agents (e.g., polymerization reaction).</P> <P> <E T="03">Thermoplastic product</E> means one of the following types of products:</P> <P>(1) ABS latex;</P> <P>(2) ABS using a batch emulsion process;</P> <P>(3) ABS using a batch suspension process;</P> <P>(4) ABS using a continuous emulsion process;</P> <P>(5) ABS using a continuous mass process;</P> <P>(6) ASA/AMSAN;</P> <P>(7) EPS;</P> <P>(8) MABS;</P> <P>(9) MBS;</P> <P>(10) nitrile resin;</P> <P>(11) PET using a batch dimethyl terephthalate process;</P> <P>(12) PET using a batch terephthalic acid process;</P> <P>(13) PET using a continuous dimethyl terephthalate process;</P> <P>(14) PET using a continuous terephthalic acid process;</P> <P>(15) PET using a continuous terephthalic acid high viscosity multiple end finisher process;</P> <P>(16) Polystyrene resin using a batch process;</P> <P>(17) Polystyrene resin using a continuous process;</P> <P>(18) SAN using a batch process; or</P> <P>(19) SAN using a continuous process.<PRTPAGE P="189"/> </P> <P> <E T="03">Thermoplastic product process unit (TPPU)</E> means a collection of equipment assembled and connected by process pipes or ducts, excluding gas, sanitary sewage, water (i.e., not wastewater), and steam connections, used to process raw materials and to manufacture a thermoplastic product as its primary product. This collection of equipment includes process vents from process vessels; storage vessels, as determined in § 63.1310(g); and the equipment (i.e., pumps, compressors, agitators, pressure relief devices, sampling connection systems, open-ended valves or lines, valves, connectors, and instrumentation systems that are associated with the thermoplastic product process unit) that are subject to the equipment leak provisions as specified in § 63.1331.</P> <P> <E T="03">Total organic compounds (TOC)</E> means those compounds excluding methane and ethane measured according to the procedures of Method 18 or Method 25A, 40 CFR part 60, appendix A.</P> <P> <E T="03">Year</E> means any consecutive 12-month period or 365 rolling days. For the purposes of emissions averaging, the term year applies to any 12-month period selected by the facility and defined in its Emissions Averaging Plan. For the purposes of batch cycle limitations, the term year applies to the 12-month period defined by the facility in its Notification of Compliance Status.</P> <CITA>[61 FR 48229, Sept. 12, 1996, as amended at 64 FR 11547, Mar. 9, 1999]</CITA> </SECTION> <SECTION> <SECTNO>§ 63.1313</SECTNO> <SUBJECT>Emission standards.</SUBJECT> <P>(a) Except as allowed under paragraphs (b) and (c) of this section, the owner or operator of an existing or new affected source shall comply with the provisions in:</P> <P>(1) Section 63.1314 for storage vessels;</P> <P>(2) Sections 63.1315 or 63.1316 through 63.1320, as appropriate, for continuous process vents;</P> <P>(3) Section 63.1321 for batch process vents;</P> <P>(4) Section 63.1328 for heat exchange systems;</P> <P>(5) Section 63.1329 for process contact cooling towers;</P> <P>(6) Section 63.1330 for wastewater;</P> <P>(7) Section 63.1331 for equipment leaks;</P> <P>(8) Section 63.1333 for additional test methods and procedures;</P> <P>(9) Section 63.1334 for parameter monitoring levels and excursions; and</P> <P>(10) Section 63.1335 for general recordkeeping and reporting requirements.</P> <P>(b) Instead of complying with §§ 63.1314, 63.1315, 63.1316 through 63.1320, 63.1321, and 63.1330, the owner or operator of an existing affected source may elect to control any or all of the storage vessels, batch process vents, continuous process vents, and wastewater streams within the affected source to different levels using an emissions averaging compliance approach that uses the procedures specified in § 63.1332. An owner or operator electing to use emissions averaging must still comply with the provisions of §§ 63.1314, 63.1315, 63.1316 through 63.1320, 63.1321, and 63.1330 for affected source emission points not included in the emissions average.</P> <P>(c) A State may decide not to allow the use of the emissions averaging compliance approach specified in paragraph (b) of this section.</P> </SECTION> <SECTION> <SECTNO>§ 63.1314</SECTNO> <SUBJECT>Storage vessel provisions.</SUBJECT> <P>(a) This section applies to each storage vessel that belongs to an affected source, as determined by § 63.1310(g). Except as provided in paragraphs (b) through (d) of this section, the owner or operator of said storage vessels shall comply with the requirements of §§ 63.119 through 63.123 and 63.148, with the differences noted in paragraphs (a)(1) through (a)(16) of this section for the purposes of this subpart.</P> <P>(1) When the term “storage vessel” is used in §§ 63.119 through 63.123 and 63.148, the definition of this term in § 63.1312 shall apply for the purposes of this subpart.</P> <P>(2) When the term “Group 1 storage vessel” is used in §§ 63.119 through 63.123 and 63.148, the definition of this term in § 63.1312 shall apply for the purposes of this subpart.</P> <P>(3) When the term “Group 2 storage vessel” is used in §§ 63.119 through 63.123 and 63.148, the definition of this term in § 63.1312 shall apply for the purposes of this subpart.</P> <P>(4) When the emissions averaging provisions of § 63.150 are referred to in §§ 63.119 and 63.123, the emissions averaging provisions contained in § 63.1332 <PRTPAGE P="190"/>shall apply for the purposes of this subpart.</P> <P>(5) When December 31, 1992, is referred to in § 63.119, March 29, 1995 shall apply instead, for the purposes of this subpart.</P> <P>(6) When April 22, 1994, is referred to in § 63.119, September 12, 1996 shall apply instead, for the purposes of this subpart.</P> <P>(7) Each owner or operator shall comply with this paragraph (a)(7) instead of § 63.120(d)(1)(ii) for the purposes of this subpart. If the control device used to comply with this section is also used to comply with §§ 63.1315 through 63.1330, the performance test required for these sections is acceptable for demonstrating compliance with § 63.119(e) for the purposes of this subpart. The owner or operator is not required to prepare a design evaluation for the control device as described in § 63.120(d)(1)(i) for the purposes of this subpart if the performance test meets the criteria specified in § 63.120 (d)(1)(ii)(A) and (d)(1)(ii)(B).</P> <P>(8) When the term “operating range” is used in § 63.120(d)(3), the term “level” shall apply instead, for the purposes of this subpart. This level shall be established using the procedures specified in § 63.1334.</P> <P>(9) When the Notification of Compliance Status requirements contained in § 63.152(b) are referred to in §§ 63.120, 63.122, and 63.123, the Notification of Compliance Status requirements contained in § 63.1335(e)(5) shall apply for the purposes of this subpart.</P> <P>(10) When the Periodic Report requirements contained in § 63.152(c) are referred to in §§ 63.120, 63.122, and 63.123, the Periodic Report requirements contained in § 63.1335(e)(6) shall apply for the purposes of this subpart.</P> <P>(11) When other reports as required in § 63.152(d) are referred to in § 63.122, the reporting requirements contained in § 63.1335(e)(7) shall apply for the purposes of this subpart.</P> <P>(12) When the Implementation Plan requirements contained in § 63.151(c) are referred to in § 63.120 and § 63.122, the owner or operator of an affected source subject to this subpart need not comply for the purposes of this subpart.</P> <P>(13) When the Initial Notification Plan requirements contained in § 63.151(b) are referred to in § 63.122, the owner or operator of an affected source subject to this subpart need not comply for the purposes of this subpart.</P> <P>(14) When the determination of equivalence criteria in § 63.102(b) is referred to in § 63.121(a), the provisions in § 63.6(g) shall apply for the purposes of this subpart.</P> <P>(15) When a performance test is required under the provisions of § 63.120(d)(1)(ii), the use of Method 18 or Method 25A, 40 CFR part 60, appendix A is allowed for the purposes of this subpart. The use of Method 25A, 40 CFR part 60, appendix A shall comply with paragraphs (a)(15)(i) and (a)(15)(ii) of this section.</P> <P>(i) The organic HAP used as the calibration gas for Method 25A, 40 CFR part 60, appendix A shall be the single organic HAP representing the largest percent by volume of the emissions.</P> <P>(ii) The use of Method 25A, 40 CFR part 60, appendix A is acceptable if the response from the high-level calibration gas is at least 20 times the standard deviation of the response from the zero calibration gas when the instrument is zeroed on the most sensitive scale.</P> <P>(16) The compliance date for storage vessels at affected sources subject to the provisions of this section is specified in § 63.1311.</P> <P>(b) Owners or operators of Group 1 storage vessels that belong to a new affected source producing SAN using a continuous process shall control emissions to the levels indicated in paragraphs (b)(1) and (b)(2) of this section.</P> <P>(1) For storage vessels with capacities greater than or equal to 2,271 cubic meters (m<SU>3</SU>) containing a liquid mixture having a vapor pressure greater than or equal to 0.5 kilopascal (kPa) but less than 0.7 kPa, emissions shall be controlled by at least 90 percent relative to uncontrolled emissions.</P> <P>(2) For storage vessels with capacities less than 151 m<E T="51">3</E> containing a liquid mixture having a vapor pressure greater than or equal to 10 kPa, emissions shall be controlled by at least 98 percent relative to uncontrolled emissions.<PRTPAGE P="191"/> </P> <P>(3) For all other storage vessels designated as Group 1 storage vessels, emissions shall be controlled to the level designated in § 63.119.</P> <P>(c) Owners or operators of Group 1 storage vessels that belong to a new or existing affected source producing ASA/AMSAN shall control emissions by at least 98 percent relative to uncontrolled emissions.</P> <P>(d) The provisions of this subpart do not apply to storage vessels containing ethylene glycol at existing or new affected sources and storage vessels containing styrene at existing affected sources.</P> <CITA>[61 FR 48229, Sept. 12, 1996, as amended at 64 FR 11547, Mar. 9, 1999]</CITA> </SECTION> <SECTION> <SECTNO>§ 63.1315</SECTNO> <SUBJECT>Continuous process vents provisions.</SUBJECT> <P>(a) For each continuous process vent located at an affected source, the owner or operator shall comply with the requirements of §§ 63.113 through 63.118, with the differences noted in paragraphs (a)(1) through (a)(18) of this section for the purposes of this subpart, except as provided in paragraphs (b) through (e) of this section.</P> <P>(1) When the term “process vent” is used in §§ 63.113 through 63.118, apply the term “continuous process vent,” and the definition of this term in § 63.1312 shall apply for the purposes of this subpart.</P> <P>(2) When the term “Group 1 process vent” is used in §§ 63.113 through 63.118, apply the term “Group 1 continuous process vent,” and the definition of this term in § 63.1312 shall apply for the purposes of this subpart.</P> <P>(3) When the term “Group 2 process vent” is used in §§ 63.113 through 63.118, apply the term “Group 2 continuous process vent,” and the definition of this term in § 63.1312 shall apply for the purposes of this subpart.</P> <P>(4) When December 31, 1992, (i.e., subpart G of this part proposal date) is referred to in § 63.113, apply the date March 29, 1995 (i.e., proposal date for this subpart) for the purposes of this subpart.</P> <P>(5) When § 63.151(f), alternative monitoring parameters, and § 63.152(e), submission of an operating permit, are referred to in §§ 63.114(c) and 63.117(e), § 63.1335(f), alternative monitoring parameters, and § 63.1335(e)(8), submission of an operating permit, respectively, shall apply for the purposes of this subpart.</P> <P>(6) When the Notification of Compliance Status requirements contained in § 63.152(b) are referred to in §§ 63.114, 63.117, and 63.118, the Notification of Compliance Status requirements contained in § 63.1335(e)(5) shall apply for the purposes of this subpart.</P> <P>(7) When the Periodic Report requirements contained in § 63.152(c) are referred to in §§ 63.117 and 63.118, the Periodic Report requirements contained in § 63.1335(e)(6) shall apply for the purposes of this subpart.</P> <P>(8) When the definition of excursion in § 63.152(c)(2)(ii)(A) is referred to in § 63.118(f)(2), the definition of excursion in § 63.1334(f) of this subpart shall apply for the purposes of this subpart.</P> <P>(9) Owners and operators shall comply with § 63.1334, parameter monitoring levels and excursions, instead of § 63.114(e) for the purposes of this subpart. When the term “range” is used in §§ 63.117 and 63.118, the term “level” shall be used instead for the purposes of this subpart. This level is determined in accordance with § 63.1334.</P> <P>(10) If a batch process vent is combined with a continuous process vent prior to being routed to a control device, the combined vent stream shall comply with either paragraph (a)(10)(i) or (a)(10)(ii) of this section, as appropriate.</P> <P>(i) If the continuous process vent is a Group 1 continuous process vent, the combined vent stream shall comply with all requirements for a Group 1 continuous process vent stream in §§ 63.113 through 63.118, with the differences noted in paragraphs (a)(1) through (a)(9) of this section, for the purposes of this subpart.</P> <P>(ii) If the continuous process vent is a Group 2 continuous process vent, the total resource effectiveness (TRE) index value for the combined vent stream shall be calculated at the exit of any recovery device and prior to the control device at maximum representative operating conditions. For combined vent streams containing continuous and batch process vents, the maximum representative operating conditions shall be during periods when <PRTPAGE P="192"/>batch emission episodes are venting to the control device, resulting in the highest concentration of organic HAP in the combined vent stream.</P> <P>(11) If a batch process vent is combined with a continuous process vent prior to being routed to a recovery device, the TRE index value for the combined vent stream shall be calculated at the exit of the recovery device at maximum representative operating conditions for the purposes of this subpart. For combined vent streams containing continuous and batch process vents, the maximum representative operating conditions shall be during periods when batch emission episodes are venting to the recovery device, resulting in the highest concentration of organic HAP in the combined vent stream.</P> <P>(12) When reports of process changes are required under § 63.118 (g), (h), (i), and (j), paragraphs (a)(12)(i) through (a)(12)(iv) of this section shall apply for the purposes of this subpart.</P> <P>(i) For the purposes of this subpart, whenever a process change, as defined in § 63.115(e), is made that causes a Group 2 continuous process vent to become a Group 1 continuous process vent, the owner or operator shall submit a report within 180 operating days after the process change is made or the information regarding the process change is known to the owner or operator. This report may be included in the next Periodic Report, as specified in § 63.1335(e)(6)(iii)(D)(<E T="03">2</E>). The following information shall be submitted:</P> <P>(A) A description of the process change; and</P> <P>(B) A schedule for compliance with the provisions of this subpart, as required under § 63.1335(e)(6)(iii)(D)(<E T="03">2</E>).