[Federal Register Volume 77, Number 23 (Friday, February 3, 2012)]
From the Federal Register Online via the Government Publishing Office [www.gpo.gov]
[FR Doc No: 2012-2442]
ENVIRONMENTAL PROTECTION AGENCY
Mandatory Reporting of Greenhouse Gases: Notice of Preliminary
Determinations Regarding Requests To Use Provisional Global Warming
Potentials Under the Fluorinated Gas Production Category of the
Greenhouse Gas Reporting Rule
AGENCY: Environmental Protection Agency (EPA).
ACTION: Notice of data availability and request for comment.
SUMMARY: The EPA is announcing and explaining to the public its
preliminary determinations regarding requests to use provisional global
warming potentials for eight fluorinated greenhouse gases submitted by
DuPont de Nemours, Inc. and Honeywell International for purposes of
certain calculations in the Fluorinated Gas Production portion of the
Mandatory Greenhouse Gas Reporting Rule. EPA's preliminary
determination is that the requests for seven of the eight fluorinated
GHGs meet the requirements of the rule.
DATES: Comments must be received on or before February 21, 2012.
ADDRESSES: Submit your comments, identified by Docket ID No. EPA-HQ-
OAR-2009-0927, by one of the following methods:
Federal eRulemaking Portal: http://www.regulations.gov:
Follow the online instructions for submitting comments.
Email: [email protected].
Fax: (202) 566-1741.
Mail: EPA Docket Center, Attention Docket OAR-2009-0927,
Mail code: 2822T, 1200 Pennsylvania Avenue NW., Washington, DC 20460.
Hand Delivery: EPA Docket Center, Public Reading Room,
Room 3334, EPA West Building, Attention Docket EPA-HQ-OAR-2009-0927,
1301 Constitution Avenue NW., Washington, DC 20004. Such deliveries are
only accepted during the Docket's normal hours of operation, and
special arrangements should be made for deliveries of boxed
Instructions: Direct your comments to Docket ID No. EPA-HQ-OAR-
2009-0927. EPA's policy is that all comments received will be included
in the public docket without change and may be made available online at
http://www.regulations.gov, including any personal information
provided, unless the comment includes information claimed to be
Confidential Business Information (CBI) or other information whose
disclosure is restricted by statute. Do not submit information that you
consider to be CBI or otherwise protected through http://www.regulations.gov. The http://www.regulations.gov. Web site is an
``anonymous access'' system, which means EPA will not know your
identity or contact information unless you provide it in the body of
your comment. If you send an email comment directly to EPA without
going through http://www.regulations.gov your email address will be
automatically captured and included as part of the comment that is
placed in the public docket and made available on the Internet. If you
submit an electronic comment, EPA recommends that you include your name
and other contact information in the body of your comment and with any
disk or CD-ROM you submit. If EPA cannot read your comment due to
technical difficulties and cannot contact you for clarification, EPA
may not be able to consider your comment. Electronic files should avoid
the use of special characters, any form of encryption, and be free of
any defects or viruses.
Docket: All documents in the docket are listed in the http://www.regulations.gov index. Although listed in the index, some
information is not publicly available, e.g., CBI or other information
whose disclosure is restricted by statute. Certain other material, such
as copyrighted material, will be publicly available only in hard copy.
Publicly available docket materials are available either electronically
in http://www.regulations.gov or in hard copy at EPA's Docket Center,
Public Reading Room, EPA West Building, Room 3334, 1301 Constitution
Avenue NW., Washington, DC 20004. This Docket Facility is open from
8:30 a.m. to 4:30 p.m., Monday through Friday, excluding legal
holidays. The Docket telephone number for the Public Reading Room is
(202) 566-1744 and the telephone number for the Air Docket is (202)
FOR FURTHER INFORMATION CONTACT: Deborah Ottinger, Climate Change
Division, Office of Atmospheric Programs (MC-6207J), Environmental
Protection Agency, 1200 Pennsylvania Avenue NW., Washington, DC 20460;
telephone number: (202) 343-9149; fax number: (202) 343-2342; email
address: [email protected].
