[Title 40 CFR 60.50Da]
[Code of Federal Regulations (annual edition) - July 1, 2009 Edition]
[Title 40 - PROTECTION OF ENVIRONMENT]
[Chapter I - ENVIRONMENTAL PROTECTION AGENCY (CONTINUED)]
[Subchapter C - AIR PROGRAMS (CONTINUED)]
[Part 60 - STANDARDS OF PERFORMANCE FOR NEW STATIONARY SOURCES--]
[Subpart Da - Standards of Performance for Electric Utility Steam]
[Sec. 60.50da - Compliance determination procedures and methods.]
[From the U.S. Government Printing Office]
40PROTECTION OF ENVIRONMENT62009-07-012009-07-01falseCompliance determination procedures and methods.60.50DaSec. 60.50DaPROTECTION OF ENVIRONMENTENVIRONMENTAL PROTECTION AGENCY (CONTINUED)AIR PROGRAMS (CONTINUED)STANDARDS OF PERFORMANCE FOR NEW STATIONARY SOURCES--Standards of Performance for Electric Utility Steam
Sec. 60.50Da Compliance determination procedures and methods.
(a) In conducting the performance tests required in Sec. 60.8, the
owner or operator shall use as reference methods and procedures the
methods in appendix A of this part or the methods and procedures as
specified in this section, except as provided in Sec. 60.8(b). Section
60.8(f) does not apply to this section for SO2 and
NOX. Acceptable alternative methods are given in paragraph
(e) of this section.
(b) The owner or operator shall determine compliance with the PM
standards in Sec. 60.42Da as follows:
(1) The dry basis F factor (O2) procedures in Method 19
of appendix A of this part shall be used to compute the emission rate of
PM.
(2) For the particular matter concentration, Method 5 of appendix A
of this part shall be used at affected facilities without wet FGD
systems and Method 5B of appendix A of this part shall be used after wet
FGD systems.
(i) The sampling time and sample volume for each run shall be at
least 120 minutes and 1.70 dscm (60 dscf). The probe and filter holder
heating system in the sampling train may be set to provide an average
gas temperature of no greater than 16014 [deg]C
(32025 [deg]F).
(ii) For each particulate run, the emission rate correction factor,
integrated or grab sampling and analysis procedures of Method 3B of
appendix A of this part shall be used to determine the O2
concentration. The O2 sample shall be obtained simultaneously
with, and at the same traverse points as, the particulate run. If the
particulate run has more than 12 traverse points, the O2
traverse points may be reduced to 12 provided that Method 1 of appendix
A of this part is used to locate the 12 O2 traverse points.
If the grab sampling procedure is used, the O2 concentration
for the run shall be the arithmetic mean of the sample O2
concentrations at all traverse points.
(3) Method 9 of appendix A of this part and the procedures in Sec.
60.11 shall be used to determine opacity.
(c) The owner or operator shall determine compliance with the
SO2 standards in Sec. 60.43Da as follows:
(1) The percent of potential SO2 emissions (%Ps) to the
atmosphere shall be computed using the following equation:
[GRAPHIC] [TIFF OMITTED] TR13JN07.015
Where:
%Ps = Percent of potential SO2 emissions, percent;
%Rf = Percent reduction from fuel pretreatment, percent; and
%Rg = Percent reduction by SO2 control system, percent.
(2) The procedures in Method 19 of appendix A of this part may be
used to determine percent reduction (%Rf) of sulfur by such
processes as fuel pretreatment (physical coal cleaning,
hydrodesulfurization of fuel oil, etc.), coal pulverizers, and bottom
and fly ash interactions. This determination is optional.
(3) The procedures in Method 19 of appendix A of this part shall be
used to determine the percent SO2 reduction (%Rg)
of any SO2 control system. Alternatively, a combination of an
``as fired'' fuel monitor and emission rates measured after the control
system, following the procedures in Method 19 of
[[Page 180]]
appendix A of this part, may be used if the percent reduction is
calculated using the average emission rate from the SO2
control device and the average SO2 input rate from the ``as
fired'' fuel analysis for 30 successive boiler operating days.
(4) The appropriate procedures in Method 19 of appendix A of this
part shall be used to determine the emission rate.
(5) The CEMS in Sec. 60.49Da(b) and (d) shall be used to determine
the concentrations of SO2 and CO2 or
O2.
(d) The owner or operator shall determine compliance with the
NOX standard in Sec. 60.44Da as follows:
(1) The appropriate procedures in Method 19 of appendix A of this
part shall be used to determine the emission rate of NOX.
(2) The continuous monitoring system in Sec. 60.49Da(c) and (d)
shall be used to determine the concentrations of NOX and
CO2 or O2.