</P> <P>(ii) Whenever a process change, as defined in § 63.115(e), is made that causes a Group 2 process vent with a TRE greater than 4.0 to become a Group 2 process vent with a TRE less than 4.0, the owner or operator shall submit a report within 180 operating days after the process change is made or the information regarding the process change is known to the owner or operator. This report may be included in the next Periodic Report, as specified in § 63.1335(e)(6)(iii)(D)(<E T="03">2</E>). The following information shall be submitted:</P> <P>(A) A description of the process change; and</P> <P>(B) A schedule for compliance with the provisions of this subpart, as required under § 63.1335(e)(6)(iii)(D)(<E T="03">2</E>).</P> <P>(iii) Whenever a process change, as defined in § 63.115(e), is made that causes a Group 2 process vent with a flow rate less than 0.005 standard cubic meter per minute to become a Group 2 process vent with a flow rate of 0.005 standard cubic meter per minute or greater and a TRE index value less than or equal to 4.0, the owner or operator shall submit a report within 180 operating days after the process change is made or the information regarding the process change is known to the owner or operator. This report may be included in the next Periodic Report, as specified in § 63.1335(e)(6)(iii)(D)(<E T="03">2</E>). The following information shall be submitted:</P> <P>(A) A description of the process change; and</P> <P>(B) A schedule for compliance with the provisions of this subpart, as required under § 63.1335(e)(6)(iii)(D)(<E T="03">2</E>).</P> <P>(iv) Whenever a process change, as defined in § 63.115(e), is made that causes a Group 2 process vent with an organic HAP concentration less than 50 parts per million by volume to become a Group 2 process vent with an organic HAP concentration of 50 parts per million by volume or greater and a TRE index value less than or equal to 4.0, the owner or operator shall submit a report within 180 operating days after the process change is made or the information regarding the process change is known to the owner or operator. This report may be included in the next Periodic Report, as specified in § 63.1335(e)(6)(iii)(D)(<E T="03">2</E>). The following information shall be submitted:</P> <P>(A) A description of the process change; and</P> <P>(B) A schedule for compliance with the provisions of this subpart, as required under § 63.1335(e)(6)(iii)(D)(<E T="03">2</E>).</P> <P>(13) When the provisions of § 63.116 (c)(3) and (c)(4) specify that Method 18, 40 CFR part 60, appendix A shall be used, Method 18 or Method 25A, 40 CFR part 60, appendix A may be used for the purposes of this subpart. The use of Method 25A, 40 CFR part 60, appendix A <PRTPAGE P="193"/>shall comply with paragraphs (a)(13)(i) and (a)(13)(ii) of this section.</P> <P>(i) The organic HAP used as the calibration gas for Method 25A, 40 CFR part 60, appendix A shall be the single organic HAP representing the largest percent by volume of the emissions.</P> <P>(ii) The use of Method 25A, 40 CFR part 60, appendix A is acceptable if the response from the high-level calibration gas is at least 20 times the standard deviation of the response from the zero calibration gas when the instrument is zeroed on the most sensitive scale.</P> <P>(14) When the provisions of § 63.116(b) identify conditions under which a performance test is not required, for purposes of this subpart, the exemption in paragraph (a)(14)(i) shall also apply. Further, if a performance test meeting the conditions specified in paragraph (a)(14)(ii) of this section has been conducted by the owner or operator, the results of said performance test may be submitted and a performance test, as required by this section, is not required.</P> <P>(i) An incinerator burning hazardous waste for which the owner or operator complies with the requirements of 40 CFR part 264, subpart O.</P> <P>(ii) Performance tests done for other subparts in 40 CFR part 60 or part 63 where total organic HAP or TOC was measured, provided the owner or operator can demonstrate that operating conditions for the process and control or recovery device during the performance test are representative of current operating conditions.</P> <P>(15) The compliance date for continuous process vents subject to the provisions of this section is specified in § 63.1311.</P> <P>(16)-(17) [Reserved]</P> <P>(18) When a combustion device is used to comply with the 20 parts per million by volume outlet concentration standard specified in § 63.113(a)(2), the correction to 3 percent oxygen is only required when supplemental combustion air is used to combust the emissions, for the purposes of this subpart. In addition, the correction to 3 percent oxygen specified in § 63.116(c)(3) and (c)(3)(iii) is only required when supplemental combustion air is used to combust the emissions, for the purposes of this subpart. Finally, when a combustion device is used to comply with the 20 parts per million by volume outlet concentration standard specified in § 63.113(a)(2), an owner or operator shall record and report the outlet concentration required in § 63.117(a)(4)(ii) and (a)(4)(iv) corrected to 3 percent oxygen when supplemental combustion air is used to combust the emissions, for the purposes of this subpart. When supplemental combustion air is not used to combust the emissions, an owner or operator may record and report the outlet concentration required in § 63.117(a)(4)(ii) and (a)(4)(iv) on an uncorrected basis or corrected to 3 percent oxygen, for the purposes of this subpart.</P> <P>(b) Existing affected sources producing MBS shall comply with either paragraph (b)(1) or (b)(2) of this section.</P> <P>(1) Comply with paragraph (a) of this section, as specified in paragraphs (b)(1)(i) and (b)(1)(ii).</P> <P>(i) As specified in § 63.1312, Group 1 continuous process vents at MBS existing affected sources are those with a total resource effectiveness value less than or equal to 3.7.</P> <P>(ii) When complying with this paragraph (b), the term “TRE of 4.0”, or related terms indicating a TRE value of 4.0, referred to in § 63.113 through § 63.118 shall be replaced with “TRE of 6.7,” for the purposes of this subpart. The TRE range of 3.7 to 6.7 for continuous process vents at existing affected sources producing MBS corresponds to the TRE range of 1.0 to 4.0 for other continuous process vents, as it applies to monitoring, recordkeeping, and reporting.</P> <P>(2) Not allow organic HAP emissions from the collection of continuous process vents at the affected source to be greater than 0.000590 kg organic HAP/Mg of product. Compliance with this paragraph (b)(2) shall be determined using the procedures specified in § 63.1333(b).</P> <P>(c) New affected sources producing SAN using a batch process shall comply with the applicable requirements in § 63.1321.</P> <P>(d) Affected sources producing PET or polystyrene using a continuous process are subject to the emissions <PRTPAGE P="194"/>control provisions of § 63.1316, the monitoring provisions of § 63.1317, the testing and compliance demonstration provisions of § 63.1318, the recordkeeping provisions of § 63.1319, and the reporting provisions of § 63.1320.</P> <P>(e) Owners or operators of affected sources producing ASA/AMSAN shall reduce organic HAP emissions from each continuous process vent, each batch process vent, and each aggregate batch vent stream by 98 weight-percent and shall comply with either paragraph (e)(1), (e)(2), or (e)(3), as appropriate. Where batch process vents or aggregate batch vent streams are combined with continuous process vents, the provisions of paragraph (a)(13) of this section shall apply for the purposes of this paragraph (e).</P> <P>(1) For each continuous process vent, comply with paragraph (a) of this section as specified in paragraphs (e)(1)(i) through (e)(1)(ii) of this section.</P> <P>(i) For purpose of this section, each continuous process vent shall be considered to be a Group 1 continuous process vent and the owner or operator of that continuous process vent shall comply with the requirements for a Group 1 continuous process vent.</P> <P>(ii) For purposes of this section, the group determination procedure required by § 63.115 shall not apply.</P> <P>(2) For each batch process vent, comply with §§ 63.1321 through 63.1327 as specified in paragraphs (e)(2)(i) through (e)(2)(ii) of this section.</P> <P>(i) For purpose of this section, each batch process vent shall be considered to be a Group 1 batch process vent and the owner or operator of that batch process vent shall comply with the requirements for a Group 1 batch process vent contained in §§ 63.1321 through 63.1327, except that each batch process vent shall be controlled to reduce organic HAP emissions by 98 weight-percent.</P> <P>(ii) For purposes of this section, the group determination procedure required by § 63.1323 shall not apply.</P> <P>(3) For each aggregate batch vent stream, comply with §§ 63.1321 through 63.1327 as specified in paragraphs (e)(3)(i) through (e)(3)(ii) of this section.</P> <P>(i) For purpose of this section, each aggregate batch vent stream shall be considered to be a Group 1 aggregate batch vent stream and the owner or operator of that aggregate batch vent stream shall comply with the requirements for a Group 1 aggregate batch vent stream contained in §§ 63.1321 through 63.1327, except that each aggregate batch vent stream shall be controlled to reduce organic HAP emissions by 98 weight-percent.</P> <P>(ii) For purposes of this section, the group determination procedure required by § 63.1323 shall not apply.</P> <CITA>[61 FR 48229, Sept. 12, 1996, as amended at 64 FR 11547, Mar. 9, 1999]</CITA> </SECTION> <SECTION> <SECTNO>§ 63.1316</SECTNO> <SUBJECT>PET and polystyrene affected sources—emissions control provisions.</SUBJECT> <P>(a) The owner or operator of an affected source producing PET using a continuous process shall comply with paragraph (b) of this section. The owner or operator of an affected source producing polystyrene using a continuous process shall comply with paragraph (c) of this section.</P> <P>(b) Each owner or operator of an affected source producing PET using a continuous process shall comply with the requirements specified in paragraphs (b)(1) or (b)(2) of this section, as appropriate, and not with any of the requirements specified in 40 CFR part 60, subpart DDD. Compliance can be based on either organic HAP or TOC.</P> <P>(1) Each owner or operator of an affected source producing PET using a continuous dimethyl terephthalate process shall comply with paragraphs (b)(1)(i) through (b)(1)(iv) of this section.</P> <P>(i) The owner or operator of an existing affected source with organic HAP emissions greater than 0.12 kg organic HAP per Mg of product from continuous process vents in the collection of material recovery sections (i.e., methanol recovery) within the affected source shall comply with either paragraph (b)(1)(i)(A), (b)(1)(i)(B), or (b)(1)(i)(C) of this section. Emissions from continuous process vents in the collection of material recovery sections within the affected source shall be determined by the procedures specified in § 63.1318(b). The owner or operator of a new affected source shall comply with either paragraph (b)(1)(i)(A), <PRTPAGE P="195"/>(b)(1)(i)(B), or (b)(1)(i)(C) of this section.</P> <P>(A) Organic HAP emissions from all continuous process vents in each individual material recovery section shall, as a whole, be no greater than 0.018 kg organic HAP per Mg of product from the associated TPPU(s); or alternatively, organic HAP emissions from all continuous process vents in the collection of material recovery sections within the affected source shall, as a whole, be no greater than 0.018 kg organic HAP per Mg product from all associated TPPU(s);</P> <P>(B) As specified in § 63.1318(d), the owner or operator shall maintain the daily average outlet gas stream temperature from each final condenser in a material recovery section at a temperature of +3°C (+37°F) or less (i.e., colder); or</P> <P>(C) Comply with paragraph (b)(1)(v) of this section.</P> <P>(ii) Limit organic HAP emissions from continuous process vents in the collection of polymerization reaction sections within the affected source by complying with either paragraph (b)(1)(ii)(A) or (b)(1)(ii)(B) of this section.</P> <P>(A) Organic HAP emissions from all continuous process vents in each individual polymerization reaction section within the affected source (including emissions from any equipment used to further recover ethylene glycol, but excluding emissions from process contact cooling towers) shall, as a whole, be no greater than 0.02 kg organic HAP per Mg of product from the associated TPPU(s); or alternatively, organic HAP emissions from all continuous process vents in the collection of polymerization reaction sections within the affected source shall, as a whole, be no greater than 0.02 kg organic HAP per Mg product from all associated TPPU(s); or</P> <P>(B) Comply with paragraph (b)(1)(v) of this section.</P> <P>(iii) Limit organic HAP emissions from continuous process vents not included in a material recovery section, as specified in paragraph (b)(1)(i) of this section, or not included in a polymerization reaction section, as specified in paragraph (b)(1)(ii) of this section, by complying with § 63.1315.</P> <P>(iv) Limit organic HAP emissions from all batch process vents by complying with § 63.1321.</P> <P>(v) Comply with one of the following:</P> <P>(A) Reduce the emissions in a combustion device to achieve 98 weight percent reduction or to achieve a concentration of 20 parts per million by volume (ppmv) on a dry basis, whichever is less stringent. If an owner or operator elects to comply with the 20 ppmv standard, the concentration shall include a correction to 3 percent oxygen only when supplemental combustion air is used to combust the emissions;</P> <P>(B) Combust the emissions in a boiler or process heater with a design heat input capacity of 150 million Btu/hr or greater by introducing the emissions into the flame zone of the boiler or process heater; or</P> <P>(C) Combust the emissions in a flare that complies with the requirements of § 63.1333(e).</P> <P>(2) Each owner or operator of an affected source producing PET using a continuous terephthalic acid process shall comply with paragraphs (b)(2)(i) through (b)(2)(iv) of this section.</P> <P>(i) Limit organic HAP emissions from continuous process vents in the collection of raw material preparation sections within the affected source by complying with either paragraph (b)(2)(i)(A) or (b)(2)(i)(B) of this section.</P> <P>(A) Organic HAP emissions from all continuous process vents associated with the esterification vessels in each individual raw materials preparation section shall, as a whole, be no greater than 0.04 kg organic HAP per Mg of product from the associated TPPU(s); or alternatively, organic HAP emissions from all continuous process vents associated with the esterification vessels in the collection of raw material preparation sections within the affected source shall, as a whole, be no greater than 0.04 kg organic HAP per Mg of product from all associated TPPU(s). Other continuous process vents (i.e., those not associated with the esterification vessels) in the collection of raw materials preparation sections within the affected source shall comply with § 63.1315; or</P> <P>(B) Comply with paragraph (b)(2)(v) of this section.