I. General Information
A. Does this notice apply to me?
This notice applies to five facilities considered to be fluorinated
gas production facilities under subpart L (Fluorinated Gas Production)
of the Mandatory Greenhouse Gas Reporting rule (40 CFR part 98). These
facilities are Honeywell International's Buffalo Research Laboratory
and DuPont's Fayetteville, North Carolina; Deepwater, New Jersey;
Washington Works, West Virginia; and Eldorado, Arkansas facilities.
This notice may also be of interest to members of the public with
knowledge of or interest in the estimation of global warming
B. What is this notice about?
This notice announces and explains to the public EPA's preliminary
determinations regarding the provisional global warming potentials
(GWPs) for eight fluorinated greenhouse gases (GHGs) submitted by E.
DuPont de Nemours, Inc. (DuPont) and Honeywell International
(Honeywell) for the purposes of the calculations in 40 CFR 98.123(c)(1)
(a provision of subpart L of the Mandatory Greenhouse Gas Reporting
rule). EPA's preliminary determination is that the requests for seven
of the eight fluorinated GHGs meet the requirements of the rule. As
discussed further below, the calculations in 40 CFR 98.123(c)(1) are
used to determine whether a facility must use stack testing to
establish an emission factor for a continuous process vent. For
continuous process vents that are calculated to emit less than 10,000
metric tons carbon-dioxide equivalent (mtCO2e) annually,
facilities have the option to use engineering calculations rather than
stack testing to establish an emission factor.
C. What information is EPA making available for review and comment?
EPA is making available for review and comment provisional GWPs for
fluorinated GHGs submitted by Dupont and Honeywell for the purposes of
the calculations in 40 CFR 98.123(c)(1). EPA is also making available
to the public the underlying materials in the submitted requests that
were used to estimate the provisional GWPs, and EPA's analysis of those
D. Where can I get more information?
All of the information can be obtained through the Docket and at
http://www.regulations.gov (see ADDRESSES section above for docket
E. Submitting Confidential Business Information (CBI).
Do not submit information you are claiming as CBI to EPA through
http://www.regulations.gov or email. Clearly mark the part of the
information that you claim to be CBI. Information so marked will not be
disclosed except in accordance with procedures set forth in 40 CFR part
2. For CBI information in a disk or CD-ROM that you mail to EPA, mark
the outside of the disk or CD-ROM as CBI and then identify
electronically within the disk or CD-ROM the specific information that
is claimed as CBI. In addition to one complete version of the comment
that includes information claimed as CBI, a copy of the comment that
does not contain the information claimed as CBI must be submitted for
inclusion in the public docket.
Under 40 CFR 98.123(c)(1), fluorinated gas producers that wish to
use 40 CFR 98.123(c) (the Emission Factor Method or Emission
Calculation Factor Method) to estimate emissions from a continuous
process must make a preliminary estimate of the annual carbon dioxide
equivalent (CO2e) emissions of fluorinated GHGs from each
process vent. They are required to do so using the engineering
calculations or assessments specified in the rule. If the preliminary
estimate indicates that a vent emits 10,000 mtCO2e or more
annually, facilities must use stack testing to establish an emission
factor for that vent. If the preliminary estimate indicates that a vent
emits less than 10,000 mtCO2e annually, facilities may use
engineering calculations or assessments to establish an emission
Under 40 CFR 98.123(c)(1)(v), to convert the fluorinated GHG
emissions to CO2e, fluorinated gas producers must use
Equation A-1 of 40 CFR 98.2. For fluorinated GHGs whose GWPs are not
listed in Table A-1 to subpart A of part 98, producers must use a
default GWP of 2,000 unless they submit a request to use other GWPs for
those fluorinated GHGs in that process under 40 CFR 98.123(c)(1)(vi),
and EPA approves that request.
Under 40 CFR 98.123(c)(1)(vi), fluorinated gas producers may submit
a request to use a GWP other than 2,000 for fluorinated GHGs whose GWPs
are not listed in Table A-1 to subpart A if their process vent emits
one or more fluorinated GHGs (1) whose GWPs are not listed in Table A-1
to subpart A, (2) that are emitted in quantities that, with a default
GWP of 2,000, result in total calculated annual emissions equal to or
greater than 10,000 metric tons CO2e for the vent, and (3)
that they believe have GWPs that would result in total calculated
annual emissions less than 10,000 metric tons CO2e.