(e) The owner or operator may use the following as alternatives to
the reference methods and procedures specified in this section:
(1) For Method 5 or 5B of appendix A-3 of this part, Method 17 of
appendix A-6 of this part may be used at facilities with or without wet
FGD systems if the stack temperature at the sampling location does not
exceed an average temperature of 160 [deg]C (320 [deg]F). The procedures
of sections 8.1 and 11.1 of Method 5B of appendix A-3 of this part may
be used in Method 17 of appendix A-6 of this part only if it is used
after wet FGD systems. Method 17 of appendix A-6 of this part shall not
be used after wet FGD systems if the effluent is saturated or laden with
water droplets.
(2) The Fc factor (CO2) procedures in Method
19 of appendix A of this part may be used to compute the emission rate
of PM under the stipulations of Sec. 60.46(d)(1). The CO2
shall be determined in the same manner as the O2
concentration.
(f) Electric utility combined cycle gas turbines that are not
designed to burn fuels containing 50 percent (by heat input) or more
solid derived fuel not meeting the definition of natural gas are
performance tested for PM, SO2, and NOX using the
procedures of Method 19 of appendix A-7 of this part. The SO2
and NOX emission rates calculations from the gas turbine used
in Method 19 of appendix A-7 of this part are determined when the gas
turbine is performance tested under subpart GG of this part. The
potential uncontrolled PM emission rate from a gas turbine is defined as
17 ng/J (0.04 lb/MMBtu) heat input.
(g) For the purposes of determining compliance with the emission
limits in Sec. 60.45Da, the owner or operator of an electric utility
steam generating unit which is also a cogeneration unit shall use the
procedures in paragraphs (g)(1) and (2) of this section to calculate
emission rates based on electrical output to the grid plus 75 percent of
the equivalent electrical energy (measured relative to ISO conditions)
in the unit's process stream.
(1) All conversions from Btu/hr unit input to MW unit output must
use equivalents found in 40 CFR 60.40(a)(1) for electric utilities
(i.e., 250 MMBtu/hr input to an electric utility steam generating unit
is equivalent to 73 MW input to the electric utility steam generating
unit); 73 MW input to the electric utility steam generating unit is
equivalent to 25 MW output from the boiler electric utility steam
generating unit; therefore, 250 MMBtu input to the electric utility
steam generating unit is equivalent to 25 MW output from the electric
utility steam generating unit).
(2) Use the Equation 5 in this section to determine the cogeneration
Hg emission rate over a specific compliance period.
[GRAPHIC] [TIFF OMITTED] TR13JN07.016
[[Page 181]]
Where:
ERcogen = Cogeneration Hg emission rate over a compliance
period in lb/MWh;
E = Mass of Hg emitted from the stack over the same compliance period
(lb);
Vgrid = Amount of energy sent to the grid over the same
compliance period (MWh); and
Vprocess = Amount of energy converted to steam for process
use over the same compliance period (MWh).
(h) The owner or operator shall determine compliance with the Hg
limit in Sec. 60.45Da according to the procedures in paragraphs (h)(1)
through (3) of this section.
(1) The initial performance test shall be commenced by the
applicable date specified in Sec. 60.8(a). The required CEMS must be
certified prior to commencing the test. The performance test consists of
collecting hourly Hg emission data (lb/MWh) with the CEMS for 12
successive months of unit operation (excluding hours of unit startup,
shutdown and malfunction). The average Hg emission rate is calculated
for each month, and then the weighted, 12-month average Hg emission rate
is calculated according to paragraph (h)(2) or (h)(3) of this section,
as applicable. If, for any month in the initial performance test, the
minimum data capture requirement in Sec. 60.49Da(p)(4)(i) is not met,
the owner or operator shall report a substitute Hg emission rate for
that month, as follows. For the first such month, the substitute monthly
Hg emission rate shall be the arithmetic average of all valid hourly Hg
emission rates recorded to date. For any subsequent month(s) with
insufficient data capture, the substitute monthly Hg emission rate shall
be the highest valid hourly Hg emission rate recorded to date. When the
12-month average Hg emission rate for the initial performance test is
calculated, for each month in which there was insufficient data capture,
the substitute monthly Hg emission rate shall be weighted according to
the number of unit operating hours in that month. Following the initial
performance test, the owner or operator shall demonstrate compliance by
calculating the weighted average of all monthly Hg emission rates (in
lb/MWh) for each 12 successive calendar months, excluding data obtained
during startup, shutdown, or malfunction.
(2) If a CEMS is used to demonstrate compliance, follow the
procedures in paragraphs (h)(2)(i) through (iii) of this section to
determine the 12-month rolling average.
(i) Calculate the total mass of Hg emissions over a month (M), in
lb, using either Equation 6 in paragraph (h)(2)(i)(A) of this section or
Equation 7 in paragraph (h)(2)(i)(B) of this section, in conjunction
with Equation 8 in paragraph (h)(2)(i)(C) of this section.