<PRTPAGE P="196"/> </P> <P>(ii) Limit organic HAP emissions from continuous process vents in the collection of polymerization reaction sections within the affected source by complying with either paragraph (b)(2)(ii)(A) or (b)(2)(ii)(B) of this section.</P> <P>(A) Organic HAP emissions from all continuous process vents in each individual polymerization reaction section (including emissions from any equipment used to further recover ethylene glycol, but excluding emissions from process contact cooling towers) shall, as a whole, be no greater than 0.02 kg organic HAP per Mg of product from the associated TPPU(s); or alternatively, organic HAP emissions from all continuous process vents in the collection of polymerization reaction sections within the affected source shall, as a whole, be no greater than 0.02 kg organic HAP per Mg of product from all associated TPPU(s); or</P> <P>(B) Comply with paragraph (b)(2)(v) of this section.</P> <P>(iii) Limit organic HAP emissions from continuous process vents not included in a raw materials preparation section, as specified in paragraphs (b)(2)(i) of this section, or not included in a polymerization reaction section, as specified in paragraph (b)(2)(ii) of this section, by complying with § 63.1315.</P> <P>(iv) Limit organic HAP emissions from all batch process vents by complying with § 63.1321.</P> <P>(v) Comply with one of the following:</P> <P>(A) Reduce the emissions in a combustion device to achieve 98 weight percent reduction or to achieve a concentration of 20 parts per million by volume (ppmv) on a dry basis, whichever is less stringent. If an owner or operator elects to comply with the 20 ppmv standard, the concentration shall include a correction to 3 percent oxygen only when supplemental combustion air is used to combust the emissions;</P> <P>(B) Combust the emissions in a boiler or process heater with a design heat input capacity of 150 million Btu/hr or greater by introducing the emissions into the flame zone of the boiler or process heater; or</P> <P>(C) Combust the emissions in a flare that complies with the requirements of § 63.1333(e).</P> <P>(c) Each owner or operator of an affected source producing polystyrene resin using a continuous process shall comply with the requirements specified in paragraphs (c)(1) through (c)(3) of this section, as appropriate, and not with any of the requirements specified in 40 CFR part 60, subpart DDD. Compliance can be based on either organic HAP or TOC.</P> <P>(1) Limit organic HAP emissions from continuous process vents in the collection of material recovery sections within the affected source by complying with one of the following:</P> <P>(i) Not allow emissions to be greater than 0.0036 kg organic HAP/Mg of product;</P> <P>(ii) Not allow the outlet gas stream temperature from each final condenser in a material recovery section to exceed ^25°C (^13°F); or</P> <P>(iii) Comply with one of the following:</P> <P>(A) Reduce emissions by 98 weight percent or to a concentration of 20 parts per million by volume (ppmv) on a dry basis, whichever is less stringent. If an owner or operator elects to comply with the 20 ppmv standard, the concentration shall include a correction to 3 percent oxygen only when supplemental combustion air is used to combust the emissions;</P> <P>(B) Combust the emissions in a boiler or process heater with a design heat input capacity of 150 million Btu/hr or greater by introducing the emissions into the flame zone of the boiler or process heater; or</P> <P>(C) Combust the emissions in a flare that complies with the requirements of § 63.11(b).</P> <P>(2) Limit organic HAP emissions from continuous process vents not included in a material recovery section, as specified in paragraph (c)(1)(i) of this section, by complying with § 63.1315.</P> <P>(3) Limit organic HAP emissions from all batch process vents by complying with § 63.1321.</P> <CITA>[61 FR 48229, Sept. 12, 1996, as amended at 64 FR 11548, Mar. 9, 1999]</CITA> </SECTION> <SECTION> <PRTPAGE P="197"/> <SECTNO>§ 63.1317</SECTNO> <SUBJECT>PET and polystyrene continuous process affected sources—monitoring provisions.</SUBJECT> <P>Continuous process vents using a control or recovery device to comply with § 63.1316 shall comply with the applicable monitoring provisions specified for continuous process vents in § 63.1315(a), except as specified in paragraphs (a) and (b) of this section.</P> <P>(a) For the purposes of paragraph (a) of this section, owners or operators shall ignore references to group determinations (i.e., total resource effectiveness) and are not required to comply with § 63.113.</P> <P>(b) The monitoring period for condenser exit temperature when complying with § 63.1316(b)(1)(i)(B) or § 63.1316(c)(1)(ii) shall be each consecutive 3-hour continuous period (e.g., 6 am to 9 am, 9 am to 12 pm). Each owner or operator shall designate said monitoring period in the Notification of Compliance Status required by § 63.1335(e)(5).</P> </SECTION> <SECTION> <SECTNO>§ 63.1318</SECTNO> <SUBJECT>PET and polystyrene continuous process affected sources—testing and compliance demonstration provisions.</SUBJECT> <P>(a) Except as specified in paragraphs (b) through (d) of this section, continuous process vents using a control or recovery device to comply with § 63.1316 shall comply with the applicable testing and compliance provisions for continuous process vents specified in § 63.1315, except that, for the purposes of this paragraph (a), owners or operators shall ignore references to group determination (i.e., total resource effectiveness) and are not required to comply with § 63.113.</P> <P>(b) <E T="03">PET Affected Sources Using a Dimethyl Terephthalate Process—Applicability Determination Procedure</E>. Owners or operators shall calculate organic HAP emissions from the collection of material recovery sections at an existing affected source producing PET using a continuous dimethyl terephthalate process to determine whether § 63.1316(a)(1)(i) is applicable using the procedures specified in either paragraph (b)(1) or (b)(2) of this section.</P> <P>(1) Use Equation 1 of this subpart to determine mass emissions per mass product as specified in paragraphs (b)(1)(i) and (b)(1)(ii) of this section.</P> <GPH DEEP="34" SPAN="1"> <GID>ER12SE96.000</GID> </GPH> <FP>where:</FP> <FP SOURCE="FP-2">ER=Emission rate of total organic HAP or TOC, kg/Mg product.</FP> <FP SOURCE="FP-2">E<E T="52">i</E>=Emission rate of total organic HAP or TOC in continuous process vent i, kg/hr.</FP> <FP SOURCE="FP-2">P<E T="52">p</E>=The rate of polymer produced, kg/hr.</FP> <FP SOURCE="FP-2">n=Number of continuous process vents in the collection of material recovery sections at the affected source.</FP> <FP SOURCE="FP-2">0.001=Conversion factor, kg to Mg.</FP> <P>(i) The mass emission rate for each continuous process vent, E<E T="52">i</E>, shall be determined according to the procedures specified in § 63.116(c)(4). The sampling site for determining whether § 63.1316(a)(1)(i) is applicable shall be before any add-on control devices (i.e., those required by regulation) and after those recovery devices installed as part of operating the material recovery section. When the provisions of § 63.116(c)(4) specify that Method 18, 40 CFR part 60, appendix A shall be used, Method 18 or Method 25A, 40 CFR part 60, appendix A may be used for the purposes of this subpart. The use of Method 25A, 40 CFR part 60, appendix A shall comply with paragraphs (b)(1)(i)(A) and (b)(1)(i)(B) of this section.</P> <P>(A) The organic HAP used as the calibration gas for Method 25A, 40 CFR part 60, appendix A shall be the single organic HAP representing the largest percent by volume of the emissions.</P> <P>(B) The use of Method 25A, 40 CFR part 60, appendix A is acceptable if the response from the high-level calibration gas is at least 20 times the standard deviation of the response from the zero calibration gas when the instrument is zeroed on the most sensitive scale.</P> <P>(ii) The rate of polymer produced, P<E T="52">p</E> (kg/hr), shall be determined by dividing the weight (kg) of polymer pulled from the process line during the performance test by the number of hours taken to perform the performance test. The <PRTPAGE P="198"/>weight of polymer pulled shall be determined by direct measurement or by an alternate methodology, such as materials balance. If an alternate methodology is used, a description of the methodology, including all procedures, data, and assumptions shall be submitted as part of the Notification of Compliance Status required by § 63.1335(e)(5).</P> <P>(2) Use engineering assessment, as described in § 63.1323(b)(6)(i), to demonstrate that mass emissions per mass product are less than or equal to 0.07 kg organic HAP/Mg product. If engineering assessment shows that mass emissions per mass product are greater than 0.07 kg organic HAP/Mg product and the owner or operator wishes to demonstrate that mass emissions per mass product are less than the threshold emission rate of 0.12 kg organic HAP/Mg product, the owner or operator shall use the procedures specified in paragraph (b)(1) of this section.</P> <P>(c) <E T="03">Compliance with Mass Emissions per Mass Product Standards.</E> Owners or operators complying with § 63.1316 (b)(1)(i)(A), (b)(1)(ii), (b)(2)(i), (b)(2)(ii), and (c)(1)(i) shall demonstrate compliance with the mass emissions per mass product requirements using the procedures specified in paragraph (b)(1) of this section, except that the sampling site specified in paragraph (b)(1)(i) of this section shall be at the outlet of the last control or recovery device.</P> <P>(d) <E T="03">Compliance with Temperature Limits for Final Condensers.</E> Owners or operators complying with § 63.1316(b)(1)(i)(B) or § 63.1316(c)(1)(ii) shall perform an initial performance test as specified in paragraph (d)(1) of this section to demonstrate initial compliance with the temperature limit requirements and shall demonstrate continuous compliance as specified in paragraph (d)(2) of this section.</P> <P>(1) Using the temperature monitoring device specified by the applicable monitoring provisions specified for continuous process vents in § 63.1315, an average exit temperature shall be determined based on the average exit temperature for three performance tests. The average exit temperature for each 3-hour performance test shall be based on measurements taken at least every 15 minutes for 3 hours of continuous operation under maximum representative operating conditions for the process. For emissions streams containing continuous and batch process vents, the maximum representative operating conditions shall be during periods when batch emission episodes are venting to the control device resulting in the highest concentration of organic HAP in the emissions stream.</P> <P>(2) As specified in § 63.1317(b), continuous compliance shall be determined based on an average exit temperature determined for each consecutive 3-hour continuous period. Each 3-hour period where the average exit temperature is more than 6 °C (10 °F) above the applicable specified temperature limit shall be considered an exceedance of the monitoring provisions.</P> </SECTION> <SECTION> <SECTNO>§ 63.1319</SECTNO> <SUBJECT>PET and polystyrene continuous process affected sources—recordkeeping provisions.</SUBJECT> <P>(a) Except as specified in paragraphs (b) and (c) of this section, owners or operators using a control or recovery device to comply with § 63.1316 shall comply with the applicable recordkeeping provisions specified in § 63.1315, except that, for the purposes of this paragraph (a), owners or operators shall ignore references to group determinations (i.e., total resource effectiveness) and are not required to comply with § 63.113.</P> <P>(b) <E T="03">Records Demonstrating Compliance With the Applicability Determination Procedure for PET Affected Sources Using a Dimethyl Terephthalate Process.</E> Each owner or operator, as appropriate, shall keep the following data, as appropriate, up-to-date and readily accessible:</P> <P>(1) Results of the mass emissions per mass product calculation specified in § 63.1318(b).</P> <P>(2) If complying with § 63.1316 by demonstrating that mass emissions per mass product are less than or equal to the level specified in § 63.1316(a)(1)(i), the information specified in paragraphs (b)(2)(i) and (b)(2)(ii) of this section.</P> <P>(i) Each process operation variable (e.g., pressure, temperature, type of catalyst) that may result in an increase in the mass emissions per mass product should said variable be changed.<PRTPAGE P="199"/> </P> <P>(ii) Records of any change in process operation that increases the mass emissions per mass product.</P> <P>(c) <E T="03">Records Demonstrating Compliance with Temperature Limits for Final Condensers.</E> Owners or operators of continuous process vents complying with § 63.1316(b)(1)(i)(B) or § 63.1316(c)(1)(ii) shall keep the following data, as appropriate, up-to-date and readily accessible:</P> <P>(1) Records of monitoring data as specified in § 63.1315, except that the monitoring period shall be each consecutive 3-hour continuous period.</P> <P>(2) Results of the performance test specified in § 63.1318(d)(1) and any other performance test that may be subsequently required.</P> </SECTION> <SECTION> <SECTNO>§ 63.1320</SECTNO> <SUBJECT>PET and polystyrene continuous process affected sources—reporting provisions.</SUBJECT> <P>(a) Except as specified in paragraphs (b) and (c) of this section, owners and operators using a control or recovery device to comply with § 63.1316 shall comply with the applicable reporting provisions specified in § 63.1315, except that, for the purposes of this paragraph (a), owners or operators shall ignore references to group determinations (i.e., total resource effectiveness) and are not required to comply with § 63.113.</P> <P>(b) <E T="03">Reporting for PET Affected Sources Using a Dimethyl Terephthalate Process.</E> Each owner or operator complying with § 63.1316 by demonstrating that mass emissions per mass product are less than or equal to the level specified in § 63.1316(a)(1)(i) shall comply with paragraphs (b)(1) through (b)(3) of this section.</P> <P>(1) Include the information specified in § 63.1319(b)(2)(ii) in each Periodic Report, required by § 63.1335(e)(6), as appropriate.</P> <P>(2) Include the information specified in § 63.1319 (b)(1) or (b)(2) in the Notification of Compliance Status, required by § 63.1335(e)(5), for the initial determination and in the appropriate Periodic Report, required by § 63.1335(e)(6), for any subsequent determinations that may be required.</P> <P>(3) Whenever a process change, as defined in § 63.115(e), is made that causes emissions from continuous process vents in the collection of material recovery sections (i.e., methanol recovery) within the affected source to be greater than 0.12 kg organic HAP/Mg of product, the owner or operator shall submit a report within 180 operating days after the process change is made or the information regarding the process change is known to the owner or operator. This report may be included in the next Periodic Report as specified in § 63.1335(e)(6)(iii)(D)(<E T="03">2</E>). The following information shall be submitted:</P> <P>(i) A description of the process change; and</P> <P>(ii) A schedule for compliance with the provisions of this subpart, as required under § 63.1335(e)(6)(iii(D)(<E T="03">2</E>).