Under 40 CFR 98.123(c)(1)(vi)(B), EPA reviews each request to
determine whether it is complete, substantiates each of the provisional
GWPs, and demonstrates that the process vents are calculated to emit
less than 10,000 metric tons CO2e of fluorinated GHGs only
when the proposed provisional GWPs, not the default GWP of 2,000, are
used for the fluorinated GHGs for which the provisional GWPs are
requested. If EPA makes a preliminary determination that each of these
criteria is met, EPA publishes a notice for public comment including
the determination and the data and analysis submitted by the producers
under 40 CFR 98.123(c)(1)(vi)(A)(1) through (3).
Under 40 CFR 98.123(c)(1)(vi)(A)(1) through (3), fluorinated gas
producers must include the following information in the request for
each fluorinated GHG that does not have a GWP listed in Table A-1 to
subpart A of part 98 and that constitutes more than one percent by mass
of the stream emitted from the vent:
(1) The identity of the fluorinated GHG, including its chemical
formula and, if available, CAS number.
(2) The estimated GWP of the fluorinated GHG.
(3) The data and analysis that supports the estimate of the GWP of
the fluorinated GHG, including:
(i) Data and analysis related to the low-pressure gas phase
infrared absorption spectrum of the fluorinated GHG.
(ii) Data and analysis related to the estimated atmospheric
lifetime of the fluorinated GHG (reaction mechanisms and rates,
including for example, photolysis and reaction with atmospheric
components such as hydroxyl radicals (OH), ozone (O3),
carbon monoxide (CO), and water).
(iii) The radiative transfer analysis that integrates the lifetime
and infrared absorption spectrum data to calculate the GWP.
(iv) Any published or unpublished studies of the GWP of the gas.
A. Requests to Use Provisional GWPs
On February 25, 2011, Honeywell requested to use provisional GWPs
for two fluorinated GHGs for the purposes of the calculations in
paragraph (c)(1) of 40 CFR 98.123. Honeywell requested to use
provisional (i.e., lower) GWPs for two commercial chemicals produced at
their Buffalo Research Laboratory: HFC-1234ze and HFC-1234yf. Honeywell
included published scientific papers and other information to fulfill
the requirements under paragraphs (c)(1)(vi)(A)(1) through (3) of 40
On February 28, 2011, DuPont requested to use provisional GWPs for
six fluorinated GHGs for the purposes of calculations in 40 CFR
98.123(c)(1). DuPont requested to use provisional (i.e., lower) GWPs
for six chemicals at DuPont plant sites subject to subpart L:
hexafluoropropylene (HFP), perfluoromethyl vinyl ether (PMVE),
tetrafluoroethylene (TFE), 3,3,3-trifluoropropene (TFP), vinyl fluoride
(VF), and vinylidine fluoride (VF2). For each chemical, DuPont included
peer-reviewed scientific data and other information to fulfill the
requirements under paragraphs (c)(1)(vi)(A)(1) through (3).
B. Preliminary Determinations and Their Rationale
In accordance with 40 CFR 98.123(c)(1)(vi)(B), EPA reviewed the
requests from both Honeywell and DuPont to determine whether each was
complete, substantiated each of the provisional GWPs, and demonstrated
that the process vents were calculated to emit less than 10,000 metric
tons CO2e of fluorinated GHGs only when the proposed
provisional GWPs, not the default GWP of 2,000, were used for the
fluorinated GHGs for which the provisional GWPs were requested.
EPA made a preliminary determination that each of these criteria
was met for the requests submitted by both Honeywell and DuPont, with
one exception. The exception was for HFC-1234yf, which was emitted in
quantities that, with a default GWP of 2,000, resulted in total
calculated annual emissions of less than 10,000 mtCO2e.
Because the calculated emissions did not meet the threshold criterion,
EPA is not evaluating the provisional GWP for HFC-1234yf in this
action. EPA notes, however, that the provisional GWP submitted by
Honeywell is the same as the GWP recognized in other EPA final actions
(e.g., March 29, 2011; 76 FR 17488). EPA will consider this information
in future updates to Table A-1 of 40 CFR part 98.