(A) If the Hg CEMS measures Hg concentration on a wet basis, use
Equation 6 below to calculate the Hg mass emissions for each valid hour:
[GRAPHIC] [TIFF OMITTED] TR13JN07.017
Where:
Eh = Hg mass emissions for the hour, (lb);
K = Units conversion constant, 6.24 x 10-\11\ lb-scm/
[micro]gm-scf;
Ch = Hourly Hg concentration, wet basis,
([micro]gm/scm);
Qh = Hourly stack gas volumetric flow rate, (scfh); and
th = Unit operating time, i.e., the fraction of the hour for
which the unit operated. For example, th = 0.50 for a half-hour of unit
operation and 1.00 for a full hour of operation.
(B) If the Hg CEMS measures Hg concentration on a dry basis, use
Equation 7 below to calculate the Hg mass emissions for each valid hour:
[GRAPHIC] [TIFF OMITTED] TR13JN07.018
Where:
Eh = Hg mass emissions for the hour, (lb);
K = Units conversion constant, 6.24 x 10-11 lb-scm/[micro]gm-
scf;
Ch = Hourly Hg concentration, dry basis, ([micro]gm/dscm);
Qh = Hourly stack gas volumetric flow rate, (scfh);
th = Unit operating time, i.e., the fraction of the hour for
which the unit operated; and
Bws = Stack gas moisture content, expressed as a decimal
fraction (e.g., for 8 percent H2O, Bws = 0.08).
(C) Use Equation 8, below, to calculate M, the total mass of Hg
emitted for the month, by summing the hourly masses derived from
Equation 6 or 7 (as applicable):
[[Page 182]]
[GRAPHIC] [TIFF OMITTED] TR13JN07.019
Where:
M = Total Hg mass emissions for the month, (lb);
Eh = Hg mass emissions for hour ``h'', from Equation 6 or 7
of this section, (lb); and
n = Number of unit operating hours in the month with valid CE and
electrical output data, excluding hours of unit startup, shutdown and
malfunction.
(ii) Calculate the monthly Hg emission rate on an output basis (lb/
MWh) using Equation 9, below. For a cogeneration unit, use Equation 5 in
paragraph (g) of this section instead.
[GRAPHIC] [TIFF OMITTED] TR13JN07.020
Where:
ER = Monthly Hg emission rate, (lb/MWh);
M = Total mass of Hg emissions for the month, from Equation 8, above,
(lb); and
P = Total electrical output for the month, for the hours used to
calculate M, (MWh).
(iii) Until 12 monthly Hg emission rates have been accumulated,
calculate and report only the monthly averages. Then, for each
subsequent calendar month, use Equation 10 below to calculate the 12-
month rolling average as a weighted average of the Hg emission rate for
the current month and the Hg emission rates for the previous 11 months,
with one exception. Calendar months in which the unit does not operate
(zero unit operating hours) shall not be included in the 12-month
rolling average.
[GRAPHIC] [TIFF OMITTED] TR13JN07.021
Where:
Eavg = Weighted 12-month rolling average Hg emission rate,
(lb/MWh);
ERi = Monthly Hg emission rate, for month ``i'', (lb/MWh);
and
n = Number of unit operating hours in month ``i'' with valid CEM and
electrical output data, excluding hours of unit startup, shutdown, and
malfunction.
(3) If a sorbent trap monitoring system is used in lieu of a Hg
CEMS, as described in Sec. 75.15 of this chapter and in appendix K to
part 75 of this chapter, calculate the monthly Hg emission rates using
Equations 7 through 9 of this section, except that for a particular pair
of sorbent traps, Ch in Equation 7 shall be the flow-
proportional average Hg concentration measured over the data collection
period.
(i) Daily calibration drift (CD) tests and quarterly accuracy
determinations shall be performed for Hg CEMS in accordance with
Procedure 1 of appendix F to this part. For the CD assessments, you may
use either elemental mercury or mercuric chloride (Hg[deg]
HgCl2) standards. The four quarterly accuracy determinations
shall consist of one RATA and three measurement error (ME) tests using
HgCl2 standards, as described in section 8.3 of Performance
Specification 12-A in appendix B to this part (note: Hg[deg] standards
may be used if the Hg monitor does not have a converter). Alternatively,
the owner or operator may implement the applicable daily, weekly,
quarterly, and annual quality assurance (QA) requirements for Hg CEMS in
appendix B to part 75 of this chapter, in lieu of the QA procedures in
appendices B and F to this part. Annual RATA of sorbent trap monitoring
systems shall be performed in accordance with appendices A and B to part
75 of this chapter, and all other quality assurance requirements
specified in appendix K to part 75 of this chapter shall be met for
sorbent trap monitoring systems.
[72 FR 32722, June 13, 2007, as amended at 74 FR 5083, Jan. 28, 2009]