</P> <P>(c) <E T="03">Reporting for Affected Sources Complying With Temperature Limits for Final Condensers.</E> Each owner or operator complying with § 63.1316(b)(1)(i)(B) or § 63.1316(c)(1)(ii) shall comply with paragraphs (c)(1) and (c)(2) of this section.</P> <P>(1) Report periods when the 3-hour average exit temperature is more than 6° C (10° F) above the applicable specified temperature limit in each Periodic Report, required by § 63.1335(e)(6), as appropriate.</P> <P>(2) Include the information specified in § 63.1319(c)(2) in the Notification of Compliance Status, required by § 63.1335(e)(5), for the initial performance test and in the appropriate Periodic Report, required by § 63.1335(e)(6), for any subsequent performance tests that may be required.</P> <P>(3) Include the information specified in § 63.1317(b) in the Notification of Compliance Status, required by § 63.1335(e)(5).</P> </SECTION> <SECTION> <SECTNO>§ 63.1321</SECTNO> <SUBJECT>Batch process vents provisions.</SUBJECT> <P>(a) <E T="03">Batch process vents.</E> Except as specified in paragraphs (b) and (c) of this section, owners and operators of new and existing affected sources with batch process vents shall comply with the requirements in §§ 63.1322 through 63.1327. The batch process vent group status shall be determined in accordance with § 63.1323. Batch process vents classified as Group 1 shall comply with the reference control technology requirements for Group 1 batch process <PRTPAGE P="200"/>vents in § 63.1322, the monitoring requirements in § 63.1324, the performance test methods and procedures to determine compliance requirements in § 63.1325, the recordkeeping requirements in § 63.1326, and the reporting requirements in § 63.1327. All Group 2 batch process vents shall comply with the applicable reference control technology requirements in § 63.1322, the recordkeeping requirements in § 63.1326, and the reporting requirements in § 63.1327.</P> <P>(b) <E T="03">New SAN batch affected sources.</E> Owners and operators of new SAN affected sources using a batch process shall comply with the requirements of § 63.1322 through § 63.1327 for batch process vents and aggregate batch vent streams except as specified in paragraphs (b)(1) through (b)(2) of this section. For continuous process vents, owners and operators shall comply with the requirements of § 63.1322 through § 63.1327 except as specified in paragraph (b)(3) of this section.</P> <P>(1) For batch process vents, the determination of group status (i.e., Group 1/Group 2) under § 63.1323 is not required.</P> <P>(2) For batch process vents and aggregate batch vent streams, the control requirements for individual batch process vents or aggregate batch vent streams (e.g., 90 percent emission reduction) as specified in § 63.1322(a)(1), (a)(2), (b)(1), and (b)(2) shall not apply.</P> <P>(3) Continuous process vents using a control or recovery device to comply with § 63.1322(a)(3) are subject to the applicable requirements in § 63.1315(a), as appropriate, except as specified in paragraphs (b)(3)(i) and (b)(3)(ii) of this section.</P> <P>(i) Said continuous process vents are not subject to the group determination procedures of § 63.115 for the purposes of this subpart.</P> <P>(ii) Said continuous process vents are not subject to the reference control technology provisions of § 63.113 for the purposes of this subpart.</P> <P>(c) <E T="03">Aggregate batch vent streams.</E> Aggregate batch vent streams, as defined in § 63.1312, are subject to the control requirements for individual batch process vents, as specified in § 63.1322(b), as well as the monitoring, testing, recordkeeping, and reporting requirements specified in § 63.1324 through § 63.1327.</P> <P>(d) Owners and operators of affected sources producing ASA/AMSAN shall comply with the provisions of § 63.1315(e).</P> <CITA>[61 FR 48229, Sept. 12, 1996, as amended at 64 FR 11549, Mar. 9, 1999]</CITA> </SECTION> <SECTION> <SECTNO>§ 63.1322</SECTNO> <SUBJECT>Batch process vents—reference control technology.</SUBJECT> <P>(a) <E T="03">Batch process vents.</E> The owner or operator of a Group 1 batch process vent, as determined using the procedures in § 63.1323, shall comply with the requirements of either paragraph (a)(1) or (a)(2) of this section, except as provided for in paragraph (a)(3) of this section. Compliance can be based on either organic HAP or TOC.</P> <P>(1) For each batch process vent, reduce organic HAP emissions using a flare.</P> <P>(i) The flare shall comply with the requirements of § 63.11(b).</P> <P>(ii) Halogenated batch process vents, as defined in § 63.1312, shall not be vented to a flare.</P> <P>(2) For each batch process vent, reduce organic HAP emissions for the batch cycle by 90 weight percent using a control device. Owners or operators may achieve compliance with this paragraph (a)(2) through the control of selected batch emission episodes or the control of portions of selected batch emission episodes. Documentation demonstrating how the 90 weight percent emission reduction is achieved is required by § 63.1325(c)(2).</P> <P>(3) The owner or operator of a new affected source producing SAN using a batch process shall reduce organic HAP emissions from the collection of batch process vents, aggregate batch vent streams, and continuous process vents by 84 weight percent. Compliance with this paragraph (a)(3) shall be demonstrated using the procedures specified in § 63.1333(c).</P> <P>(b) <E T="03">Aggregate batch vent streams.</E> The owner or operator of an aggregate batch vent stream that contains one or more Group 1 batch process vents shall comply with the requirements of either paragraph (b)(1) or (b)(2) of this section, except as provided for in paragraph (b)(3) of this section. Compliance <PRTPAGE P="201"/>can be based on either organic HAP or TOC.</P> <P>(1) For each aggregate batch vent stream, reduce organic HAP emissions using a flare.</P> <P>(i) The flare shall comply with the requirements of § 63.11(b).</P> <P>(ii) Halogenated aggregate batch vent streams, as defined in § 63.1312, shall not be vented to a flare.</P> <P>(2) For each aggregate batch vent stream, reduce organic HAP emissions by 90 weight percent or to a concentration of 20 parts per million by volume, whichever is less stringent, on a continuous basis using a control device. For purposes of complying with the 20 parts per million by volume outlet concentration standard, the outlet concentration shall be calculated on a dry basis. When a combustion device is used for purposes of complying with the 20 parts per million by volume outlet concentration standard, the concentration shall be corrected to 3 percent oxygen if supplemental combustion air is used to combust the emissions. If supplemental combustion air is not used, a correction to 3 percent oxygen is not required.</P> <P>(3) The owner or operator of a new affected source producing SAN using a batch process shall comply with paragraph (a)(3) of this section.</P> <P>(c) <E T="03">Halogenated emissions.</E> Halogenated Group 1 batch process vents, halogenated aggregate batch vent streams, and halogenated continuous process vents that are combusted as part of complying with paragraph (a)(2), (a)(3), (b)(2), or (b)(3) of this section, as appropriate, shall be controlled according to either paragraph (c)(1) or (c)(2) of this section.</P> <P>(1) If a combustion device is used to comply with paragraph (a)(2), (a)(3), (b)(2), or (b)(3) of this section for a halogenated batch process vent, halogenated aggregate batch vent stream, or halogenated continuous process vent, said emissions shall be ducted from the combustion device to an additional control device that reduces overall emissions of hydrogen halides and halogens by 99 percent before said emissions are discharged to the atmosphere.</P> <P>(2) A control device may be used to reduce the halogen atom mass emission rate of said emissions to less than 3,750 kg/yr for batch process vents or aggregate batch vent streams and to less than 0.45 kilograms per hour for continuous process vents prior to venting to any combustion control device, and thus make the batch process vent, aggregate batch vent stream, or continuous process vent nonhalogenated. The nonhalogenated batch process vent, aggregate batch vent stream, or continuous process vent must then comply with the requirements of either paragraph (a) or (b) of this section, as appropriate.</P> <P>(d) If a boiler or process heater is used to comply with the percent reduction requirement specified in paragraph (a)(2), (a)(3), (b)(2), or (b)(3) of this section, the batch process vent, aggregate batch vent stream, or continuous process vent shall be introduced into the flame zone of such a device.</P> <P>(e) <E T="03">Combination of batch process vents or aggregate batch vent streams with continuous process vents.</E> A batch process vent or aggregate batch vent stream combined with a continuous process vent is not subject to the provisions of §§ 63.1323 through 63.1327, providing the requirements of paragraphs (e)(1), (e)(2), and either (e)(3) or (e)(4) of this section are met.</P> <P>(1) The batch process vent or aggregate batch vent stream is combined with a continuous process vent prior to routing the continuous process vent to a control or recovery device. In this paragraph (e)(1), the definitions of control device and recovery device as they relate to continuous process vents shall be used.</P> <P>(2) The only emissions to the atmosphere from the batch process vent or aggregate batch vent stream prior to being combined with the continuous process vent are from equipment subject to and in compliance with § 63.1331.</P> <P>(3) If the batch process vent or aggregate batch vent stream is combined with a continuous process vent prior to being routed to a control device, the combined vent stream shall comply with the requirements in § 63.1315(a)(10). In this paragraph (e)(3), the definition of control device as it relates to continuous process vents shall be used.<PRTPAGE P="202"/> </P> <P>(4) If the batch process vent or aggregate batch vent stream is combined with a continuous process vent prior to being routed to a recovery device, the combined vent stream shall comply with the requirements in § 63.1315(a)(11). In this paragraph (e)(4), the definition of recovery device as it relates to continuous process vents shall be used.</P> <P>(f) <E T="03">Group 2 batch process vents with annual emissions greater than or equal to the level specified in § 63.1323(d).</E> The owner or operator of a Group 2 batch process vent with annual emissions greater than or equal to the level specified in § 63.1323(d) shall comply with the provisions of (f)(1) and (f)(2) of this section.</P> <P>(1) Establish a batch cycle limitation that ensures the Group 2 batch process vent does not become a Group 1 batch process vent.</P> <P>(2) Comply with the recordkeeping requirements in § 63.1326(d)(2), and the reporting requirements in § 63.1327 (a)(3) and (b).</P> <P>(g) <E T="03">Group 2 batch process vents with annual emissions less than the level specified in § 63.1323(d).</E> The owner or operator of a Group 2 batch process vent with annual emissions less than the level specified in § 63.1323(d) shall comply with either paragraphs (g)(1) and (g)(2) of this section or with paragraphs (f)(1) and (f)(2) of this section.</P> <P>(1) Establish a batch cycle limitation that ensures emissions do not exceed the level specified in § 63.1323(d).</P> <P>(2) Comply with the recordkeeping requirements in § 63.1326(d)(1), and the reporting requirements in § 63.1327 (a)(2), (b), and (c).</P> <CITA>[61 FR 48229, Sept. 12, 1996, as amended at 64 FR 11549, Mar. 9, 1999]</CITA> </SECTION> <SECTION> <SECTNO>§ 63.1323</SECTNO> <SUBJECT>Batch process vents—methods and procedures for group determination.</SUBJECT> <P>(a) <E T="03">General requirements.</E> Except as provided in paragraph (a)(3) of this section and in § 63.1321(b)(1), the owner or operator of batch process vents at affected sources shall determine the group status of each batch process vent in accordance with the provisions of this section. This determination may be based on either organic HAP or TOC emissions.</P> <P>(1) The procedures specified in paragraphs (b) through (h) of this section shall be followed for the expected mix of products for a given batch process vent, as specified in paragraph (a)(1)(i) of this section, or for the worst-case HAP emitting product, as specified in paragraphs (a)(1)(ii) through (a)(1)(iv) of this section. “Worst-case HAP emitting product” is defined in paragraph (a)(1)(iii) of this section.</P> <P>(i) If an owner or operator chooses to follow the procedures specified in paragraphs (b) through (h) of this section for the expected mix of products, an identification of the different products and the number of batch cycles accomplished for each is required as part of the group determination documentation, as specified in § 63.1326(a)(1).</P> <P>(ii) If an owner or operator chooses to follow the procedures specified in paragraphs (b) through (h) of this section for the worst-case HAP emitting product, documentation identifying the worst-case HAP emitting product is required as part of the group determination documentation, as specified in § 63.1326(a)(1).</P> <P>(iii) Except as specified in paragraph (a)(1)(iii)(B) of this section, the worst-case HAP emitting product is as defined in paragraph (a)(1)(iii)(A) of this section.</P> <P>(A) The worst-case HAP emitting product is the one with the highest mass emission rate (kg organic HAP per hour) averaged over the entire time period of the batch cycle.</P> <P>(B) Alternatively, when one product is produced more than 75 percent of the time, accounts for more than 75 percent of the annual mass of product, and the owner or operator can show that the mass emission rate (kg organic HAP per hour) averaged over the entire time period of the batch cycle can reasonably be expected to be similar to the mass emission rate for other products having emissions from the same batch process vent, said product may be considered the worst-case HAP emitting product.</P> <P>(C) An owner or operator shall determine the worst-case HAP emitting product for a batch process vent as specified in paragraphs (a)(1)(iii)(C)(<E T="03">1</E>) through (a)(1)(iii)(C)(<E T="03">3</E>) of this section.<PRTPAGE P="203"/> </P> <P>(<E T="03">1</E>) The emissions per batch emission episode shall be determined using any of the procedures specified in paragraph (b) of this section. The mass emission rate (kg organic HAP per hour) averaged over the entire time period of the batch cycle shall be determined by summing the emissions for each batch emission episode making up a complete batch cycle and dividing by the total duration in hours of the batch cycle.</P> <P>(<E T="03">2</E>) To determine the worst-case HAP emitting product as specified under paragraph (a)(1)(iii)(A) of this section, the mass emission rate for each product shall be determined and compared.