The remainder of this section includes a summary of the
determination and the data and analysis submitted by the producers
under 40 CFR 98.123(c)(1)(vi)(A)(1) through (3).
EPA's preliminary determination included review of the submitted
information by a leading subject matter expert on GWP estimation who
was also a co-developer of the GWP concept. EPA concluded that the
were likely to overestimate GWPs (maybe by an order of magnitude or
more) rather than underestimate them. Because 40 CFR 98.123(c)(1)
allows the use of engineering calculations only when estimated
emissions fall below 10,000 metric tons CO2e, an
overestimated GWP is considered acceptable by EPA in the context of 40
CFR 98.123(c)(1). Therefore, the conclusion of EPA's review was that
the background information was adequate and that it justified the use
of the alternative GWPs in the context of 40 CFR 98.123(c)(1)(vi).
The overestimation of the GWPs submitted by both Honeywell and
DuPont results from the fact that the commonly-used estimation
techniques employed in the analyses cited by both companies use
simplifying assumptions that are not fully applicable to compounds that
are short-lived in the atmosphere--defined here as any compound with an
atmospheric lifetime less than 1 year. (All of the compounds for which
provisional GWPs were requested are short-lived based on this
definition.) Essentially, the estimation techniques assume that the
compounds are well-mixed in the atmosphere, but short-lived compounds
do not last long enough to become well mixed (i.e., spread evenly over
all longitudes, latitudes, and altitudes). Instead, their
concentrations decrease rapidly with distance from their emission
point, particularly with changing latitude and altitude.
The assumption that the compounds are well mixed affects the
estimates of both of the primary components of GWPs: Atmospheric
lifetime and radiative forcing. In the analyses cited by the companies,
atmospheric lifetimes are estimated either by assuming that the short-
lived compound is exposed to the global average concentration of
hydroxyl radicals (OH) or by deriving the lifetime of the short-lived
(i.e., not well mixed) compound from the known lifetime of a long-lived
(i.e., well mixed) reference compound based on the compounds'
respective reaction rates with OH. Both approaches are likely to
overestimate the lifetime (and therefore the GWP) of the short-lived
compound because they essentially assume that the concentration of the
short-lived compound remains constant with altitude. This overestimates
the share of the short-lived compound that resides higher in the
atmosphere, where lower OH concentrations, temperatures, and pressures
slow reaction rates and lengthen lifetimes. Radiative forcing is also
estimated based on the assumption that the concentration of the short-
lived compound remains constant with altitude. This assumption is
likely to overestimate the radiative forcing (and therefore the GWP) of
short-lived compounds because, again, it overestimates the share of the
short-lived compound that resides higher in the atmosphere. GHGs higher
in the atmosphere (i.e., near the tropopause) are responsible for more
radiative forcing than the same GHGs lower in the atmosphere. (As
discussed in the Supporting Analysis, this is related to the fact that
temperatures near the tropopause are lower than those at the surface.)
Together, these assumptions may result in overestimates of the GWP by a
factor of ten or more. The rationale for EPA's preliminary
determination is discussed in more detail in the Supporting Analysis,
which is available in the docket.
The provisional GWPs are shown in Table 1.
Table 1--Provisional Global Warming Potentials for Fluorinated
Greenhouse Gases for Which EPA Has Made Preliminary Determinations That
All Approval Criteria Have Been Met for the Purposes of the Calculations
in 98.123(c)(1) of Subpart L
Fluorinated GHG CAS No. Provisional GWP
HFC-1234ze....................... 29118-24-9 6
Hexafluoropropylene (HFP)........ 116-15-4 0.25
Perfluoromethyl vinyl ether 1187-93-5 3
Tetrafluoroethylene (TFE)........ 116-14-3 0.02
Trifluoro propene (TFP).......... 677-21-4 3
Vinyl fluoride (VF).............. 75-02-5 0.7
Vinylidine fluoride (VF2)........ 75-38-7 0.9
EPA will review public comment on this notice prior to taking final
action on its preliminary determinations. The final determinations will
be placed in the docket for this action.
Dated: January 27, 2012.
Director, Office of Atmospheric Programs.
[FR Doc. 2012-2442 Filed 2-2-12; 8:45 am]
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