</P> <P>(<E T="03">3</E>) To determine the worst-case HAP emitting product as specified under paragraph (a)(1)(iii)(B) of this section, the mass emission rate for the product meeting the time and mass criteria of paragraph (a)(1)(iii)(B) of this section shall be determined, and the owner or operator shall provide adequate information to demonstrate that the mass emission rate for said product is similar to the mass emission rates for the other products having emissions from the same batch process vent. In addition, the owner or operator shall provide information demonstrating that the selected product meets the time and mass criteria of paragraph (a)(1)(iii)(B) of this section.</P> <P>(iv) The annual production of the worst-case HAP emitting product shall be determined by ratioing the production time of said product up to a 12 month period of actual production. It is not necessary to ratio up to a maximum production rate (i.e., 8,760 hours per year at maximum design production).</P> <P>(2) The annual uncontrolled organic HAP or TOC emissions and annual average batch vent flow rate shall be determined at the exit from the batch unit operation. For the purposes of these determinations, the primary condenser operating as a reflux condenser on a reactor or distillation column, the primary condenser recovering monomer, reaction products, by-products, or solvent from a stripper operated in batch mode, and the primary condenser recovering monomer, reaction products, by-products, or solvent from a distillation operation operated in batch mode shall be considered part of the batch unit operation. All other devices that recover or oxidize organic HAP or TOC vapors shall be considered control devices as defined in § 63.1312.</P> <P>(3) The owner or operator of a batch process vent complying with the flare provisions in § 63.1322(a)(1) or § 63.1322(b)(1) or routing the batch process vent to a control device to comply with the requirements in § 63.1322(a)(2) or § 63.1322(b)(2) is not required to perform the batch process vent group determination described in this section, but shall comply with all requirements applicable to Group 1 batch process vents for said batch process vent.</P> <P>(b) <E T="03">Determination of annual emissions</E>. The owner or operator shall calculate annual uncontrolled TOC or organic HAP emissions for each batch process vent using the methods described in paragraphs (b)(1) through (b)(8) of this section. Paragraphs (b)(1) through (b)(4) of this section present procedures that can be used to calculate the emissions from individual batch emission episodes. Emissions from batch processes involving multicomponent systems are to be calculated using the procedures in paragraphs (b)(1) through (b)(4) of this section. Individual HAP partial pressures in multicomponent systems shall be determined by the following methods: If the components are miscible in one another, use Raoult's law to calculate the partial pressures; if the solution is a dilute aqueous mixture use Henry's law constants to calculate partial pressures; if Raoult's law or Henry's law are not appropriate (or available) use experimentally obtained activity coefficients, Henry's law constants, or solubility data; if Raoult's law or Henry's law are not appropriate use models, such as the group-contribution models, to predict activity coefficients; and if Raoult's law or Henry's law are not appropriate assume the components of the system behave independently and use the summation of all vapor pressures from the HAP's as the total HAP partial pressure. Chemical property data can be obtained from standard reference texts. Paragraph <PRTPAGE P="204"/>(b)(5) of this section describes how direct measurement can be used to estimate emissions. If the owner or operator can demonstrate that the procedures in paragraphs (b)(1) through (b)(4) of this section are not appropriate to estimate emissions from a batch emission episode, emissions may be estimated using engineering assessment, as described in paragraph (b)(6) of this section. Owners or operators are not required to demonstrate that direct measurement is not appropriate before utilizing engineering assessment. Paragraph (b)(6)(ii) of this section describes how an owner or operator shall demonstrate that the procedures in paragraphs (b)(1) through (b)(4) of this section are not appropriate. Emissions from a batch cycle shall be calculated in accordance with paragraph (b)(7) of this section, and annual emissions from the batch process vent shall be calculated in accordance with paragraph (b)(8) of this section.</P> <P>(1) TOC or organic HAP emissions from the purging of an empty vessel shall be calculated using Equation 2 of this subpart. Equation 2 of this subpart does not take into account evaporation of any residual liquid in the vessel.</P> <GPH DEEP="33" SPAN="2"> <GID>ER12SE96.001</GID> </GPH> <FP>where:</FP> <FP SOURCE="FP-2">E<E T="52">episode</E>=Emissions, kg/episode.</FP> <FP SOURCE="FP-2">V<E T="52">ves</E>=Volume of vessel, m<E T="51">3</E>.</FP> <FP SOURCE="FP-2">P=TOC or total organic HAP partial pressure, kPa.</FP> <FP SOURCE="FP-2">MW<E T="52">wavg</E>=Weighted average molecular weight of TOC or organic HAP in vapor, determined in accordance with paragraph (b)(4)(iii) of this section, kg/kmol.</FP> <FP SOURCE="FP-2">R=Ideal gas constant, 8.314 m<E T="51">3</E> <E T="63">δ</E> kPa/kmol <E T="63">δ</E> K.</FP> <FP SOURCE="FP-2">T=Temperature of vessel vapor space, K.</FP> <FP SOURCE="FP-2">m=Number of volumes of purge gas used.</FP> <P>(2) TOC or organic HAP emissions from the purging of a filled vessel shall be calculated using Equation 3 of this subpart.</P> <GPH DEEP="55" SPAN="2"> <GID>ER12SE96.002</GID> </GPH> <FP>where:</FP> <FP SOURCE="FP-2">E<E T="52">episode</E>=Emissions, kg/episode.</FP> <FP SOURCE="FP-2">y=Saturated mole fraction of all TOC or organic HAP in vapor phase.</FP> <FP SOURCE="FP-2">V<E T="52">dr</E>=Volumetric gas displacement rate, m<E T="51">3</E>/min.</FP> <FP SOURCE="FP-2">P=Pressure in vessel vapor space, kPa.</FP> <FP SOURCE="FP-2">MW<E T="52">wavg</E>=Weighted average molecular weight of TOC or organic HAP in vapor, determined in accordance with paragraph (b)(4)(iii) of this section, kg/kmol.</FP> <FP SOURCE="FP-2">R=Ideal gas constant, 8.314 m<E T="51">3</E> <E T="63">δ</E> kPa/kmol <E T="63">δ</E> K.</FP> <FP SOURCE="FP-2">T=Temperature of vessel vapor space, K.</FP> <FP SOURCE="FP-2">P<E T="52">i</E>=Vapor pressure of TOC or individual organic HAP i, kPa.</FP> <FP SOURCE="FP-2">x<E T="52">i</E>=Mole fraction of TOC or organic HAP i in the liquid.</FP> <FP SOURCE="FP-2">n=Number of organic HAP in stream.</FP> <NOTE> <HD SOURCE="HED">Note:</HD> <P>Summation not required if TOC emissions are being estimated.</P> </NOTE> <FP SOURCE="FP-2">T<E T="52">m</E>=Minutes/episode.</FP> <P>(3) Emissions from vapor displacement due to transfer of material into <PRTPAGE P="205"/>or out of a vessel shall be calculated using Equation 4 of this subpart.</P> <GPH DEEP="30" SPAN="1"> <GID>ER12SE96.003</GID> </GPH> <FP>where:</FP> <FP SOURCE="FP-2">E<E T="52">episode</E>=Emissions, kg/episode.</FP> <FP SOURCE="FP-2">y=Saturated mole fraction of all TOC or organic HAP in vapor phase.</FP> <FP SOURCE="FP-2">V=Volume of gas displaced from the vessel, m<E T="51">3</E>.</FP> <FP SOURCE="FP-2">P=Pressure in vessel vapor space, kPa.</FP> <FP SOURCE="FP-2">MW<E T="52">wavg</E>=Weighted average molecular weight of TOC or organic HAP in vapor, determined in accordance with paragraph (b)(4)(i)(D) of this section, kg/kmol.</FP> <FP SOURCE="FP-2">R=Ideal gas constant, 8.314 m<E T="51">3</E> <E T="63">δ</E> kPa/kmol <E T="63">δ</E> K.</FP> <FP SOURCE="FP-2">T=Temperature of vessel vapor space, K.</FP> <P>(4) Emissions caused by the heating of a vessel shall be calculated using the procedures in either paragraphs (b)(4)(i), (b)(4)(ii), or (b)(4)(iii) of this section, as appropriate.</P> <P>(i) If the final temperature to which the vessel contents is heated is lower than 50 K below the boiling point of the HAP in the vessel, then emissions shall be calculated using the equations in paragraphs (b)(4)(i)(A) through (b)(4)(i)(D) of this section.</P> <P>(A) Emissions caused by heating of a vessel shall be calculated using Equation 5 of this subpart. The assumptions made for this calculation are atmospheric pressure of 760 millimeters of mercury (mm Hg) and the displaced gas is always saturated with volatile organic compounds (VOC) vapor in equilibrium with the liquid mixture.</P> <GPH DEEP="119" SPAN="2"> <GID>ER12SE96.004</GID> </GPH> <FP>where:</FP> <FP SOURCE="FP-2">E<E T="52">episode</E>=Emissions, kg/episode.</FP> <FP SOURCE="FP-2">(P<E T="52">i</E>)T1, (P<E T="52">i</E>)T2=Partial pressure (kPa) of TOC or each organic HAP i in the vessel headspace at initial (T1) and final (T2) temperature.</FP> <FP SOURCE="FP-2">n=Number of organic HAP in stream. Note: Summation not required if TOC emissions are being estimated.</FP> <FP SOURCE="FP-2"> <E T="73">▵</E> <E T="51">n</E>=Number of kilogram-moles (kg-moles) of gas displaced, determined in accordance with paragraph (b)(4)(i)(B) of this section.</FP> <FP SOURCE="FP-2">101.325=Constant, kPa.</FP> <FP SOURCE="FP-2">MW<E T="52">wavg</E>=Weighted average molecular weight of TOC or organic HAP in vapor, determined in accordance with paragraph (b)(4)(i)(D) of this section, kg/kmol.</FP> <P>(B) The moles of gas displaced, <E T="73">▵</E> <E T="51">n</E>, is calculated using Equation 6 of this subpart.</P> <GPH DEEP="33" SPAN="1"> <GID>ER12SE96.005</GID> </GPH> <FP>where:</FP> <FP SOURCE="FP-2"> <E T="73">▵</E> <E T="51">n</E>=Number of kg-moles of gas displaced.</FP> <FP SOURCE="FP-2">V<E T="52">fs</E>=Volume of free space in the vessel, m<E T="51">3</E>.</FP> <FP SOURCE="FP-2">R=Ideal gas constant, 8.314 m<E T="51">3</E> <E T="63">δ</E> kPa/kmol <E T="63">δ</E> K.<PRTPAGE P="206"/> </FP> <FP SOURCE="FP-2">Pa<E T="52">1</E>=Initial noncondensible gas pressure in the vessel, kPa.</FP> <FP SOURCE="FP-2">Pa<E T="52">2</E>=Final noncondensible gas pressure, kPa.</FP> <FP SOURCE="FP-2">T<E T="52">1</E>=Initial temperature of vessel, K.</FP> <FP SOURCE="FP-2">T<E T="52">2</E>=Final temperature of vessel, K.</FP> <P>(C) The initial and final pressure of the noncondensible gas in the vessel shall be calculated using Equation 7 of this subpart.</P> <GPH DEEP="29" SPAN="1"> <GID>ER12SE96.006</GID> </GPH> <FP>where:</FP> <FP SOURCE="FP-2">Pa=Initial or final partial pressure of noncondensible gas in the vessel headspace, kPa.</FP> <FP SOURCE="FP-2">101.325=Constant, kPa.</FP> <FP SOURCE="FP-2">(P<E T="52">i</E>)T=Partial pressure of TOC or each organic HAP i in the vessel headspace, kPa, at the initial or final temperature (T1 or T2).</FP> <FP SOURCE="FP-2">n=Number of organic HAP in stream.</FP> <NOTE> <HD SOURCE="HED">Note:</HD> <P>Summation not required if TOC emissions are being estimated.</P> </NOTE> <P>(D) The weighted average molecular weight of TOC or organic HAP in the displaced gas, MW<E T="52">wavg</E>, shall be calculated using Equation 8 of this subpart.</P> <GPH DEEP="62" SPAN="2"> <GID>ER12SE96.007</GID> </GPH> <FP>where:</FP> <FP SOURCE="FP-2">C=TOC or organic HAP component</FP> <FP SOURCE="FP-2">n=Number of TOC or organic HAP components in stream.</FP> <P>(ii) If the vessel contents are heated to a temperature greater than 50 K below the boiling point, then emissions from the heating of a vessel shall be calculated as the sum of the emissions calculated in accordance with paragraphs (b)(4)(ii)(A) and (b)(4)(ii)(B) of this section.</P> <P>(A) For the interval from the initial temperature to the temperature 50 K below the boiling point, emissions shall be calculated using Equation 5 of this subpart, where T<E T="52">2</E> is the temperature 50 K below the boiling point.</P> <P>(B) For the interval from the temperature 50 K below the boiling point to the final temperature, emissions shall be calculated as the summation of emissions for each 5 K increment, where the emissions for each increment shall be calculated using Equation 5 of this subpart.</P> <P>(<E T="03">1</E>) If the final temperature of the heatup is lower than 5 K below the boiling point, the final temperature for the last increment shall be the final temperature for the heatup, even if the last increment is less than 5 K.</P> <P>(<E T="03">2</E>) If the final temperature of the heatup is higher than 5 K below the boiling point, the final temperature for the last increment shall be the temperature 5 K below the boiling point, even if the last increment is less than 5 K.</P> <P>(<E T="03">3</E>) If the vessel contents are heated to the boiling point and the vessel is not operating with a condenser, the final temperature for the final increment shall be the temperature 5 K below the boiling point, even if the last increment is less than 5 K.</P> <P>(iii) If the vessel is operating with a condenser, and the vessel contents are heated to the boiling point, the primary condenser, as specified in paragraph (a)(2) of this section, is considered part of the process. Emissions shall be calculated as the sum of emissions calculated using Equation 5 of this subpart, which calculates emissions due to heating the vessel contents to the temperature of the gas existing the condenser, and emissions calculated using Equation 4 of this subpart, which calculates emissions due to the displacement of the remaining saturated noncondensible gas in the <PRTPAGE P="207"/>vessel. The final temperature in Equation 5 of this subpart shall be set equal to the exit gas temperature of the condenser. Equation 4 of this subpart shall be used as written below in Equation 4a of this subpart, using free space volume, and T is set equal to the condenser exit gas temperature.</P> <GPH DEEP="30" SPAN="1"> <GID>ER12SE96.008</GID> </GPH> <FP>where:</FP> <FP SOURCE="FP-2">E<E T="52">episode</E>=Emissions, kg/episode.</FP> <FP SOURCE="FP-2">y=Saturated mole fraction of all TOC or organic HAP in vapor phase.</FP> <FP SOURCE="FP-2">V<E T="52">fs</E>=Volume of the free space in the vessel, m<E T="51">3</E>.</FP> <FP SOURCE="FP-2">P=Pressure in vessel vapor space, kPa.</FP> <FP SOURCE="FP-2">MW<E T="52">wavg</E>=Weighted average molecular weight of TOC or organic HAP in vapor, determined in accordance with paragraph (b)(4)(i)(D) of this section, kg/kmol.</FP> <FP SOURCE="FP-2">R=Ideal gas constant, 8.314 m<E T="51">3</E> <E T="63">δ</E> kPa/kmol <E T="63">δ</E> K.</FP> <FP SOURCE="FP-2">T=Temperature of condenser exit stream, K.</FP> <P>(5) The owner or operator may estimate annual emissions for a batch emission episode by direct measurement. If direct measurement is used, the owner or operator shall either perform a test for the duration of a representative batch emission episode or perform a test during only those periods of the batch emission episode for which the emission rate for the entire episode can be determined or for which the emissions are greater than the average emission rate of the batch emission episode. The owner or operator choosing either of these options must develop an emission profile for the entire batch emission episode, based on either process knowledge or test data collected, to demonstrate that test periods are representative. Examples of information that could constitute process knowledge include calculations based on material balances and process stoichiometry. Previous test results may be used provided the results are still relevant to the current batch process vent conditions. Performance tests shall follow the procedures specified in paragraphs (b)(5)(i) through (b)(5)(iii) of this section. The procedures in either paragraph (b)(5)(iv) or (b)(5)(v) of this section shall be used to calculate the emissions per batch emission episode.</P> <P>(i) Method 1 or 1A, 40 CFR part 60, appendix A as appropriate, shall be used for selection of the sampling sites if the flow measuring device is a pitot tube. No traverse is necessary when Method 2A or 2D, 40 CFR part 60, appendix A is used to determine gas stream volumetric flow rate.</P> <P>(ii) Gas stream volumetric flow rate and/or average flow rate shall be determined as specified in paragraph (e) of this section.</P> <P>(iii) Method 18 or Method 25A, 40 CFR part 60, appendix A, shall be used to determine the concentration of TOC or organic HAP, as appropriate. Alternatively, any other method or data that has been validated according to the applicable procedures in Method 301 of appendix A of this part may be used. The use of Method 25A, 40 CFR part 60, appendix A shall comply with paragraphs (b)(5)(iii)(A) and (b)(5)(iii)(B) of this section.</P> <P>(A) The organic HAP used as the calibration gas for Method 25A, 40 CFR part 60, appendix A shall be the single organic HAP representing the largest percent by volume of the emissions.</P> <P>(B) The use of Method 25A, 40 CFR part 60, appendix A is acceptable if the response from the high-level calibration gas is at least 20 times the standard deviation of the response from the zero calibration gas when the instrument is zeroed on the most sensitive scale.</P> <P>(iv) If an integrated sample is taken over the entire batch emission episode to determine TOC or average total organic HAP concentration, emissions shall be calculated using Equation 9 of this subpart.</P> <GPH DEEP="37" SPAN="2"> <PRTPAGE P="208"/> <GID>ER12SE96.009</GID> </GPH> <FP>where:</FP> <FP SOURCE="FP-2">E<E T="52">episode</E>=Emissions, kg/episode.</FP> <FP SOURCE="FP-2">K=Constant, 2.494 × 10<E T="51">−</E> <E T="51">6</E> (ppmv)<E T="51">−</E> <E T="51">1</E> (gm-mole/scm) (kg/gm) (min/hr), where standard temperature is 20 °C.</FP> <FP SOURCE="FP-2">C<E T="52">j</E>=Average concentration of TOC or sample organic HAP component j of the gas stream, dry basis, ppmv.</FP> <FP SOURCE="FP-2">M<E T="52">j</E>=Molecular weight of TOC or sample organic HAP component j of the gas stream, gm/gm-mole.</FP> <FP SOURCE="FP-2">AFR=Average flow rate of gas stream, dry basis, scmm.</FP> <FP SOURCE="FP-2">T<E T="52">h</E>=Hours/episode.</FP> <FP SOURCE="FP-2">n=Number of organic HAP in stream.</FP> <NOTE> <HD SOURCE="HED">Note:</HD> <P>Summation not required if TOC emissions are being estimated using a TOC concentration measured using Method 25A, 40 CFR part 60, appendix A.</P> </NOTE> <P>(v) If grab samples are taken to determine TOC or average total organic HAP concentration, emissions shall be calculated according to paragraphs (b)(5)(v)(A) and (b)(5)(v)(B) of this section.</P> <P>(A) For each measurement point, the emission rate shall be calculated using Equation 10 of this subpart.</P> <GPH DEEP="37" SPAN="1"> <GID>ER12SE96.010</GID> </GPH> <FP>where:</FP> <FP SOURCE="FP-2">E<E T="52">point</E>=Emission rate for individual measurement point, kg/hr.</FP> <FP SOURCE="FP-2">K=Constant, 2.494 × 10-6 (ppmv)<E T="51">−1</E> (gm-mole/scm) (kg/gm) (min/hr), where standard temperature is 20 °C.</FP> <FP SOURCE="FP-2">C<E T="52">j</E>=Concentration of TOC or sample organic HAP component j of the gas stream, dry basis, ppmv.</FP> <FP SOURCE="FP-2">M<E T="52">j</E>=Molecular weight of TOC or sample organic HAP component j of the gas stream, gm/gm-mole.</FP> <FP SOURCE="FP-2">FR=Flow rate of gas stream for the measurement point, dry basis, scmm.</FP> <FP SOURCE="FP-2">n=Number of organic HAP in stream.</FP> <NOTE> <HD SOURCE="HED">Note:</HD> <P>Summation not required if TOC emissions are being estimated using a TOC concentration measured using Method 25A, 40 CFR part 60, appendix A.</P> </NOTE> <P>(B) The emissions per batch emission episode shall be calculated using Equation 11 of this subpart.</P> <GPH DEEP="35" SPAN="1"> <GID>ER12SE96.011</GID> </GPH> <FP>where:</FP> <FP SOURCE="FP-2">E<E T="52">episode</E>=Emissions, kg/episode.</FP> <FP SOURCE="FP-2">DUR=Duration of the batch emission episode, hr/episode.</FP> <FP SOURCE="FP-2">E<E T="52">i</E>=Emissions for measurement point i, kg/hr.</FP> <FP SOURCE="FP-2">n=Number of measurements.</FP> <P>(6) If the owner or operator can demonstrate that the methods in paragraphs (b)(1) through (b)(4) of this section are not appropriate to estimate emissions for a batch emissions episode, the owner or operator may use engineering assessment to estimate emissions as specified in paragraphs (b)(6)(i) and (b)(6)(ii) of this section. All data, assumptions, and procedures used in an engineering assessment shall be documented.</P> <P>(i) Engineering assessment includes, but is not limited to, the following:</P> <P>(A) Previous test results, provided the tests are representative of current operating practices;</P> <P>(B) Bench-scale or pilot-scale test data representative of the process under representative operating conditions;</P> <P>(C) Flow rate, TOC emission rate, or organic HAP emission rate specified or implied within a permit limit applicable to the batch process vent; and</P> <P>(D) Design analysis based on accepted chemical engineering principles, measurable process parameters, or physical or chemical laws or properties. Examples of analytical methods include, but are not limited to:</P> <P>(<E T="03">1</E>) Use of material balances;</P> <P>(<E T="03">2</E>) Estimation of flow rate based on physical equipment design such as pump or blower capacities; and<PRTPAGE P="209"/> </P> <P>(<E T="03">3</E>) Estimation of TOC or organic HAP concentrations based on saturation conditions.</P> <P>(ii) The emissions estimation equations in paragraphs (b)(1) through (b)(4) of this section shall be considered inappropriate for estimating emissions for a given batch emissions episode if one or more of the criteria in paragraphs (b)(6)(ii)(A) through (b)(6)(ii)(B) of this section are met.</P> <P>(A) Previous test data are available that show a greater than 20 percent discrepancy between the test value and the estimated value.</P> <P>(B) The owner or operator can demonstrate to the Administrator that the emissions estimation equations are not appropriate for a given batch emissions episode.</P> <P>(C) Data or other information supporting a finding that the emissions estimation equations are inappropriate as specified under paragraph (b)(6)(ii)(A) of this section shall be reported in the Notification of Compliance Status, as required in § 63.1335(e)(5).</P> <P>(D) Data or other information supporting a finding that the emissions estimation equations are inappropriate as specified under paragraph (b)(6)(ii)(B) of this section shall be reported in the Precompliance Report, as required in § 63.1335(e)(3).</P> <P>(7) For each batch process vent, the TOC or organic HAP emissions associated with a single batch cycle shall be calculated using Equation 12 of this subpart.</P> <GPH DEEP="31" SPAN="1"> <GID>ER12SE96.012</GID> </GPH> <FP SOURCE="FP-2">where:</FP> <FP SOURCE="FP-2">E<E T="52">cycle</E>=Emissions for an individual batch cycle, kg/batch cycle</FP> <FP SOURCE="FP-2">E<E T="52">episode </E> <E T="0362">i</E>=Emissions from batch emission episode i, kg/episode</FP> <FP SOURCE="FP-2">n=Number of batch emission episodes for the batch cycle</FP> <P>(8) Annual TOC or organic HAP emissions from a batch process vent shall be calculated using Equation 13 of this subpart.</P> <GPH DEEP="31" SPAN="1"> <GID>ER12SE96.013</GID> </GPH> <FP>where:</FP> <FP SOURCE="FP-2">AE=Annual emissions from a batch process vent, kg/yr.</FP> <FP SOURCE="FP-2">N<E T="52">i</E>=Number of type i batch cycles performed annually, cycles/year</FP> <FP SOURCE="FP-2">E<E T="52">cycle </E> <E T="0362">i</E>=Emissions from the batch process vent associated with a single type i batch cycle, as determined in paragraph (b)(7) of this section, kg/batch cycle</FP> <FP SOURCE="FP-2">n=Number of different types of batch cycles that cause the emission of TOC or organic HAP from the batch process vent</FP> <P>(c) [Reserved]</P> <P>(d) <E T="03">Minimum emission level exemption.</E> A batch process vent with annual emissions less than 11,800 kg/yr is considered a Group 2 batch process vent and the owner or operator of said batch process vent shall comply with the requirements in § 63.1322 (f) or (g). The owner or operator of said batch process vent is not required to comply with the provisions in paragraphs (e) through (g) of this section.</P> <P>(e) <E T="03">Determination of average flow rate.</E> The owner or operator shall determine the average flow rate for each batch emission episode in accordance with one of the procedures provided in paragraphs (e)(1) through (e)(2) of this section. The annual average flow rate for a batch process vent shall be calculated as specified in paragraph (e)(3) of this section.</P> <P>(1) Determination of the average flow rate for a batch emission episode by direct measurement shall be made using the procedures specified in paragraphs (e)(1)(i) through (e)(1)(iii) of this section.</P> <P>(i) The volumetric flow rate for a batch emission episode, in standard cubic meters per minute (scmm) at 20° C, shall be determined using Method 2, 2A, 2C, or 2D, 40 CFR part 60, appendix A, as appropriate.</P> <P>(ii) The volumetric flow rate of a representative batch emission episode shall be measured every 15 minutes.</P> <P>(iii) The average flow rate for a batch emission episode shall be calculated using Equation 14 of this subpart.</P> <GPH DEEP="45" SPAN="1"> <PRTPAGE P="210"/> <GID>ER12SE96.014</GID> </GPH> <FP>where:</FP> <FP SOURCE="FP-2">AFR<E T="52">episode</E> = Average flow rate for the batch emission episode, scmm.</FP> <FP SOURCE="FP-2">FR<E T="52">i</E> = Flow rate for individual measurement i, scmm.</FP> <FP SOURCE="FP-2">n = Number of flow rate measurements taken during the batch emission episode.</FP> <P>(2) The average flow rate for a batch emission episode may be determined by engineering assessment, as defined in paragraph (b)(6)(i) of this section. All data, assumptions, and procedures used shall be documented.</P> <P>(3) The annual average flow rate for a batch process vent shall be calculated using Equation 15 of this subpart.</P> <GPH DEEP="62" SPAN="1"> <GID>ER12SE96.015</GID> </GPH> <FP>where:</FP> <FP SOURCE="FP-2">AFR = Annual average flow rate for the batch process vent, scmm.</FP> <FP SOURCE="FP-2">DUR<E T="52">i</E> = Duration of type i batch emission episodes annually, hrs/yr.</FP> <FP SOURCE="FP-2">AFR<E T="52">episode,i</E> = Average flow rate for type i batch emission episode, scmm.</FP> <FP SOURCE="FP-2">n = Number of types of batch emission episodes venting from the batch process vent.</FP> <P>(f) <E T="03">Determination of cutoff flow rate.</E> For each batch process vent, the owner or operator shall calculate the cutoff flow rate using Equation 16 of this subpart. </P> <FP SOURCE="FP-2">CFR = (0.00437) (AE)^51.6 [Eq. 16]</FP> <FP>where:</FP> <FP SOURCE="FP-2">CFR = Cutoff flow rate, scmm.</FP> <FP SOURCE="FP-2">AE = Annual TOC or organic HAP emissions, as determined in paragraph (b)(8) of this section, kg/yr.</FP> <P>(g) <E T="03">Group 1/Group 2 status determination.</E> The owner or operator shall compare the cutoff flow rate, calculated in accordance with paragraph (f) of this section, with the annual average flow rate, determined in accordance with paragraph (e)(4) of this section. The group determination status for each batch process vent shall be made using the criteria specified in paragraphs (g)(1) and (g)(2) of this section.</P> <P>(1) If the cutoff flow rate is greater than or equal to the annual average flow rate of the stream, the batch process vent is classified as a Group 1 batch process vent.</P> <P>(2) If the cutoff flow rate is less than the annual average flow rate of the stream, the batch process vent is classified as a Group 2 batch process vent.</P> <P>(h) <E T="03">Determination of halogenation status.</E> To determine whether a batch process vent or an aggregate batch vent stream is halogenated, the annual mass emission rate of halogen atoms contained in organic compounds shall be calculated using the procedures specified in paragraphs (h)(1) through (h)(3) of this section.</P> <P>(1) The concentration of each organic compound containing halogen atoms (ppmv, by compound) for each batch emission episode shall be determined based on any one of the following procedures:</P> <P>(i) Process knowledge that no halogens or hydrogen halides are present in the process may be used to demonstrate that a batch emission episode is nonhalogenated. Halogens or hydrogen halides that are unintentionally introduced into the process shall not be considered in making a finding that a batch emission episode is nonhalogenated.</P> <P>(ii) Engineering assessment as discussed in paragraph (b)(6)(i) of this section.</P> <P>(iii) Concentration of organic compounds containing halogens and hydrogen halides as measured by Method 26 or 26A, 40 CFR part 60, appendix A.</P> <P>(iv) Any other method or data that has been validated according to the applicable procedures in Method 301 of appendix A of this part.</P> <P>(2) The annual mass emissions of halogen atoms for a batch process vent shall be calculated using Equation 17 of this subpart.</P> <GPH DEEP="37" SPAN="2"> <PRTPAGE P="211"/> <GID>ER12SE96.016</GID> </GPH> <FP>where:</FP> <FP SOURCE="FP-2">E<E T="52">halogen</E> = Mass of halogen atoms, dry basis, kg/yr.</FP> <FP SOURCE="FP-2">K = Constant, 0.022 (ppmv)<E T="51">−1</E> (kg-mole per scm) (minute/yr), where standard temperature is 20°C.</FP> <FP SOURCE="FP-2">AFR = Annual average flow rate of the batch process vent, determined according to paragraph (e) of this section, scmm.</FP> <FP SOURCE="FP-2">M<E T="52">j,i</E> = Molecular weight of halogen atom i in compound j, kg/kg-mole.</FP> <FP SOURCE="FP-2">L<E T="52">j,i</E> = Number of atoms of halogen i in compound j.</FP> <FP SOURCE="FP-2">n = Number of halogenated compounds j in the batch process vent.</FP> <FP SOURCE="FP-2">m = Number of different halogens i in each compound j of the batch process vent.</FP> <FP SOURCE="FP-2">C<E T="52">avgj</E> = Average annual concentration of halogenated compound j in the batch process vent as determined by using Equation 18 of this subpart, dry basis, ppmv.</FP> <GPH DEEP="62" SPAN="1"> <GID>ER12SE96.017</GID> </GPH> <FP>where:</FP> <FP SOURCE="FP-2">DUR<E T="52">i</E> = Duration of type i batch emission episodes annually, hrs/yr.</FP> <FP SOURCE="FP-2">C<E T="52">i</E> = Average concentration of halogenated compound j in type i batch emission episode, ppmv.</FP> <FP SOURCE="FP-2">n = Number of types of batch emission episodes venting from the batch process vent.</FP> <P>(3) The annual mass emissions of halogen atoms for an aggregate batch vent stream shall be the sum of the annual mass emissions of halogen atoms for all batch process vents included in the aggregate batch vent stream.</P> <P>(i) <E T="03">Process changes affecting Group 2 batch process vents.</E> Whenever process changes, as described in paragraph (i)(1) of this section, are made that affect one or more Group 2 batch process vents, the owner or operator shall comply with paragraphs (i) (2) and (3) of this section.</P> <P>(1) Examples of process changes include, but are not limited to, changes in production capacity, production rate, feedstock type, or catalyst type; or whenever there is replacement, removal, or modification of recovery equipment considered part of the batch unit operation as specified in paragraph (a)(2) of this section. An increase in the annual number of batch cycles beyond the batch cycle limitation constitutes a process change. For purposes of this paragraph (i), process changes do not include: process upsets; unintentional, temporary process changes; and changes that are within the margin of variation on which the original group determination was based.</P> <P>(2) For each batch process vent affected by a process change, the owner or operator shall redetermine the group status by repeating the procedures specified in paragraphs (b) through (g) of this section, as applicable; alternatively, engineering assessment, as described in paragraph (b)(6)(i) of this section, can be used to determine the effects of the process change.</P> <P>(3) Based on the results from paragraph (i)(2) of this section, owners or operators shall comply with either paragraph (i)(3) (i), (ii), or (iii) of this section.</P> <P>(i) If the redetermination described in paragraph (i)(2) of this section indicates that a Group 2 batch process vent has become a Group 1 batch process vent as a result of the process change, the owner or operator shall submit a report as specified in § 63.1327(b) and shall comply with the Group 1 provisions in § 63.1322 through § 63.1327 in accordance with the compliance schedule described in § 63.1335(e)(6)(iii)(D)(<E T="03">2</E>).</P> <P>(ii) If the redetermination described in paragraph (i)(2) of this section indicates that a Group 2 batch process vent with annual emissions less than the <PRTPAGE P="212"/>level specified in paragraph (d) of this section, that is in compliance with § 63.1322(g), now has annual emissions greater than or equal to the level specified in paragraph (d) of this section but remains a Group 2 batch process vent, the owner or operator shall submit a report as specified in § 63.1327(c) and shall comply with § 63.1322(f) in accordance with the compliance schedule required by § 63.1335(e)(6)(iii)(D)(<E T="03">2</E>).</P> <P>(iii) If the redetermination described in paragraph (i)(2) of this section indicates no change in group status or no change in the relation of annual emissions to the levels specified in paragraph (d) of this section, the owner or operator is not required to submit a report, as described in § 63.1327(e).</P> <P>(j) <E T="03">Process changes to new SAN affected sources using a batch process.</E> Whenever process changes, as described in paragraph (j)(1) of this section, are made to a new affected source producing SAN using a batch process, the owner or operator shall comply with paragraphs (j) (2) and (3) of this section.</P> <P>(1) Examples of process changes include, but are not limited to, changes in production capacity, production rate, feedstock type, or catalyst type; replacement, removal, or addition of recovery equipment considered part of a batch unit operation, as specified in paragraph (a)(1) of this section; replacement, removal, or addition of control equipment associated with a continuous or batch process vent or an aggregate batch vent stream. For purposes of this paragraph (j)(1), process changes do not include process upsets or unintentional, temporary process changes.</P> <P>(2) The owner or operator shall redetermine the percent emission reduction achieved using the procedures specified in § 63.1333(c). If engineering assessment, as described in paragraph (b)(6)(i) of this section, can demonstrate that the process change did not cause the percent emission reduction to decrease, it may be used in lieu of redetermining the percent reduction using the procedures specified in § 63.1333(c).</P> <P>(3) Where the redetermined percent reduction is less than 84 percent, the owner or operator shall submit a report as specified in § 63.1327(d) and shall comply with § 63.1322(a)(3) and all associated provisions in accordance with the compliance schedule described in § 63.1335(e)(6)(iii)(D)(<E T="03">2</E>).</P> <CITA>[61 FR 48229, Sept. 12, 1996, as amended at 64 FR 11549, Mar. 9, 1999]</CITA> </SECTION> <SECTION> <SECTNO>§ 63.1324</SECTNO> <SUBJECT>Batch process vents—monitoring provisions.</SUBJECT> <P>(a) <E T="03">General requirements.</E> Each owner or operator of a batch process vent or aggregate batch vent stream that uses a control device to comply with the requirements in § 63.1322(a) or § 63.1322(b), shall install the monitoring equipment specified in paragraph (c) of this section.</P> <P>(1) This monitoring equipment shall be in operation at all times when batch emission episodes, or portions thereof, that the owner or operator has selected to control are vented to the control device, or at all times when an aggregate batch vent stream is vented to the control device.</P> <P>(2) The owner or operator shall operate control devices such that monitored parameters remain above the minimum level or below the maximum level, as appropriate, established as specified in paragraph (f) of this section.</P> <P>(b) <E T="03">Continuous process vents.</E> Each owner or operator of a continuous process vent that uses a control device or recovery device to comply with the requirements in § 63.1322(a)(3) shall comply with the applicable requirements of § 63.1315(a) as specified in § 63.1321(b).</P> <P>(c) <E T="03">Batch process vent and aggregate batch vent stream monitoring parameters.</E> The monitoring equipment specified in paragraphs (c)(1) through (c)(8) of this section shall be installed as specified in paragraph (a) of this section. The parameters to be monitored are specified in Table 7 of this subpart.</P> <P>(1) Where an incinerator is used, a temperature monitoring device equipped with a continuous recorder is required.</P> <P>(i) Where an incinerator other than a catalytic incinerator is used, the temperature monitoring device shall be installed in the firebox or in the ductwork immediately downstream of the firebox in a position before any substantial heat exchange occurs.<PRTPAGE P="213"/> </P> <P>(ii) Where a catalytic incinerator is used, temperature monitoring devices shall be installed in the gas stream immediately before and after the catalyst bed.</P> <P>(2) Where a flare is used, a device (including but not limited to a thermocouple, ultra-violet beam sensor, or infrared sensor) capable of continuously detecting the presence of a pilot flame is required.</P> <P>(3) Where a boiler or process heater of less than 44 megawatts design heat input capacity is used, a temperature monitoring device in the firebox equipped with a continuous recorder is required. Any boiler or process heater in which all batch process vents or aggregate batch vent streams are introduced with the primary fuel or are used as the primary fuel is exempt from this requirement.</P> <P>(4) Where a scrubber is used with an incinerator, boiler, or process heater in concert with the combustion of halogenated batch process vents or halogenated aggregate batch vent streams, the following monitoring equipment is required for the scrubber.</P> <P>(i) A pH monitoring device equipped with a continuous recorder to monitor the pH of the scrubber effluent.</P> <P>(ii) A flow meter equipped with a continuous recorder shall be located at the scrubber influent to monitor the scrubber liquid flow rate.</P> <P>(5) Where an absorber is used, a scrubbing liquid temperature monitoring device and a specific gravity monitoring device are required, each equipped with a continuous recorder.</P> <P>(6) Where a condenser is used, a condenser exit temperature (product side) monitoring device equipped with a continuous recorder is required.</P> <P>(7) Where a carbon adsorber is used, an integrating regeneration stream flow monitoring device having an accuracy of <E T="61">±</E>10 percent, capable of recording the total regeneration stream mass flow for each regeneration cycle; and a carbon bed temperature monitoring device, capable of recording the carbon bed temperature after each regeneration and within 15 minutes of completing any cooling cycle are required.</P> <P>(8) As an alternate to paragraphs (c)(5) through (c)(7) of this section, the owner or operator may install an organic monitoring device equipped with a continuous recorder.</P> <P>(d) <E T="03">Alternative monitoring parameters.</E> An owner or operator of a batch process vent or aggregate batch vent stream may request approval to monitor parameters other than those required by paragraph (c) of this section. The request shall be submitted according to the procedures specified in § 63.1335(f). Approval shall be requested if the owner or operator:</P> <P>(1) Uses a control device other than those included in paragraph (c) of this section; or</P> <P>(2) Uses one of the control devices included in paragraph (c) of this section, but seeks to monitor a parameter other than those specified in Table 7 of this subpart and paragraph (c) of this section.</P> <P>(e) <E T="03">Monitoring of bypass lines.</E> Owners or operators of a batch process vent or aggregate batch vent stream using a vent system that contains bypass lines that could divert emissions away from a control device used to comply with § 63.1322(a) or § 63.1322(b) shall comply with either paragraph (d)(1), (d)(2), or (d)(3) of this section. Equipment such as low leg drains, high point bleeds, analyzer vents, open-ended valves or lines, and pressure relief valves needed for safety purposes are not subject to this paragraph (e).</P> <P>(1) Properly install, maintain, and operate a flow indicator that takes a reading at least once every 15 minutes. Records shall be generated as specified in § 63.1326(e)(3). The flow indicator shall be installed at the entrance to any bypass line that could divert emissions away from the control device and to the atmosphere; or</P> <P>(2) Secure the bypass line valve in the non-diverting position with a car-seal or a lock-and-key type configuration. A visual inspection of the seal or closure mechanism shall be performed at least once every month to ensure that the valve is maintained in the non-diverting position and emissions are not diverted through the bypass line. Records shall be generated as specified in § 63.1326(e)(4).</P> <P>(3) Continuously monitor the bypass line valve position using computer monitoring and record any periods when the position of the bypass line <PRTPAGE P="214"/>valve has changed as specified in § 63.1326(e)(4).</P> <P>(f) <E T="03">Establishment of parameter monitoring levels.</E> Parameter monitoring levels for batch process vents and aggregate batch vent streams shall be established as specified in paragraphs (f)(1) through (f)(3) of this section. For continuous process vents complying with § 63.1322(a)(3), parameter monitoring levels shall be established as specified in § 63.1315(a), except as specified in paragraph (f)(4) of this section.</P> <P>(1) For each parameter monitored under paragraph (c) of this section, the owner or operator shall establish a level, defined as either a maximum or minimum operating parameter as denoted in Table 8 of this subpart, that indicates proper operation of the control device. The level shall be established in accordance with the procedures specified in § 63.1334.</P> <P>(i) For batch process vents using a control device to comply with § 63.1322(a)(2), the established level shall reflect the control efficiency established as part of the initial compliance demonstration specified in § 63.1325(c)(2).</P> <P>(ii) For aggregate batch vent streams using a control device to comply with § 63.1322(b)(2), the established level shall reflect the control efficiency requirement specified in § 63.1322(b)(2).</P> <P>(iii) For batch process vents and aggregate batch vent streams using a control device to comply with § 63.1322(a)(3), the established level shall reflect the control efficiency established as part of the initial compliance demonstration specified in § 63.1325(f)(4).</P> <P>(2) The established level, along with supporting documentation, shall be submitted in the Notification of Compliance Status or the operating permit application as required in § 63.1335(e)(5) or § 63.1335(e)(8), respectively.</P> <P>(3) The operating day shall be defined as part of establishing the parameter monitoring level and shall be submitted with the information in paragraph (f)(2) of this section. The definition of operating day shall specify the times at which an operating day begins and ends. The operating day shall not exceed 24 hours.</P> <P>(4) For continuous process vents using a control or recovery device to comply with § 63.1322(a)(3), the established level shall reflect the control efficiency established as part of the initial compliance demonstration specified in § 63.1325(f)(4).</P> </SECTION> <SECTION> <SECTNO>§ 63.1325</SECTNO> <SUBJECT>Batch process vents—performance test methods and procedures to determine compliance.</SUBJECT> <P>(a) <E T="03">Use of a flare.</E> When a flare is used to comply with §§ 63.1322 (a)(1), (a)(3), (b)(1), or (b)(3), the owner or operator shall comply with the flare provisions in § 63.11(b).</P> <P>(b) <E T="03">Exceptions to performance tests.</E> An owner or operator is not required to conduct a performance test when a control device specified in paragraphs (b)(1) through (b)(5) of this section is used to comply with § 63.1322 (a)(2) or (a)(3). Further, if a performance test meeting the conditions specified in paragraph (b)(6) of this section has been conducted by the owner or operator, the results of said performance test may be submitted and a performance test, as required by this section, is not required.</P> <P>(1) A boiler or process heater with a design heat input capacity of 44 megawatts or greater.</P> <P>(2) A boiler or process heater where the vent stream is introduced with the primary fuel or is used as the primary fuel.</P> <P>(3) A control device for which a performance test was conducted for determining compliance with a New Source Performance Standard (NSPS) and the test was conducted using the same procedures specified in this section and no process changes have been made since the test. Recovery devices used for controlling emissions from continuous process vents complying with § 63.1322(a)(3) are also eligible for the exemption described in this paragraph (b)(3).</P> <P>(4) A boiler or process heater burning hazardous waste for which the owner or operator:</P> <P>(i) Has been issued a final permit under 40 CFR part 270 and complies with the requirements of 40 CFR part 266, subpart H; or<PRTPAGE P="215"/> </P> <P>(ii) Has certified compliance with the interim status requirements of 40 CFR part 266, subpart H.</P> <P>(5) An incinerator burning hazardous waste for which the owner or operator complies with the requirements of 40 CFR part 264, subpart O.</P> <P>(6) Performance tests done for other subparts in 40 CFR part 60 or part 63 where total organic HAP or TOC was measured, provided the owner or operator can demonstrate that operating conditions for the process and control device during the performance test are representative of current operating conditions.</P> <P>(c) <E T="03">Batch process vent testing and procedures for compliance with § 63.1322(a)(2).</E> Except as provided in paragraph (b) of this section, an owner or operator using a control device to comply with § 63.1322(a)(2) shall conduct a performance test using the procedures specified in paragraph (c)(1) of this section in order to determine the control efficiency of the control device. An owner or operator shall determine the percent reduction for the batch cycle using the control efficiency of the control device as specified in paragraphs (c)(2)(i) through (c)(2)(iii) of this section and the procedures specified in paragraph (c)(2) of this section. Compliance may be based on either total organic HAP or TOC. For purposes of this paragraph (c) and all paragraphs that are part of this paragraph (c), the term “batch emission episode” shall have the meaning “period of the batch emission episode selected for control,” which may be the entire batch emission episode or may only be a portion of the batch emission episode.</P> <P>(1) Performance tests shall be conducted as specified in paragraphs (c)(1)(i) through (c)(1)(v) of this section.</P> <P>(i) Except as specified in paragraph (c)(1)(i)(A) of this section, a test shall be performed for the entire period of each batch emission episode in the batch cycle that the owner or operator selects to control as part of achieving the required 90 percent emission reduction for the batch cycle specified in § 63.1322(a)(2). Only one test is required for each batch emission episode selected by the owner or operator for control. The owner or operator shall follow the procedures listed in paragraphs (c)(1)(i)(B) through (c)(1)(i)(D) of this section.</P> <P>(A) Alternatively, an owner or operator may choose to test only those periods of the batch emission episode during which the emission rate for the entire episode can be determined or during which the emissions are greater than the average emission rate of the batch emission episode. The owner or operator choosing either of these options must develop an emission profile for the entire batch emission episode, based on either process knowledge or test data collected, to demonstrate that test periods are representative. Examples of information that could constitute process knowledge include calculations based on material balances and process stoichiometry. Previous test results may be used provided the results are still relevant to the current batch process vent conditions.</P> <P>(B) Method 1 or 1A, 40 CFR part 60, appendix A, as appropriate, shall be used for selection of the sampling sites if the flow measuring device is a pitot tube. No traverse is necessary when Method 2A or 2D, 40 CFR part 60, appendix A is used to determine gas stream volumetric flow rate. Inlet sampling sites shall be located as specified in paragraphs (c)(1)(i)(B)(<E T="03">1</E>) and (c)(1)(i)(B)(<E T="03">2</E>) of this section. Outlet sampling sites shall be located at the outlet of the control device prior to release to the atmosphere.</P> <P>(<E T="03">1</E>) The control device inlet sampling site shall be located at the exit from the batch unit operation before any control device. § 63.1323(a)(2) describes those recovery devices considered part of the unit operation. Inlet sampling sites would be after these specified recovery devices.</P> <P>(<E T="03">2</E>) If a batch process vent is introduced with the combustion air or as a secondary fuel into a boiler or process heater with a design capacity less than 44 megawatts, selection of the location of the inlet sampling sites shall ensure the measurement of total organic HAP or TOC (minus methane and ethane) concentrations in all batch process vents and primary and secondary fuels introduced into the boiler or process heater.<PRTPAGE P="216"/> </P> <P>(C) Gas stream volumetric flow rate and/or average flow rate shall be determined as specified in § 63.1323(e).</P> <P>(D) Method 18 or Method 25A, 40 CFR part 60, appendix A shall be used to determine the concentration of organic HAP or TOC, as appropriate. Alternatively, any other method or data that has been validated according to the applicable procedures in Method 301 of appendix A of this part may be used. The use of Method 25A, 40 CFR part 60, appendix A shall comply with paragraphs (c)(1)(i)(D)(<E T="03">1</E>) and (c)(1)(i)(D)(<E T="03">2</E>) of this section.</P> <P>(<E T="03">1</E>) The organic HAP used as the calibration gas for Method 25A, 40 CFR part 60, appendix A shall be the single organic HAP representing the largest percent by volume of the emissions.</P> <P>(<E T="03">2</E>) The use of Method 25A, 40 CFR part 60, appendix A is acceptable if the response from the high-level calibration gas is at least 20 times the standard deviation of the response from the zero calibration gas when the instrument is zeroed on the most sensitive scale.</P> <P>(ii) If an integrated sample is taken over the entire test period to determine TOC or average total organic HAP concentration, emissions per batch emission episode shall be calculated using Equations 19 and 20 of this subpart.</P> <GPH DEEP="37" SPAN="2"> <GID>ER12SE96.018</GID> </GPH> <P/> <GPH DEEP="37" SPAN="2"> <GID>ER12SE96.019</GID> </GPH> <FP>where:</FP> <FP SOURCE="FP-2">E<E T="52">episode</E> = Inlet or outlet emissions, kg/episode.</FP> <FP SOURCE="FP-2">K = Constant, 2.494 x 10<E T="51">−6</E> (ppmv)<E T="51">−1</E> (gm-mole/scm) (kg/gm) (min/hr), where standard temperature is 20°C.</FP> <FP SOURCE="FP-2">C<E T="52">j</E> = Average inlet or outlet concentration of TOC or sample component j of the gas stream for the batch emission episode, dry basis, ppmv.</FP> <FP SOURCE="FP-2">M<E T="52">j</E> = Molecular weight of TOC or sample component j of the gas stream, gm/gm-mole.</FP> <FP SOURCE="FP-2">AFR = Average inlet or outlet flow rate of gas stream for the batch emission episode, dry basis, scmm.</FP> <FP SOURCE="FP-2">T<E T="52">h</E> = Hours/episode</FP> <FP SOURCE="FP-2">n = Number of organic HAP in stream.</FP> <NOTE> <HD SOURCE="HED">Note:</HD> <P>Summation not required if TOC emissions are being estimated using a TOC concentration measured using Method 25A, 40 CFR part 60, appendix A.</P> </NOTE> <P>(iii) If grab samples are taken to determine TOC or total organic HAP concentration, emissions shall be calculated according to paragraphs (c)(1)(iii) (A) and (B) of this section.</P> <P>(A) For each measurement point, the emission rates shall be calculated using Equations 21 and 22 of this subpart.</P> <GPH DEEP="37" SPAN="2"> <PRTPAGE P="217"/> <GID>ER12SE96.020</GID> </GPH> <P/> <GPH DEEP="37" SPAN="2"> <GID>ER12SE96.021</GID> </GPH> <FP>where:</FP> <FP SOURCE="FP-2">E<E T="52">point</E> = Inlet or outlet emission rate for the measurement point, kg/hr.</FP> <FP SOURCE="FP-2">K = Constant, 2.494 x 10<E T="51">−6</E> (ppmv)<E T="51">−1</E> (gm-mole/scm) (kg/gm) (min/hr), where standard temperature is 20°C.</FP> <FP SOURCE="FP-2">C<E T="52">j</E> = Inlet or outlet concentration of TOC or sample organic HAP component j of the gas stream, dry basis, ppmv.</FP> <FP SOURCE="FP-2">M<E T="52">j</E> = Molecular weight of TOC or sample organic HAP component j of the gas stream, gm/gm-mole.</FP> <FP SOURCE="FP-2">FR = Inlet or outlet flow rate of gas stream for the measurement point, dry basis, scmm.</FP> <FP SOURCE="FP-2">n = Number of organic HAP in stream.</FP> <NOTE> <HD SOURCE="HED">Note:</HD> <P>Summation not required if TOC emissions are being estimated using a TOC concentration measured using Method 25A, 40 CFR part 60, appendix A.</P> </NOTE> <P>(B) The emissions per batch emission episode shall be calculated using Equations 23 and 24 of this subpart.</P> <GPH DEEP="35" SPAN="2"> <GID>ER12SE96.022</GID> </GPH> <P/> <GPH DEEP="35" SPAN="2"> <GID>ER12SE96.023</GID> </GPH> <FP>where:</FP> <FP SOURCE="FP-2">E<E T="52">episode</E> = Inlet or outlet emissions, kg/episode.</FP> <FP SOURCE="FP-2">DUR = Duration of the batch emission episode, hr/episode.</FP> <FP SOURCE="FP-2">E<E T="52">point,i</E> = Inlet or outlet emissions for measurement point i, kg/hr.</FP> <FP SOURCE="FP-2">n = Number of measurements.</FP> <P>(iv) The control efficiency for the control device shall be calculated using Equation 25 of this subpart.</P> <GPH DEEP="62" SPAN="2"> <PRTPAGE P="218"/> <GID>ER12SE96.024</GID> </GPH> <FP>where:</FP> <FP SOURCE="FP-2">R = Control efficiency of control device, percent.</FP> <FP SOURCE="FP-2">E<E T="52">inlet</E> = Mass rate of TOC or total organic HAP for batch emission episode i at the inlet to the control device as calculated under paragraph (c)(1)(ii) or (c)(1)(iii) of this section, kg/hr.</FP> <FP SOURCE="FP-2">E<E T="52">outlet</E> = Mass rate of TOC or total organic HAP for batch emission episode i at the outlet of the control device, as calculated under paragraph (c)(1)(ii) or (c)(1)(iii) of this section, kg/hr.</FP> <FP SOURCE="FP-2">n = Number of batch emission episodes in the batch cycle selected to be controlled.</FP> <P>(v) If the batch process vent entering a boiler or process heater with a design capacity less than 44 megawatts is introduced with the combustion air or as a secondary fuel, the weight-percent reduction of total organic HAP or TOC across the device shall be determined by comparing the TOC or total organic HAP in all combusted batch process vents and primary and secondary fuels with the TOC or total organic HAP exiting the combustion device, respectively.</P> <P>(2) The percent reduction for the batch cycle shall be determined using Equation 26 of this subpart and the control device efficiencies specified in paragraphs (c)(2)(i) through (c)(2)(iii) of this section. All information used to calculate the batch cycle percent reduction, including a definition of the batch cycle identifying all batch emission episodes, must be recorded as specified in § 63.1326(b)(2). This information shall include identification of those batch emission episodes, or portions thereof, selected for control.</P> <GPH DEEP="62" SPAN="2"> <GID>ER12SE96.025</GID> </GPH> <FP>where:</FP> <FP SOURCE="FP-2">PR = Percent reduction</FP> <FP SOURCE="FP-2">E<E T="52">unc</E> = Mass rate of TOC or total organic HAP for uncontrolled batch emission episode i, kg/hr.</FP> <FP SOURCE="FP-2">E<E T="52">inlet,con</E> = Mass rate of TOC or total organic HAP for controlled batch emission episode i at the inlet to the control device, kg/hr.</FP> <FP SOURCE="FP-2">R = Control efficiency of control device as specified in paragraphs (c)(2) (i) through (c) (2)(iii) of this section.</FP> <FP SOURCE="FP-2">n = Number of uncontrolled batch emission episodes, controlled batch emission episodes, and control devices. The value of n is not necessarily the same for these three items.</FP> <P>(i) If a performance test is required by paragraph (c) of this section, the control efficiency of the control device shall be as determined in paragraph (c)(1)(iv) of this section.</P> <P>(ii) If a performance test is not required by paragraph (c) of this section for a combustion control device, as specified in paragraph (b) of this section, the control efficiency shall be 98 <PRTPAGE P="219"/>percent. The control efficiency for a flare shall be 98 percent.</P> <P>(iii) If a performance test is not required by paragraph (c) of this section for a noncombustion control device, the control efficiency shall be determined by the owner or operator based on engineering assessment.</P> <P>(d) <E T="03">Batch process vent and aggregate batch vent stream testing for compliance with § 63.1322(c) [halogenated emission streams].</E> An owner or operator controlling halogenated emissions in compliance with § 63.1322(c) shall conduct a performance test to determine compliance with the control efficiency specified in § 63.1322(c)(1) or the emission limit specified in § 63.1322(c)(2) for hydrogen halides and halogens.</P> <P>(1) Sampling sites shall be located at the inlet and outlet of the scrubber or other control device used to reduce halogen emissions in complying with § 63.1322(c)(1) or at the outlet of the control device used to reduce halogen emissions in complying with § 63.1322(c)(2).</P> <P>(2) The mass emissions of each hydrogen halide and halogen compound for the batch cycle or aggregate batch vent stream shall be calculated from the measured concentrations and the gas stream flow rate(s) determined by the procedures specified in paragraphs (d)(2)(i) and (d)(2)(ii) of this section except as specified in paragraph (d)(5) of this section.</P> <P>(i) Method 26 or Method 26A, 40 CFR part 60, appendix A, shall be used to determine the concentration, in Mg per dry scm, of total hydrogen halides and halogens present in the emissions stream.</P> <P>(ii) Gas stream volumetric flow rate and/or average flow rate shall be determined as specified in § 63.1323(e).</P> <P>(3) To determine compliance with the percent reduction specified in § 63.1322(c)(1), the mass emissions for any hydrogen halides and halogens present at the inlet of the scrubber or other control device shall be summed together. The mass emissions of any hydrogen halides or halogens present at the outlet of the scrubber or other control device shall be summed together. Percent reduction shall be determined by subtracting the outlet mass emissions from the inlet mass emissions and then dividing the result by the inlet mass emissions.</P> <P>(4) To determine compliance with the emission limit specified in § 63.1322(c)(2), the annual mass emissions for any hydrogen halides and halogens present at the outlet of the control device and prior to any combustion device shall be summed together and compared to the emission limit specified in § 63.1322(c)(2).</P> <P>(5) The owner or operator may use any other method to demonstrate compliance if the method or data has been validated according to the applicable procedures of Method 301 of appendix A of this part.</P> <P>(e) <E T="03">Aggregate batch vent stream testing for compliance with § 63.1322(b)(2) or (b)(3).</E> Except as specified in paragraphs (e)(1) through (e)(3) of this section, owners or operators of aggregate batch vent streams complying with § 63.1322(b)(2) or (b)(3) shall conduct a performance test using the performance testing procedures for continuous process vents in § 63.116(c).</P> <P>(1) The organic HAP used as the calibration gas for Method 25A, 40 CFR part 60, appendix A, shall be the single organic HAP representing the largest percent by volume of the emissions.</P> <P>(2) The use of Method 25A, 40 CFR part 60, appendix A, is acceptable if the response from the high-level calibration gas is at least 20 times the standard deviation of the response from the zero calibration gas when the instrument is zeroed on the most sensitive scale.</P> <P>(3) When a combustion device is used to comply with the 20 parts per million by volume outlet concentration standard specified in § 63.1322(b)(2), the correction to 3 percent oxygen specified in the performance testing procedures of § 63.116(c)(3) and § 63.116(c)(3)(iii) is only required when supplemental combustion air is used to combust the emissions, for the purposes of this subpart.</P> <P>(f) <E T="03">Compliance with § 63.1322(a)(3) [new SAN batch affected sources].</E> Except as provided in paragraph (b) of this section, an owner or operator using a control or recovery device to comply with the percent reduction requirement in <PRTPAGE P="220"/>§ 63.1322(a)(3) shall conduct performance tests as specified in either paragraph (f)(1), (f)(2), or (f)(3) of this section, as applicable. Compliance with § 63.1322(a)(3) shall be determined as specified in paragraph (f)(4) of this section.</P> <P>(1) For batch process vents, performance tests shall be conducted using the procedures specified in paragraph (c) of this section, except that the owner or operator is not required to determine the percent reduction for the batch cycle as specified in paragraph (c)(2) of this section.</P> <P>(2) For continuous pr